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In this paper a perturbation-theory study of vibrational lifetimes for the bending and stretching modes of hydrogen adsorbed on a Si(100) surface is presented. The hydrogen-silicon interaction is treated with a semiempirical bond-order potential. Calculations are performed for H-Si clusters of different sizes. The finite lifetime is due to vibration-phonon coupling, which is assumed to be linear or bilinear in the phonon and nonlinear in the H-Si stretching and bending modes. Lifetimes and vibrational transition rates are evaluated with one- and two-phonon processes taken into account. Temperature effects are also discussed. In agreement with the experiment and previous theoretical treatment it is found that the H-Si (upsilon(s)=1) stretching vibration decays on a nanosecond timescale, whereas for the H-Si (upsilon(b)=1) bending mode a picosecond decay is predicted. For higher-excited vibrations, simple scaling laws are found if the excitation energies are not too large. The relaxation mechanisms for the excited H-Si stretching and the H-Si bending modes are analyzed in detail.
We present a detailed, realistic analysis of the implementation of a proposal for a quantum phase gate based on atomic vibrational states, specializing it to neutral rubidium atoms on atom chips. We show how to create a double-well potential with static currents on the atom chips, using for all relevant parameters values that are achieved with present technology. The potential barrier between the two wells can be modified by varying the currents in order to realize a quantum phase gate for qubit states encoded in the atomic external degree of freedom. The gate performance is analyzed through numerical simulations; the operation time is similar to 10 ms with a performance fidelity above 99.9%. For storage of the state between the operations the qubit state can be transferred efficiently via Raman transitions to two hyperfine states, where its decoherence is strongly inhibited. In addition we discuss the limits imposed by the proximity of the surface to the gate fidelity.
We study mixed boundary value problems for an elliptic operator A on a manifold X with boundary Y, i.e., Au = f in int X, T (+/-) u = g(+/-) on int Y+/-, where Y is subdivided into subsets Y+/- with an interface Z and boundary conditions T+/- on Y+/- that are Shapiro-Lopatinskij elliptic up to Z from the respective sides. We assume that Z subset of Y is a manifold with conical singularity v. As an example we consider the Zaremba problem, where A is the Laplacian and T- Dirichlet, T+ Neumann conditions. The problem is treated as a corner boundary value problem near v which is the new point and the main difficulty in this paper. Outside v the problem belongs to the edge calculus as is shown in Bull. Sci. Math. ( to appear). With a mixed problem we associate Fredholm operators in weighted corner Sobolev spaces with double weights, under suitable edge conditions along Z {v} of trace and potential type. We construct parametrices within the calculus and establish the regularity of solutions.
This study assessed the extent to which second-language learners are sensitive to phonetic information contained in visual cues when identifying a non-native phonemic contrast. In experiment 1, Spanish and Japanese learners of English were tested on their perception of a labial/labiodental consonant contrast in audio (A), visual (V), and audio-visual (AV) modalities. Spanish students showed better performance overall, and much greater sensitivity to visual cues than Japanese students. Both learner groups achieved higher scores in the A V than in the A test condition, thus showing evidence of audio-visual benefit. Experiment 2 examined the perception of the less visually-salient /1/-/r/ contrast in Japanese and Korean learners of English. Korean learners obtained much higher scores in auditory and audio- visual conditions than in the visual condition, while Japanese learners generally performed poorly in both modalities. Neither. group showed evidence of audio-visual benefit. These results show the impact of the language background of the learner and visual salience of the contrast on the use of visual cues for a non-native contrast. Significant correlations between scores in the auditory and visual conditions suggest that increasing auditory proficiency in identifying a non-native contrast is linked with an increasing proficiency in using visual cues to the contrast.
Fractional crystallization of peraluminous F- and H(2)O-rich granite magmas progressively enriches the remaining melt with volatiles. We show that, at saturation, the melt may separate into two immiscible conjugate melt fractions, one of the fractions shows increasing peraluminosity and the other increasing peralkalinity. These melt fractions also fractionate the incompatible elements to significantly different degrees. Coexisting melt fractions have differing chemical and physical properties and, due to their high density and viscosity contrasts, they will tend to separate readily from each other. Once separated, each melt fraction evolves independently in response to changing T/P/X conditions and further immiscibility events may occur, each generating its own conjugate pair of melt fractions. The strongly peralkaline melt fractions in particular are very reactive and commonly react until equilibrium is attained. Consequently, the peralkaline melt fraction is commonly preserved only in the isolated melt and mineral inclusions. We demonstrate that the differences between melt fractions that can be seen most clearly in differing melt inclusion compositions are also visible in the composition of the resulting ore-forming and accessory minerals, and are visible on scales from a few micrometers to hundreds of meters.
