Novel pattern formation in blends of asymmetric ABC triblock terpolymers
- A series of polystyrene-block-poly(1,2-butadiene)-block-poly(2-vinyl-pyridine) (SBV) triblock terpolymers were used to prepare blends with symmetric polystyrene-block-poly(2-vinylpyridine) (SV) and poly(2-vinylpyridine)-block-poly- (cyclohexyl methacrylate) (VC) diblock copolymers. Morphological characterization was carried out by transmission electron microscopy. These triblock terpolymers self-assemble into various core-shell type or lamellar morphologies. In the SBV/SV blends, macrophase separation between the two block copolymers, continuous centrosymmetric lamellae and stacks of non-centrosymmetric lamellae with anti-parallel orientation were found. In the blends of SBV/VC, macrophase separation was never observed, what is due to the specific interactions between S and C domains. These systems showed among other morphologies also a cylindrical morphology in which rings surround the cylinders
| Author details: | Volker AbetzORCiDGND, S. M. Jiang, A. Gopfert |
|---|---|
| ISSN: | 1618-7229 |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2004 |
| Publication year: | 2004 |
| Release date: | 2017/03/24 |
| Source: | E-Polymers. - ISSN 1618-7229. - (2004), S. 9 |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie |
| Peer review: | Referiert |
| Publishing method: | Open Access |
| Institution name at the time of the publication: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik |
