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Deutsche Blauhelme in Afrika
(2023)
Warum trat die Bundesregierung ab Ende der 1980er Jahre weltweit als sicherheitspolitischer Akteur in Erscheinung? Warum engagierte sie sich in multinationalen Missionen der Vereinten Nationen etwa in Somalia, Namibia und Ruanda mit Soldaten oder Polizisten - und in anderen Missionen in Afrika im gleichen Zeitraum nicht? Gestützt auf ministerielle Archivquellen untersucht Torsten Konopka die Prozesse der nationalen Entscheidungsfindung, die zu einer Beteiligung oder Nichtbeteiligung an VN-Missionen in Afrika führten. Das Buch leistet einen politik- sowie militärgeschichtlichen Beitrag zur Genese der frühen Auslandsverwendungen der Bundeswehr.
An exploration of activity and therapist preferences and their predictors in German-speaking samples
(2023)
According to current definitions of evidence-based practice, patients’ preferences play an important role for the psychotherapeutic process and outcomes. However, whereas a significant body of research investigated preferences regarding specific treatments, research on preferred activities or therapist characteristics is rare, investigated heterogeneous aspects with inconclusive results, lacked validated assessment tools, and neglected relevant preferences, their predictors as well as the perspective of mental health professionals. Therefore, the three studies of this dissertation aimed to address the most fundamental drawbacks in current preference research by providing a validated questionnaire, focus efforts on activity and therapist preferences and add preferences of psychotherapy trainees. To this end, Paper I reports the translation and validation of the 18-item Cooper-Norcross Inventory of Preference (C-NIP) in a broad, heterogeneous sample of N = 969 laypeople, resulting in good to acceptable reliabilities and first evidence of validity. However, the original factor structure was not replicated. Paper II assesses activity preferences of psychotherapists in training using the C-NIP and compares them with the initial laypeople sample. There were significant differences between both samples, with trainees preferring a more patient-directed, emotionally intense and confrontational approach than laypeople. CBT trainees preferred a more therapist-directed, present-focused, challenging and less emotional intense approach than psychodynamic or -analytic trainees. Paper III explores therapist preferences and tests predictors for specific preference choices. For most characteristics, more than half of the participants did not have specific preferences. Results pointed towards congruency effects (i.e., preference for similar characteristics), especially for members of marginalized groups. The dissertation provides both researchers and practitioners with a validated questionnaire, shows potentially obstructive differences between patients and therapists and underlines the importance of therapist characteristics for marginalized groups, thereby laying the foundation for future applications and implementations in research and practice.
Aging is a complex process characterized by several factors, including loss of genetic and epigenetic information, accumulation of chronic oxidative stress, protein damage and aggregates and it is becoming an emergent drug target. Therefore, it is the utmost importance to study aging and agerelated diseases, to provide treatments to develop a healthy aging process. Skeletal muscle is one of the earliest tissues affected by age-related changes with progressive loss of muscle mass and function from 30 years old, effect known as sarcopenia. Several studies have shown the accumulation of protein aggregates in different animal models, as well as in humans, suggesting impaired proteostasis, a hallmark of aging, especially regarding degradation systems. Thus, different publications have explored the role of the main proteolytic systems in skeletal muscle from rodents and humans, like ubiquitin proteasomal system (UPS) and autophagy lysosomal system (ALS), however with contradictory results. Yet, most of the published studies are performed in muscles that comprise more than one fiber type, that means, muscles composed by slow and fast fibers. These fiber types, exhibit different metabolism and contraction speed; the slow fibers or type I display an oxidative metabolism, while fast fibers function towards a glycolytic metabolism ranging from fast oxidative to fast glycolytic fibers. To this extent, the aim of this thesis sought to understand on how aging impacts both fiber types not only regarding proteostasis but also at a metabolome and transcriptome network levels. Therefore, the first part of this thesis, presents the differences between slow oxidative (from Soleus muscle) and fast glycolytic fibers (Extensor digitorum longus, EDL) in terms of degradation systems and how they cope with oxidative stress during aging, while the second part explores the differences between young and old EDL muscle transcriptome and metabolome, unraveling molecular features. More specifically, the results from the present work show that slow oxidative muscle performs better at maintaining the function of UPS and ALS during aging than EDL muscle, which is clearly affected, accounting for the decline in the catalytic activity rates and accumulation of autophagy-related proteins. Strinkingly, transcriptome and metabolome analyses reveal that fast glycolytic muscle evidences significant downregulation of mitochondrial related processes and damaged mitochondria morphology during aging, despite of having a lower oxidative metabolism compared to oxidative fibers. Moreover, predictive analyses reveal a negative association between aged EDL gene signature and lifespan extending interventions such as caloric restriction (CR). Although, CR intervention does not alter the levels of mitochondrial markers in aged EDL muscle, it can reverse the higher mRNA levels of muscle damage markers. Together, the results from this thesis give new insights about how different metabolic muscle fibers cope with age-related changes and why fast glycolytic fibers are more susceptible to aging than slow oxidative fibers.
