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Sediment-discharge hysteresis loops are frequently analyzed to facilitate the understanding of sediment transport processes. Hysteresis patterns, however, are often complex and their interpretation can be complicated. Particularly, quantifying hysteresis patterns remains a problematic issue. Moreover, it is currently unknown how much data is required for analyzing sediment-discharge hysteresis loops in a given area. These open questions and challenges motivated us to develop a new method for quantifying suspended-sediment hysteresis. Subsequently, we applied the new hysteresis index to three suspended-sediment and discharge datasets from a small tropical rainforest catchment. The datasets comprised a different number of events and sampling sites. Our analyses show three main findings: (1) datasets restricted to only few events, which is typical for rapid assessment surveys, were always sufficient to identify the dominating hysteresis pattern in our research area. Furthermore, some of these small datasets contained multiple-peak events that allowed identifying intra-event exhaustion effects and hence, limitations in sediment supply. (2) Datasets comprising complete hydrological years were particularly useful for analyzing seasonal dynamics of hysteresis. These analyses revealed an exhaustion of hysteresis on the inter-event scale which also points to a limited sediment supply. (3) Datasets comprising measurements from two consecutive gauges installed at the catchment outlet and on a slope within that catchment allowed analyzing the change of hysteresis patterns along the flowpath. On the slope, multiple-peak events showed a stronger intra-event exhaustion of hysteresis than at the catchment outlet. Furthermore, exhaustion of hysteresis on the inter-event scale was not evident on the slope but occurred at the catchment outlet. Our results indicate that even small sediment datasets can provide valuable insights into sediment transport processes of small catchments. Furthermore, our results may serve as a first guideline on what to expect from an analysis of hysteresis patterns for datasets of varying quality and quantity. (c) 2014 Elsevier B.V. All rights reserved.
Soils play a crucial role in biogeochemical cycles as spatially distributed sources and sinks of nutrients. Any spatial patterns depend on soil forming processes, our understanding of which is still limited, especially in regards to tropical rainforests. The objective of our study was to investigate the effects of landscape properties, with an emphasis on the geometry of the land surface, on the spatial heterogeneity of soil chemical properties, and to test the suitability of soil-landscape modeling as an appropriate technique to predict the spatial variability of exchangeable K and Mg in a humid tropical forest in Panama. We used a design-based, stratified sampling scheme to collect soil samples at 108 sites on Barro Colorado Island, Panama. Stratifying variables are lithology, vegetation and topography. Topographic variables were generated from high-resolution digital elevation models with a grid size of 5 m. We took samples from five depths down to I m, and analyzed for total and exchangeable K and Mg. We used simple explorative data analysis techniques to elucidate the importance of lithology for soil total and exchangeable K and Mg. Classification and Regression Trees (CART) were adopted to investigate importance of topography, lithology and vegetation for the spatial distribution of exchangeable K and Mg and with the intention to develop models that regionalize the point observations using digital terrain data as explanatory variables. Our results suggest that topography and vegetation do not control the spatial distribution of the selected soil chemical properties at a landscape scale and lithology is important to some degree. Exchangeable K is distributed equally across the study area indicating that other than landscape processes, e.g. biogeochemical processes, are responsible for its spatial distribution. Lithology contributes to the spatial variation of exchangeable Mg but controlling variables could not be detected. The spatial variation of soil total K and Mg is mainly influenced by lithology.
A hydrochemical approach to quantify the role of return flow in a surface flow-dominated catchment
(2017)
Stormflow generation in headwater catchments dominated by subsurface flow has been studied extensively, yet catchments dominated by surface flow have received less attention. We addressed this by testing whether stormflow chemistry is controlled by either (a) the event-water signature of overland flow, or (b) the pre-event water signature of return flow. We used a high-resolution hydrochemical data set of stormflow and end-members of multiple storms in an end-member mixing analysis to determine the number of end-members needed to explain stormflow, characterize and identify potential end-members, calculate their contributions to stormflow, and develop a conceptual model of stormflow. The arrangement and relative positioning of end-members in stormflow mixing space suggest that saturation excess overland flow (26-48%) and return flow from two different subsurface storage pools (17-53%) are both similarly important for stormflow. These results suggest that pipes and fractures are important flow paths to rapidly release stored water and highlight the value of within-event resolution hydrochemical data to assess the full range and dynamics of flow paths.
The expansion of soybean cultivation into the Amazon in Brazil has potential hydrological effects at local to regional scales. To determine the impacts of soybean agriculture on hydrology, a comparison of net precipitation (throughfall, stemflow) in undisturbed tropical forest and soybean fields on the southern edge of the Amazon Basin in the state of Mato Grosso is needed. This study measured throughfall with troughs and stemflow with collar collectors during two rainy seasons. The results showed that in forest 91.6% of rainfall was collected as throughfall and 0.3% as stemflow, while in soybean fields with two-month old plants, 46.2% of rainfall was collected as throughfall and 9.0% as stemflow. Hence, interception of precipitation in soybean fields was far greater than in intact forests. Differences in throughfall, stemflow and net precipitation were found to be mainly associated with differences in plant structure and stem density in transitional forest and soybean cropland. Because rainfall interception in soybean fields is higher than previously believed and because both the area of cropland and the frequency of crop cycles (double cropping) are increasing rapidly, interception needs to be reconsidered in regional water balance models when consequences of land cover changes are analyzed in the Amazon soybean frontier region. Based on the continued expansion of soybean fields across the landscape and the finding that net precipitation is lower in soy agriculture, a reduction in water availability in the long term can be assumed.
This study investigates spatial patterns of Ks and tests the hypothesis of whether structural variance emerges from noise with increasing sampling precision. We analyzed point measurements of Ks along independent transects at sampling intervals of 25, 10, 1 and 0.25 m. The field area is a tropical rainforest catena (i.e. toposequence) characterized by systematic downslope changes in soil properties including color (red to yellow), mineralogy (kaolinite- illite to kaolinite) and texture (sandy clay to sand). Independent tramsects spanning the entire catena at lag intervals of 25 and 10 in reveal little to no spatial patterns in Ks; i.e. scatter plots are noisy and lack apparent spatial trends, and semivariograms suggest little to no autocorrelation in Ks. As sampling precision is increased (h = 1 and 0.25 m), spatial patterns emerge in Ks for the downslope areas, in which distinctive hydraulic boundaries in Ks correlate with relatively small-scale, topography-controlled soils with coarse textures (greater than or equal to 80% sand). For these areas, semivariograms of Ks and those of %sand and %clay exhibit similar spatial structure characterized by small nugget variances and large ranges, and nugget variance is reduced as sampling precision increases from 1 to 0.25 m. In the upslope, clay-rich locations along this toposequence, Ks exhibits few spatial patterns, irrespective of sampling scale. For these locations, scatter plots are noisy without apparent spatial trends, and semivariograms show almost complete nugget variance, suggesting little to no correlation in this hydraulic parameter at any scale. This study suggests that in the absence of coarse textures (greater than or equal to 80% sand), there is little predictability in Ks, even at sampling intervals of 0.25 m. We believe this lack of spatial structure is due to a predominance of small-scale processes such as biological activity that largely control Ks in this forested setting. (C) 2003 Elsevier B.V. All rights reserved
Nitrogen transformations in flowpaths leading from soils to streams in Amazon forest and pasture
(2009)
Phosphorus availability is commonly assumed to limit productivity in lowland tropical rainforests, yet there is relatively little information on the chemical forms of soil phosphorus in such ecosystems. We used the Hedley sequential fractionation scheme to assess phosphorus chemistry in five soils supporting tropical rainforest on Barro Colorado Island, Republic of Panama. The soils represented a range of orders (Inceptisols, Alfisols, and Oxisols) formed on contrasting geological substrates and topography, but under uniform climate and vegetation. Total phosphorus in surface horizons ranged between 315 and 1114 mg P kg(-1), being lowest on a soil derived from marine sediments and highest on soils derived from andesite. The majority of the phosphorus occurred in recalcitrant forms, although between 14% and 39% occurred as organic phosphorus. Readily-available phosphate, as extracted by anion-exchange membranes, occurred in small concentrations (4-13 mg P kg(-1)), although labile phosphorus, defined as phosphate extracted by anion-exchange membrane plus inorganic and organic phosphorus extracted by 0.5 M NaHCO3, accounted for between 4.7% and 11.4% of the total soil phosphorus. Our results indicate a strong control of geology and topography on soil phosphorus in tropical rainforests, which may have important implications for understanding the diversity and distribution of plant species in such ecosystems. Further, some of the most common soils on Barro Colorado Island, including those on the 50 ha forest dynamics plot, are rich in phosphorus despite their relatively advanced stage of pedogenesis.
