Refine
Has Fulltext
- no (70) (remove)
Year of publication
- 1997 (70) (remove)
Document Type
- Article (48)
- Doctoral Thesis (15)
- Monograph/Edited Volume (7)
Is part of the Bibliography
- yes (70)
Institute
- Institut für Chemie (70) (remove)
The influence of polyelectrolytes on structure formation in liquid crystalline Na-dodecylsulfate/decanol/water systems was investigated by means of small angle X-ray diffraction, rheology, NMR spectroscopy, and microscopy. By adding Na-polyacrylate (PAA) into the mesophase, the one-phase region is left and phenomena of phase separation into a solvent-rich and a polymer/surfactantrich phase occurs. By incoporating an anionic and cationic polyelectrolyte step by step the tendency of phase separation is increased drastically. The self-organization process can be regulated directly by varying the water content of the system. However, at a water content of 30% the properties of the resulting liquid crystal were changed drastically. X-ray diffraction shows a multitude of Bragg peaks, NMR shows a peak-splitting, and rheology shows a change from non-Newtonian to Newtonian-flow behavior. On the basis of the experimental results an ordered multilayer associate structure can be assumed.
Natur- und Kunststoffe
(1997)
Chemie : Stoffe, Reaktionen, Umwelt ; Ausgabe Mecklenburg-Vorpommern, Regelschule, 10, Lehrbuch
(1997)
NMR spectroscopic and theoretical structural analysis of 5,5-disubstituted hydantoins in solution
(1997)
13 C NMR Chemical shift calculations for some substituted pyridines - a comparative consideration
(1997)
Reactin of 2-(halogenomethyl)-quinoxalines and quinolines with hydroxybenzoic acids and their esters
(1997)
Study of the tautomerism by experimentally and theoretically estimated 13C and 15N chemical shifts
(1997)
Glas
(1997)
Stoffströme
(1997)
Erste Ergebnisse einer Fallstudie zur Stoffdynamik naturschutzrelevanter Böden der Döberitzer Heide
(1997)
Stoffströme und Textilien
(1997)
Chitin handbook
(1997)
Primärstoffwechsel, Shikimat- und Phenylpropan-Gruppe, Vitamine, Coenzyme, Pflanzeninhaltsstoffe
(1997)
Chitinase inhibitors
(1997)
NMR spectroscopic and theoretical structural analysis of 5,5-disubstituted hydantoins in solution
(1997)