The simple generator
(2006)
I argue that the shift of explanatory burden from the generator to the evaluator in OT syntax – together with the difficulties that arise when we try to formulate a working theory of the interfaces of syntax – leads to a number of assumptions about syntactic structures in OT which are quite different from those typical of minimalist syntax: formal features, as driving forces behind syntactic movement, are useless, and derivational and representational economy are problematic for both empirical and conceptual reasons. The notion of markedness, central in Optimality Theory, is not fully compatible with the idea of synactic economy. Even more so, seemingly obvious cases of blocking by structural economy do not seem to result from grammar proper, but reflect (economical) aspects of language use.
China, as being the largest foreign direct investment (FDI) host country in the world and the leading developing country in terms of volume of FDI inflows, has been increasingly attracting international attention from companies and policy makers. As more and more German manufacturing companies move into China, the investment is becoming larger in size and of higher quality. In the meantime, issues of the motives and nature of German FDI in China and related technological activities are developed to a more important topic for both Chinese and overseas researchers. This paper aims at the analysis and explanation of FDI movement driven by German companies in China and the role of technology hereby. Our research includes a literature review, a database analysis and a mail survey on German firms investing in China. Different indicators suggest that the motives for German FDI are long-term based and are deeply market-oriented, which can be characterised through seeking new markets and enlarging market shares. Technology transfer is therefore mainly dedicated to production and managerial facilities.
Investigating the mechanisms which underlie the biomass fluctuations of populations and communities is important to better understand the processes which buffer community biomass in a variable environment. Based on long- term data of plankton biomass in Lake Constance (Bodensee), this study aims at explaining the different degree of synchrony among populations observed within two freshwater plankton groups, phytoplankton and ciliates. Established measures of temporal variability such as the variance ratio and cross-correlation coefficients were combined with first- order autoregressive models that allow estimating species interactions from time-series data. We found that predation was an important driver of the observed seasonal variability patterns in phytoplankton and ciliates, and that competitive interactions only played a subordinate role. In Lake Constance copepods and cladocerans, two major invertebrate predator groups, focus their grazing pressure at different times of the season. Model results suggested that compensatory dynamics detected in phytoplankton originate from the differential vulnerability of species to either one of these two predator groups. For ciliates model results advocated that synchrony among species occurs because ciliates tend to be vulnerable to both predator groups. Our findings underline the necessity of extending studies of community variability to multiple trophic levels because accounting for predator-prey interactions may often be more important than accounting for competitive interactions at one trophic level
When Galactic microlensing events of stars are observed, one usually measures a symmetric light curve corresponding to a single lens, or an asymmetric light curve, often with caustic crossings, in the case of a binary lens system. In principle, the fraction of binary stars at a certain separation range can be estimated based on the number of measured microlensing events. However, a binary system may produce a light curve which can be fitted well as a single lens light curve, in particullary if the data sampling is poor and the errorbars are large. We investigate what fraction of microlensing events produced by binary stars for different separations may be well fitted by and hence misinterpreted as single lens events for various observational conditions. We find that this fraction strongly depends on the separation of the binary components, reaching its minimum at between 0.6 and 1.0 Einstein radius, where it is still of the order of 5% The Einstein radius is corresponding to few A.U. for typical Galactic microlensing scenarios. The rate for misinterpretation is higher for short microlensing events lasting up to few months and events with smaller maximum amplification. For fixed separation it increases for binaries with more extreme mass ratios. Problem of degeneracy in photometric light curve solution between binary lens and binary source microlensing events was studied on simulated data, and data observed by the PLANET collaboration. The fitting code BISCO using the PIKAIA genetic algorithm optimizing routine was written for optimizing binary-source microlensing light curves observed at different sites, in I, R and V photometric bands. Tests on simulated microlensing light curves show that BISCO is successful in finding the solution to a binary-source event in a very wide parameter space. Flux ratio method is suggested in this work for breaking degeneracy between binary-lens and binary-source photometric light curves. Models show that only a few additional data points in photometric V band, together with a full light curve in I band, will enable breaking the degeneracy. Very good data quality and dense data sampling, combined with accurate binary lens and binary source modeling, yielded the discovery of the lowest-mass planet discovered outside of the Solar System so far, OGLE-2005-BLG-390Lb, having only 5.5 Earth masses. This was the first observed microlensing event in which the degeneracy between a planetary binary-lens and an extreme flux ratio binary-source model has been successfully broken. For events OGLE-2003-BLG-222 and OGLE-2004-BLG-347, the degeneracy was encountered despite of very dense data sampling. From light curve modeling and stellar evolution theory, there was a slight preference to explain OGLE-2003-BLG-222 as a binary source event, and OGLE-2004-BLG-347 as a binary lens event. However, without spectra, this degeneracy cannot be fully broken. No planet was found so far around a white dwarf, though it is believed that Jovian planets should survive the late stages of stellar evolution, and that white dwarfs will retain planetary systems in wide orbits. We want to perform high precision astrometric observations of nearby white dwarfs in wide binary systems with red dwarfs in order to find planets around white dwarfs. We selected a sample of observing targets (WD-RD binary systems, not published yet), which can possibly have planets around the WD component, and modeled synthetic astrometric orbits which can be observed for these targets using existing and future astrometric facilities. Modeling was performed for the astrometric accuracy of 0.01, 0.1, and 1.0 mas, separation between WD and planet of 3 and 5 A.U., binary system separation of 30 A.U., planet masses of 10 Earth masses, 1 and 10 Jupiter masses, WD mass of 0.5M and 1.0 Solar masses, and distances to the system of 10, 20 and 30 pc. It was found that the PRIMA facility at the VLTI will be able to detect planets around white dwarfs once it is operating, by measuring the astrometric wobble of the WD due to a planet companion, down to 1 Jupiter mass. We show for the simulated observations that it is possible to model the orbits and find the parameters describing the potential planetary systems.
