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We demonstrate that tungsten disulphide (WS2) with thicknesses ranging from monolayer (ML) to several monolayers can be grown on SiO2/Si, Si, and Al2O3 by pulsed direct current-sputtering.
The presence of high quality monolayer and multilayered WS2 on the substrates is confirmed by Raman spectroscopy since the peak separations between the A(1g)-E-2g and A(1g)-2LA vibration modes exhibit a gradual increase depending on the number of layers. X-ray diffraction confirms a textured (001) growth of WS2 films.
The surface roughness measured with atomic force microscopy is between 1.5 and 3 angstrom for the ML films. The chemical composition WSx (x = 2.03 +/- 0.05) was determined from X-ray Photoelectron Spectroscopy.
Transmission electron microscopy was performed on a multilayer film to show the 2D layered structure. A unique method for growing 2D layers directly by sputtering opens up the way for designing 2D materials and batch production of high-uniformity and high-quality (stochiometric, large grain sizes, flatness) WS2 films, which will advance their practical applications in various fields.
We consider a one-dimensional Brownian search in the presence of trapping.
The diffusion equation of the particle is represented by a memory kernel that enters the general waiting time probability density function.
We find the general form of the first arrival time density, search reliability and efficiency and analyze several special cases of the memory kernel.
We also analyze the Levy search in the presence of trapping in cases of single and multiple targets, as well as combined Levy-Brownian search strategies in case of a single target.
The presented results are general and could be of interest for further investigation of different optimal search strategies, as well as in the animal foraging or spreading of contamination particles in the environment.
We present a novel method of temporal modulation of X-ray radiation for time resolved experiments. To control the intensity of the X-ray beam, the Bragg reflection of a piezoelectric crystal is modified using comb-shaped electrodes deposited on the crystal surface. Voltage applied to the electrodes induces a periodic deformation of the crystal that acts as a diffraction grating, splitting the original Bragg reflection into several satellites. A pulse of X-rays can be created by rapidly switching the voltage on and off. In our prototype device the duty cycle was limited to similar to 1 ns by the driving electronics. The prototype can be used to generate X-ray pulses from a continuous source. It can also be electrically correlated to a synchrotron light source and be activated to transmit only selected synchrotron pulses. Since the device operates in a non-resonant mode, different activation patterns and pulse durations can be achieved. Published by The Optical Society under the terms of the Creative Commons Attribution 4.0 License.
Based on the multiple barriers concept of deep geological disposal of high-level waste, fractional advection diffusion equations for radionuclide migration in multiple layers low-permeability porous media are proposed in this work. The presented fractional advection diffusion models in terms of different definitions of fractional derivative are analytically addressed via the Laplace integral transform method. This work provides a theoretical foundation for further simulations of radionuclide migration in the multiple barriers system of the high-level waste repository.
The plasmon-driven dimerization of 4-nitrothiophenol (4NTP) to 4-4 '-dimercaptoazobenzene (DMAB) is a testbed for understanding bimolecular photoreactions enhanced by nanoscale metals, in particular, regarding the relevance of electron transfer and heat transfer from the metal to the molecule. By adding a methylene group between the thiol bond and the nitrophenyl, structural flexibility is added to the reactant molecule. Time-resolved surface-enhanced Raman-spectroscopy proves that this (4-nitrobenzyl)mercaptan (4NBM) molecule has a larger dimerization rate and dimerization yield than 4NTP and higher selectivity toward dimerization. X-ray photoelectron spectroscopy and density functional theory calculations show that the electron transfer prefers activation of 4NTP over 4NBM. It is concluded that the rate limiting step of this plasmonic reaction is the dimerization step, which is dramatically enhanced by the additional flexibility of the reactant. This study may serve as an example for using nanoscale metals to simultaneously provide charge carriers for bond activation and localized heat for driving bimolecular reaction steps. The molecular structure of reactants can be tuned to control the reaction kinetics.
Context. Without a doubt, mass transfer in close binary systems contributes to the populations ofWolf-Rayet (WR) stars in the MilkyWay and the Magellanic Clouds. However, the binary formation channel is so far not well explored. Aims. We want to remedy this by exploring large grids of detailed binary and single star evolution models computed with the publicly available MESA code, for a metallicity appropriate for the Large Magellanic Cloud (LMC). Methods. The binary models were calculated through Roche-lobe overflow and mass transfer, until the initially more massive star exhausted helium in its core. We distinguish models of WR and helium stars based on the estimated stellar wind optical depth. We used these models to build a synthetic WR population, assuming constant star formation. Results. Our models can reproduce the WR population of the LMC to significant detail, including the number and luminosity functions of the main WR subtypes. We find that for binary fractions of 100% (50%), all LMC WR stars below 10(6) L-circle dot (10(5.7) L-circle dot) are stripped binary mass donors. We also identify several insightful mismatches. With a single star fraction of 50%, our models produce too many yellow supergiants, calling either for a larger initial binary fraction, or for enhanced mass loss near the Humphreys-Davidson limit. Our models predict more long-period WR binaries than observed, arguably due to an observational bias toward short periods. Our models also underpredict the shortest-period WR binaries, which may have implications for understanding the progenitors of double black hole mergers. Conclusions. The fraction of binary-produced WR stars may be larger than often assumed and outline the risk to miscalibrate stellar physics when only single star models are used to reproduce the observed WR stars.
