Base catalysed decomposition of anthracene endoperoxide

  • Catalytic amounts of a weak base are sufficient to induce the decomposition of anthracene endoperoxides to anthraquinone. The mechanism has been elucidated by isolation of intermediates in combination with DFT calculations. The whole process is suitable for the convenient generation of hydrogen peroxide under very mild conditions.

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Metadaten
Author details:M. Klaper, Pablo WessigORCiDGND, Torsten LinkerORCiDGND
DOI:https://doi.org/10.1039/C5CC08606J
ISSN:1364-548X
Title of parent work (English):Chemical communications : ChemComm
Publisher:Royal Society of Chemistry
Place of publishing:Cambridge
Publication type:Article
Language:English
Date of first publication:2015/11/20
Publication year:2015
Publishing institution:Universität Potsdam
Release date:2016/04/12
Issue:52
First page:1210
Last Page:1213
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
DDC classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer review:Referiert
Publishing method:Open Access
License (English):License LogoCreative Commons - Namensnennung 3.0 Unported
External remark:Zweitveröffentlichung als Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe ; 219
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