Fördern und Zensieren
(2023)
»European Environmental Law and its Influence on Grandfathering – a Limiting Factor?«: How to deal with conflicts that arise between legally permitted activities and nature despite prior comprehensive environmental assessments? The author examines this question regarding EU species, habitat protection and environmental damage law. The material EU environmental law requirements for the use of permits are outlined, as well as the administrative instruments for their enforcement. A differentiation is made between permits under the Federal Immission Control Act and plan approvals.
Evaluation of nitrogen dynamics in high-order streams and rivers based on high-frequency monitoring
(2023)
Nutrient storage, transform and transport are important processes for achieving environmental and ecological health, as well as conducting water management plans. Nitrogen is one of the most noticeable elements due to its impacts on tremendous consequences of eutrophication in aquatic systems. Among all nitrogen components, researches on nitrate are blooming because of widespread deployments of in-situ high-frequency sensors. Monitoring and studying nitrate can become a paradigm for any other reactive substances that may damage environmental conditions and cause economic losses.
Identifying nitrate storage and its transport within a catchment are inspiring to the management of agricultural activities and municipal planning. Storm events are periods when hydrological dynamics activate the exchange between nitrate storage and flow pathways. In this dissertation, long-term high-frequency monitoring data at three gauging stations in the Selke river were used to quantify event-scale nitrate concentration-discharge (C-Q) hysteretic relationships. The Selke catchment is characterized into three nested subcatchments by heterogeneous physiographic conditions and land use. With quantified hysteresis indices, impacts of seasonality and landscape gradients on C-Q relationships are explored. For example, arable area has deep nitrate legacy and can be activated with high intensity precipitation during wetting/wet periods (i.e., the strong hydrological connectivity). Hence, specific shapes of C-Q relationships in river networks can identify targeted locations and periods for agricultural management actions within the catchment to decrease nitrate output into downstream aquatic systems like the ocean.
The capacity of streams for removing nitrate is of both scientific and social interest, which makes the quantification motivated. Although measurements of nitrate dynamics are advanced compared to other substances, the methodology to directly quantify nitrate uptake pathways is still limited spatiotemporally. The major problem is the complex convolution of hydrological and biogeochemical processes, which limits in-situ measurements (e.g., isotope addition) usually to small streams with steady flow conditions. This makes the extrapolation of nitrate dynamics to large streams highly uncertain. Hence, understanding of in-stream nitrate dynamic in large rivers is still necessary. High-frequency monitoring of nitrate mass balance between upstream and downstream measurement sites can quantitatively disentangle multi-path nitrate uptake dynamics at the reach scale (3-8 km). In this dissertation, we conducted this approach in large stream reaches with varying hydro-morphological and environmental conditions for several periods, confirming its success in disentangling nitrate uptake pathways and their temporal dynamics. Net nitrate uptake, autotrophic assimilation and heterotrophic uptake were disentangled, as well as their various diel and seasonal patterns. Natural streams generally can remove more nitrate under similar environmental conditions and heterotrophic uptake becomes dominant during post-wet seasons. Such two-station monitoring provided novel insights into reach-scale nitrate uptake processes in large streams.
Long-term in-stream nitrate dynamics can also be evaluated with the application of water quality model. This is among the first time to use a data-model fusion approach to upscale the two-station methodology in large-streams with complex flow dynamics under long-term high-frequency monitoring, assessing the in-stream nitrate retention and its responses to drought disturbances from seasonal to sub-daily scale. Nitrate retention (both net uptake and net release) exhibited substantial seasonality, which also differed in the investigated normal and drought years. In the normal years, winter and early spring seasons exhibited extensive net releases, then general net uptake occurred after the annual high-flow season at later spring and early summer with autotrophic processes dominating and during later summer-autumn low-flow periods with heterotrophy-characteristics predominating. Net nitrate release occurred since late autumn until the next early spring. In the drought years, the late-autumn net releases were not so consistently persisted as in the normal years and the predominance of autotrophic processes occurred across seasons. Aforementioned comprehensive results of nitrate dynamics on stream scale facilitate the understanding of instream processes, as well as raise the importance of scientific monitoring schemes for hydrology and water quality parameters.