The topography of first-order catchments in a region of western Amazonia was found to exhibit distinctive, recurrent features: a steep, straight lower side slope, a flat or nearly flat terrace at an intermediate elevation between valley floor and interfluve, and an upper side slope connecting interfluve and intermediate terrace. A detailed survey of soil-saturated hydraulic conductivity (K sat)-depth relationships, involving 740 undisturbed soil cores, was conducted in a 0.75-ha first-order catchment. The sampling approach was stratified with respect to the above slope units. Exploratory data analysis suggested fourth-root transformation of batches from the 0–0.1 m depth interval, log transformation of batches from the subsequent 0.1 m depth increments, and the use of robust estimators of location and scale. The K sat of the steep lower side slope decreased from 46 to 0.1 mm/h over the overall sampling depth of 0.4 m. The corresponding decrease was from 46 to 0.1 mm/h on the intermediate terrace, from 335 to 0.01 mm/h on the upper side slope, and from 550 to 0.015 mm/h on the interfluve. A depthwise comparison of these slope units led to the formulation of several hypotheses concerning the link between K sat and topography.
Rainfall erosivities as defined by the R factor from the universal soil loss equation were determined for all events during a two-year period at the station La Cuenca in western Amazonia. Three methods based on a power relationship between rainfall amount and erosivity were then applied to estimate event and daily rainfall erosivities from the respective rainfall amounts. A test of the resulting regression equations against an independent data set proved all three methods equally adequate in predicting rainfall erosivity from daily rainfall amount. We recommend the Richardson model for testing in the Amazon Basin, and its use with the coefficient from La Cuenca in western Amazonia.
Throughfall measurements were made under primary terra firme rainforest in the Rio Pichis valley, in the Upper Amazon Basin of Peru. Based on 214 precipitation events over nearly 18 months, throughfall was estimated to be 83.1±8.8% of gross precipitation. Regression analysis of all events revealed that gross precipitation is the only significant explanatory variable; the use of one-burst events does not significantly improve the regression relationship. Gross precipitation is, however, a poor predictor of throughfall for small rainfall events. The two forest structure parameters, canopy capacity, S, and free throughfall coefficient, p, were determined to be 1.3±0.2 mm and 0.32±0.18 mm. Rainfall intensity was found to influence these parameters. New methods which attempt to minimize the influence of meteorologic variables are used to estimate the potential values of these canopy parameters.
Chemical fingerprints of hydrological compartments and flow paths at La Cuenca, western Amazonia
(1995)
A forested first-order catchment in western Amazonia was monitored for 2 years to determine the chemical fingerprints of precipitation, throughfall, overland flow, pipe flow, soil water, groundwater, and streamflow. We used five tracers (hydrogen, calcium, magnesium, potassium, and silica) to distinguish “fast” flow paths mainly influenced by the biological subsystem from “slow” flow paths in the geochemical subsystem. The former comprise throughfall, overland flow, and pipe flow and are characterized by a high potassium/silica ratio; the latter are represented by soil water and groundwater, which have a low potassium/silica ratio. Soil water and groundwater differ with respect to calcium and magnesium. The groundwater-controlled streamflow chemistry is strongly modified by contributions from fast flow paths during precipitation events. The high potassium/silica ratio of these flow paths suggests that the storm flow response at La Cuenca is dominated by event water.
Previous hydrometric studies demonstrated the prevalence of overland flow as a hydrological pathway in the tropical rain forest catchment of South Creek, northeast Queensland. The purpose of this study was to consider this information in a mixing analysis with the aim of identifying sources of, and of estimating their contribution to, storm flow during two events in February 1993. K and acid-neutralizing capacity (ANC) were used as tracers because they provided the best separation of the potential sources, saturation overland flow, soil water from depths of 0.3, 0.6, and 1.2 m, and hillslope groundwater in a two-dimensional mixing plot. It was necessary to distinguish between saturation overland flow, generated at the soil surface and following unchanneled pathways, and overland flow in incised pathways. This latter type of overland flow was a mixture of saturation overland flow (event water) with high concentrations of K and a low ANC, soil water (preevent water) with low concentrations of K and a low ANC, and groundwater (preevent water) with low concentrations of K and a high ANC. The same sources explained the streamwater chemistry during the two events with strongly differing rainfall and antecedent moisture conditions. The contribution of saturation overland flow dominated the storm flow during the first, high-intensity, 178-mm event, while the contribution of soil water reached 50% during peak flow of the second, low-intensity, 44-mm event 5 days later. This latter result is remarkably similar to soil water contributions to storm flow in mountainous forested catchments of the southeastern United States. In terms of event and preevent water the storm flow hydrograph of the high-intensity event is dominated by event water and that of the low-intensity event by preevent water. This study highlights the problems of applying mixing analyses to overland flow-dominated catchments and soil environments with a poorly developed vertical chemical zonation and emphasizes the need for independent hydrometric information for a complete characterization of watershed hydrology and chemistry.