We present time-series spectroscopy and photometry of Gaia DR2 6097540197980557440, a new deeply eclipsing hot subdwarf B (sdB) + M dwarf (dM) binary. We discovered this object during the course of the Eclipsing Reflection Effect Binaries from Optical Surveys (EREBOS) project, which aims to find new eclipsing sdB+dM binaries (HW Vir systems) and increase the small sample of studied systems. In addition to the primary eclipse, which is in excess of similar to 5 mag in the optical, the light curve also shows features typical for other HW Vir binaries such as a secondary eclipse and strong reflection effect from the irradiated, cool companion. The orbital period is 0.127037 days (similar to 3 hr), falling right at the peak of the orbital period distribution of known HW Vir systems. Analysis of our time-series spectroscopy yields a radial velocity semiamplitude of K (sdB) = 100.0 +/- 2.0 km s(-1), which is among the fastest line-of-sight velocities found to date for an HW Vir binary. State-of-the-art atmospheric models that account for deviations from local thermodynamic equilibrium are used to determine the atmospheric parameters of the sdB. Although we cannot claim a unique light-curve modeling solution, the best-fitting model has an sdB mass of M (sdB) = 0.47 +/- 0.03 M (circle dot) and a companion mass of M (dM) = 0.18 +/- 0.01 M (circle dot). The radius of the companion appears to be inflated relative to theoretical mass-radius relationships, consistent with other known HW Vir binaries. Additionally, the M dwarf is one of the most massive found to date among this type of binary.
Influence of a 265 °C heat treatment on the residual stress state of a PBF-LB/M AlSi10Mg alloy
(2022)
Laser Powder Bed Fusion (PBF-LB/M) additive manufacturing (AM) induces high magnitude residual stress (RS) in structures due to the extremely heterogeneous cooling and heating rates. As the RS can be deleterious to the fatigue resistance of engineering components, great efforts are focused on understanding their generation and evolution after post-process heat treatments.
In this study, one of the few of its kind, the RS relaxation induced in an as-built PBF-LB/M AlSi10Mg material by a low-temperature heat treatment (265 & DEG;C for 1 h) is studied by means of X-ray and neutron diffraction. Since the specimens are manufactured using a baseplate heated up to 200 & DEG;C, low RS are found in the as-built condition.
After heat treatment a redistribution of the RS is observed, while their magnitude remains constant. It is proposed that the redistribution is induced by a repartition of stresses between the alpha-aluminium matrix and the silicon phase, as the morphology of the silicon phase is affected by the heat treatment.
A considerable scatter is observed in the neutron diffraction RS profiles, which is principally correlated to the presence (or absence) of pockets of porosity developed at the borders of the chessboard pattern.
Despite the impressive performance and incredible promise for a variety of applications, the wide-scale commercialization of graphene is still behind its full potential. One of the main challenges is related to preserving graphene's unique properties upon transfer onto practically desirable substrates. In this work, few-layer graphene sheets deposited via liquid-phase transfer from copper onto a quartz substrate have been studied using a suite of experimental techniques, including scanning electron microscopy (SEM), Raman spectroscopy, admittance spectroscopy, and four-point probe electrical measurements. SEM measurements suggest that the transfer of graphene from copper foil to quartz using the aqueous solution of ammonium persulfate was accompanied by unintentional etching of the entire surface of the quartz substrate and, as a result, the formation of microscopic facet structures covering the etched surface of the substrate. As revealed by Raman spectroscopy and the electrical measurements, the transfer process involving the etching of the copper foil in a 0.1 M solution of (NH4)(2)S2O8 resulted in its p-type doping. This was accompanied by the appearance of an electronic gap of 0.022 eV, as evidenced by the Arrhenius analysis. The observed increase in the conductance of the samples with temperature can be explained by thermally activated carrier transport, dominating the scattering processes.
New continuum and polarization observations of the Cygnus Loop with FAST. II. Images and analyses
(2022)
We present total-intensity and polarized-intensity images of the Cygnus Loop supernova remnant (SNR) observed by the Five-hundred-meter Aperture Spherical radio Telescope. The high angular-resolution and high-sensitivity images enable us to thoroughly compare the properties of the northern part with the southern part of the SNR. The central filament in the northern part and the southern part have a similar foreground rotation measure, meaning their distances are likely similar. The polarization analysis indicates that the random magnetic field is larger than the regular field in the northern part, but negligible in the southern part. The total-intensity image is decomposed into components of various angular scales, and the brightness-temperature spectral index of the shell structures in the northern part is similar to that in the southern part in the component images. All the evidence suggests that the northern and southern parts of the Cygnus Loop are situated and thus evolved in different environments of interstellar medium, while belonging to the same SNR.