Planets outside our solar system, so-called "exoplanets", can be detected with different methods, and currently more than 5000 exoplanets have been confirmed, according to NASA Exoplanet Archive. One major highlight of the studies on exoplanets in the past twenty years is the characterization of their atmospheres usingtransmission spectroscopy as the exoplanet transits. However, this characterization is a challenging process and sometimes there are reported discrepancies in the literature regarding the atmosphere of the same exoplanet. One potential reason for the observed atmospheric inconsistencies is called impact parameter degeneracy, and it is highly driven by the limb darkening effect of the host star. A brief introductionto those topics in presented in chapter 1, while the motivation and objectives of thiswork are described in chapter 2.The first goal is to clarify the origin of the transmission spectrum, which is anindicator of an exoplanet’s atmosphere; whether it is real or influenced by the impactparameter degeneracy. A second goal is to determine whether photometry from space using the Transiting Exoplanet Survey Satellite (TESS), could improve on the major parameters, which are responsible for the aforementioned degeneracy, of known exoplanetary systems. Three individual projects were conducted in order toaddress those goals. The three manuscripts are presented, in short, in the manuscriptoverview in chapter 3.More specifically, in chapter 4, the first manuscript is presented, which is an ex-tended investigation on the impact parameter degeneracy and its application onsynthetic transmission spectra. Evidently, the limb darkening of the host star isan important driver for this effect. It keeps the degeneracy persisting through different groups of exoplanets, based on the uncertainty of their impact parameter and on the type of their host star. The second goal, was addressed in the second and third manuscripts (chapter 5 and chapter 6 respectively). Using observationsfrom the TESS mission, two samples of exoplanets were studied; 10 transiting inflated hot-Jupiters and 43 transiting grazing systems. Potentially, the refinement or confirmation of their major system parameters’ measurements can assist in solving current or future discrepancies regarding their atmospheric characterization.In chapter 7 the conclusions of this work are discussed, while in chapter 8 itis proposed how TESS’s measurements can be able to discern between erroneousinterpretations of transmission spectra, especially on systems where the impact parameter degeneracy is likely not applicable.
Transposable elements (TEs) are loci that can replicate and multiply within the genome of their host. Within the host, TEs through transposition are responsible for variation on genomic architecture and gene regulation across all vertebrates. Genome assemblies have increased in numbers in recent years. However, to explore in deep the variations within different genomes, such as SNPs (single nucleotide polymorphism), INDELs (Insertion-deletion), satellites and transposable elements, we need high-quality genomes. Studies of molecular markers in the past 10 years have limitations to correlate with biological differences because molecular markers rely on the accuracy of the genomic resources. This has generated that a substantial part of the studies of TE in recent years have been on high quality genomic resources such as Drosophila, zebrafinch and maize. As testudine have a slow mutation rate lower only to crocodilians, with more than 300 species, adapted to different environments all across the globe, the testudine clade can help us to study variation. Here we propose Testudines as a clade to study variation and the abundance of TE on different species that diverged a long time ago. We investigated the genomic diversity of sea turtles, identifying key genomic regions associated to gene family duplication, specific expansion of particular TE families for Dermochelyidae and that are important for phenotypic differentiation, the impact of environmental changes on their populations, and the dynamics of TEs within different lineages. In chapter 1, we identify that despite high levels of genome synteny within sea turtles, we identified that regions of reduced collinearity and microchromosomes showed higher concentrations of multicopy gene families, as well as genetic distances between species, indicating their potential importance as sources of variation underlying phenotypic differentiation. We found that differences in the ecological niches occupied by leatherback and green turtles have led to contrasting evolutionary paths for their olfactory receptor genes. We identified in leatherback turtles a long-term low population size. Nonetheless, we identify no correlation between the regions of reduced collinearity with abundance of TEs or an accumulation of a particular TE group. In chapter 2, we identified that sea turtle genomes contain a significant proportion of TEs, with differences in TE abundance between species, and the discovery of a recent expansion of Penelope-like elements (PLEs) in the highly conserved sea turtle genome provides new insights into the dynamics of TEs within Testudines. In chapter 3, we compared the proportion of TE across the Testudine clade, and we identified that the proportion of transposable elements within the clade is stable, regardless of the quality of the assemblies. However, we identified that the proportion of TEs orders has correlation with genome quality depending of their expanded abundancy. For retrotransposon, a highly abundant element for this clade, we identify no correlation. However, for DNA elements a rarer element on this clade, correlate with the quality of the assemblies.
Here we confirm that high-quality genomes are fundamental for the study of transposable element evolution and the conservation within the clade. The detection and abundance of specific orders of TEs are influenced by the quality of the genomes. We identified that a reduction in the population size on D. coriacea had left signals of long-term low population sizes on their genomes. On the same note we identified an expansion of TE on D. coriacea, not present in any other member of the available genomes of Testudines, strongly suggesting that it is a response of deregulation of TE on their genomes as consequences of the low population sizes.