Earlier investigations at South Creek in northeastern Queensland established the importance of overland flow as a hydrologic pathway in this tropical rainforest environment. Since this pathway is ‘fast’, transmitting presumably ‘new’ water, its importance should be reflected in the stormflow chemistry of South Creek: the greater the volumentric contribution to the stormflow hydrograph, the more similarity between the chemical composition of streamwater and of overland flow is to be expected. Water samples were taken during two storm events in an ephemeral gully (gully A), an intermittent gully (gully B) and at the South Creek catchment outlet; additional spot checks were made in several poorly defined rills. The chemical composition of ‘old’ water was determined from 45 baseflow samples collected throughout February. The two events differed considerably in their magnitudes, intensities and antecedent moisture conditions. In both events, the stormflow chemistry in South Creek was characterized by a sharp decrease in Ca, Mg, Na, Si, Cl, EC, ANC, alkalinity and total inorganic carbon. pH remained nearly constant with discharge, whereas K increased sharply, as did sulfate in an ill-defined manner. In event 1, this South Creek stormflow pattern was closely matched by the pattern in gully A, implying a dominant contribution of ‘new’ water. This match was confirmed by the spot samples from rills. Gully B behaved like South Creek itself, but with a dampened ‘new’ water signal, indicating less overland flow generation in its subcatchment. In event 2, which occurred five days later, the initial ‘new’ water signal in gully A was rapidly overwhelmed by a different signal which is attributed to rapid drainage from a perched water table. This study shows that stormflow in this rainforest catchment consists predominantly of ‘new’ water which reaches the stream channel via ‘fast’ pathways. Where the ephemeral gullies delivering overland flow are incised deeply enough to intersect a perched water table, a delayed, ‘old’ water-like signal may be transmitted.
Influence of land-use change on near-surface hydrological processes : undisturbed forest to pasture
(2010)
Soil compaction that follows the clearing of tropical forest for cattle pasture is associated with lower soil hydraulic conductivity and increased frequency and volume of overland flow. We investigated the frequency of perched water tables, overland flow and stormflow in an Amazon forest and in an adjacent 25-year-old pasture cleared from the same forest. We compared the results with the frequencies of these phenomena estimated from comparisons of rainfall intensity and soil hydraulic conductivity. The frequency of perched water tables based on rainfall intensity and soil hydraulic conductivity was expected to double in pasture compared with forest. This corresponded closely with an approximate doubling of the frequency of stormflow and overland flow in pasture. In contrast, the stormflow volume in pasture increased 17-fold. This disproportional increase of stormflow resulted from overland flow generation over large areas of pasture, while overland flow generation in the forest was spatially limited and was observed only very near the stream channel. In both catchments, stormflow was generated by saturation excess because of perched water tables and near-surface groundwater levels. Stormflow was occasionally generated in the forest by rapid return flow from macropores, while slow return flow from a continuous perched water table was more common in the pasture. These results suggest that deforestation for pasture alters fundamental mechanisms of stormflow generation and may increase runoff volumes over wide regions of Amazonia.
Prolonged dry periods, and increasingly the generation of smoke and dust in partially-deforested regions, can influence the chemistry of rainfall and throughfall in moist tropical forests. We investigated rainfall and throughfall chemistry in a palm-rich open tropical rainforest in the southwestern Brazilian Amazon state of Rondonia, where precipitation averages 2300 mm year(-1) with a marked seasonal pattern, and where the fragmentation of remaining forest is severe. Covering the transition from dry to wet season (TDWS) and the wet season (WS) of 2004-2005, we sampled 42 rainfall events on event basis as well as 35 events on a within-event basis, and measured concentrations of DOC, Na+, K+, Ca2+, Mg2+, NH4+ , Cl-, SO42- , NO3- and pH in rainfall and throughfall. We found strong evidence of both seasonal and within-event solute rainfall concentration dynamics. Seasonal volume-weighted mean (VWMS) concentrations in rainfall of DOC, K+, Ca2+, Mg2+, NH4+ , SO42- and NO3- were significantly higher in the TDWS than the WS, while VWMS concentrations in throughfall were significantly higher for all solutes except DOC. Patterns were generally similar within rain events, with solute concentrations declining sharply during the first few millimeters of rainfall. Rainfall and throughfall chemistry dynamics appeared to be strongly influenced by forest and pasture burning and a regional atmosphere rich in aerosols at the end of the dry season. These seasonal and within-event patterns of rainfall and throughfall chemistry were stronger than those recorded in central Amazonia, where the dry season is less pronounced and where regional deforestation is less severe. Fragmentation and fire in Rondonia now appear to be altering the patterns in which solutes are delivered to remaining moist tropical forests.
