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Future precipitation levels remain uncertain because climate models have struggled to reproduce observed variations in temperature-precipitation correlations. Our analyses of Holocene proxy-based temperature-precipitation correlations and hydrological sensitivities from 2,237 Northern Hemisphere extratropical pollen records reveal a significant latitudinal dependence and temporal variations among the early, middle, and late Holocene. These proxy-based variations are largely consistent with patterns obtained from transient climate simulations (TraCE21k). While high latitudes and subtropical monsoon areas show mainly stable positive correlations throughout the Holocene, the mid-latitude pattern is temporally and spatially more variable. In particular, we identified a reversal from positive to negative temperature-precipitation correlations in the eastern North American and European mid-latitudes from the early to mid-Holocene that mainly related to slowed down westerlies and a switch to moisture-limited convection under a warm climate. Our palaeoevidence of past temperature-precipitation correlation shifts identifies those regions where simulating past and future precipitation levels might be particularly challenging.
Sustainable electricity systems need renewable and dispatchable energy sources. Solar energy is an abundant source of renewable energy globally which is, though, by nature only available during the day, and especially in clear weather conditions. We compare three technology configurations able to provide dispatchable solar power at times without sunshine: Photovoltaics (PV) combined with battery (BESS) or thermal energy storage (TES) and concentrating solar power (CSP) with TES. Modeling different periods without sunshine, we find that PV+BESS is competitive for shorter storage durations while CSP+TES gains economic advantages for longer storage periods (also over PV+TES). The corresponding tipping points lie at 2-3 hours (current cost), and 4-10 hours if expectations on future cost developments are taken into consideration. PV+TES becomes only more competitive than CSP+TES with immense additional cost reductions of PV. Hence, there remain distinct niches for two technologies: PV+BESS for short storage durations and CSP+TES for longer ones.
Spatiotemporal coordination in word-medial stop-lateral and s-stop clusters of American English
(2021)
This paper is concerned with the relation between syllabic organization and intersegmental spatiotemporal coordination using Electromagnetic Articulometry recordings from seven speakers of American English (henceforth, English). Whereas previous work on English has focused on word-initial clusters (preceding a vowel whose identity was not systematically varied), the present work examined word-medial clusters /pl, kl, sp, sk/ in the context of three different vowel heights (high, mid, low). Our results provide evidence for a global organization for the segments involved in these cluster-vowel combinations. This is reflected in a number of ways: compression of the prevocalic consonant and reduction of CV timing in the word-medial cluster case compared to its singleton paired word in both stop-lateral and s-stop clusters, early vowel initiation (as permitted by the clusters' phonetic properties), and presence of compensatory relations between phonetic properties of different segments or intersegmental transitions within each cluster. In other words, we find that the global organization presiding over the segments partaking in these word-medial tautosyllabic CCVs is pleiotropic, that is, simultaneously expressed in multiple phonetic exponents rather than via a privileged metric such as c-center stability or any other such given single measure employed in previous works.
Bio-interactive hydrogel formation in situ requires sensory capabilities toward physiologically relevant stimuli. Here, we report on pH-controlled in situ hydrogel formation relying on latent cross-linkers, which transform from pH sensors to reactive molecules. In particular, thiopeptolide/thio-depsipeptides were capable of pH-sensitive thiol-thioester exchange reactions to yield a,co-dithiols, which react with maleimide-functionalized multi-arm polyethylene glycol to polymer networks. Their water solubility and diffusibility qualify thiol/thioester-containing peptide mimetics as sensory precursors to drive in situ localized hydrogel formation with potential applications in tissue regeneration such as treatment of inflamed tissues of the urinary tract.
Flood warning systems are longstanding success stories with respect to protecting human life, but monetary losses continue to grow. Knowledge on the effectiveness of flood early warning in reducing monetary losses is scarce, especially at the individual level. To gain more knowledge in this area, we analyze a dataset that is unique with respect to detailed information on warning reception and monetary losses at the property level and with respect to amount of data available. The dataset contains 4,468 loss cases from six flood events in Germany. These floods occurred between 2002 and 2013. The data from each event were collected by computer-aided telephone interviews in four surveys following a repeated cross-sectional design. We quantitatively reveal that flood early warning is only effective in reducing monetary losses when people know what to do when they receive the warning. We also show that particularly long-term preparedness is associated with people knowing what to do when they receive a warning. Thus, risk communication, training, and (financial) support for private preparedness are effective in mitigating flood losses in two ways: precautionary measures and more effective emergency responses.