Here we have identified important genomic regions and gene families for phenotypic differentiation and highlighted the impact of environmental changes on the populations of sea turtles. We stated that accurate classification and analysis of TE families are important and require high-quality genome assemblies. Using TE analysis we manage to identify differences in highly syntenic species. These findings have significant implications for conservation and provide a foundation for further research into genome evolution and gene function in turtles and other vertebrates. Overall, this study contributes to our understanding of evolutionary change and adaptation mechanisms.
Distributed decision-making studies the choices made among a group of interactive and self-interested agents. Specifically, this thesis is concerned with the optimal sequence of choices an agent makes as it tries to maximize its achievement on one or multiple objectives in the dynamic environment. The optimization of distributed decision-making is important in many real-life applications, e.g., resource allocation (of products, energy, bandwidth, computing power, etc.) and robotics (heterogeneous agent cooperation on games or tasks), in various fields such as vehicular network, Internet of Things, smart grid, etc.
This thesis proposes three multi-agent reinforcement learning algorithms combined with game-theoretic tools to study strategic interaction between decision makers, using resource allocation in vehicular network as an example. Specifically, the thesis designs an interaction mechanism based on second-price auction, incentivizes the agents to maximize multiple short-term and long-term, individual and system objectives, and simulates a dynamic environment with realistic mobility data to evaluate algorithm performance and study agent behavior.
Theoretical results show that the mechanism has Nash equilibria, is a maximization of social welfare and Pareto optimal allocation of resources in a stationary environment. Empirical results show that in the dynamic environment, our proposed learning algorithms outperform state-of-the-art algorithms in single and multi-objective optimization, and demonstrate very good generalization property in significantly different environments. Specifically, with the long-term multi-objective learning algorithm, we demonstrate that by considering the long-term impact of decisions, as well as by incentivizing the agents with a system fairness reward, the agents achieve better results in both individual and system objectives, even when their objectives are private, randomized, and changing over time. Moreover, the agents show competitive behavior to maximize individual payoff when resource is scarce, and cooperative behavior in achieving a system objective when resource is abundant; they also learn the rules of the game, without prior knowledge, to overcome disadvantages in initial parameters (e.g., a lower budget).
To address practicality concerns, the thesis also provides several computational performance improvement methods, and tests the algorithm in a single-board computer. Results show the feasibility of online training and inference in milliseconds.
There are many potential future topics following this work. 1) The interaction mechanism can be modified into a double-auction, eliminating the auctioneer, resembling a completely distributed, ad hoc network; 2) the objectives are assumed to be independent in this thesis, there may be a more realistic assumption regarding correlation between objectives, such as a hierarchy of objectives; 3) current work limits information-sharing between agents, the setup befits applications with privacy requirements or sparse signaling; by allowing more information-sharing between the agents, the algorithms can be modified for more cooperative scenarios such as robotics.
Unveiling the Local Universe
(2023)
Was bewegt Menschen dazu, freiwillig in einem Krieg zu kämpfen, obwohl ihr Heimatland nicht involviert ist? Warum riskieren sie in Konflikten weltweit ihr Leben für eine fremde Sache? Bedeutet das Fehlen institutioneller Strukturen, die den Akteuren klare Regeln und Verhaltensweisen vorgeben würden, immer eine Eskalation von Gewalt? Diese Studie hilft, das Phänomen freiwilliger Kombattanten zu verstehen. Am Fallbeispiel internationaler Kriegsfreiwilliger, die in den Jugoslawienkriegen der 1990er Jahre auf Seiten Kroatiens kämpften, macht Julia Ludwig zudem den Mehrwert einer Analyse kultureller Faktoren in der Gewaltforschung deutlich.
Extreme weather and climate events are one of the greatest dangers for present-day society. Therefore, it is important to provide reliable statements on what changes in extreme events can be expected along with future global climate change. However, the projected overall response to future climate change is generally a result of a complex interplay between individual physical mechanisms originated within the different climate subsystems. Hence, a profound understanding of these individual contributions is required in order to provide meaningful assessments of future changes in extreme events. One aspect of climate change is the recently observed phenomenon of Arctic Amplification and the related dramatic Arctic sea ice decline, which is expected to continue over the next decades. The question to what extent Arctic sea ice loss is able to affect atmospheric dynamics and extreme events over mid-latitudes has received a lot of attention over recent years and still remains a highly debated topic.
In this respect, the objective of this thesis is to contribute to a better understanding on the impact of future Arctic sea ice retreat on European temperature extremes and large-scale atmospheric dynamics.
The outcomes are based on model data from the atmospheric general circulation model ECHAM6. Two different sea ice sensitivity simulations from the Polar Amplification Intercomparison Project are employed and contrasted to a present day reference experiment: one experiment with prescribed future sea ice loss over the entire Arctic, as well as another one with sea ice reductions only locally prescribed over the Barents-Kara Sea.% prescribed over the entire Arctic, as well as only locally over the Barent/Karasea with a present day reference experiment.
