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- 2020 (2795) (entfernen)
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- transfer (3)
- validity (3)
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- 11-mercaptoundecanoic acid (2)
- 19. Jahrhundert (2)
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- Russland (2)
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- Shakespeare (2)
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- Siberian tree line (2)
- Sicherheit (2)
- Simulated patients (2)
- Sklavenhandel (2)
- Sklaverei (2)
- Smpd1 (2)
- Social capital (2)
- Social origin (2)
- Soft Law (2)
- Solarzellen (2)
- Solidago canadensis (2)
- Solidago gigantea (2)
- Somatic (2)
- South Asia (2)
- South Korea (2)
- Soziale Herkunft (2)
- Sozialer Survey Österreich (2)
- Sozialkapital (2)
- Spaltsätze (2)
- Speed (2)
- Sprachtherapie (2)
- Sputum (2)
- Staatsgrenzen (2)
- Standardized patients (2)
- Staphylococcus aureus (2)
- Strain measurement (2)
- Stratigraphy (2)
- Studienabbruch (2)
- Studienerfolg (2)
- Subduction (2)
- Survey Research Methods (2)
- Sustainability (2)
- Switzerland (2)
- Südkorea (2)
- TAVI (2)
- TEM (2)
- Tableau Physique (2)
- Tacitus (2)
- Terminologie und Technologie der antiken Weberei (2)
- TerraceM (2)
- Textbooks (2)
- Thermal effects (2)
- Toll and Imd pathways (2)
- Transcriptome assembly (2)
- Transformation (2)
- Translation (2)
- Treatment pathways (2)
- UV radiation (2)
- UX (2)
- Ultrafast X-rays (2)
- Uncertainties (2)
- Union (2)
- Universidad Incca de Colombia (2)
- Unsicherheiten (2)
- Urbanization (2)
- Utopie (2)
- VIIRS DNB (2)
- Venom proteins (2)
- Verkhoyansk mountains (2)
- Verwaltung (2)
- Visual system (2)
- Vues des Cordillères (2)
- Vulnerabilität (2)
- Völkerrecht (2)
- Weather (2)
- Weberei (2)
- Weight (2)
- Weight bias internalization (2)
- West Africa (2)
- West Germany (2)
- Western Interior Basin (2)
- Western Qaidam Basin (2)
- Widerstandstraining (2)
- Wind (2)
- Wissensmanagement (2)
- X-ray absorption (2)
- X-ray emission (2)
- X-ray photoelectron spectroscopy (2)
- X-ray probe (2)
- XRF (2)
- Zweitveröffentlichung (2)
- absorption (2)
- academic leadership (2)
- academic-achievement (2)
- accountability (2)
- acid sphingomyelinase (2)
- acoustic variability (2)
- actin polymerization (2)
- action processing (2)
- activation (2)
- activator–inhibitor models (2)
- actuation (2)
- acute alcohol consumption (2)
- acute chronic workload ratio (2)
- acute coronary syndrome (2)
- acute kidney injury (2)
- adaptive force (2)
- addiction (2)
- adiponectin (2)
- adiposity (2)
- adjectives (2)
- adolescence (2)
- adsorption (2)
- aerobic power (2)
- affect (2)
- age (2)
- ageing (2)
- aggregation (2)
- aggression (2)
- agro-infiltration (2)
- airglow (2)
- alexithymia (2)
- alkylphospholipids (2)
- all-cause mortality (2)
- allometry (2)
- alphaherpesvirus (2)
- alternaria group (2)
- alternative rewards (2)
- alumni work (2)
- analytics (2)
- anchor peptides (2)
- ancient sedimentary DNA (2)
- animal and computational models (2)
- animal behavior (2)
- answer set programming (2)
- anthropogenic food subsidies (2)
- anthropometric measures (2)
- antimicrobial peptide (2)
- antonymy (2)
- anxiety (2)
- anxiety-like behavior (2)
- apis mellifera (2)
- apodemus-agrarius (2)
- apple (2)
- apple replant disease (2)
- approximation (2)
- aquatic ecosystems (2)
- aquatic fungi (2)
- aqueous dispersion (2)
- aqueous-solution (2)
- aquifer (2)
- architecture (2)
- area-based conservation (2)
- arthropod (2)
- articulation (2)
- artificial light (2)
- artificial muscles (2)
- assault (2)
- assembly processes (2)
- assembly rules (2)
- associations (2)
- astronomical calibration (2)
- astroparticle physics (2)
- atmospheric blocking (2)
- atomic force microscopy (AFM) (2)
- attitudes (2)
- attitudes toward intimate partner violence (2)
- autocorrelation (2)
- automatic processing (2)
- auxotrophy (2)
- avian personalities (2)
- axillary bud (2)
- azobenzene (2)
- balance (2)
- barbell velocity (2)
- base excision repair (incision activity) (2)
- batch process (2)
- bias (2)
- bibliometrics (2)
- bidirectional reflectance (2)
- bifurcation theory (2)
- biochemistry (2)
- biodegradable polymers (2)
- biodiversity facets (2)
- biofortification (2)
- biological invasions (2)
- biological maturation (2)
- biological soil crusts (2)
- biomarker (2)
- biomechanics (2)
- biorefineries (2)
- biostimulant (2)
- biotic filtering (2)
- biotin sulfoxide reductase (2)
- body image (2)
- body waves (2)
- body weight gain (2)
- bone mineral density (2)
- bone pathologies (2)
- borehole leakage (2)
- brain (2)
- branching (2)
- broadband and narrowband dimensions of behavior (2)
- bullying victimization (2)
- business (2)
- cadmium-free (2)
- calcium influx (2)
- calibration (2)
- cancer epidemiology (2)
- capacities (2)
- carbohydrate‐ based (2)
- carbon (2)
- carbon cycling (2)
- carbon dots (2)
- carbon-cycle (2)
- carbonaceous aerosols (2)
- carbonate (2)
- carotenoid biosynthesis (2)
- carotenoids (2)
- carrion ecology (2)
- carryover effects (2)
- cartography (2)
- catalysts (2)
- catchment (2)
- cell cycle (2)
- cell-based in vitro assay (2)
- cells (2)
- cellular bioimaging (2)
- cement (2)
- central fixation bias (2)
- central south island (2)
- ceramide (2)
- cesium lead halides (2)
- chains (2)
- channel (2)
- characteristics (2)
- charcoal (2)
- child abuse (2)
- chitosan (2)
- chlorophyll a (2)
- chloroplast (2)
- cholesterol (2)
- chromatin (2)
- chromatin regulation (2)
- chronology (AICC2012) (2)
- classical conditioning (2)
- classical reception (2)
- click chemistry (2)
- client preferences (2)
- climate change impacts (2)
- climate dynamics (2)
- climate networks (2)
- clonal complex (2)
- co-limitation (2)
- coagulation (2)
- coarticulation (2)
- coefficient (2)
- coffee by-products (2)
- cognition (2)
- cognitive-behavioral control (2)
- cognitive-control (2)
- collaborative consumption (2)
- college students (2)
- colonialism (2)
- colony viability (2)
- coloring agents (2)
- combat sport (2)
- common ground (2)
- common ownership (2)
- common‐garden experiment (2)
- communities (2)
- comparison (2)
- comparison of devices (2)
- complex networks (2)
- composites (2)
- composition (2)
- comprehension (2)
- computer-based training (2)
- concepts (2)
- concurrent training (2)
- conduct problems (2)
- confidence (2)
- conformational rearrangement (2)
- consequences (2)
- constraint-based modeling (2)
- consumptive resistance (2)
- continental lithosphere (2)
- continuity (2)
- continuous process (2)
- continuous time random walk (2)
- contract workers (2)
- contrast effect (2)
- conversational implicature (2)
- converting factor (2)
- cooperation (2)
- coordination (2)
- copper-related disorders (2)
- core PG1351 (2)
- cori cycle (2)
- coronary artery disease (2)
- coronary heart disease (2)
- corporate citizenship (2)
- corporate foresight (2)
- corporate social responsibility (2)
- cortisol (2)
- coupled surface (2)
- cow's milk (2)
- craving and relapse (2)
- critical solution temperature (2)
- crop diversity (2)
- cropping system (2)
- cross ownership (2)
- crust (2)
- cryptic species complex (2)
- crystal orientation (2)
- culture (2)
- cyanobacteria (2)
- cyanobacterial sucrose-phosphatase (2)
- cyber victimization (2)
- cyberbullying victimization (2)
- cysteine alkylation (2)
- dark triad (2)
- dark virus (2)
- data (2)
- data cleaning (2)
- data fusion (2)
- data matching (2)
- data preparation (2)
- data processing (2)
- data sharing (2)
- data wrangling (2)
- database (2)
- de novo genome assembly (2)
- decarbonization (2)
- decision-theory (2)
- decline (2)
- deep biosphere (2)
- deep-sea (2)
- deformation monitoring (2)
- dehydration (2)
- density (2)
- density functional theory (2)
- depressive-like behavior (2)
- derivation (2)
- derivational complexity (2)
- development (2)
- developmental dyscalculia (2)
- developmental dyslexia (2)
- developmental trajectories (2)
- dietary patterns (2)
- dietary restriction (2)
- diffraction (2)
- digital bathymetric model (2)
- digital health (2)
- digitales Lernen (2)
- digitalization (2)
- dimension independent bound (2)
- dimerization of 4-nitrothiophenol (2)
- disaster risk reduction (2)
- discrepancy principle (2)
- disease (2)
- diselenide (2)
- disorders (2)
- dispersal filtering (2)
- diversity climate (2)
- donor (2)
- drained lake basins (2)
- drought index (2)
- drug delivery system (2)
- dual GLP-1/glucagon receptor agonist (2)
- duplicate detection (2)
- dust (2)
- dust sources (2)
- dyadic coping (2)
- dynamic (2)
- dynamic capabilities (2)
- dynamical model (2)
- dynamical models (2)
- dyslexia (2)
- e-z reader (2)
- early eocene (2)
- early warning (2)
- earth system model (2)
- earthquake (2)
- earthquake source observations (2)
- eastern continental Asia (2)
- eco-hydrology (2)
- ecological novelty (2)
- ecological speciation (2)
- econometrics (2)
- ecosystem services provisioning (2)
- edge computing (2)
- effectiveness (2)
- effects (2)
- efficiency (2)
- efficient (2)
- electric fish (2)
- electron-transfer (2)
- electropolymerization (2)
- emission factors (2)
- emotion regulation (2)
- emotional difficulties (2)
- emotions (2)
- empirical mode decomposition (2)
- emulsion (2)
- end-stage kidney disease (2)
- endotoxin (2)
- energy (2)
- energy storage (2)
- enrichment experiments (2)
- ensemble and time averaged mean squared displacement (2)
- entity resolution (2)
- entropy production (2)
- enzyme (2)
- eocene thermal maximum (2)
- epigenetic variation (2)
- episodic memory (2)
- equatorial electrojet (2)
- equifinality (2)
- equine (2)
- erosion hotspots (2)
- error reduction (2)
- ethnic social capital (2)
- ethnic-racial identity (2)
- europe (2)
- european (2)
- evaluative study (2)
- evaporation (2)
- evaporites (2)
- event expectations (2)
- evidence (2)
- evolutionary (2)
- evolutionary ecology (2)
- excitonic materials (2)
- executive function (2)
- executive functions (2)
- exendin-4 (2)
- exercise intensity (2)
- exercise therapy (2)
- exhaustivity (2)
- existence (2)
- expanding medium (2)
- expectancies (2)
- experiences survey (2)
- experimental evidence (2)
- exploit (2)
- exploratory-behavior (2)
- exposed water ice (2)
- exposome (2)
- exposome‐ wide association study (2)
- expression patterns (2)
- external training load (2)
- externalization (2)
- extinction drivers (2)
- extinction event (2)
- extremal values (2)
- eye tracking (2)
- family farming (2)
- fastest first-passage time of N walkers (2)
- fault creep (2)
- feedback (2)
- feeding behaviour (2)
- ferroelectric polymers (2)
- fetal origins hypothesis (2)
- fiber actuators (2)
- field-aligned currents (2)
- filter (2)
- fine dining (2)
- firmware update (2)
- fitness (2)
- fitness consequences (2)
- fixation locations (2)
- fièvre jaune (2)
- flagellum (2)
- flat-slab subduction (2)
- floating mat (2)
- flood (2)
- flood recovery (2)
- flood risk (2)
- flooded grasslands (2)
- floodplains (2)
- fluctuations (2)
- fluid injection (2)
- fluorescence (2)
- fluorescence correlation spectroscopy (2)
- fluorinated organic spacer (2)
- flux tracking (2)
- focus group (2)
- food frequency questionnaire (2)
- forage availability (2)
- forage gaps (2)
- foraging (2)
- force (2)
- force profiles (2)
- forebrain (2)
- foreign language (2)
- formal verification (2)
- formate dehydrogenase (2)
- freshwater (2)
- freshwater heterotrophic bacteria (2)
- frictional properties (2)
- fsQCA (2)
- functional richness (2)
- functionalization (2)
- gait (2)
- gait analysis (2)
- galaxies (2)
- galaxies: high-redshift (2)
- gallbladder cancer (2)
- gamma rays: general (2)
- gamma-rays: general (2)
- gas phase electron spectroscopy (2)
- gate effect (2)