A localized dehydration zone, Sondrum stone quarry, Halmstad, SW Sweden, consists of a central, 1 m wide granitic pegmatoid dyke, on either side of which extends a 2.5-3 m wide dehydration zone (650-700 degrees C; 800 MPa; orthopyroxene-clinopyroxene-biotite-amphibole-garnet) overprinting a local migmatized granitic gneiss (amphibole-biotite- garnet). Whole-rock chemistry indicates that dehydration of the granitic gneiss was predominantly isochemical. Exceptions include [Y + heavy rare earth elements (HREE)], Ba, Sr, and F, which are markedly depleted throughout the dehydration zone. Systematic trends in the silicate and fluorapatite mineral chemistry across the dehydration zone include depletion in Fe, (Y + HREE), Na, K, F, and Cl, and enrichment in Mg, Mn, Ca, and Ti. Fluid inclusion chemistry is similar in all three zones and indicates the presence of a fluid containing CO2, NaCl, and H2O components. Water activities in the dehydration zone average 0.36, or XH2O = 0.25. All lines of evidence suggest that the formation of the dehydration zone was due to advective transport of a CO2-rich fluid with a minor NaCl brine component originating from a tectonic fracture. Fluid infiltration resulted in the localized partial breakdown of biotite and amphiboles to pyroxenes releasing Ti and Ca, which were partitioned into the remaining biotite and amphibole, as well as uniform depletion in (Y + HREE), Ba, Sr, Cl, and F. At some later stage, H2O-rich fluids (H2O activity > 0.8) gave rise to localized partial melting and the probable injection of a granitic melt into the tectonic fracture, which resulted in the biotite and amphibole recording a diffusion profile for F across the dehydration zone into the granitic gneiss as well as a diffusion profile in Fe, Mn, and Mg for all Fe-Mg silicate minerals within 100 cm of the pegmatoid dyke
The present thesis deals with the mental representation of numbers in space. Generally it is assumed that numbers are mentally represented on a mental number line along which they ordered in a continuous and analogical manner. Dehaene, Bossini and Giraux (1993) found that the mental number line is spatially oriented from left-to-right. Using a parity-judgment task they observed faster left-hand responses for smaller numbers and faster right-hand responses for larger numbers. This effect has been labelled as Spatial Numerical Association of Response Codes (SNARC) effect. The first study of the present thesis deals with the question whether the spatial orientation of the mental number line derives from the writing system participants are adapted to. According to a strong ontogenetic interpretation the SNARC effect should only obtain for effectors closely related to the comprehension and production of written language (hands and eyes). We asked participants to indicate the parity status of digits by pressing a pedal with their left or right foot. In contrast to the strong ontogenetic view we observed a pedal SNARC effect which did not differ from the manual SNARC effect. In the second study we evaluated whether the SNARC effect reflects an association of numbers and extracorporal space or an association of numbers and hands. To do so we varied the spatial arrangement of the response buttons (vertical vs. horizontal) and the instruction (handrelated vs. button-related). For vertically arranged buttons and a buttonrelated instruction we found a button-related SNARC effect. In contrast, for a hand-related instruction we obtained a hand-related SNARC effect. For horizontally arranged buttons and a handrelated instruction, however, we found a buttonrelated SNARC effect. The results of the first to studies were interpreted in terms of weak ontogenetic view. In the third study we aimed to examine the functional locus of the SNARC effect. We used the psychological refractory period paradigm. In the first experiment participants first indicated the pitch of a tone and then the parity status of a digit (locus-of-slack paradigma). In a second experiment the order of stimulus presentation and thus tasks changed (effect-propagation paradigm). The results led us conclude that the SNARC effect arises while the response is centrally selected. In our fourth study we test for an association of numbers and time. We asked participants to compare two serially presented digits. Participants were faster to compare ascending digit pairs (e.g., 2-3) than descending pairs (e.g., 3-2). The pattern of our results was interpreted in terms of forwardassociations (“1-2-3”) as formed by our ubiquitous cognitive routines to count of objects or events.