The first part of the thesis focuses on how future Arctic sea ice reductions affect large-scale atmospheric dynamics over the Northern Hemisphere in terms of occurrence frequency changes of five preferred Euro-Atlantic circulation regimes. When compared to circulation regimes computed from ERA5 it shows that ECHAM6 is able to realistically simulate the regime structures. Both ECHAM6 sea ice sensitivity experiments exhibit similar regime frequency changes. Consistent with tendencies found in ERA5, a more frequent occurrence of a Scandinavian blocking pattern in midwinter is for instance detected under future sea ice conditions in the sensitivity experiments. Changes in occurrence frequencies of circulation regimes in summer season are however barely detected.
After identifying suitable regime storylines for the occurrence of European temperature extremes in winter, the previously detected regime frequency changes are used to quantify dynamically and thermodynamically driven contributions to sea ice-induced changes in European winter temperature extremes.
It is for instance shown how the preferred occurrence of a Scandinavian blocking regime under low sea ice conditions dynamically contributes to more frequent midwinter cold extreme occurrences over Central Europe. In addition, a reduced occurrence frequency of a Atlantic trough regime is linked to reduced winter warm extremes over Mid-Europe. Furthermore, it is demonstrated how the overall thermodynamical warming effect due to sea ice loss can result in less (more) frequent winter cold (warm) extremes, and consequently counteracts the dynamically induced changes.
Compared to winter season, circulation regimes in summer are less suitable as storylines for the occurrence of summer heat extremes.
Therefore, an approach based on circulation analogues is employed in order to quantify thermodyamically and dynamically driven contributions to sea ice-induced changes of summer heat extremes over three different European sectors. Reduced occurrences of blockings over Western Russia are detected in the ECHAM6 sea ice sensitivity experiments; however, arguing for dynamically and thermodynamically induced contributions to changes in summer heat extremes remains rather challenging.
During the Cenozoic, global cooling and uplift of the Tian Shan, Pamir, and Tibetan plateau modified atmospheric circulation and reduced moisture supply to Central Asia. These changes led to aridification in the region during the Neogene. Afterwards, Quaternary glaciations led to modification of the landscape and runoff.
In the Issyk-Kul basin of the Kyrgyz Tian Shan, the sedimentary sequences reflect the development of the adjacent ranges and local climatic conditions. In this work, I reconstruct the late Miocene – early Pleistocene depositional environment, climate, and lake development in the Issyk-Kul basin using facies analyses and stable δ18O and δ13C isotopic records from sedimentary sections dated by magnetostratigraphy and 26Al/10Be isochron burial dating. Also, I present 10Be-derived millennial-scale modern and paleo-denudation rates from across the Kyrgyz Tian Shan and long-term exhumation rates calculated from published thermochronology data. This allows me to examine spatial and temporal changes in surface processes in the Kyrgyz Tian Shan.
In the Issyk-Kul basin, the style of fluvial deposition changed at ca. 7 Ma, and aridification in the basin commenced concurrently, as shown by magnetostratigraphy and the δ18O and δ13C data. Lake formation commenced on the southern side of the basin at ca. 5 Ma, followed by a ca. 2 Ma local depositional hiatus. 26Al/10Be isochron burial dating and paleocurrent analysis show that the Kungey range to the north of the basin grew eastward, leading to a change from fluvial-alluvial deposits to proximal alluvial fan conglomerates at 5-4 Ma in the easternmost part of the basin. This transition occurred at 2.6-2.8 Ma on the southern side of the basin, synchronously with the intensification of the Northern Hemisphere glaciation. The paleo-denudation rates from 2.7-2.0 Ma are as low as long-term exhumation rates, and only the millennial-scale denudation rates record an acceleration of denudation.
This work concludes that the growth of the ranges to the north of the basin led to creation of the topographic barrier at ca. 7 Ma and a subsequent aridification in the Issyk-Kul basin. Increased subsidence and local tectonically-induced river system reorganization on the southern side of the basin enabled lake formation at ca. 5 Ma, while growth of the Kungey range blocked westward-draining rivers and led to sediment starvation and lake expansion. Denudational response of the Kyrgyz Tian Shan landscape is delayed due to aridity and only substantial cooling during the late Quaternary glacial cycles led to notable acceleration of denudation. Currently, increased glacier reduction and runoff controls a more rapid denudation of the northern slope of the Terskey range compared to other ranges of the Kyrgyz Tian Shan.