- gender stereotype trait (2)
- gene delivery (2)
- gene expression (2)
- generalized dissimilarity modelling (2)
- genetic differentiation (2)
- genetic diversity (2)
- genetic programming (2)
- genome-wide association (2)
- genotype (2)
- geochronology (2)
- geographic distribution (2)
- gestural organization (2)
- glacial maximum (2)
- global datasets (2)
- global mean temperature (2)
- global monsoon (2)
- global surface warming (2)
- global warming (2)
- global warming levels (2)
- glucocorticoid receptor (2)
- glycogen (2)
- gold nanoparticle assembly (2)
- government (2)
- gradient boosting (2)
- gradient flow (2)
- grafted polymers (2)
- grain-size distribution (2)
- granulite (2)
- graph transformation systems (2)
- green polymers (2)
- greenland shelf (2)
- grief (2)
- ground-motion modelling (2)
- groundwater inflow (2)
- groundwater vulnerability (2)
- growth restriction (2)
- gulf coastal plain (2)
- gwas (2)
- habit formation (2)
- habituation (2)
- habituation-switch paradigm (2)
- handheld device (2)
- hanging wall (2)
- hate speech detection (2)
- haute cuisine (2)
- health anxiety (2)
- health risks (2)
- healthy diets (2)
- heart failure (2)
- heat stress (2)
- heat stress memory (2)
- heat-stress (2)
- heavy precipitation (2)
- heme (2)
- hemoglobin amount (2)
- heroism (2)
- heterojunction silicon solar cells (2)
- heuristics (2)
- hierarchy-of-hypotheses approach (2)
- high dimensional (2)
- high gastronomy (2)
- high-resolution record (2)
- higher education management (2)
- high‐risk drinking (2)
- holocene (2)
- honey bees (2)
- hormones (2)
- host adaptation (2)
- household analysis (2)
- hsp70 (2)
- human endotoxemia (2)
- human motion (2)
- human nutrition (2)
- human physical conditioning (2)
- human values (2)
- human-robot interaction (2)
- hybrid modelling (2)
- hydrological drought (2)
- hydrological models (2)
- hydrological signatures (2)
- hydroxyl-functional poly(2-vinyl pyridine) (2)
- hyperactivity (2)
- hyperbolic tilings (2)
- hyperthermia (2)
- ice absorption features (2)
- ice sheet (2)
- ideal-observer model (2)
- identifying influential nodes (2)
- identity (2)
- identity development (2)
- image processing (2)
- imaging (2)
- immune evasion cluster (2)
- immunogenicity (2)
- impact on pre-activated Achilles tendon (2)
- implicit bias (2)
- in-vitro-synthesis (2)
- indigene Völker (2)
- individual (2)
- individual effects (2)
- individual variation (2)
- induced pluripotent stem cells (2)
- industry 4.0 (2)
- inertial measurement unit (2)
- infant development (2)
- infant word learning (2)
- infection (2)
- infiltration (2)
- inflection (2)
- information (2)
- injury (2)
- injury risk (2)
- insights (2)
- institutional entrepreneurship (2)
- insulin receptor (2)
- insulin signaling (2)
- integrated flood risk management (2)
- integration (2)
- intelligence (2)
- intelligent tutoring system (ITS) (2)
- interaction (2)
- interactive technologies (2)
- interest (2)
- interfaces (2)
- interference control (2)
- internal load (2)
- internal structure (2)
- internalization (2)
- internalizing behavior (2)
- internationaler Handel (2)
- internet addiction (2)
- interpersonal relations (2)
- interstellar ice (2)
- intertextuality (2)
- invasibility (2)
- invasion success (2)
- ionic liquid (2)
- ionogel (2)
- island disharmony (2)
- island syndromes (2)
- isometric muscle action (2)
- isotopes (2)
- isotopic tiling theory (2)
- jasmonate (2)
- job (2)
- judgement accuracy (2)
- kernel density estimation (2)
- kettle hole (2)
- knowledge and movement (2)
- laboratory (2)
- lactate (2)
- lake Donggi Cona (2)
- lake drainage (2)
- lake periphyton (2)
- laminitis (2)
- land management (2)
- landing positions (2)
- landscape generator (2)
- landscape of fear (2)
- landscape transience (2)
- landslides (2)
- large-scale (2)
- last glacial maximum (2)
- last glacial period (2)
- late pleistocene (2)
- later health (2)
- le Patrimoine d’Alexander von Humboldt (2)
- learning factories (2)
- length measurements (2)
- level of personality functioning (2)
- leverage areas (2)
- levoglucosan (2)
- lifestyle (2)
- ligand exchange (2)
- light scattering (2)
- lignocellulosic biomass (2)
- line: profiles (2)
- linear sprint (2)
- lipidation (2)
- lipid–lipid interactions (2)
- lipoplexes (2)
- liquid-phase catalysis (2)
- liveness (2)
- localisation (2)
- location prediction algorithm (2)
- loci (2)
- logarithmic source condition (2)
- logistic regression (2)
- low (2)
- low-back pain (2)
- low-energy electrons (2)
- lower thermosphere (2)
- luminescence (2)
- lymphoma (2)
- magma-poor (2)
- maintenance (2)
- maintenance of genomic integrity (2)
- major depression (2)
- manual muscle testing (2)
- manuscrits (2)
- maps on surfaces (2)
- margins (2)
- marine terrace (2)
- mass (2)
- mass conservation (2)
- mass index (2)
- matching dependencies (2)
- mathematics (2)
- mathematics instruction (2)
- maximum and range (2)
- meal timing (2)
- mechanical strength (2)
- mechanical tendinous oscillations (2)
- mechanism (2)
- media (2)
- mediated delivery (2)
- medicine (2)
- melatonin (2)
- membrane biophysics (2)
- membrane fusion (2)
- membrane microdomains (2)
- membrane stabilization (2)
- mental disorders (2)
- mental number line (MNL) (2)
- mentalization (2)
- mercaptocarboxylic acids (2)
- mesenchymal stem cells (2)
- mesoscale (2)
- metabolomic (2)
- metabolomics (2)
- metagenome (2)
- metagenomic analysis (2)
- metal halide perovskites (2)
- metal species (2)
- metallic nanolattices (2)
- metaophiolite (2)
- meteoric 10Be (2)
- methane (2)
- methodology (2)
- methods: observational (2)
- microbial interactions (2)
- microcomputed tomography (2)
- microcontact printing (2)
- microcystin (2)
- micronutrients (2)
- microplastics (2)
- microsatellites (2)
- microscopy (2)
- middle adulthood (2)
- mild solution (2)
- minimal pairs (2)
- minority shareholdings (2)
- mitochondria (2)
- mixed methods (2)
- mobile eye-tracking (2)
- modified Landweber method (2)
- molecular architecture (2)
- molecular bottle brushes (2)
- molecular dynamics simulations (2)
- molecular phylogeny (2)
- molecular tracers (2)
- molecularly imprinted polymers (2)
- molybdenum (2)
- molybdopterin synthase (2)
- monomers (2)
- mood (2)
- morphological decomposition (2)
- morphological errors (2)
- motion capture (2)
- motor neurons (2)
- movement ecology (2)
- multi-slab (2)
- multidisciplinary pain treatment (2)
- multiplicative noise (2)
- multishell (2)
- multi‐ year flooding cycle (2)
- murchison meteorite (2)
- muscle oxygenation (2)
- muscle power (2)
- muscle strength (2)
- musicality (2)
- n-oxide reductase (2)
- narcissism (2)
- national multiplication training (2)
- native American ancestry (2)
- natural climate solutions (2)
- natural language processing (2)
- natural-selection (2)
- naturalism (2)
- nature conservation (2)
- necrobiome (2)
- negation (2)
- nested vulnerabilities (2)
- neurodegenerative diseases (2)
- neuroendocrine (2)
- neuromuscular diagnostics (2)
- neuroscience (2)
- neutron (2)
- newborns (2)
- news media (2)
- nightlights (2)
- nitrogen (2)
- nitrogen limitation (2)
- non-Gaussianity (2)
- non-radiative interface recombination (2)
- nonfullerene acceptors (2)
- nonlinear operator (2)
- nonlinear waves (2)
- nonstationarity (2)
- nonumiform background configuration (2)
- nouvelle cuisine (2)
- novel ecosystems (2)
- novel species (2)
- nucleus (2)
- numerical development (2)
- numerical model (2)
- numerical simulations (2)
- nutrient bioavailability (2)
- nutrient transport (2)
- nutritional characteristics (2)
- ocean acidification (2)
- ocean heat uptake (2)
- oligocene climate (2)
- one-carbon metabolism (2)
- open materials (2)
- orchard management (2)
- organic aerosols (2)
- organic dye pigments (2)
- organic photovoltaics (2)
- organic search (2)
- organic solar cell (2)
- organic–inorganic hybrid (2)
- origination (2)
- orogeny (2)
- osmotic-pressure (2)
- osteoporosis (2)
- other-race effect (2)
- overhead athlete (2)
- overhunting (2)
- overreaching (2)
- overtraining (2)
- overweight (2)
- oxidative stress tolerance (2)
- pacific oyster (2)
- palaeogenomics (2)
- paleoenvironmental records (2)
- paleosol sequence (2)
- parafoveal and foveal processing (2)
- paralinguistic features (2)
- parameterization (2)
- parameters (2)
- paraquat (2)
- parent (2)
- parent–child relationship (2)
- part 1 (2)
- passive microwave (2)
- patholinguistics (2)
- pathways (2)
- pattern formation (2)
- people (2)
- peptides markers (2)
- perfluorocarbon emulsion (2)
- perialpine lakes (2)
- periplasmic nitrate reductase (2)
- permafrost degradation (2)
- permafrost regions (2)
- permafrost thaw (2)
- permeability (2)
- permeability test (2)
- perpetration (2)
- personality-traits (2)
- perspective-taking (2)
- pervasive healthcare (2)
- phagocytosis (2)
- phase purity (2)
- phase transfer (2)
- phase transition (2)
- phenotypic phase plane (2)
- phonological development (2)
- phosphatidylserine (2)
- phosphorylation (2)
- photo-isomerization kinetics (2)
- photo-sensitive surfactant (2)
- photocatalysis (2)
- photocurrent generation (2)
- photon recycling (2)
- photostability (2)
- photovoltaics (2)
- physical activity (2)
- physical fitness (2)
- physical performance (2)
- physiology (2)
- pickering emulsion (2)
- piezoelectric polymers (2)
- planetary-waves (2)
- planets and satellites: atmospheres (2)
- plankton (2)
- plant Mediator (2)
- plant clonality (2)
- plant drinks (2)
- plant macrofossil data (2)
- plant naturalization (2)
- plant–soil feedback (2)
- plasma (2)
- plasma membrane (2)
- playa (2)
- polarization (2)
- politeness (2)
- political ideology (2)
- pollen records (2)
- pollution (2)
- poly (acrylic acid, sodium salt) (2)
- poly(ADP-ribosyl)ation (2)
- polyacrylamide (2)
- polydimethylsiloxane wrinkles (2)
- polymer amphiphile (2)
- polymer degradation (2)
- polymersomes (2)
- polypropylene (2)
- poly‐ ε ‐ caprolactone (2)
- poor literacy (2)
- population-specific risk marker (2)
- porous carbon materials (2)
- postural sway (2)
- potential-functions (2)
- power spectrum (2)
- practice (2)
- pre-service teachers (2)
- preactivation (2)
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Institut
- Institut für Biochemie und Biologie (250)
- Institut für Physik und Astronomie (246)
- Institut für Geowissenschaften (205)
- Institut für Chemie (153)
- Bürgerliches Recht (148)
- Historisches Institut (142)
- Department Psychologie (101)
- Institut für Umweltwissenschaften und Geographie (98)
- Institut für Mathematik (90)
- Institut für Ernährungswissenschaft (84)
Real-world scene perception is typically studied in the laboratory using static picture viewing with restrained head position. Consequently, the transfer of results obtained in this paradigm to real-word scenarios has been questioned. The advancement of mobile eye-trackers and the progress in image processing, however, permit a more natural experimental setup that, at the same time, maintains the high experimental control from the standard laboratory setting. We investigated eye movements while participants were standing in front of a projector screen and explored images under four specific task instructions. Eye movements were recorded with a mobile eye-tracking device and raw gaze data were transformed from head-centered into image-centered coordinates. We observed differences between tasks in temporal and spatial eye-movement parameters and found that the bias to fixate images near the center differed between tasks. Our results demonstrate that current mobile eye-tracking technology and a highly controlled design support the study of fine-scaled task dependencies in an experimental setting that permits more natural viewing behavior than the static picture viewing paradigm.