We study pseudo-differential operators on a cylinder R x B where B has conical singularities. Configurations of that kind are the local model of corner singularities with cross section B. Operators in our calculus are assumed to have symbols a which are meromorphic in the complex covariable with values in the algebra of all cone operators on B. We show an explicit formula for solutions of the homogeneous equation if a is independent of the axial variable t is an element of R. Each non-bijectivity point of the symbol in the complex plane corresponds to a finite-dimensional space of solutions. Moreover, we give a relative index formula
The recognition of the prosodic focus position in German-Learning Infants from 4 to 14 Months
(2006)
The recognition of the prosodic focus position in German-learning infants from 4 to 14 months
(2006)
The aim of the present study was to elucidate in a study with 4-, 6-, 8-, and 14-month-old German-learning children, when and how they may acquire the regularities which underlie Focus-to-Stress Alignment (FSA) in the target language, that is, how prosody is associated with specific communicative functions. Our findings suggest, that 14-month-olds have already found out that German allows for variable focus positions, after having gone through a development which goes from a predominantly prosodically driven processing of the input to a processing where prosody interacts more and more with the growing lexical and syntactic knowledge of the child.
Recent work has shown that English-learning 18-month-olds can detect the relationship between discontinuous morphemes such as is and -ing in Grandma is always running (Gomez, 2002; Santelmann & Jusczyk, 1998) but only at a maximum of 3 intervening syllables. In this article we examine the tracking of discontinuous dependencies in children acquiring German. Due to freer word order, German allows for greater distances between dependent elements and a greater syntactic variety of the intervening elements than English does. The aim of this study was to investigate whether factors other than distance may influence the child’s capacity to recognize discontinuous elements. Our findings provide evidence that children’s recognition capacities are affected not only by distance but also by their ability to linguistically analyze the material intervening between the dependent elements. We speculate that this result supports the existence of processing mechanisms that reduce a discontinuous relation to a local one based on subcategorization relations.
In this paper, we give a complete classification of all finite simple groups with maximal subgroups of index n, where n = 2(a)center dot 3b for a, b >= 1. As a consequence, for such n, all primitive permutation groups of degree n are given. The motivation of this work comes also from a study of Cayley graphs of certain valency on a finite simple group
Garnets in continentally derived high-pressure (HP) rocks of the Sesia Zone (Western Alps) exhibit three different chemical zonation patterns, depending on sample locality. Comparison of observed garnet zonation patterns with thermodynamically modelled patterns shows that the different patterns are caused by differences in the water content of the subducted protoliths during prograde metamorphism. Zonation patterns of garnets in water-saturated host rocks show typical prograde chemical zonations with steadily increasing pyrope content and increasing XMg, together with bell-shaped spessartine patterns. In contrast, garnets in water-undersaturated rocks have more complex zonation patterns with a characteristic decrease in pyrope and XMg between core and inner rim. In some cases, garnets show an abrupt compositional change in core-to-rim profiles, possibly due to water-undersaturation prior to HP metamorphism. Garnets from both water-saturated and water-undersaturated rocks show signs of intervening growth interruptions and core resorption. This growth interruption results from bulk-rock depletion caused by fractional garnet crystallization. The water content during burial influences significantly the physical properties of the subducted rocks. Due to enhanced garnet crystallization, water-undersaturated rocks, i.e. those lacking a free fluid phase, become denser than their water-saturated equivalents, facilitating the subduction of continental material. Although water-bearing phases such as phengite and epidote are stable up to eclogite-facies conditions in these rocks, dehydration reactions during subduction are lacking in water-undersaturated rocks up to the transition to the eclogite facies, due to the thermodynamic stability of such hydrous phases at high P-T conditions. Our calculations show that garnet zonation patterns strongly depend on the mineral parageneses stable during garnet growth and that certain co-genetic mineral assemblages cause distinct garnet zonation patterns. This observation enables interpretation of complex garnet growth zonation patterns in terms of garnet-forming reactions and water content during HP metamorphism, as well determination of detailed P-T paths.