Numerous nanostructured materials have been reported as efficient sulfur hosts to suppress the problematic "shuttling" of lithium polysulfides (LiPSs) in lithium-sulfur (Li-S) batteries. However, direct comparison of these materials in their efficiency of suppressing LiPSs shuttling is challenging, owing to the structural and morphological differences between individual materials. This study introduces a simple route to synthesize a series of sulfur host materials with the same yolk-shell nanospindle morphology but tunable compositions (Fe3O4, FeS, or FeS2), which allows for a systematic investigation into the specific effect of chemical composition on the electrochemical performances of Li-S batteries. Among them, the S/FeS2-C electrode exhibits the best performance and delivers an initial capacity of 877.6 mAh g(-1) at 0.5 C with a retention ratio of 86.7 % after 350 cycles. This approach can also be extended to the optimization of materials for other functionalities and applications.
On the classical understanding, an agent is fully excused for an action if and only if performing this action was a case of faultless wrongdoing. A major motivation for this view is the apparent existence of paradigmatic types of excusing considerations, affecting fault but not wrongness. I show that three such considerations, ignorance, duress and compulsion, can be shown to have direct bearing on the permissibility of actions. The appeal to distinctly identifiable excusing considerations thus does not stand up to closer scrutiny, undermining the classical view and giving us reason to seek alternative ways of drawing the justification/excuse distinction.
The digital transformation sets new requirements to all classes of enterprise systems in companies. ERP systems in particular, which represent the dominant class of enterprise systems, are struggling to meet the new requirements at all levels of the architecture. Therefore, there is an urgent need to reconsider the overall architecture of the systems and address the root of the related issues. Given that many restrictions ERP pose on their adaptability are related to the standardization of data, the database layer of ERP systems is addressed. Since database serve as the foundation for data storage and retrieval, they limit the flexibility of enterprise systems and the chance to adapt to new requirements accordingly. So far, relational databases are widely used. Using a systematic literature approach, recent requirements for ERP systems were identified. Prominent database approaches were assessed against the 23 requirements identified. The results reveal the strengths and weaknesses of recent database approaches. To this end, the results highlight the demand to combine multiple database approaches to fulfill recent business requirements. From a conceptual point of view, this paper supports the idea of federated databases which are interoperable to fulfill future requirements and support business operation. This research forms the basis for renewal of the current generation of ERP systems and proposes to ERP vendors to use different database concepts in the future.
The initiation of starch granule formation and the mechanism controlling the number of granules per plastid have been some of the most elusive aspects of starch metabolism. This review covers the advances made in the study of these processes. The analyses presented herein depict a scenario in which starch synthase isoform 4 (SS4) provides the elongating activity necessary for the initiation of starch granule formation. However, this protein does not act alone; other polypeptides are required for the initiation of an appropriate number of starch granules per chloroplast. The functions of this group of polypeptides include providing suitable substrates (maltooligosaccharides) to SS4, the localization of the starch initiation machinery to the thylakoid membranes, and facilitating the correct folding of SS4. The number of starch granules per chloroplast is tightly regulated and depends on the developmental stage of the leaves and their metabolic status. Plastidial phosphorylase (PHS1) and other enzymes play an essential role in this process since they are necessary for the synthesis of the substrates used by the initiation machinery. The mechanism of starch granule formation initiation in Arabidopsis seems to be generalizable to other plants and also to the synthesis of long-term storage starch. The latter, however, shows specific features due to the presence of more isoforms, the absence of constantly recurring starch synthesis and degradation, and the metabolic characteristics of the storage sink organs.
What is the processing cost of being garden-pathed by a temporary syntactic ambiguity? We argue that comparing average reading times in garden-path versus non-garden-path sentences is not enough to answer this question. Trial-level contaminants such as inattention, the fact that garden pathing may occur non-deterministically in the ambiguous condition, and "triage" (rejecting the sentence without reanalysis; Fodor & Inoue, 2000) lead to systematic underestimates of the true cost of garden pathing. Furthermore, the "pure" garden-path effect due to encountering an unexpected word needs to be separated from the additional cost of syntactic reanalysis. To get more realistic estimates for the individual processing costs of garden pathing and syntactic reanalysis, we implement a novel computational model that includes trial-level contaminants as probabilistically occurring latent cognitive processes. The model shows a good predictive fit to existing reading time and judgment data. Furthermore, the latent-process approach captures differences between noun phrase/zero complement (NP/Z) garden-path sentences and semantically biased reduced relative clause (RRC) garden-path sentences: The NP/Z garden path occurs nearly deterministically but can be mostly eliminated by adding a comma. By contrast, the RRC garden path occurs with a lower probability, but disambiguation via semantic plausibility is not always effective.