We present a new model of the geomagnetic field spanning the last 20 years and called Kalmag. Deriving from the assimilation of CHAMP and Swarm vector field measurements, it separates the different contributions to the observable field through parameterized prior covariance matrices. To make the inverse problem numerically feasible, it has been sequentialized in time through the combination of a Kalman filter and a smoothing algorithm. The model provides reliable estimates of past, present and future mean fields and associated uncertainties. The version presented here is an update of our IGRF candidates; the amount of assimilated data has been doubled and the considered time window has been extended from [2000.5, 2019.74] to [2000.5, 2020.33].
Initiation of subduction following the impingement of a hot buoyant mantle plume is one of the few scenarios that allow breaking the lithosphere and recycling a stagnant lid without requiring any preexisting weak zones. Here, we investigate factors controlling the number and shape of retreating subducting slabs formed by plume-lithosphere interaction. Using 3-D thermomechanical models we show that the deformation regime, which defines formation of single-slab or multi-slab subduction, depends on several parameters such as age of oceanic lithosphere, thickness of the crust and large-scale lithospheric extension rate. Our model results indicate that on present-day Earth multi-slab plume-induced subduction is initiated only if the oceanic lithosphere is relatively young (<30-40 Myr, but >10 Myr), and the crust has a typical thickness of 8 km. In turn, development of single-slab subduction is facilitated by older lithosphere and pre-imposed extensional stresses. In early Earth, plume-lithosphere interaction could have led to formation of either episodic short-lived circular subduction when the oceanic lithosphere was young or to multi-slab subduction when the lithosphere was old.
It has recently been demonstrated that the interaction of a mantle plume with sufficiently old oceanic lithosphere can initiate subduction. However, the existence of large lithospheric heterogeneities, such as a buoyant plateau, in proximity to a rising plume head may potentially hinder the formation of a new subduction zone. Here, we investigate this scenario by means of 3-D numerical thermomechanical modeling. We explore how plume-lithosphere interaction is affected by lithospheric age, relative location of plume head and plateau border, and the strength of the oceanic crust. Our numerical experiments suggest four different geodynamic regimes: (a) oceanic trench formation, (b) circular oceanic-plateau trench formation, (c) plateau trench formation, and (d) no trench formation. We show that regardless of the age and crustal strength of the oceanic lithosphere, subduction can initiate when the plume head is either below the plateau border or at a distance less than the plume radius from the plateau edge. Crustal heterogeneity facilitates subduction initiation of old oceanic lithosphere. High crustal strength hampers the formation of a new subduction zone when the plume head is located below a young lithosphere containing a thick and strong plateau. We suggest that plume-plateau interaction in the western margin of the Caribbean could have resulted in subduction initiation when the plume head impinged onto the oceanic lithosphere close to the border between plateau and oceanic crust.
Initiation of subduction following the impingement of a hot buoyant mantle plume is one of the few scenarios that allow breaking the lithosphere and recycling a stagnant lid without requiring any preexisting weak zones. Here, we investigate factors controlling the number and shape of retreating subducting slabs formed by plume-lithosphere interaction. Using 3-D thermomechanical models we show that the deformation regime, which defines formation of single-slab or multi-slab subduction, depends on several parameters such as age of oceanic lithosphere, thickness of the crust and large-scale lithospheric extension rate. Our model results indicate that on present-day Earth multi-slab plume-induced subduction is initiated only if the oceanic lithosphere is relatively young (<30-40 Myr, but >10 Myr), and the crust has a typical thickness of 8 km. In turn, development of single-slab subduction is facilitated by older lithosphere and pre-imposed extensional stresses. In early Earth, plume-lithosphere interaction could have led to formation of either episodic short-lived circular subduction when the oceanic lithosphere was young or to multi-slab subduction when the lithosphere was old.
The formation of the supercontinent Pangaea during the Permo-Triassic gave rise to an extreme monsoonal climate (often termed 'mega-monsoon') that has been documented by numerous palaeo-records. However, considerable debate exists about the role of orbital forcing in causing humid intervals in an otherwise arid climate. To shed new light on the forcing of monsoonal variability in subtropical Pangaea, this study focuses on sediment facies and colour variability of playa and alluvial fan deposits in an outcrop from the late Carnian (ca 225 Ma) in the southern Germanic Basin, south-western Germany. The sediments were deposited against a background of increasingly arid conditions following the humid Carnian Pluvial Event (ca 234 to 232 Ma). The ca 2 center dot 4 Myr long sedimentary succession studied shows a tripartite long-term evolution, starting with a distal mud-flat facies deposited under arid conditions. This phase was followed by a highly variable playa-lake environment that documents more humid conditions and finally a regression of the playa-lake due to a return of arid conditions. The red-green (a*) and lightness (L*) records show that this long-term variability was overprinted by alternating wet/dry cycles driven by orbital precession and ca 405 kyr eccentricity, without significant influence of obliquity. The absence of obliquity in this record indicates that high-latitude forcing played only a minor role in the southern Germanic Basin during the late Carnian. This is different from the subsequent Norian when high-latitude signals became more pronounced, potentially related to the northward drift of the Germanic Basin. The recurring pattern of pluvial events during the late Triassic demonstrates that orbital forcing, in particular eccentricity, stimulated the occurrence and intensity of wet phases. It also highlights the possibility that the Carnian Pluvial Event, although most likely triggered by enhanced volcanic activity, may also have been modified by an orbital stimulus.
Effects of social and individual school self-concepts on school engagement during adolescence
(2020)
While school self-concept is an important facilitator of a student's school engagement, previous studies rarely investigated whether it may also explain the change in students' school engagement during secondary school. Moreover, as social relations play an increasingly important role in adolescence, the current research distinguishes between the social and individual school self-concepts of a student. Whereas individual school self-concept uses the perception of a student's own ability in the past in order to estimate perceived current ability, social school self-concept refers to the comparison of a student's own perceived current ability with the current perceived abilities of others. We examined the role of students' individual and social school self-concepts in the development of behavioral and emotional school engagement during the period from grade 8 to grade 9. The sample consisted of 1088 German adolescents at the first measurement time (M-age = 13.70, SD = 0.53; 53.9% girls). The findings suggested a significant decline in both emotional and behavioral school engagement over the span of 1.5 years. In addition, social-but not individual-school self-concept was associated with the change in both dimensions of school engagement over time, such as it may intensify a student's decline in school engagement levels. This might be due to the fact that students with a high social school self-concept tend to increasingly emphasize competition and comparison and strive for high grades, which lowers students' school participation and identification in the long term.
Special issue
(2020)
The structure, formation and dynamics of both animate and inanimate matter on the nanoscale are a highly interdisciplinary field of rapidly emerging research engaging a broad community encompassing experimentalists, theorists, and technologists. It is relevant for a large variety of molecular and nanosystems of different origin and composition and concerns numerous phenomena originating from physics, chemistry, biology, or materials science. This Topical Issue presents a collection of original research papers devoted to different aspects of structure and dynamics on the nanoscale. Some of the contributions discuss specific applications of the research results in several modern technologies and in next generation medicine. Most of the works of this topical issue were reported at the Fifth International Conference on Dynamics of Systems on the Nanoscale (DySoN) - the premier forum for the presentation of cutting-edge research in this field that was held in Potsdam, Germany in October of 2018.
Thirteen N-butylpyridinium salts, including three monometallic [C4Py](2)[MCl4], nine bimetallic [C4Py](2)[(M1-xMxCl4)-M-a-Cl-b] and one trimetallic compound [C4Py](2)[(M1-y-zMyMz (c) Cl4)-M-a-M-b] (M=Co, Cu, Mn; x=0.25, 0.50 or 0.75 and y=z=0.33), were synthesized and their structure and thermal and electrochemical properties were studied. All compounds are ionic liquids (ILs) with melting points between 69 and 93 degrees C. X-ray diffraction proves that all ILs are isostructural. The conductivity at room temperature is between 10(-4) and 10(-8) S cm(-1). Some Cu-based ILs reach conductivities of 10(-2) S cm(-1), which is, however, probably due to IL dec. This correlates with the optical bandgap measurements indicating the formation of large bandgap semiconductors. At elevated temperatures approaching the melting points, the conductivities reach up to 1.47x10(-1) S cm(-1) at 70 degrees C. The electrochemical stability windows of the ILs are between 2.5 and 3.0 V.
Polyester-based shape-memory polymer actuators are multifunctional materials providing reversible macroscopic shape shifts as well as hydrolytic degradability. Here, the function-function interdependencies (between shape shifts and degradation behaviour) will determine actuation performance and its life time. In this work, glycolide units were incorporated in poly(epsilon-caprolactone) based actuator materials in order to achieve an accelerated hydrolytic degradation and to explore the function-function relationship. Three different oligo[(epsilon-caprolactone)-co-glycolide] copolymers (OCGs) with similar molecular weights (10.5 +/- 0.5 kg center dot mol(-1)) including a glycolide content of 8, 16, and 26 mol% (ratio 1:1:1 wt%) terminated with methacrylated moieties were crosslinked. The obtained actuators provided a broad melting transition in the range from 27 to 44 degrees C. The hydrolytic degradation of programmed OCG actuators (200% of elongation) resulted in a reduction of sample mass to 51 wt% within 21 days at pH = 7.4 and 40 degrees C. Degradation results in a decrease of T-m associated to the actuating units and increasing T-m associated to the skeleton forming units. The actuation capability decreased almost linear as function of time. After 11 days of hydrolytic degradation the shape-memory functionality was lost. Accordingly, a fast degradation behaviour as required, e.g., for actuator materials intended as implant material can be realized.
Unternehmensleitbilder sind zu einem beliebten strategischen Instrument geworden, dem eine motivationssteigernde Wirkung zugeschrieben wird. In KMU und Startups wird die Notwendigkeit von Leitbildern infrage gestellt, da entsprechende Inhalte in der persönlichen Führung vermittelt werden. Doch gerade die gemeinsame Erstellung eines Leitbilds kann dessen Akzeptanz sowie die Mitarbeitermotivation erhöhen. Entsprechend verfolgen wir einen explorativen Aktionsforschungsansatz und entwickelten in einem Workshop mit Mitarbeitern eines in Berlin ansässigen E-Commerce-Startups ein Leitbild. Eine Woche vor und nach dem Workshop wurde die Motivation der Mitarbeiter quantitativ mit Hinblick auf Engagement, Mitarbeiterzufriedenheit, Commitment und Kündigungsabsicht gemessen. Unsere Ergebnisse legen nahe, dass die gemeinsame Formulierung eines Leitbilds einen signifikanten positiven Effekt auf die Mitarbeitermotivation hat, insbesondere für Mitarbeiter mit einem niedrigen initialen Motivationsniveau.