Hypersubstitutions were introduced in [3] as a way of making precise the concepts of hyperidentity and M- hyperidentity. The monoid of hypersubstitutions has been widely studied by many authors. Knowledge of the monoid of hypersubstitutions can be applied to the concept of M-hyperidentities. In this paper, we show that the order of hypersubstitutions of type tau = (3) is 1, 2, 3 or infinite
If we want to compare the explanatory and descriptive adequacy of the MP and OT, the original definitions by Chomsky (1964) are or little direct use. However, a relativized version of both notions can be defined, which can be used to express a number of parallels between the study of individual I-languages and the language faculty. In any version of explanatory and descriptive adequacy, the two notions derive from the research programme and can only be achieved together. They can therefore not be used to characterize the difference in orientation between OT and the MP. Even if ‘OT’ is restricted to a particular theory in Chomskyan linguistics (to the exclusion of, for instance, its use in LFG), it cannot be said to be stronger in descriptive adequacy than in explanatory adequacy in the technical sense of these terms.
In planetary rings, binary collisions and mutual gravity are the predominant particle interactions. Based on a viscoelastic contact model we implement the concept of static adhesion. We discuss the collision dynamics and obtain a threshold velocity for restitution or agglomeration to occur. The latter takes place within a range of a few cm s(-1) for icy grains at low temperatures. The stability of such two-body agglomerates bound by adhesion and gravity in a tidal environment is discussed and applied to the saturnian system. A maximal agglomerate size for a given orbit location is obtained. In this way we are able to resolve the borderline of the zone where agglomerates can exist as a function of the agglomerate size and thus gain an alternative to the classical Roche limit. An increasing ring grain size with distance to Saturn as observed by the VIMS-experiment on board the Cassini spacecraft can be found by our estimates and implications for the saturnian system will be addressed.
The influence of land-use changes on soil hydraulic properties : implications for runoff generation
(2006)
One of the most important insights of Optimality Theory (Prince and Smolensky, 1993) is that phonological processes can be reduced to the interaction between faithfulness and universal markedness principles. In the most constrained version of the theory, all phonological processes should be thus reducible. This hypothesis is tested by alternations that appear to be phonological but in which universal markedness principles appear to play no role. If we are to pursue the claim that all phonological processes depend on the interaction of faithfulness and markedness, then processes that are not dependent on markedness must lie outside phonology. In this paper I will examine a group of such processes, the initial consonant mutations of the Celtic languages, and argue that they belong entirely to the morphology of the languages, not the phonology.
The first step in the estimation of probabilistic seismic hazard in a region commonly consists of the definition and characterization of the relevant seismic sources. Because in low-seismicity regions seismicity is often rather diffuse and faults are difficult to identify, large areal source zones are mostly used. The corresponding hypothesis is that seismicity is uniformly distributed inside each areal seismic source zone. In this study, the impact of this hypothesis on the probabilistic hazard estimation is quantified through the generation of synthetic spatial seismicity distributions. Fractal seismicity distributions are generated inside a given source zone and probabilistic hazard is computed for a set of sites located inside this zone. In our study, the impact of the spatial seismicity distribution is defined as the deviation from the hazard value obtained for a spatially uniform seismicity distribution. From the generation of a large number of synthetic distributions, the correlation between the fractal dimension D and the impact is derived. The results show that the assumption of spatially uniform seismicity tends to bias the hazard to higher values. The correlation can be used to determine the systematic biases and uncertainties for hazard estimations in real cases, where the fractal dimension has been determined. We apply the technique in Germany (Cologne area) and in France (Alps).
In Arabidopsis thaliana and Oryza sativa, two types of PI 4-kinase (PI4Ks) have been isolated and functionally characterized. The alpha-type PI4Ks (similar to 220 kDa) contain a PH domain, which is lacking in beta-type PI4Ks (similar to 120 kDa). beta-Type PI4Ks, exemplified by Arabidopsis AtPI4K beta and rice OsPI4K2, contain a highly charged repetitive segment designated PPC (Plant PI4K Charged) region, which is an unique domain only found in plant beta-type PI4Ks at present. The PPC region has a length of similar to 300 amino acids and harboring 11 (AtPI4K beta) and 14 (OsPI4K2) repeats, respectively, of a 20-aa motif. Studies employing a modified yeast-based "Sequence of Membrane- Targeting Detection'' system demonstrate that the PPC(OsPI4K2) region, as well as the former 8 and latter 6 repetitive motifs within the PPC region, are able to target fusion proteins to the plasma membrane. Further detection on the transiently expressed GFP fusion proteins in onion epidermal cells showed that the PPC(OsPI4K2) region alone, as well as the region containing repetitive motifs 1-8, was able to direct GFP to the plasma membrane, while the regions containing less repetitive motifs, i.e. 6, 4, 2 or single motif(s) led to predominantly intracellular localization. Agrobacterium-mediated transient expression of PPC-GFP fusion protein further confirms the membrane-targeting capacities of PPC region. In addition, the predominant plasma membrane localization of AtPI4Kb was mediated by the PPC region. Recombinant PPC peptide, expressed in E. coli, strongly binds phosphatidic acid, PI and PI4P, but not phosphatidylcholine, PI5P, or PI(4,5) P-2 in vitro, providing insights into potential mechanisms for regulating sub- cellular localization and lipid binding for the plant beta-type PI4Ks
The concept of the virtual corporation (VC), which describes a modern form of collaboration among organizations, was introduced in the scientific discussion in the mid 1990th. The practice shows that VCs need new forms of governance because the traditional mechanisms of control, management, and steering are hardly applicable. Until now there is only a few research related to the question how to govern VC. The main problems to govern a VC are to coordinate the communication among dispersed partners and to motivate employees to actively involve themselves into the network. Open source projects are confronted with similar problems. As several governance mechanisms are already analyzed in this context, the authors analyze and adopt governance concepts from open source projects to extract a governance framework for virtual corporations. This new approach leads to innovative insights in governing virtual corporations by using community techniques as an appropriate way for communication and collaboration purposes.
