R-Group stabilization in methylated formamides observed by resonant inelastic X-ray scattering
- The inherent stability of methylated formamides is traced to a stabilization of the deep-lying sigma-framework by resonant inelastic X-ray scattering at the nitrogen K-edge. Charge transfer from the amide nitrogen to the methyl groups underlie this stabilization mechanism that leaves the aldehyde group essentially unaltered and explains the stability of secondary and tertiary amides.
| Author details: | Miguel OchmannORCiDGND, Vinicius Vaz da CruzORCiD, Sebastian EckertORCiDGND, Nils HuseORCiDGND, Alexander FöhlischORCiDGND |
|---|---|
| DOI: | https://doi.org/10.1039/d2cc00053a |
| ISSN: | 1359-7345 |
| ISSN: | 1364-548X |
| Pubmed ID: | https://pubmed.ncbi.nlm.nih.gov/35848855 |
| Title of parent work (English): | Chemical communications: ChemComm |
| Publisher: | The Royal Society of Chemistry |
| Place of publishing: | Cambridge |
| Publication type: | Article |
| Language: | English |
| Date of first publication: | 2022/06/11 |
| Publication year: | 2022 |
| Release date: | 2024/04/11 |
| Volume: | 58 |
| Issue: | 63 |
| Number of pages: | 4 |
| First page: | 8834 |
| Last Page: | 8837 |
| Funding institution: | ERC-ADG-2014 Advanced Investigator Grant via the Horizon 2020 EU; Framework, Programme for Research and Innovation [669531 EDAX]; Deutsche; Forschungsgemeinschaft (DFG, German Research Foundation) [SFB 925,; 170620586] |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie |
| DDC classification: | 5 Naturwissenschaften und Mathematik / 53 Physik / 530 Physik |
| Peer review: | Referiert |
| Publishing method: | Open Access / Hybrid Open-Access |
| License (English): |  Creative Commons - Namensnennung 3.0 Unported |
