Numerical investigation of barite scaling kinetics in fractures
- Barite stands out as one of the most ubiquitous scaling agents in deep geothermal systems, responsible for irreversible efficiency loss. Due to complex parameter interplay, it is imperative to utilise numerical simulations to investigate temporal and spatial precipitation effects. A one-dimensional reactive transport model is set up with heterogeneous nucleation and crystal growth kinetics. In line with geothermal systems in the North German Basin, the following parameters are considered in a sensitivity analysis: temperature (25 to 150 degrees C), pore pressure (10 to 50 MPa), fracture aperture (10(-4) to 10(-2) m), flow velocity (10(-3) to 10(0) m s(-1)), molar volume (50.3 to 55.6 cm(3) mol(-1)), contact angle for heterogeneous nucleation (0 degrees to 180 degrees), interfacial tension (0.07 to 0.134 J m(-2)), salinity (0.1 to 1.5 mol kgw(-1) NaCl), pH (5 to 7), and supersaturation ratio (1 to 30). Nucleation and consequently crystal growth can only begin if the threshold supersaturation is exceeded, therefore contact angle andBarite stands out as one of the most ubiquitous scaling agents in deep geothermal systems, responsible for irreversible efficiency loss. Due to complex parameter interplay, it is imperative to utilise numerical simulations to investigate temporal and spatial precipitation effects. A one-dimensional reactive transport model is set up with heterogeneous nucleation and crystal growth kinetics. In line with geothermal systems in the North German Basin, the following parameters are considered in a sensitivity analysis: temperature (25 to 150 degrees C), pore pressure (10 to 50 MPa), fracture aperture (10(-4) to 10(-2) m), flow velocity (10(-3) to 10(0) m s(-1)), molar volume (50.3 to 55.6 cm(3) mol(-1)), contact angle for heterogeneous nucleation (0 degrees to 180 degrees), interfacial tension (0.07 to 0.134 J m(-2)), salinity (0.1 to 1.5 mol kgw(-1) NaCl), pH (5 to 7), and supersaturation ratio (1 to 30). Nucleation and consequently crystal growth can only begin if the threshold supersaturation is exceeded, therefore contact angle and interfacial tension are the most sensitive in terms of precipitation kinetics. If nucleation has occurred, crystal growth becomes the dominant process, which is mainly controlled by fracture aperture. Results show that fracture sealing takes place within months (median 33 days) and the affected range can be on the order of tens of metres (median 10 m). The presented models suggest that barite scaling must be recognised as a serious threat if the supersaturation threshold is exceeded, in which case, large fracture apertures could help to minimise kinetic rates. The models further are of use for adjusting the fluid injection temperature.…
Author details: | Morgan Alan TranterORCiDGND, Marco De LuciaORCiD, Michael KühnORCiDGND |
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ISSN: | 0375-6505 |
ISSN: | 1879-3576 |
Title of parent work (English): | Geothermics : an international journal of geothermal research and its applications |
Publisher: | Elsevier |
Place of publishing: | Amsterdam [u.a.] |
Publication type: | Article |
Language: | English |
Date of first publication: | 2021/03/01 |
Publication year: | 2021 |
Release date: | 2023/11/27 |
Tag: | Crystal nucleation; Fracture sealing; Geochemical modelling; Geothermal; PHREEQC; Reactive transport |
Volume: | 91 |
Article number: | 102027 |
Number of pages: | 14 |
Funding institution: | Federal Ministry for Economics and Energy of Germany BMWi [0324244C]; Helmholtz Association of German Research CentresHelmholtz Association [ZT-I-0010]; (project Reduced Complexity Models) |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Geowissenschaften |
DDC classification: | 5 Naturwissenschaften und Mathematik / 55 Geowissenschaften, Geologie / 550 Geowissenschaften |
Peer review: | Referiert |
Publishing method: | Open Access / Hybrid Open-Access |
License (German): | CC-BY-NC-ND - Namensnennung, nicht kommerziell, keine Bearbeitungen 4.0 International |