The ancestral galectin from the sponge Geodia cydonium (GCG) is classified on a structural basis to the prototype subfamily, whereas its carbohydrate-binding specificity is related to that of the mammalian chimera-type galectin-3. This dual coordination reveals GCG as a potential precursor of the later evolved galectin subfamilies, which is reflected in the primary structure of the protein. This study provides evidence that GCG is the LECT1 gene product, while neither a previously described LECT2 gene nor a functional LECT2 gene product was found in the specimen under investigation. The electrophoretically separated protein isomers with apparent molecular masses of 13, 15, and 16 kDa correspond to variants of the LECT1 protein-exhibiting peptide sequence polymorphisms that concern critical positions of the carbohydrate recognition domain (13 kDa: Leu51, Asn55, His130, Gly137; 15 kDa: Ser51, Asn55, Asn130, Gly137; 16 kDa: Ser51, Tyr55, Asn130, Glu137). Four residues, highly conserved in the galectin family, are substituted. None of the residues claimed to be involved in interactions with GalNAc alpha 1-3 moieties at an extended binding subsite of galectin-3 was identified in the corresponding positions of GCG. Apparently, the substitutions do not confer distinct binding characteristics to the GCG variants as evidenced by binding studies with a recombinantly expressed 15-kDa isoform. The natural isoforms as well as the recombinant 15-kDa isoform oligomerize by the formation of non-covalent heteromeric or homomeric complexes. A phosphorylation of the galectin was confirmed neither by mass spectrometry nor by alkaline phosphatase treatment combined with isoelectric focusing
Context. Very massive stars pass through the Wolf-Rayet (WR) stage before they finally explode. Details of their evolution have not yet been safely established, and their physics are not well understood. Their spectral analysis requires adequate model atmospheres, which have been developed step by step during the past decades and account in their recent version for line blanketing by the millions of lines from iron and iron-group elements. However, only very few WN stars have been re-analyzed by means of line-blanketed models yet. Aims. The quantitative spectral analysis of a large sample of Galactic WN stars with the most advanced generation of model atmospheres should provide an empirical basis for various studies about the origin, evolution, and physics of the Wolf-Rayet stars and their powerful winds. Methods. We analyze a large sample of Galactic WN stars by means of the Potsdam Wolf-Rayet (PoWR) model atmospheres, which account for iron line blanketing and clumping. The results are compared with a synthetic population, generated from the Geneva tracks for massive star evolution. Results. We obtain a homogeneous set of stellar and atmospheric parameters for the GalacticWN stars, partly revising earlier results. Conclusions. Comparing the results of our spectral analyses of the Galactic WN stars with the predictions of the Geneva evolutionary calculations, we conclude that there is rough qualitative agreement. However, the quantitative discrepancies are still severe, and there is no preference for the tracks that account for the effects of rotation. It seems that the evolution of massive stars is still not satisfactorily understood.
The new tetrathiacrown ethers maleonitrile-tetrathia-12-crown-4 (mn12S(4)) and maleonitrile-tetrathia-13-crown- 4 (mn13S(4)) have been prepared and characterised by X-ray crystallographic analysis. These crown ethers form 2:1, 3:2 and 1: 1 complexes with AgY (Y = BF4, PF6). The crystal structures of [Ag(mn12S(4))(2)]BF4 (3a), [Ag(mn13S(4))(2)]BF4 (4a) and [Ag-2(mn13S(4))(3)](PF6)(2) (6b) have been determined. Compound 3a contains the centrosymmetric sandwich complex cation [Ag(mn12S(4))(2)](+) where each mn12S(4) ligand is coordinated to the Ag centre in an endo manner through all four S atoms. The 2:1 complex [Ag(mn12S(4))(2)](+) is the first sandwich complex with a tetrathiacrown ether and the first complex with an octa(thioether) coordination sphere. The crystal structure of compound 4a also reveals a 2:1 complex. This complex, [Ag(mnl3S(4))(2)](+), exhibits a half-sandwich structure. One mn13S(4) ligand coordinates to Ag+ by all four S donor atoms and the other 13S(4) crown by only one S atom. Compound 6b contains a dinuclear Ag complex. The Ag complexes 3a,b-8a,b were also studied by electrospray ionisation mass spectrometry. Collision-induced dissociation (CID) was used to compare the relative stability of 2:1 complexes [AgL2]+ and 1:1 complexes [AgL](+) (L = mn12S(4), mn13S(4)). The C-13 NMR chemical shifts of 2:1 and 1:1 Ag complexes and their corresponding free ligands were also estimated and compared. The free energy of the barrier of ring inversion (Delta G(double dagger)) for [Ag(mn12S(4))(2)](+) was determined to be 64 kJmol(-1).