The trace elements, selenium (Se) and copper (Cu) play an important role in maintaining normal brain function. Since they have essential functions as cofactors of enzymes or structural components of proteins, an optimal supply as well as a well-defined homeostatic regulation are crucial. Disturbances in trace element homeostasis affect the health status and contribute to the incidence and severity of various diseases. The brain in particular is vulnerable to oxidative stress due to its extensive oxygen consumption and high energy turnover, among other factors. As components of a number of antioxidant enzymes, both elements are involved in redox homeostasis. However, high concentrations are also associated with the occurrence of oxidative stress, which can induce cellular damage. Especially high Cu concentrations in some brain areas are associated with the development and progression of neurodegenerative diseases such as Alzheimer's disease (AD). In contrast, reduced Se levels were measured in brains of AD patients. The opposing behavior of Cu and Se renders the study of these two trace elements as well as the interactions between them being particularly relevant and addressed in this work.
This cumulative doctoral thesis consists of five empirical studies examining various aspects of crisis and change from a management-accounting perspective. Within the first study, a bibliometric analysis is conducted. More precisely, based on publications between the financial crisis (since 2007) and the COVID-19 crisis (starting in 2020), the crisis literature in management accounting is investigated to uncover the most influential aspects of the field and to analyze the theoretical foundations of the literature. Moreover, this investigation also serves to identify future research streams and to provide starting points for future research. Based on a survey, the second study investigates the impact of several management-accounting tools on organizational resilience and its effect on a company’s competitive advantage during a crisis. The results show that their target-oriented use positively influences organizational resilience and contributes to the company’s competitive advantage during the crisis. The third study provides a more detailed view on the relationship between budgeting and risk management and their benefit for companies in times of crisis. For this purpose, the relationship between the relevance of budgeting functions and risk management in the company and the corresponding impact on company performance are investigated. The results show a positive relationship. However, a crisis can also affect the relationship between the company and its shareholders: Thus, the fourth study – based on publicly available data and a survey – examines the consequences of virtual annual general meetings on shareholder rights. The results show that, temporarily, particularly the right to information was severely restricted. For the following year, this problem was fixed, and ultimately, the virtual option was introduced permanently. The crisis has thus brought about a lasting change. But not only crises cause changes: The fifth study, also based on survey data, investigates the changes in the role of management accountants caused by digitalization. More precisely, it investigates how management accountants deal with tasks that are considered outdated and unattractive. The results of the study show that different types of personalities also act differently as far as the willingness to do those unattractive tasks is concerned, and career ambitions also influence that willingness. In addition to this, the results provide insights into the motivation of management accountants to conduct tasks and thus counteract existing assumptions based on stereotypes and clichés circulating within the research community.
Understanding hydrological processes is of fundamental importance for the Vietnamese national food security and the livelihood of the population in the Vietnamese Mekong Delta (VMD). As a consequence of sparse data in this region, however, hydrologic processes, such as the controlling processes of precipitation, the interaction between surface and groundwater, and groundwater dynamics, have not been thoroughly studied. The lack of this knowledge may negatively impact the long-term strategic planning for sustainable groundwater resources management and may result in insufficient groundwater recharge and freshwater scarcity. It is essential to develop useful methods for a better understanding of hydrological processes in such data-sparse regions. The goal of this dissertation is to advance methodologies that can improve the understanding of fundamental hydrological processes in the VMD, based on the analyses of stable water isotopes and monitoring data. The thesis mainly focuses on the controlling processes of precipitation, the mechanism of surface–groundwater interaction, and the groundwater dynamics. These processes have not been fully addressed in the VMD so far. The thesis is based on statistical analyses of the isotopic data of Global Network of Isotopes in Precipitation (GNIP), of meteorological and hydrological data from Vietnamese agencies, and of the stable water isotopes and monitoring data collected as part of this work.
First, the controlling processes of precipitation were quantified by the combination of trajectory analysis, multi-factor linear regression, and relative importance analysis (hereafter, a model‐based statistical approach). The validity of this approach is confirmed by similar, but mainly qualitative results obtained in other studies. The total variation in precipitation isotopes (δ18O and δ2H) can be better explained by multiple linear regression (up to 80%) than single-factor linear regression (30%). The relative importance analysis indicates that atmospheric moisture regimes control precipitation isotopes rather than local climatic conditions. The most crucial factor is the upstream rainfall along the trajectories of air mass movement. However, the influences of regional and local climatic factors vary in importance over the seasons. The developed model‐based statistical approach is a robust tool for the interpretation of precipitation isotopes and could also be applied to understand the controlling processes of precipitation in other regions.