Early numeracy is one of the strongest predictors for later success in school mathematics (e.g., Duncan et al., 2007). The main goal of first grade mathematics teachers should therefore be to provide learning opportunities that enable all students to develop sound early numeracy skills. Developmental models, or learning progressions, can describe how early numerical understanding typically develops. Assessments that are aligned to empirically validated learning progressions can support teachers to understand their students learning better and target instruction accordingly. To date, there have been no progression-based instruments made available for German teachers to monitor their students’ progress in the domain of early numeracy. This dissertation contributes to the design of such an instrument. The first study analysed the suitability of early numeracy assessments currently used in German primary schools at school entry to identify students’ individual starting points for subsequent progress monitoring. The second study described the development of progression-based items and investigated the items in regards to main test quality criteria, such as reliability, validity, and test fairness, to find a suitable item pool to build targeted tests. The third study described the construction of the progress monitoring measure, referred to as the learning progress assessment (LPA). The study investigated the extent to which the LPA was able to monitor students’ individual learning progress in early numeracy over time. The results of the first study indicated that current school entry assessments were not able to provide meaningful information about the students’ initial learning status. Thus, the MARKO-D test (Ricken, Fritz, & Balzer, 2013) was used to determine the students’ initial numerical understanding in the other two studies, because it has been shown to be an effective measure of conceptual numerical understanding (Fritz, Ehlert, & Leutner, 2018). Both studies provided promising evidence for the quality of the LPA and its ability to detect changes in numerical understanding over the course of first grade. The studies of this dissertation can be considered an important step in the process of designing an empirically validated instrument that supports teachers to monitor their students’ early numeracy development and to adjust their teaching accordingly to enhance school achievement.
We consider rough metrics on smooth manifolds and corresponding Laplacians induced by such metrics. We demonstrate that globally continuous heat kernels exist and are Holder continuous locally in space and time. This is done via local parabolic Harnack estimates for weak solutions of operators in divergence form with bounded measurable coefficients in weighted Sobolev spaces.
Glycosylphosphatidylinositols (GPIs) are highly complex glycolipids that serve as membrane anchors to a large variety of eukaryotic proteins. These are covalently attached to a group of peripheral proteins called GPI-anchored proteins (GPI-APs) through a post-translational modification in the endoplasmic reticulum. The GPI anchor is a unique structure composed of a glycan, with phospholipid tail at one end and a phosphoethanolamine linker at the other where the protein attaches. The glycan part of the GPI comprises a conserved pseudopentasaccharide core that could branch out to carry additional glycosyl or phosphoethanolamine units. GPI-APs are involved in a diverse range of cellular processes, few of which are signal transduction, protein trafficking, pathogenesis by protozoan parasites like the malaria- causing parasite Plasmodium falciparum. GPIs can also exist freely on the membrane surface without an attached protein such as those found in parasites like Toxoplasma gondii, the causative agent of Toxoplasmosis. These molecules are both structurally and functionally diverse, however, their structure-function relationship is still poorly understood. This is mainly because no clear picture exists regarding how the protein and the glycan arrange with respect to the lipid layer. Direct experimental evidence is rather scarce, due to which inconclusive pictures have emerged, especially regarding the orientation of GPIs and GPI-APs on membrane surfaces and the role of GPIs in membrane organization. It appears that computational modelling through molecular dynamics simulations would be a useful method to make progress. In this thesis, we attempt to explore characteristics of GPI anchors and GPI-APs embedded in lipid bilayers by constructing molecular models at two different resolutions – all-atom and coarse-grained.
First, we show how to construct a modular molecular model of GPIs and GPI-anchored proteins that can be readily extended to a broad variety of systems, addressing the micro-heterogeneity of GPIs. We do so by creating a hybrid link to which GPIs of diverse branching and lipid tails of varying saturation with their optimized force fields, GLYCAM06 and Lipid14 respectively, can be attached. Using microsecond simulations, we demonstrate that GPI prefers to “flop-down” on the membrane, thereby, strongly interacting with the lipid heads, over standing upright like a “lollipop”. Secondly, we extend the model of the GPI core to carry out a systematic study of the structural aspects of GPIs carrying different side chains (parasitic and human GPI variants) inserted in lipid bilayers. Our results demonstrate the importance of the side branch residues as these are the most accessible, and thereby, recognizable epitopes. This finding qualitatively agrees with experimental observations that highlight the role of the side branches in immunogenicity of GPIs and the specificity thereof. The overall flop-down orientation of the GPIs with respect to the bilayer surface presents the side chain residues to face the solvent. Upon attaching the green fluorescent protein (GFP) to the GPI, it is seen to lie in close proximity to the bilayer, interacting both with the lipid heads and glycan part of the GPI. However the orientation of GFP is sensitive to the type of GPI it is attached to. Finally, we construct a coarse-grained model of the GPI and GPI-anchored GFP using a modified version of the MARTINI force-field, using which the timescale is enhanced by at least an order of magnitude compared to the atomistic system.
This study provides a theoretical perspective on the conformational behavior of the GPI core and some of its branched variations in presence of lipid bilayers, as well as draws comparisons with experimental observations. Our modular atomistic model of GPI can be further employed to study GPIs of variable branching, and thereby, aid in designing future experiments especially in the area of vaccines and drug therapies. Our coarse-grained model can be used to study dynamic aspects of GPIs and GPI-APs w.r.t plasma membrane organization. Furthermore, the backmapping technique of converting coarse-grained trajectory back to the atomistic model would enable in-depth structural analysis with ample conformational sampling.
Coarse-grained molecular model for the Glycosylphosphatidylinositol anchor with and without protein
(2020)
Glycosylphosphatidylinositol (GPI) anchors are a unique class of complex glycolipids that anchor a great variety of proteins to the extracellular leaflet of plasma membranes of eukaryotic cells. These anchors can exist either with or without an attached protein called GPI-anchored protein (GPI-AP) both in vitro and in vivo. Although GPIs are known to participate in a broad range of cellular functions, it is to a large extent unknown how these are related to GPI structure and composition. Their conformational flexibility and microheterogeneity make it difficult to study them experimentally. Simplified atomistic models are amenable to all-atom computer simulations in small lipid bilayer patches but not suitable for studying their partitioning and trafficking in complex and heterogeneous membranes. Here, we present a coarse-grained model of the GPI anchor constructed with a modified version of the MARTINI force field that is suited for modeling carbohydrates, proteins, and lipids in an aqueous environment using MARTINI's polarizable water. The nonbonded interactions for sugars were reparametrized by calculating their partitioning free energies between polar and apolar phases. In addition, sugar-sugar interactions were optimized by adjusting the second virial coefficients of osmotic pressures for solutions of glucose, sucrose, and trehalose to match with experimental data. With respect to the conformational dynamics of GPI-anchored green fluorescent protein, the accessible time scales are now at least an order of magnitude larger than for the all-atom system. This is particularly important for fine-tuning the mutual interactions of lipids, carbohydrates, and amino acids when comparing to experimental results. We discuss the prospective use of the coarse-grained GPI model for studying protein-sorting and trafficking in membrane models.
Coarse-grained molecular model for the Glycosylphosphatidylinositol anchor with and without protein
(2020)
Glycosylphosphatidylinositol (GPI) anchors are a unique class of complex glycolipids that anchor a great variety of proteins to the extracellular leaflet of plasma membranes of eukaryotic cells. These anchors can exist either with or without an attached protein called GPI-anchored protein (GPI-AP) both in vitro and in vivo. Although GPIs are known to participate in a broad range of cellular functions, it is to a large extent unknown how these are related to GPI structure and composition. Their conformational flexibility and microheterogeneity make it difficult to study them experimentally. Simplified atomistic models are amenable to all-atom computer simulations in small lipid bilayer patches but not suitable for studying their partitioning and trafficking in complex and heterogeneous membranes. Here, we present a coarse-grained model of the GPI anchor constructed with a modified version of the MARTINI force field that is suited for modeling carbohydrates, proteins, and lipids in an aqueous environment using MARTINI's polarizable water. The nonbonded interactions for sugars were reparametrized by calculating their partitioning free energies between polar and apolar phases. In addition, sugar-sugar interactions were optimized by adjusting the second virial coefficients of osmotic pressures for solutions of glucose, sucrose, and trehalose to match with experimental data. With respect to the conformational dynamics of GPI-anchored green fluorescent protein, the accessible time scales are now at least an order of magnitude larger than for the all-atom system. This is particularly important for fine-tuning the mutual interactions of lipids, carbohydrates, and amino acids when comparing to experimental results. We discuss the prospective use of the coarse-grained GPI model for studying protein-sorting and trafficking in membrane models.
Die Auswirkungen der reformierten Psychotherapierichtlinie auf die ambulante Patentenversorgung
(2020)
Ziel der Studie Dieser Artikel untersucht, inwiefern sich die 2016 reformierte Richtlinie im Stadt-Land- sowie im Ost-West-Vergleich auf die ambulante psychotherapeutische Arbeit und Versorgung auswirkt.
Methodik Eine Onlineumfrage unter vertragsärztlich tätigen TherapeutInnen wurde durchgeführt. Die Fragen bezogen sich auf verschiedene Neuerungen in der Richtlinie.
Ergebnisse Unabhängig von der Region schätzten die Befragten ein, dass die Reform zu keiner verbesserten Versorgung führte.
Im Westen und in der Stadt tätige TherapeutInnen verwiesen PatientInnen nach der Sprechstunde öfter an andere Psychotherapiepraxen, im Osten und auf dem Land tätige hingegen öfter auf andere Hilfeangebote.
Schlussfolgerung Stärkere Anreize für die psychotherapeutische Tätigkeit auf dem Land sind zu schaffen. Abbaumaßnahmen der Ost-West-Ungleichheiten in der Versorgungsdichte scheinen nötig.
Ziel der Studie Dieser Artikel untersucht, inwiefern Aspekte der 2016 reformierten Psychotherapierichtlinie aus Sicht der drei Richtlinienverfahren für die praktische Arbeit unterschiedlich bewertet und genutzt werden. <br /> Methodik Eine Onlineumfrage wurde unter vertragsärztlich tätigen PsychotherapeutInnen (n = 987) durchgeführt. Die Fragen bezogen sich auf die unterschiedlichen Neuerungen in der Psychotherapierichtlinie.
Ergebnisse Signifikante Unterschiede wurden u. a. in der Nutzung der erweiterten Befugnisse sowie in der Abrechnung bestimmter Leistungen deutlich. Die Gruppen unterschieden sich auch in der Beantragung von Behandlungskontingenten. <br /> Schlussfolgerung Es scheint sinnvoll, Elemente der Richtlinienreform aus der Sicht des bevorzugten Behandlungsverfahrens zu evaluieren. Jene Aspekte scheinen bedeutsam, die sich auf die unmittelbare Arbeit mit den PatientInnen beziehen.
The origins and development of the arid and highly seasonal steppe-desert biome in Central Asia, the largest of its kind in the world, remain largely unconstrained by existing records. It is unclear how Cenozoic climatic, geological, and biological forces, acting at diverse spatial and temporal scales, shaped Central Asian ecosystems through time. Our synthesis shows that the Central Asian steppe-desert has existed since at least Eocene times but experienced no less than two regime shifts, one at the Eocene-Oligocene Transition and one in the mid-Miocene. These shifts separated three successive "stable states," each characterized by unique floral and faunal structures. Past responses to disturbance in the Asian steppe-desert imply that modern ecosystems are unlikely to recover their present structures and diversity if forced into a new regime. This is of concern for Asian steppes today, which are being modified for human use and lost to desertification at unprecedented rates.
Studies on the unsustainable use of groundwater resources are still considered incipient since it is frequently a poorly understood and managed, devalued and inadequately protected natural resource. Groundwater Recharge (GWR) is one of the most challenging elements to estimate since it can rarely be measured directly and cannot easily be derived from existing data. To overcome these limitations, many hydro(geo)logists have combined different approaches to estimate large-scale GWR, namely: remote sensing products, such as IMERG product; Water Budget Equation, also in combination with hydrological models, and; Geographic Information System (GIS), using estimation formulas. For intermediary-scale GWR estimation, there exist: Non-invasive Cosmic-Ray Neutron Sensing (CRNS); wireless networks from local soil probes; and soil hydrological models, such as HYDRUS. Accordingly, this PhD thesis aims, on the one hand, to demonstrate a GIS-based model coupling for estimating the GWR distribution on a large scale in tropical wet basins. On the other hand, it aims to use the time series from CRNS and invasive soil moisture probes to inversely calibrate the soil hydraulic properties, and based on this, estimating the intermediary-scale GWR using a soil hydrological model. For such purpose, two tropical wet basins located in a complex sedimentary aquifer in the coastal Northeast region of Brazil were selected. These are the João Pessoa Case Study Area and the Guaraíra Experimental Basin. Several satellite products in the first area were used as input to the GIS-based water budget equation model for estimating the water balance components and GWR in 2016 and 2017. In addition, the point-scale measurement and CRNS data were used in the second area to determine the soil hydraulic properties, and to estimate the GWR in the 2017-2018 and 2018-2019 hydrological years. The resulting values of GWR on large- and intermediary-scale were then compared and validated by the estimates obtained by groundwater table fluctuations. The GWR rates for IMERG- and rain-gauge-based scenarios showed similar coefficients between 68% and 89%, similar mean errors between 30% and 34%, and slightly-different bias between -13% and 11%. The results of GWR rates for soil probes and CRNS soil moisture scenarios ranged from -5.87 to -61.81 cm yr-1, which corresponds to 5% and 38% of the precipitation. The calculations of the mean GWR rates on large-scale, based on remote sensing data, and on intermediary-scale, based on CRNS data, held similar results for the Podzol soil type, namely 17.87% and 17% of the precipitation. It is then concluded that the proposed methodologies allowed for estimating realistically the GWR over the study areas, which can be a ground-breaking step towards improving the water management and decision-making in the Northeast of Brazil.
