Base catalysed decomposition of anthracene endoperoxide
- Catalytic amounts of a weak base are sufficient to induce the decomposition of anthracene endoperoxides to anthraquinone. The mechanism has been elucidated by isolation of intermediates in combination with DFT calculations. The whole process is suitable for the convenient generation of hydrogen peroxide under very mild conditions.
Author details: | M. Klaper, Pablo WessigORCiDGND, Torsten LinkerORCiDGND |
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URN: | urn:nbn:de:kobv:517-opus4-89676 |
Publication series (Volume number): | Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (219) |
Publication type: | Postprint |
Language: | English |
Date of first publication: | 2015/11/20 |
Publication year: | 2015 |
Publishing institution: | Universität Potsdam |
Release date: | 2016/04/12 |
First page: | 1210 |
Last Page: | 1213 |
Source: | Chem. Commun. (2015) Nr. 52, S. 1210-1213. DOI: 10.1039/C5CC08606J |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
DDC classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Peer review: | Referiert |
Publishing method: | Open Access |
License (German): | Keine öffentliche Lizenz: Unter Urheberrechtsschutz |
External remark: | Bibliographieeintrag der Originalveröffentlichung/Quelle |