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Base catalysed decomposition of anthracene endoperoxide

  • Catalytic amounts of a weak base are sufficient to induce the decomposition of anthracene endoperoxides to anthraquinone. The mechanism has been elucidated by isolation of intermediates in combination with DFT calculations. The whole process is suitable for the convenient generation of hydrogen peroxide under very mild conditions.

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Metadaten
Author:M. Klaper, Pablo WessigORCiDGND, Torsten LinkerORCiDGND
URN:urn:nbn:de:kobv:517-opus4-89676
Series (Serial Number):Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (219)
Document Type:Postprint
Language:English
Date of first Publication:2015/11/20
Year of Completion:2015
Publishing Institution:Universität Potsdam
Release Date:2016/04/12
First Page:1210
Last Page:1213
Source:Chem. Commun. (2015) Nr. 52, S. 1210-1213. DOI: 10.1039/C5CC08606J
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer Review:Referiert
Publication Way:Open Access
Licence (German):License LogoKeine Nutzungslizenz vergeben - es gilt das deutsche Urheberrecht
Notes extern:Bibliographieeintrag der Originalveröffentlichung/Quelle