The replacement of undisturbed tropical forest with cattle pasture has the potential to greatly modify the hydrology of small watersheds and the fluxes of solutes. We examined the fluxes of water, Cl-, NO3--N: SO42---S, NH4+-N, Na+, K+, Mg2+ and Ca2+ in different flow paths in similar to 1 ha catchments of undisturbed open tropical rainforest and a 20 year-old pasture established from forest in the southwestern Brazilian Amazon state of Rondonia. Storm flow discharge was 18% of incident rainfall in pasture, but only 1% in forest. Quickflow predominated over baseflow in both catchments and in both wet and dry seasons. In the pasture, groundwater and quickflow were important flow paths for the export of all solutes. In the forest, quickflow was important for NO3--N export, but all other solutes were exported primarily by groundwater outflow. Both catchments were sinks for SO42--S and Ca2+, and sources of Na+. The pasture catchment also lost K+ and Mg2+ because of higher overland flow frequency and volume and to cattle excrement. These results show that forest clearing dramatically influences small watershed hydrology by increasing quickflow and water export to streams. They also indicate that tropical forest watersheds are highly conservative for most solutes but that pastures continue to lose important cations even decades after deforestation and pasture establishment.
Disproportionate single-species contribution to canopy-soil nutrient flux in an Amazonian rainforest
(2012)
Rainfall, throughfall and stemflow were monitored on an event basis in an undisturbed open tropical rainforest with a large number of palm trees located in the southwestern Amazon basin of Brazil. Stemflow samples were collected from 24 trees with a diameter at breast height (DBH) > 5 cm, as well as eight young and four full-grown babassu palms (Attalea speciosa Mart.) for 5 weeks during the peak of the wet season. We calculated rainfall, throughfall and stemflow concentrations and fluxes of Na+, K+, Ca2+, Mg2+,, Cl-, SO42-, NO3- and H+ and stemflow volume-weighted mean concentrations and fluxes for three size classes of broadleaf trees and three size classes of palms. The concentrations of most solutes were higher in stemflow than in rainfall and increased with increasing tree and palm size. Concentration enrichments from rainfall to stemflow and throughfall were particularly high (81-fold) for NO3-. Stemflow fluxes of NO3- and H+ exceeded throughfall fluxes but stemflow fluxes of other solutes were less than throughfall fluxes. Stemflow solute fluxes to the forest soil were dominated by fluxes on babassu palms, which represented only 4% of total stem number and 10% of total basal area. For NO3-, stemflow contributed 51% of the total mass of nitrogen delivered to the forest floor (stemflow + throughfall) and represented more than a 2000-fold increase in NO3- flux compared what would have been delivered by rainfall alone on the equivalent area. Because these highly localized fluxes of both water and NO3- persist in time and space, they have the potential to affect patterns of soil moisture, microbial populations and other features of soil biogeochemistry conducive to the creation of hotspots for nitrogen leaching and denitrification, which could amount to an important fraction of total ecosystem fluxes. Because these hotspots occur over very small areas, they have likely gone undetected in previous studies and need to be considered as an important feature of the biogeochemistry of palm-rich tropical forest.
Streams on uniformly rainforest-covered, but lithologically very diverse Barro Colorado Island in central Panamd show remarkable differences in their runoff response to rainfall. This lithological diversity is reflected in equally diverse soilscapes, and our objective was to test the hypothesis that contrasting runoff responses derive from soilscape features that control the generation of overland flow. We determined the soil saturated hydraulic conductivity (K-s) of two neighboring, but hydrologically contrasting catchments (Lutz Creek with a flashy and Conrad Trail with a delayed response to rainfall), and quantified the spatial and temporal frequency of overland flow occurrence. The median K-s values at a depth of 12.5 cm are large enough to rule out Hortonian overland flow, but a marked decrease in K-s in Lutz Creek catchment at 30 cm suggests the formation of a perched water table and the generation saturation overland flow; the decrease in K-s in the Conrad Trail catchment is more gradual, and a perched water table is expected to form only at depths below 50 cm. In Lutz Creek, overland flow was generated frequently in time and space and regardless of topographic position, including near the interfluve, with very low thresholds of storm magnitude, duration, intensity and antecedent wetness, whereas in Conrad Trail, overland flow was generated much less frequently and then only locally. We conclude that soilscape features and microtopography are important controls of overland flow generation in these catchments. Our results contribute to the growing evidence that overland flow and forests are not a priori a contradiction in terms. (C) 2004 Elsevier B.V. All rights reserved