Background Recent shoulder injury prevention programs have utilized resistance exercises combined with different forms of instability, with the goal of eliciting functional adaptations and thereby reducing the risk of injury. However, it is still unknown how an unstable weight mass (UWM) affects the muscular activity of the shoulder stabilizers. Aim of the study was to assess neuromuscular activity of dynamic shoulder stabilizers under four conditions of stable and UWM during three shoulder exercises. It was hypothesized that a combined condition of weight with UWM would elicit greater activation due to the increased stabilization demand. Methods Sixteen participants (7 m/9 f) were included in this cross-sectional study and prepared with an EMG-setup for the: Mm. upper/lower trapezius (U.TA/L.TA), lateral deltoid (DE), latissimus dorsi (LD), serratus anterior (SA) and pectoralis major (PE). A maximal voluntary isometric contraction test (MVIC; 5 s.) was performed on an isokinetic dynamometer. Next, internal/external rotation (In/Ex), abduction/adduction (Ab/Ad) and diagonal flexion/extension (F/E) exercises (5 reps.) were performed with four custom-made-pipes representing different exercise conditions. First, the empty-pipe (P; 0.5 kg) and then, randomly ordered, water-filled-pipe (PW; 1 kg), weight-pipe (PG; 4.5 kg) and weight + water-filled-pipe (PWG; 4.5 kg), while EMG was recorded. Raw root-mean-square values (RMS) were normalized to MVIC (%MVIC). Differences between conditions for RMS%MVIC, scapular stabilizer (SR: U.TA/L.TA; U.TA/SA) and contraction (CR: concentric/eccentric) ratios were analyzed (paired t-test; p <= 0.05; Bonferroni adjusted alpha = 0.008). Results PWG showed significantly greater muscle activity for all exercises and all muscles except for PE compared to P and PW. Condition PG elicited muscular activity comparable to PWG (p > 0.008) with significantly lower activation of L.TA and SA in the In/Ex rotation. The SR ratio was significantly higher in PWG compared to P and PW. No significant differences were found for the CR ratio in all exercises and for all muscles. Conclusion Higher weight generated greater muscle activation whereas an UWM raised the neuromuscular activity, increasing the stabilization demands. Especially in the In/Ex rotation, an UWM increased the RMS%MVIC and SR ratio. This might improve training effects in shoulder prevention and rehabilitation programs.
Background Recent shoulder injury prevention programs have utilized resistance exercises combined with different forms of instability, with the goal of eliciting functional adaptations and thereby reducing the risk of injury. However, it is still unknown how an unstable weight mass (UWM) affects the muscular activity of the shoulder stabilizers. Aim of the study was to assess neuromuscular activity of dynamic shoulder stabilizers under four conditions of stable and UWM during three shoulder exercises. It was hypothesized that a combined condition of weight with UWM would elicit greater activation due to the increased stabilization demand. Methods Sixteen participants (7 m/9 f) were included in this cross-sectional study and prepared with an EMG-setup for the: Mm. upper/lower trapezius (U.TA/L.TA), lateral deltoid (DE), latissimus dorsi (LD), serratus anterior (SA) and pectoralis major (PE). A maximal voluntary isometric contraction test (MVIC; 5 s.) was performed on an isokinetic dynamometer. Next, internal/external rotation (In/Ex), abduction/adduction (Ab/Ad) and diagonal flexion/extension (F/E) exercises (5 reps.) were performed with four custom-made-pipes representing different exercise conditions. First, the empty-pipe (P; 0.5 kg) and then, randomly ordered, water-filled-pipe (PW; 1 kg), weight-pipe (PG; 4.5 kg) and weight + water-filled-pipe (PWG; 4.5 kg), while EMG was recorded. Raw root-mean-square values (RMS) were normalized to MVIC (%MVIC). Differences between conditions for RMS%MVIC, scapular stabilizer (SR: U.TA/L.TA; U.TA/SA) and contraction (CR: concentric/eccentric) ratios were analyzed (paired t-test; p <= 0.05; Bonferroni adjusted alpha = 0.008). Results PWG showed significantly greater muscle activity for all exercises and all muscles except for PE compared to P and PW. Condition PG elicited muscular activity comparable to PWG (p > 0.008) with significantly lower activation of L.TA and SA in the In/Ex rotation. The SR ratio was significantly higher in PWG compared to P and PW. No significant differences were found for the CR ratio in all exercises and for all muscles. Conclusion Higher weight generated greater muscle activation whereas an UWM raised the neuromuscular activity, increasing the stabilization demands. Especially in the In/Ex rotation, an UWM increased the RMS%MVIC and SR ratio. This might improve training effects in shoulder prevention and rehabilitation programs.
Bank filtration is considered to improve water quality through microbially mediated degradation of pollutants and is suitable for waterworks to increase their production. In particular, aquifer temperatures and oxygen supply have a great impact on many microbial processes. To investigate the temporal and spatial behavior of selected organic micropollutants during bank filtration in dependence of relevant biogeochemical conditions, we have set up a 2D reactive transport model using MODFLOW and PHT3D under the user interface ORTI3D. The considered 160-m-long transect ranges from the surface water to a groundwater extraction well of the adjacent waterworks. For this purpose, water levels, temperatures, and chemical parameters were regularly measured in the surface water and groundwater observation wells over one and a half years. To simulate the effect of seasonal temperature variations on microbial mediated degradation, we applied an empirical temperature factor, which yields a strong reduction of the degradation rate at groundwater temperatures below 11 degrees C. Except for acesulfame, the considered organic micropollutants are substantially degraded along their subsurface flow paths with maximum degradation rates in the range of 10(-6) mol L-1 s(-1). Preferential biodegradation of phenazone, diclofenac, and valsartan was found under oxic conditions, whereas carbamazepine and sulfamethoxazole were degraded under anoxic conditions. This study highlights the influence of seasonal variations in oxygen supply and temperature on the fate of organic micropollutants in surface water infiltrating into an aquifer.
In recent years, the increased interest in application areas such as social networks has resulted in a rising popularity of graph-based approaches for storing and processing large amounts of interconnected data. To extract useful information from the growing network structures, efficient querying techniques are required.
In this paper, we propose an approach for graph pattern matching that allows a uniform handling of arbitrary constraints over the query vertices. Our technique builds on a previously introduced matching algorithm, which takes concrete host graph information into account to dynamically adapt the employed search plan during query execution. The dynamic algorithm is combined with an existing static approach for search plan generation, resulting in a hybrid technique which we further extend by a more sophisticated handling of filtering effects caused by constraint checks. We evaluate the presented concepts empirically based on an implementation for our graph pattern matching tool, the Story Diagram Interpreter, with queries and data provided by the LDBC Social Network Benchmark. Our results suggest that the hybrid technique may improve search efficiency in several cases, and rarely reduces efficiency.
Consensify
(2020)
A standard practise in palaeogenome analysis is the conversion of mapped short read data into pseudohaploid sequences, frequently by selecting a single high-quality nucleotide at random from the stack of mapped reads. This controls for biases due to differential sequencing coverage, but it does not control for differential rates and types of sequencing error, which are frequently large and variable in datasets obtained from ancient samples. These errors have the potential to distort phylogenetic and population clustering analyses, and to mislead tests of admixture using D statistics. We introduce Consensify, a method for generating pseudohaploid sequences, which controls for biases resulting from differential sequencing coverage while greatly reducing error rates. The error correction is derived directly from the data itself, without the requirement for additional genomic resources or simplifying assumptions such as contemporaneous sampling. For phylogenetic and population clustering analysis, we find that Consensify is less affected by artefacts than methods based on single read sampling. For D statistics, Consensify is more resistant to false positives and appears to be less affected by biases resulting from different laboratory protocols than other frequently used methods. Although Consensify is developed with palaeogenomic data in mind, it is applicable for any low to medium coverage short read datasets. We predict that Consensify will be a useful tool for future studies of palaeogenomes.
Consensify
(2020)
A standard practise in palaeogenome analysis is the conversion of mapped short read data into pseudohaploid sequences, frequently by selecting a single high-quality nucleotide at random from the stack of mapped reads. This controls for biases due to differential sequencing coverage, but it does not control for differential rates and types of sequencing error, which are frequently large and variable in datasets obtained from ancient samples. These errors have the potential to distort phylogenetic and population clustering analyses, and to mislead tests of admixture using D statistics. We introduce Consensify, a method for generating pseudohaploid sequences, which controls for biases resulting from differential sequencing coverage while greatly reducing error rates. The error correction is derived directly from the data itself, without the requirement for additional genomic resources or simplifying assumptions such as contemporaneous sampling. For phylogenetic and population clustering analysis, we find that Consensify is less affected by artefacts than methods based on single read sampling. For D statistics, Consensify is more resistant to false positives and appears to be less affected by biases resulting from different laboratory protocols than other frequently used methods. Although Consensify is developed with palaeogenomic data in mind, it is applicable for any low to medium coverage short read datasets. We predict that Consensify will be a useful tool for future studies of palaeogenomes.
Homotherium was a genus of large-bodied scimitar-toothed cats, morphologically distinct from any extant felid species, that went extinct at the end of the Pleistocene [1-4]. They possessed large, saber-form serrated canine teeth, powerful forelimbs, a sloping back, and an enlarged optic bulb, all of which were key characteristics for predation on Pleistocene megafauna [5]. Previous mitochondrial DNA phylogenies suggested that it was a highly divergent sister lineage to all extant cat species [6-8]. However, mitochondrial phylogenies can be misled by hybridization [9], incomplete lineage sorting (ILS), or sex-biased dispersal patterns [10], which might be especially relevant for Homotherium since widespread mito-nuclear discrepancies have been uncovered in modern cats [10]. To examine the evolutionary history of Homotherium, we generated a -7x nuclear genome and a similar to 38x exome from H. latidens using shotgun and target-capture sequencing approaches. Phylogenetic analyses reveal Homotherium as highly divergent (similar to 22.5 Ma) from living cat species, with no detectable signs of gene flow. Comparative genomic analyses found signatures of positive selection in several genes, including those involved in vision, cognitive function, and energy consumption, putatively consistent with diurnal activity, well-developed social behavior, and cursorial hunting [5]. Finally, we uncover relatively high levels of genetic diversity, suggesting that Homotherium may have been more abundant than the limited fossil record suggests [3, 4, 11-14]. Our findings complement and extend previous inferences from both the fossil record and initial molecular studies, enhancing our understanding of the evolution and ecology of this remarkable lineage.
An effective strategy for combining variance- and distribution-based global sensitivity analysis
(2020)
We present a new strategy for performing global sensitivity analysis capable to estimate main and interaction effects from a generic sampling design. The new strategy is based on a meaningful combination of varianceand distribution-based approaches. The strategy is tested on four analytic functions and on a hydrological model. Results show that the analysis is consistent with the state-of-the-art Saltelli/Jansen formula but to better quantify the interaction effect between the input factors when the output distribution is skewed. Moreover, the estimation of the sensitivity indices is much more robust requiring a smaller number of simulations runs. Specific settings and alternative methods that can be integrated in the new strategy are also discussed. Overall, the strategy is considered as a new simple and effective tool for performing global sensitivity analysis that can be easily integrated in any environmental modelling framework.
The Southern Central Andes (33°-36°S) are an excellent natural laboratory to study orogenic deformation processes, where boundary conditions, such as the geometry of the subducted plate, impose an important control on the evolution of the orogen. On the other hand, the South American plate presents a series of heterogeneities that additionally impart control on the mode of deformation. This thesis aims to test the control of this last factor over the construction of the Cenozoic Andean orogenic system.