The estimation of minimum-misfit stochastic models from empirical ground-motion prediction equations
(2006)
In areas of moderate to low seismic activity there is commonly a lack of recorded strong ground motion. As a consequence, the prediction of ground motion expected for hypothetical future earthquakes is often performed by employing empirical models from other regions. In this context, Campbell's hybrid empirical approach (Campbell, 2003, 2004) provides a methodological framework to adapt ground-motion prediction equations to arbitrary target regions by using response spectral host-to-target-region-conversion filters. For this purpose, the empirical ground-motion prediction equation has to be quantified in terms of a stochastic model. The problem we address here is how to do this in a systematic way and how to assess the corresponding uncertainties. For the determination of the model parameters we use a genetic algorithm search. The stochastic model spectra were calculated by using a speed-optimized version of SMSIM (Boore, 2000). For most of the empirical ground-motion models, we obtain sets of stochastic models that match the empirical models within the full magnitude and distance ranges of their generating data sets fairly well. The overall quality of fit and the resulting model parameter sets strongly depend on the particular choice of the distance metric used for the stochastic model. We suggest the use of the hypocentral distance metric for the stochastic Simulation of strong ground motion because it provides the lowest-misfit stochastic models for most empirical equations. This is in agreement with the results of two recent studies of hypocenter locations in finite-source models which indicate that hypocenters are often located close to regions of large slip (Mai et al., 2005; Manighetti et al., 2005). Because essentially all empirical ground-motion prediction equations contain data from different geographical regions, the model parameters corresponding to the lowest-misfit stochastic models cannot necessarily be expected to represent single, physically realizable host regions but to model the generating data sets in an average way. In addition, the differences between the lowest-misfit stochastic models and the empirical ground-motion prediction equation are strongly distance, magnitude, and frequency dependent, which, according to the laws of uncertainty propagation, will increase the variance of the corresponding hybrid empirical model predictions (Scherbaum et al., 2005). As a consequence, the selection of empirical ground-motion models for host-to-target-region conversions requires considerable judgment of the ground-motion analyst
The Enigma of Arrival
(2006)
The empire in 1871 - 1914
(2006)
Receiver functions (RF) are used to investigate the upper mantle structure beneath the Eifel, the youngest volcanic area of Central Europe. Data from 96 teleseismic events recorded by 242 seismological stations from permanent and a temporary network has been analysed. The temporary network operated from 1997 November to 1998 June and covered an area of approximately 400 x 250 km(2) centred on the Eifel volcanic fields. The average Moho depth in the Eifel is approximately 30 km, thinning to ca. 28 km under the Eifel volcanic fields. RF images suggest the existence of a low velocity zone at about 60-90 km depth under the West Eifel. This observation is supported by P- and S-wave tomographic results and absorption (but the array aperture limits the resolution of the tomographic methods to the upper 400 km). There are also indications for a zone of elevated velocities at around 200 km depth, again in agreement with S-wave and absorption tomographic results. This anomaly is not visible in P-wave tomography and could be due to S-wave anisotropy. The RF anomalies at the Moho, at 60-90 km, and near 200 km depth have a lateral extent of about 100 km. The 410 km discontinuity under the Eifel is depressed by 15-25 km, which could be explained by a maximum temperature increase of +200 degrees C to +300 degrees C. In the 3-D RF image of the Eifel Plume we also notice two additional currently unexplained conversions between 410 and 550 km depth. They could represent remnants of previous subduction or anomalies due to delayed phase changes. The lateral extent of these conversions and the depression of the 410 km discontinuity is about 200 km. The 660 km discontinuity does not show any depth deviation from its expected value. Our observations are consistent with interpretation in terms of an upper mantle plume but they do not rule out connections to processes at larger depth
In this study the effect of phonotactic constraints concerning word-initial consonant clusters in children with delayed phonological acquisition was explored. Twelve German-speaking children took part (mean age 5;1). The spontaneous speech of all children was characterized by the regular appearance of the error patterns fronting, e.g., Kuh (cow) → /tu:/, or stopping, e.g., Schaf (sheep) → /ta:f/, which were inappropriate for their chronological age. The children were asked to produce words (picture naming task, word repetition task) with initial consonant clusters, in which the application of the error patterns would violate phonotactic sequence constraints. For instance, if fronting would apply in /kl-/, e.g., Kleid (dress), it would be realized as the phontactically illegal consonant cluster /tl-/. The results indicate that phonotactic constraints affect word production in children with delayed phonological developments. Surprisingly, we found that children with fronting produced the critical consonants correctly significantly more often in word-initial consonant clusters than in words in which they appeared as singleton onsets. In addition, the results provide evidence for a similar developmental trajectory of acquisition in children with typical development and in children with delayed phonological acquisition. Keywords: Children with delayed phonological acquisition, phonotactic constraints, word-initial consonant clusters, fronting, stopping.