Second, the concept of the two-component lumped-parameter model (LPM) in conjunction with stable water isotopes was applied to examine the surface–groundwater interaction in the VMD. A calibration framework was also set up to evaluate the behaviour, parameter identifiability, and uncertainties of two-component LPMs. The modelling results provided insights on the subsurface flow conditions, the recharge contributions, and the spatial variation of groundwater transit time. The subsurface flow conditions at the study site can be best represented by the linear-piston flow distribution. The contributions of the recharge sources change with distance to the river. The mean transit time (mTT) of riverbank infiltration increases with the length of the horizontal flow path and the decreasing gradient between river and groundwater. River water infiltrates horizontally mainly via the highly permeable aquifer, resulting in short mTTs (<40 weeks) for locations close to the river (<200 m). The vertical infiltration from precipitation takes place primarily via a low‐permeable overlying aquitard, resulting in considerably longer mTTs (>80 weeks). Notably, the transit time of precipitation infiltration is independent of the distance to the river. All these results are hydrologically plausible and could be quantified by the presented method for the first time. This study indicates that the highly complex mechanism of surface–groundwater interaction at riverbank infiltration systems can be conceptualized by exploiting two‐component LPMs. It is illustrated that the model concept can be used as a tool to investigate the hydrological functioning of mixing processes and the flow path of multiple water components in riverbank infiltration systems.
Lastly, a suite of time series analysis approaches was applied to examine the groundwater dynamics in the VMD. The assessment was focused on the time-variant trends of groundwater levels (GWLs), the groundwater memory effect (representing the time that an aquifer holds water), and the hydraulic response between surface water and multi-layer alluvial aquifers. The analysis indicates that the aquifers act as low-pass filters to reduce the high‐frequency signals in the GWL variations, and limit the recharge to the deep groundwater. The groundwater abstraction has exceeded groundwater recharge between 1997 and 2017, leading to the decline of groundwater levels (0.01-0.55 m/year) in all considered aquifers in the VMD. The memory effect varies according to the geographical location, being shorter in shallow aquifers and flood-prone areas and longer in deep aquifers and coastal regions. Groundwater depth, season, and location primarily control the variation of the response time between the river and alluvial aquifers. These findings are important contributions to the hydrogeological literature of a little-known groundwater system in an alluvial setting. It is suggested that time series analysis can be used as an efficient tool to understand groundwater systems where resources are insufficient to develop a physical-based groundwater model.
This doctoral thesis demonstrates that important aspects of hydrological processes can be understood by statistical analysis of stable water isotope and monitoring data. The approaches developed in this thesis can be easily transferred to regions in similar tropical environments, particularly those in alluvial settings. The results of the thesis can be used as a baseline for future isotope-based studies and contribute to the hydrogeological literature of little-known groundwater systems in the VMD.
Biofilms are heterogeneous structures made of microorganisms embedded in a self-secreted extracellular matrix. Recently, biofilms have been studied as sustainable living materials with a focus on the tuning of their mechanical properties. One way of doing so is to use metal ions. In particular biofilms have been shown to stiffen in presence of some metal cations and to soften in presence of others. However, the specificity and the determinants of those interactions vary between species. While Escherichia coli is a widely studied model organism, little is known concerning the response of its biofilms to metal ions. In this work, we aimed at tuning the mechanics of E. coli biofilms by acting on the interplay between matrix composition and metal cations. To do so, we worked with E. coli strains producing a matrix composed of curli amyloid fibres or phosphoethanolamine-cellulose (pEtN-cellulose) fibres or both. The viscoelastic behaviour of the resulting biofilms was investigated with rheology after incubation with one of the following metal ion solutions: FeCl3, AlCl3, ZnCl2 and CaCl2 or ultrapure water. We observed that the strain producing both fibres stiffen by a factor of two when exposed to the trivalent metal cations Al(III) and Fe(III) while no such response is observed for the bivalent cations Zn(II) and Ca(II). Strains producing only one matrix component did not show any stiffening in response to either cation, but even a small softening. In order to investigate further the contribution of each matrix component to the mechanical properties, we introduced additional bacterial strains producing curli fibres in combination with non-modified cellulose, non-modified cellulose only or neither component. We measured biofilms produced by those different strains with rheology and without any solution. Since rheology does not preserve the architecture of the matrix, we compared those results to the mechanical properties of biofilms probed with the non-destructive microindentation. The microindentation results showed that biofilm stiffness is mainly determined by the presence of curli amyloid fibres in the matrix. However, this clear distinction between biofilm matrices containing or not containing curli is absent from the rheology results, i.e. following partial destruction of the matrix architecture. In addition, rheology also indicated a negative impact of curli on biofilm yield stress and flow stress. This suggests that curli fibres are more brittle and therefore more affected by the mechanical treatments. Finally, to examine the molecular interactions between the biofilms and the metal cations, we used Attenuated total reflectance - Fourier transform infrared spectroscopy (ATR-FTIR) to study the three E.coli strains producing a matrix composed of curli amyloid fibres, pEtN-cellulose fibres or both. We measured biofilms produced by those strains in presence of each of the aforementioned metal cation solutions or ultrapure water. We showed that the three strains cannot be distinguished based on their FTIR spectra and that metal cations seem to have a non-specific effect on bacterial membranes in absence of pEtN-cellulose. We subsequently conducted similar experiments on purified curli or pEtN-cellulose fibres. The spectra of the pEtN-cellulose fibres revealed a non-valence-specific interaction between metal cations and the phosphate of the pEtN-modification. Altogether, these results demonstrate that the mechanical properties of E. coli biofilms can be tuned via incubation with metal ions. While the mechanism involving curli fibres remains to be determined, metal cations seem to adsorb onto pEtN-cellulose and this is not valence-specific. This work also underlines the importance of matrix architecture to biofilm mechanics and emphasises the specificity of each matrix composition.