From the integration of surface and subsurface information in the southern area (34-36°S), the evolution of Andean deformation over the steeply dipping subduction segment was studied. A structural model was developed evaluating the stress state from the Miocene to the present-day and its influence in the migration of magmatic fluids and hydrocarbons. Based on these data, together with the data generated by other researchers in the northern zone of the study area (33-34°S), geodynamic numerical modeling was performed to test the hypothesis of the decisive role of upper-plate heterogeneities in the Andean evolution. Geodynamic codes (LAPEX-2D and ASPECT) which simulate the behavior of materials with elasto-visco-plastic rheologies under deformation, were used. The model results suggest that upper-plate contractional deformation is significantly controlled by the strength of the lithosphere, which is defined by the composition of the upper and lower crust, and by the proportion of lithospheric mantle, which in turn is determined by previous tectonic events. In addition, the previous regional tectono-magmatic events also defined the composition of the crust and its geometry, which is another factor that controls the localization of deformation. Accordingly, with more felsic lower crustal composition, the deformation follows a pure-shear mode, while more mafic compositions induce a simple-shear deformation mode. On the other hand, it was observed that initial lithospheric thickness may fundamentally control the location of deformation, with zones characterized by thin lithosphere are prone to concentrate it. Finally, it was found that an asymmetric lithosphere-astenosphere boundary resulting from corner flow in the mantle wedge of the eastward-directed subduction zone tends to generate east-vergent detachments.
Geopolitical shifts and the changing significance of borders in the EU's neighbourhood are usually understood as a matter of international power politics. Factors that accompany geopolitical impact on borders, such as media coverage of geopolitical change, often appear as secondary or irrelevant. However the recent Ukraine conflict revealed the contrary as pro-EU attitudes were strongly supported by 'western' media. Therefore this paper seeks to clarify the role of news media in creating perspectives and attitudes on geopolitical shifts and the significance of European borders. Empirical evidence on the coverage of the evolving Ukraine crisis by German news sources portrays the media as promoters of biased framings and imaginaries which suggest that the EU be a potential conflict party in the newly evolving geostrategic confrontation in its eastern neighbourhood. The findings indicate that during critical periods of the Ukraine crisis media reports combined rising euphoria about Europe and 'the West', as defenders of the 'good cause', with excessive moral polarising and the discursive normalisation of a rhetoric of escalation. Imaginaries of a bipolar world (The West against Russia) and a new Cold War prepared the ground for a new understanding of European borders and neighbourhood relations as being manipulable at will.
Lanthanide resonance energy transfer (LRET) was used to investigate the motion of dopant ions during the synthesis of core-shell-shell-nanocrystals (NCs) that are frequently used as frequency upconversion materials. Reaction conditions (temperature, solvent) as well as lattice composition and precursors were adapted from a typical hydrothermal synthesis approach used to obtain upconversion nanoparticles (UCNPs). Instead of adding the lanthanide ions Yb3+/Er3+ as the sensitizer/activator couple, Eu3+/Nd3+ as the donor/acceptor were added as the LRET pair to the outer shell (Eu-3) and the core (Nd-3). By tailoring the thickness of the insulation shell ("middle shell"), the expected distance between the donor and the acceptor was increased beyond 2 R-0, a distance for which no LRET is expected. The successful synthesis of core- shell-shell NCs with different thicknesses of the insulation layer was demonstrated by high-resolution transmission electron microscopy measurement. The incorporation of the Eu3+ ions into the NaYF4 lattice was investigated by high-resolution time-resolved luminescence measurements. Two major Eu3+ species (bulk and surface) were found. This was supported by steady-state as well as time-resolved luminescence data. Based on the luminescence decay kinetics, the intermixing of lanthanides during synthesis of core- shell UCNPs was evaluated. The energy transfer between Eu3+ (donor) and Nd3+ (acceptor) ions was exploited to quantify the motion of the dopant ions. This investigation reveals the migration of Ln(3+) ions between different compatiments in core-shell NCs and affects the concept of using core-shell architectures to increase the efficiency of UCNPs. In order to obtain well-separated core and shell structures with different dopants, alternative concepts are needed.
Bioinspired confinement of upconversion nanoparticles for improved performance in aqueous solution
(2020)
The resonance energy transfer (RET) from NaYF4:Yb,Er upconverting nanoparticles (UNCPs) to a dye (5-carboxytetramethylrhodamine (TAMRA)) was investigated by photoluminescence experiments and microscale thermophoresis (MST). The dye was excited via RET from the UCNPs which was excited in the near-infrared (NIR). The change of the dye diffusion speed (free vs coupled) was investigated by MST. RET shows significant changes in the decay times of the dye as well as of the UCNPs. MST reveals significant changes in the diffusion speed. A unique amphiphilic coating polymer (customized mussel protein (CMP) polymer) for UCNP surface coating was used, which mimics blood protein adsorption and mussel food protein adhesion to transfer the UCNP into the aqueous phase and to allow surface functionalization. The CMP provides very good water dispersibility to the UCNPs and minimizes ligand exchange and subsequent UCNP aging reactions because of the interlinkage of the CMP on the UCNP surface. Moreover, CMP provides N-3-functional groups for dick chemistry-based functionalization demonstrated with the dye 5-carboxytetramethylrhodamine (TAMRA). This establishes the principle coupling scheme for suitable biomarkers such as antibodies. The CMP provides very stable aqueous UCNP dispersions that are storable up to 3 years in a fridge at 5 degrees C without dissolution or coagulation. The outstanding properties of CMP in shielding the UCNP from unwanted solvent effects is reflected in the distinct increase of the photoluminescence decay times after UCNP functionalization. The UCNP-to-TAMRA energy transfer is also spectroscopically investigated at low temperatures (4-200 K), revealing that one of the two green Er(III) emission bands contributes the major part to the energy transfer. The TAMRA fluorescence decay time increases by a factor of 9500 from 2.28 ns up to 22 mu s due to radiationless energy transfer from the UCNP after NIR excitation of the latter. This underlines the unique properties of CMP as a versatile capping ligand for distinctly improving the UCNPs' performance in aqueous solutions, for coupling of biomolecules, and for applications for in vitro and in vivo experiments using UCNPs as optical probes in life science applications.
Editorial
(2020)
Living in a world of plenty?
(2020)
Inequality in the distribution of economic wealth within populations has been rising steadily over the past century, having reached unprecedented highs in many Western societies. However, this development is not reflected in people’s perceptions of wealth inequality, as the public tends to underestimate it. Research suggests that inequality estimates are derived from personal reference groups, which, as we propose, are expanded by social network site (SNS) use. As content on SNSs frequently revolves around events of consumption, signaling enhanced overall population wealth, this study tests the hypothesis that SNS use distorts inequality perceptions downward, i.e., increases the perception of societal equality. Responses of 534 survey participants in the United States confirm that SNS use negatively predicts perceived inequality. The relationship is stronger the more SNS users perceive the content they encounter online as real, supporting the assumption that observing other people’s behavior online lowers estimates of nationwide wealth inequality. These findings provide novel insights on inequality misperceptions by suggesting individuals’ SNS use as a new predictor of perceived wealth inequality.
The P22 tailspike endorhamnosidase confers the high specificity of bacteriophage P22 for some serogroups of Salmonella differing only slightly in their O-antigen polysaccharide. We used several biophysical methods to study the binding and hydrolysis of O-antigen fragments of different lengths by P22 tailspike protein. O-Antigen saccharides of defined length labeled with fluorophors could be purified with higher resolution than previously possible. Small amounts of naturally occurring variations of 0antigen fragments missing the nonreducing terminal galactose could be used to determine the contribution of this part to the free energy of binding to be similar to 7 kJ/mol. We were able to show via several independent lines of evidence that an unproductive binding mode is highly favored in binding over all other possible binding modes leading to hydrolysis. This is true even under circumstances under which the O-antigen fragment is long enough to be cleaved efficiently by the enzyme. The high-affinity unproductive binding mode results in a strong self-competitive inhibition in addition to product inhibition observed for this system. Self-competitive inhibition is observed for all substrates that have a free reducing end rhamnose. Naturally occurring O-antigen, while still attached to the bacterial outer membrane, does not have a free reducing end and therefore does not perform self-competitive inhibition.
Wechselwirkung zwischen elektromagnetischer Strahlung und Stoff – Grundlagen der Spektroskopie
(2020)
Unter elektromagnetischer Strahlung versteht man eine Welle aus gekoppelten elektrischen und magnetischen Feldern. Stoffe, die dieser Welle ausgesetzt sind, können von ihr Energie aufnehmen. Dabei wechseln die Stoffe zwischen ihrem, der jeweiligen Temperatur entsprechenden energetischen Grundzustand G und einem energetisch angeregten Zustand A* (Abbildung 4.1).
Reaktionskinetik
(2020)
Bei der Untersuchung chemischer Reaktionen interessiert zunächst, welche Reaktionsprodukte aus gegebenen Ausgangsstoffen gebildet werden können. Wichtig sind weiterhin Angaben zum möglichen Grad der Umsetzung der Ausgangsstoffe und zur Energiebilanz einer Reaktion. Damit sind aber noch keine Aussagen über den zeitlichen Ablauf der Stoffumwandlung getroffen.
Elektrochemie
(2020)
Es war eine Reihe experimenteller Befunde, die zur Entwicklung dieses Teilgebietes der Physikalischen Chemie und auch zu seiner Unterteilung führte. Die Liste der Namen, die mit den Experimenten verknüpft sind, liest sich nicht nur wie eine Zeittafel der Geschichte der Elektrizitätslehre, sondern auch der Physikalischen Chemie selbst.
Chemische Thermodynamik
(2020)
Lösungen
(2020)
This work provides a necessary and sufficient condition for a symbolic dynamical system to admit a sequence of periodic approximations in the Hausdorff topology. The key result proved and applied here uses graphs that are called De Bruijn graphs, Rauzy graphs, or Anderson-Putnam complex, depending on the community. Combining this with a previous result, the present work justifies rigorously the accuracy and reliability of algorithmic methods used to compute numerically the spectra of a large class of self-adjoint operators. The so-called Hamiltonians describe the effective dynamic of a quantum particle in aperiodic media. No restrictions on the structure of these operators other than general regularity assumptions are imposed. In particular, nearest-neighbor correlation is not necessary. Examples for the Fibonacci and the Golay-Rudin-Shapiro sequences are explicitly provided illustrating this discussion. While the first sequence has been thoroughly studied by physicists and mathematicians alike, a shroud of mystery still surrounds the latter when it comes to spectral properties. In light of this, the present paper gives a new result here that might help uncovering a solution.
LetH be a Schrodinger operator defined on a noncompact Riemannianmanifold Omega, and let W is an element of L-infinity (Omega; R). Suppose that the operator H + W is critical in Omega, and let phi be the corresponding Agmon ground state. We prove that if u is a generalized eigenfunction ofH satisfying vertical bar u vertical bar <= C-phi in Omega for some constant C > 0, then the corresponding eigenvalue is in the spectrum of H. The conclusion also holds true if for some K is an element of Omega the operator H admits a positive solution in (Omega) over bar = Omega \ K, and vertical bar u vertical bar <= C psi in (Omega) over bar for some constant C > 0, where psi is a positive solution of minimal growth in a neighborhood of infinity in Omega. Under natural assumptions, this result holds also in the context of infinite graphs, and Dirichlet forms.
Porous three-dimensional (3D) scaffolds are promising treatment options in regenerative medicine. Supercritical and dense-phase fluid technologies provide an attractive alternative to solvent-based scaffold fabrication methods. In this work, we report on the fabrication of poly-etheresterurethane (PPDO-PCL) based porous scaffolds with tailorable pore size, porosity, and pore interconnectivity by using supercritical CO2(scCO(2)) fluid-foaming. The influence of the processing parameters such as soaking time, soaking temperature and depressurization on porosity, pore size, and interconnectivity of the foams were investigated. The average pore diameter could be varied between 100-800 mu m along with a porosity in the range from (19 +/- 3 to 61 +/- 6)% and interconnectivity of up to 82%. To demonstrate their applicability as scaffold materials, selected foams were sterilized via ethylene oxide sterilization. They showed negligible cytotoxicity in tests according to DIN EN ISO 10993-5 and 10993-12 using L929 cells. The study demonstrated that the pore size, porosity and the interconnectivity of this multi-phase semicrystalline polymer could be tailored by careful control of the processing parameters during the scCO(2)foaming process. In this way, PPDO-PCL scaffolds with high porosity and interconnectivity are potential candidate materials for regenerative treatment options.
