R-Group stabilization in methylated formamides observed by resonant inelastic X-ray scattering
- The inherent stability of methylated formamides is traced to a stabilization of the deep-lying sigma-framework by resonant inelastic X-ray scattering at the nitrogen K-edge. Charge transfer from the amide nitrogen to the methyl groups underlie this stabilization mechanism that leaves the aldehyde group essentially unaltered and explains the stability of secondary and tertiary amides.
Author details: | Miguel OchmannORCiDGND, Vinicius Vaz da CruzORCiD, Sebastian EckertORCiDGND, Nils HuseORCiDGND, Alexander FöhlischORCiDGND |
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DOI: | https://doi.org/10.1039/d2cc00053a |
ISSN: | 1359-7345 |
ISSN: | 1364-548X |
Pubmed ID: | https://pubmed.ncbi.nlm.nih.gov/35848855 |
Title of parent work (English): | Chemical communications: ChemComm |
Publisher: | The Royal Society of Chemistry |
Place of publishing: | Cambridge |
Publication type: | Article |
Language: | English |
Date of first publication: | 2022/06/11 |
Publication year: | 2022 |
Release date: | 2024/04/11 |
Volume: | 58 |
Issue: | 63 |
Number of pages: | 4 |
First page: | 8834 |
Last Page: | 8837 |
Funding institution: | ERC-ADG-2014 Advanced Investigator Grant via the Horizon 2020 EU; Framework, Programme for Research and Innovation [669531 EDAX]; Deutsche; Forschungsgemeinschaft (DFG, German Research Foundation) [SFB 925,; 170620586] |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie |
DDC classification: | 5 Naturwissenschaften und Mathematik / 53 Physik / 530 Physik |
Peer review: | Referiert |
Publishing method: | Open Access / Hybrid Open-Access |
License (English): | Creative Commons - Namensnennung 3.0 Unported |