A series of novel platinum-containing carbazole monomers and polymers was synthesized and fully characterized by UV-VIS absorption, luminescence, and photoinduced absorption studies. In these compounds, a carbazole unit is incorporated into the main chain via either a para- or a meta-linkage. We discuss the effects of linkage and polymerization on the energy levels of S-1, T-1, and T-n. The S-1-T-1 splitting observed for the meta-linked monomer (0.4 eV) is only half of that in the para-linked monomer (0.8 eV). Upon polymerization, the exchange energy in the para- linked compound reduces, yet still remains larger than in the meta-linked polymer. We attribute the difference in exchange energy to the difference in wave function overlap between electron and hole in these compounds. (c) 2006 American Institute of Physics
The crystal and molecular structures of sodium and barium complexes of dibenzo-24-crown-8 ether
(2006)
The sodium and barium isothiocyanate complexes of 6,7,9,10,12,13,20,21,23,24,26,27-dodecahydrodibenzo[b,n]- 1,4,7,10,13,16,19,22-octaoxacyclotetracosin (dibenzo-24-crown-8 ether = DB24C8) were synthesized and analyzed by X-ray diffraction. The sodium complex, [Na(DB24C8)(NCS)(H2O)] 1, crystallizes in the orthorhombic space group Fdd2 with 16 molecules in the unit cell. The coordination number of Na is 6 and the central ion is located in a distorted octahedric environment. Only four of the crown ether oxygen atoms are involved. The coordination polyhedron is completed by the isothiocanate anion and by a water molecule, which is stabilized by hydrogen bonds. The barium complex, [Ba(DB24C8)(NCS)(2)] 2, crystallizes in the trigonale space group P3(1)21 with 3 molecules in the unit cell. Crystallographic C-2 symmetry is observed for the complex. The coordination number of Ba is 10. Barium is coordinated with the eight oxygen atoms of the macrocyclic ligand and with two isothiocyanate anions. The absolute structure was estimated using the FLACK parameter
Relationships of annelid subtaxa are controversially discussed and additional markers are necessarily needed to get further insights into their evolution. Due to their high content of information, mitochondrial genomes have been proven very useful in phylogenetic analyses. Whereas many complete mitochondrial genomes of arthropods are available, lophotrochozoan taxa are only scarcely represented and this is especially true for annelids. Here we present the complete mitochondrial genome of the orbiniid polychaete Orbinia latreillii. The circular genome is 15,558 bp in size and contains the same 37 genes as found in most other metazoans. As in the case for all studied annelids all genes are transcribed from the same strand. Compared with the known data from other annelids at least five gene translocations must be hypothesized for O. latreillii. A comparison of the available data shows that gene translocations within Annelida seem to be less frequent than in molluscs, but more frequent as previously assumed. Phylogenetic analyses of mitochondrial DNA sequence data and amino acid data support an inclusion Of Sipuncula within Annelida and a closer relationship to orbiniids is recovered for this taxon.
The communicatory significance of localised defecation sites in bushbuck (Tragelaphus scriptus)
(2006)
Like several other mammals, bushbuck (Tragelaphus scriptus) deposit faeces in specific localised defecation sites (LDS). A previous study has ruled out a function of LDS in the context of parasite avoidance. In this study, we investigated the communicatory significance of LDS. In a free ranging population, we tested whether LDS serve to demarcate home ranges, and/or if LDS are used for communication in a non-territorial context. In both sexes, LDS increased significantly in number towards the periphery of individual home ranges. However, the distribution pattern of LDS, as revealed by a nearest-neighbour mapping technique (nearest distances between LDS), did not support the idea that LDS serve home range/territory-demarcation because LDS did not follow a pattern of minimal nearest-neighbour distances along the margins of home ranges. We found females to urinate more often in LDS than males. Notably, information transfer was most frequent between sending (urinating or defecating) females and receiving/responding males (urination or defecation at places where a female had previously signalled). Our results suggest that LDS mainly serve for inter- sexual communication in bushbuck