Boronic ester bonds can be reversibly formed between phenylboronic acid (PBA) and triol moieties. Here, we aim at a glucose-induced shape-memory effect by implementing such bonds as temporary netpoints, which are cleavable by glucose and by minimizing the volume change upon stimulation by a porous cryogel structure. The polymer system consisted of a semi-interpenetrating network (semi-IPN) architecture, in which the triol moieties were part of the permanent network and the PBA moieties were located in the linear polymer diffused into the semi-IPN. In an alkaline medium (pH = 10), the swelling ratio was approximately 35, independent of C-glu varied between 0 and 300 mg/dL. In bending experiments, shape fixity R-f approximate to 80% and shape recovery R-r approximate to 100% from five programming/recovery cycles could be determined. R-r was a function of C-glu in the range from 0 to 300 mg/dL, which accords with the fluctuation range of C-glu in human blood. In this way, the shape-memory hydrogels could play a role in future diabetes treatment options.
Today’s focus on the 1930s as a time of radical politics paving the way for the apocalypse of the Second World War ignores the complexity of the decade’s cultural responses, especially those by British women writers who highlighted gender issues within their contemporary political climate. The decade’s literature is often understood to capture the political unrest, either narrating people’s chaotic movement or their paralysed shock. This book argues that 1930s novels collapse the distinction between movement and standstill and calls this phenomenon Dynamic Stasis. This Dynamic Stasis thematically and structurally informs the novels of Nancy Mitford, Stevie Smith, Rosamond Lehmann and Jean Rhys. By disrupting the oft-repeated cliché of the 1930s as the age of political extremes, gender politics and negotiations of femininity can emerge from the discursive periphery. This book therefore corrects a persistent gender blind spot, which opens up a (re)consideration of authors that have been overlooked in literary criticism of 1930s to this day.
In the present study, we investigated younger and older Persian preschoolers' response tendency and accuracy toward yes/no questions about a coloring activity. Overall, 107 three- to four-year-olds and five- to six-year-old children were asked positive and negative yes/no questions about a picture coloring activity. The questions focused on three question contents namely, actions, environment and person. As for children's response tendency, they showed a compliance tendency. That is, they provided yes and no responses to positively and negatively formed questions respectively. Children especially younger ones were more compliant toward positive questions and their tendency decreased by age. In addition, the results revealed children's highest rate of compliance tendency toward environment inquiries. Concerning response accuracy, the effects of age and question content were significant. Specifically, older children provided more accurate responses than their younger counterparts, especially to yes/no questions asked about the actions performed during the activity. The findings suggest that depending on the format and the content of yes/no questions younger and older children's response accuracy and tendency differ.
Industry 4.0
(2020)
Industry 4.0 has had a strong influence on the debate on the digitalization of industrial processes, despite being criticized for lacking a proper definition. However, Industry 4.0 might offer a huge chance to align the goals of a sustainable development with the ongoing digital transformation in industrial development. The main contribution of this paper is therefore twofold. We provide a de-facto definition of the concept "Industry 4.0" from a sociotechnical perspective based on its most often cited key features, as well as a thorough review of how far the concept of sustainability is incorporated in it.
SandBlocks
(2020)
Visuelle Programmiersprachen werden heutzutage zugunsten textueller Programmiersprachen nahezu nicht verwendet, obwohl visuelle Programmiersprachen einige Vorteile bieten. Diese reichen von der Vermeidung von Syntaxfehlern, über die Nutzung konkreter domänenspezifischer Notation bis hin zu besserer Lesbarkeit und Wartbarkeit des Programms. Trotzdem greifen professionelle Softwareentwickler nahezu ausschließlich auf textuelle Programmiersprachen zurück.
Damit Entwickler diese Vorteile visueller Programmiersprachen nutzen können, aber trotzdem nicht auf die ihnen bekannten textuellen Programmiersprachen verzichten müssen, gibt es die Idee, textuelle und visuelle Programmelemente gemeinsam in einer Programmiersprache nutzbar zu machen. Damit ist dem Entwickler überlassen wann und wie er visuelle Elemente in seinem Programmcode verwendet.
Diese Arbeit stellt das SandBlocks-Framework vor, das diese gemeinsame Nutzung visueller und textueller Programmelemente ermöglicht. Neben einer Auswertung visueller Programmiersprachen, zeigt es die technische Integration visueller Programmelemente in das Squeak/Smalltalk-System auf, gibt Einblicke in die Umsetzung und Verwendung in Live-Programmiersystemen und diskutiert ihre Verwendung in unterschiedlichen Domänen.
The synthesis of new phenanthr[9,10-e][1,3]oxazines was achieved by the direct coupling of 9-phenanthrol with cyclic imines in the modified aza-Friedel-Crafts reaction followed by the ring closure of the resulting bifunctional aminophenanthrols with formaldehyde. Aminophenanthrol-type Mannich bases were synthesised and transformed to phenanthr[9,10-e][1,3]oxazines via [4 + 2] cycloaddition. Detailed NMR structural analyses of the new polyheterocycles as well as conformational studies including Density Functional Theory (DFT) modelling were performed. The relative stability of ortho-quinone methides (o-QMs) was calculated, the geometries obtained were compared with the experimentally determined NMR structures, and thereby, the regioselectivity of the reactions has been assigned.
In the comment on "Varves of the Dead Sea sedimentary record." Quaternary Science Reviews 215 (Ben Dor et al., 2019): 173-184. by R. Bookman, two recently published papers are suggested to prove that the interpretation of the laminated sedimentary sequence of the Dead Sea, deposited mostly during MIS2 and Holocene pluvials, as annual deposits (i.e., varves) is wrong. In the following response, we delineate several lines of evidence which coalesce to demonstrate that based on the vast majority of evidence, including some of the evidence provided in the comment itself, the interpretation of these sediments as varves is the more likely scientific conclusion. We further discuss the evidence brought up in the comment and its irrelevance and lack of robustness for addressing the question under discussion.
Digital software platforms allow third parties to develop applications and thus extend their functionality. Platform owners provide platform boundary resources that allow for application development. For developers, platform integration, understood as the employment of platform resources, helps to realize application functionality effectively. Simultaneously, it requires integration effort and increases dependencies. Developers are interested to know whether integration contributes to success in hypercompetitive platform settings. While aspects of platform participation have been studied, research on a comprehensive notion of integration and related implications are missing. By proposing a platform integration model, this study supports a better understanding of integration. Concerning dynamics related to integration, effects were tested using information from over 82,000 Apple AppStore applications. Regression model analysis reveals that application success and customer satisfaction is positively influenced by platform integration. To achieve superior results, developers should address multiple aspects of integration, such as devices, data, the operating system, the marketplace as well as other applications, and provide updates. Finally, the study highlights the importance for all platform participants and their possibilities to employ integration as a strategic instrument.
Die Auswahl von Standardsoftware stellt viele Unternehmen vor Herausforderungen. Gerade im deutschen Mittelstand kommen vermehrt eigenentwickelte Individuallösungen zum Einsatz. Ent- sprechende Unternehmen sind daher nicht mit komplexen Soft- wareauswahlprojekten vertraut. Das breite Angebot an ERP-Systemen erschwert die Vergleichbarkeit der Lösungen und die zielgerichtete Auswahl des idealen Systems zusätzlich.
Digitale Plattformen
(2020)
Obwohl digitale Plattformen vornehmlich von Großunternehmen betrieben werden, bieten sie klein- und mittelständischen Unternehmen (KMU) Potenziale zur Verbreitung innovativer Technologien und für den Ausbau ihres Geschäftsmodells. Für die Umsetzung digitaler Plattformen stehen Unternehmen mehrere Strategien zur Verfügung. Der Beitrag vergleicht und bewertet grundlegende Strategien am Beispiel eines Maschinenbauunternehmens. Die Ergebnisse dienen als Grundlage für die Entscheidungsfindung von KMU.
Digitale Plattformen
(2020)
Obwohl digitale Plattformen vornehmlich von Großunternehmen betrieben werden, bieten sie klein- und mittelständischen Unternehmen (KMU) Potenziale zur Verbreitung innovativer Technologien und für den Ausbau ihres Geschäftsmodells. Für die Umsetzung digitaler Plattformen stehen Unternehmen mehrere Strategien zur Verfügung. Der Beitrag vergleicht und bewertet grundlegende Strategien am Beispiel eines Maschinenbauunternehmens. Die Ergebnisse dienen als Grundlage für die Entscheidungsfindung von KMU.
Digitale Plattformen finden zunehmende Verbreitung in unterschiedlichen Industriezweigen. Immer mehr Unternehmen sind an der Erschließung verbundener Potenziale für ihr Geschäft interessiert. Im Maschinen- und Anlagenbau wird die Vernetzung von Maschinen zunehmend ein Wettbewerbsfaktor für Hersteller. Der Einsatz digitaler Plattformen im Maschinen- und Anlagenbau bietet Herstellern Möglichkeiten zur gezielten Erweiterung des Geschäftsmodells. Für die Bereitstellung digitaler Plattformen können Unternehmen auf unterschiedliche Strategien zurückgreifen. Hierbei sollten Unternehmen die für ihre Konstellation geeignete Variante systematisch identifizieren, um die angestrebten Ziele zu erreichen. Die geeignete Strategie ist von einer Vielzahl an Faktoren abhängig. Als Grundlage für die Identifikation der geeigneten Strategie bietet dieser Beitrag eine systematische Untersuchung der möglichen Bereitstellungsstrategien für Unternehmen. Neben der theoretischen Systematisierung werden gegenwärtig genutzte Strategien am Beispiel des Maschinen- und Anlagenbaus in Deutschland vorgestellt. Zudem werden spezifische Merkmale, welche die Nutzung einer Strategie beeinflussen, als Ansatzpunkt für einen Strategieformulierungsprozess identifiziert. Im Maschinen- und Anlagenbau ist die Bereitstellung einer eigenen Plattform, insbesondere bei Großunternehmen vorherrschend. Die Strategien von KMU unterschieden sich von Großunternehmen.
#Wirtschaft – Niedersachsen
(2020)
Zufriedenheitsanalysen durch Patientenbefragungen, wie in diesem Fall der neu entwickele und getestet Fragebogen (HNO-PROM), haben drei Säulen. Es kann zum einen eine bessere Patientenbindung geschaffen werden, die Qualität kann gemessen, verglichen und optimiert werden und es kann ein Mitarbeiterleitfaden im Sinne einer „Corporate Identity“ erstellt werden, welcher konkrete Managementimplikationen im Sinne von Handlungsimplikationen enthält. Der Leitgedanke des Qualitätsmanagements ist die Patientenorientierung im Sinne der Patientenzentrierten Medizin. Hierbei sollen nicht nur Wünsche und Bedürfnisse des Patienten erfüllt werden, sondern vorallem auch die Zufriedenheit gemessen und geplant werden. Gleichzeit muss man in diesem Zusammenhang die Behandlung der Patienten als Dienstleistung verstehen und die größtmögliche Zufriedenheit des Patienten als primäres Ziel setzen. Dies führt zu einer Kundenbindung dadurch, dass Patienten sowohl eine gleichbleibende Qualität erwarten können als auch und auch weiche Faktoren ihren Wünschen entsprechen werden. Corporate Identity mit dem Ziel als Unternehmen einheitlich für die Werte und damit die Qualität zu stehen.. Dies ermöglicht, das Wohlbefinden in der Vorstellung der Patienten beginnen zu lassen und dadurch Vertrauen zu schaffen. Alle drei Säulen haben nicht nur die Patientenzufriedenheit zum Ziel, sondern in gleichem Maße auch die Positionierung einer Institution auf dem Gesundheitsmarkt und damit die Verbesserung der Kosten-Nutzen-Rechnung durch ein positives Outcome. Damit fördern Zufriedenheitsanalysen nicht nur die ökonomische Position einer Abteilung, sondern behalten gleichermaßen die ethischen Aspekte einer Arzt-Patienten-Beziehung im Blick.
Analysis of past and present stimulation projects reveals that the temporal evolution and growth of maximum observed moment magnitudes may be linked directly to the injected fluid volume and hydraulic energy. Overall evolution of seismic moment seems independent of the tectonic stress regime and is most likely governed by reservoir specific parameters, such as the preexisting structural inventory. Data suggest that magnitudes can grow either in a stable way, indicating the constant propagation of self-arrested ruptures, or unbound, for which the maximum magnitude is only limited by the size of tectonic faults and fault connectivity. Transition between the two states may occur at any time during injection or not at all. Monitoring and traffic light systems used during stimulations need to account for the possibility of unstable rupture propagation from the very beginning of injection by observing the entire seismicity evolution in near-real time and at high resolution for an immediate reaction in injection strategy.
Plain Language Summary Predicting and controlling the size of earthquakes caused by fluid injection is currently the major concern of many projects associated with geothermal energy production. Here, we analyze the magnitude and seismic moment evolution with injection parameters for prominent geothermal and scientific projects to date. Evolution of seismicity seems to be largely independent of the tectonic stress background and seemingly depends on reservoir specific characteristics. We find that the maximum observed magnitudes relate linearly to the injected volume or hydraulic energy. A linear relation suggests stable growth of induced ruptures, as predicted by current models, or rupture growth may no longer depend on the stimulated volume but on tectonics. A system may change between the two states during the course of fluid injection. Close-by and high-resolution monitoring of seismic and hydraulic parameters in near-real time may help identify these fundamental changes in ample time to change injection strategy and manage maximum magnitudes.
The steadily rising number of investor-State arbitration proceedings within the EU has triggered an extensive backlash and an increased questioning of the international investment law regime by different Member States as well as the EU Commission. This has resulted in the EU's assertion of control over the intra-EU investment regime by promoting the termination of bilateral intra-EU investment treaties (intra-EU BITs) and by opposing the jurisdiction of arbitral tribunals in intra-EU investor-State arbitration proceedings. Against the backdrop of the landmark Achmea decision of the European Court of Justice, the book offers an in depth analysis of the interplay of international investment law and the law of the European Union with regard to intra-EU investments, i.e. investments undertaken by an investor from one EU Member State within the territory of another EU Member State. It specifically analyses the conflict between the two investment protection regimes applicable within the EU with a particular emphasis on the compatibility of the international legal instruments with the law of the European Union. The book thereby addresses the more general question of the relationship between EU law and international law and offers a conceptual framework of intra-European investment protection based on the analysis of all intra-EU BITs, the Energy Charter Treaty and EU law, as well as the arbitral practice in over 180 intra-EU investor-State arbitration proceedings. Finally, the book develops possible solutions to reconcile the international legal standards of protection with the regionalized transnational law of the European Union
Missing out on life
(2020)
Mobile devices have become an integral part of everyday life due to
their portability. As literature shows, technology use is not only beneficial but also has dark sides, such as addiction. Parents face the need to balance perceived benefits and risks of children’s exposure to mobile technologies. However, no study has uncovered what kind of benefits and concerns parents consider when implementing technology-related rules. We built on qualitative responses of 300
parents of children aged two to thirteen to explore concerns about, and perceived benefits of children’s smartphone and tablet usage, as well as the rules parents have developed regarding technology use. Findings point to concerns regarding children’s development, as well as benefits for both children and parents, and ultimately to new insights about mobile technology mediation. These results provide practical guidance for parents, physicians and mobile industry
stakeholders, trying to ensure that children are acting responsibly with mobile technology.
Mittelhochdeutsch
(2020)
Mundart und Umgangssprache
(2020)
Pattdeutsch gehört nicht nur in den äußersten Norden Deutschlands, es gehört auch zum Land Brandenburg. Die niederdeutsche Mundart bereichert unsere Geschichte und unsere Kultur bis in die Gegenwart – ist Teil unserer Heimat. In der Fibel sind zeitgemäße und kindgerechte Texte für die Jüngsten zusammengestellt worden. Eingearbeitet sind regionale Varianten, speziell aus der Prignitz und der Uckermark. Zusätzlich erklären und erleichtern die zusammengestellten Regeln mit einem kleinen Wörterverzeichnis den Umgang mit der Sprache und ihrem Verständnis. Mit den hier vorliegenden Texten, Übungen und Spielen verknüpft mit einer durchgängigen schwungvollen Illustration, macht das Erlernen der Niederdeutschen Sprache wieder Spaß und vielleicht sogar neugierig. Damit kann die Fibel einen kleinen aber beachtlichen Teil in der Verantwortung für das Kulturerbe im Land Brandenburg übernehmen.
This article explores the structural diversity of intraministerial organization over time. Based on organization theory, it proposes a generic typology for intraministerial units applicable to any hierarchically structured government organization. We empirically investigate the critical case of the German federal bureaucracy. By classifying its subunits, we analyze the longitudinal development of structural differentiation and its correspondence to denominational variety. The data stem from a novel international dataset, covering all ministries between 1980 and 2015. We find that intraministerial structure differentiates over time, across and within ministries. A stable core of traditional Weberian structure is complemented by structurally innovative intraministerial units. We conclude that the German federal bureaucracy is more diverse than suggested in previous literature. Our findings indicate that less Weberian bureaucracies are at least as structurally diverse and that more reform-driven bureaucracies will have experienced at least as many changes in structural diversity.
This article explores the structural diversity of intraministerial organization over time. Based on organization theory, it proposes a generic typology for intraministerial units applicable to any hierarchically structured government organization. We empirically investigate the critical case of the German federal bureaucracy. By classifying its subunits, we analyze the longitudinal development of structural differentiation and its correspondence to denominational variety. The data stem from a novel international dataset, covering all ministries between 1980 and 2015. We find that intraministerial structure differentiates over time, across and within ministries. A stable core of traditional Weberian structure is complemented by structurally innovative intraministerial units. We conclude that the German federal bureaucracy is more diverse than suggested in previous literature. Our findings indicate that less Weberian bureaucracies are at least as structurally diverse and that more reform-driven bureaucracies will have experienced at least as many changes in structural diversity.
During the last decade, intracellular actin waves have attracted much attention due to their essential role in various cellular functions, ranging from motility to cytokinesis. Experimental methods have advanced significantly and can capture the dynamics of actin waves over a large range of spatio-temporal scales. However, the corresponding coarse-grained theory mostly avoids the full complexity of this multi-scale phenomenon. In this perspective, we focus on a minimal continuum model of activator–inhibitor type and highlight the qualitative role of mass conservation, which is typically overlooked. Specifically, our interest is to connect between the mathematical mechanisms of pattern formation in the presence of a large-scale mode, due to mass conservation, and distinct behaviors of actin waves.
During the last decade, intracellular actin waves have attracted much attention due to their essential role in various cellular functions, ranging from motility to cytokinesis. Experimental methods have advanced significantly and can capture the dynamics of actin waves over a large range of spatio-temporal scales. However, the corresponding coarse-grained theory mostly avoids the full complexity of this multi-scale phenomenon. In this perspective, we focus on a minimal continuum model of activator–inhibitor type and highlight the qualitative role of mass conservation, which is typically overlooked. Specifically, our interest is to connect between the mathematical mechanisms of pattern formation in the presence of a large-scale mode, due to mass conservation, and distinct behaviors of actin waves.
Clefts are well-studied as a construction which induces emphasis on its clefted referent. However, little is known about the distribution of different stylistic forms of it-cleft variants. We report on a corpus study mining data from Twitter, targeting sentences clefting a pronoun in English. We examine the following features: case and syntactic role of the clefted pronoun, contraction of the copula, choice of complementiser and use of emphasis markers. The results show systematic associations between these features. A further comparison between the Twitter dataset and data from iWeb, a corpus of general-use web language, shows significant differences in levels of emphasis and formality, positioning Twitter language in the middle of the conceptual orality spectrum.
Die Entnahme
(2020)
Die Fallstudie thematisiert ein zentrales Element des GmbH-Rechts, nämlich das Stammkapital und den Gesetzessatz: »Das zur Erhaltung des Stammkapitals erforderliche Vermögen der Gesellschaft darf an die Gesellschafter nicht ausgezahlt werden« (§ 30 Abs. 1 Satz 1 GmbHG). Wenn man diesen Satz versteht, hat man Kapitalgesellschaftsrecht verstanden. Im Folgenden wird diese Regel thematisiert, und es wird aufgezeigt, dass sich das Gebot der Stammkapitalerhaltung nicht nur an die Gesellschafter richtet, sondern auch an den Geschäftsführer. Die einen dürfen nicht nehmen, und der anderen darf nicht geben. Außerdem gibt es im GmbH-Recht noch weitere Rechtsschutzbehelfe zum Schutz des Gesellschaftsvermögens gegenüber Gesellschaftern und Organmitgliedern, die ebenfalls zur Sprache kommen.
Die Geschäftsidee
(2020)
In der Klausuraufgabe geht es vordergründig um das Bürgschaftsrecht und eine besondere Form der Bürgschaft, nämlich die Globalbürgschaft. Bei ihr bezieht sich die Bürgenhaftung nicht nur auf eine bestimmte einzelne Verbindlichkeit des Hauptschuldners, sondern auch auf künftig mögliche weitere Verbindlichkeiten; das ist schon bedenklich. Aber letzten Endes geht es wie in den meisten juristischen Klausuraufgaben nicht so sehr um diese oder jene Einzelfrage, sondern um einen größeren Zusammenhang, der sich hier auf das allgemeine Vertragsrecht erstreckt. Vom Schwierigkeitsgrad und Umfang her liegt die Aufgabe zwischen einer anspruchsvollen Zwischenprüfungs-Klausur und einer eher leichten Klausur im Rahmen der Fortgeschrittenenübung zum Erwerb des großen BGB-Scheins.
Die folgenden Fallstudien wollen Standardwissen zu klassischen Themen des allgemeinen Schuldrechts in Erinnerung rufen und vor allem die Systematik der Falllösung deutlich machen. Man darf sich nicht dazu verleiten lassen, alles auf einmal lösen zu wollen, sondern muss auf die einzelnen Ansprüche blicken und sich fragen: (1) Was wird aus dem primären Erfüllungsanspruch auf die gestörte Leistung? (2) Gibt es Schadensersatzansprüche, die als Sekundäransprüche an die Stelle des Primäranspruchs oder neben ihn treten? Und schließlich (3): Was ist mit dem Anspruch auf die Gegenleistung? Vom Schwierigkeitsgrad her ist das Folgende ungefähr im Bereich einer gehobenen Zwischenprüfungsklausur anzusiedeln.
In der folgenden Klausur geht es um das alte Problem der Kollision eines verlängerten Eigentumsvorbehalts mit der Globalzession von Forderungen. Die Fallkonstellation ist allerdings ungewöhnlich, so dass man die Zusammenhänge neu überdenken und überlieferte Wissenselemente neu zusammenfügen muss. Dem Format nach entspricht das Ganze ungefähr einer Klausuraufgabe für den Erwerb des großen BGB-Scheins, wobei die inhaltlichen Anforderungen eher hoch sind und schon in Richtung Staatsexamen gehen.
§ 71 Erwerb eigener Aktien
(2020)
§ 71a Umgehungsgeschäfte
(2020)
§ 138 Gesonderte Versammlung
(2020)
§ 139 Wesen
(2020)
Ein wichtiges Anliegen aller Privatrechtsordnungen ist die Sicherheit und Verlässlichkeit des Gütertransfers. In einer entwickelten Wirtschaft, die auf Arbeitsteilung und Umsatz basiert, gibt es lange Lieferketten. Person A liefert ein Gut an B, dann liefert B an C und immer so weiter. Die einzelnen Glieder in der Kette müssen das Gut sicher und verlässlich erwerben können. Wenn nun aber das Geschäft zwischen A und B von Anfang an ungültig ist oder nachträglich hinfällig wird, stellt sich die Frage, wem das Gut gehört. Das deutsche Recht begegnet dieser Frage unter anderem mit dem Trennungs- und Abstraktionsprinzip: Kauf und Übereignung sind zwei gesonderte Verträge, und die Wirksamkeit der Übereignung ist unabhängig vom Bestand und von der Wirksamkeit des Kaufvertrag. Das wird von deutschen Juristen als Schlüssel wissenschaftlichen Rechtsdenkens hochgehalten, stößt aber außerhalb Deutschlands und speziell in Frankreich auf Unverständnis. Denn im französischen Recht sind Kauf und Übereignung Eins.
Im Folgenden geht es nicht so sehr um die geistige Qualität des deutschen Trennungs- und Abstraktionsprinzips, die unbestreitbar ist, sondern vor allem um die Frage, ob diese Prinzi-pien im Vergleich zur französischen Einheit von Kauf und Übereignung praktische Vorteile haben. Die Untersuchung konzentriert sich auf die Übertragung von beweglichen Sachen und von Rechten. Das Grundstücksrecht bleibt dagegen ausgeklammert, denn es ist wegen seiner Formalien schwerer zu vergleichen und trägt keine grundlegend neuen Erkenntnisse bei.