Advances in hydrogravimetry
(2023)
The interest of the hydrological community in the gravimetric method has steadily increased within the last decade. This is reflected by numerous studies from many different groups with a broad range of approaches and foci. Many of those are traditionally rather hydrology-oriented groups who recognized gravimetry as a potential added value for their hydrological investigations. While this resulted in a variety of interesting and useful findings, contributing to extend the respective knowledge and confirming the methodological potential, on the other hand, many interesting and unresolved questions emerged.
This thesis manifests efforts, analyses and solutions carried out in this regard. Addressing and evaluating many of those unresolved questions, the research contributes to advancing hydrogravimetry, the combination of gravimetric and hydrological methods, in showing how gravimeters are a highly useful tool for applied hydrological field research.
In the first part of the thesis, traditional setups of stationary terrestrial superconducting gravimeters are addressed. They are commonly installed within a dedicated building, the impermeable structure of which shields the underlying soil from natural exchange of water masses (infiltration, evapotranspiration, groundwater recharge). As gravimeters are most sensitive to mass changes directly beneath the meter, this could impede their suitability for local hydrological process investigations, especially for near-surface water storage changes (WSC). By studying temporal local hydrological dynamics at a dedicated site equipped with traditional hydrological measurement devices, both below and next to the building, the impact of these absent natural dynamics on the gravity observations were quantified. A comprehensive analysis with both a data-based and model-based approach led to the development of an alternative method for dealing with this limitation. Based on determinable parameters, this approach can be transferred to a broad range of measurement sites where gravimeters are deployed in similar structures. Furthermore, the extensive considerations on this topic enabled a more profound understanding of this so called umbrella effect.
The second part of the thesis is a pilot study about the field deployment of a superconducting gravimeter. A newly developed field enclosure for this gravimeter was tested in an outdoor installation adjacent to the building used to investigate the umbrella effect. Analyzing and comparing the gravity observations from both indoor and outdoor gravimeters showed performance with respect to noise and stable environmental conditions was equivalent while the sensitivity to near-surface WSC was highly increased for the field deployed instrument. Furthermore it was demonstrated that the latter setup showed gravity changes independent of the depth where mass changes occurred, given their sufficiently wide horizontal extent. As a consequence, the field setup suits monitoring of WSC for both short and longer time periods much better. Based on a coupled data-modeling approach, its gravity time series was successfully used to infer and quantify local water budget components (evapotranspiration, lateral subsurface discharge) on the daily to annual time scale.
The third part of the thesis applies data from a gravimeter field deployment for applied hydrological process investigations. To this end, again at the same site, a sprinkling experiment was conducted in a 15 x 15 m area around the gravimeter. A simple hydro-gravimetric model was developed for calculating the gravity response resulting from water redistribution in the subsurface. It was found that, from a theoretical point of view, different subsurface water distribution processes (macro pore flow, preferential flow, wetting front advancement, bypass flow and perched water table rise) lead to a characteristic shape of their resulting gravity response curve. Although by using this approach it was possible to identify a dominating subsurface water distribution process for this site, some clear limitations stood out. Despite the advantage for field installations that gravimetry is a non-invasive and integral method, the problem of non-uniqueness could only be overcome by additional measurements (soil moisture, electric resistivity tomography) within a joint evaluation. Furthermore, the simple hydrological model was efficient for theoretical considerations but lacked the capability to resolve some heterogeneous spatial structures of water distribution up to a needed scale. Nevertheless, this unique setup for plot to small scale hydrological process research underlines the high potential of gravimetery and the benefit of a field deployment.
The fourth and last part is dedicated to the evaluation of potential uncertainties arising from the processing of gravity observations. The gravimeter senses all mass variations in an integral way, with the gravitational attraction being directly proportional to the magnitude of the change and inversely proportional to the square of the distance of the change. Consequently, all gravity effects (for example, tides, atmosphere, non-tidal ocean loading, polar motion, global hydrology and local hydrology) are included in an aggregated manner. To isolate the signal components of interest for a particular investigation, all non-desired effects have to be removed from the observations. This process is called reduction. The large-scale effects (tides, atmosphere, non-tidal ocean loading and global hydrology) cannot be measured directly and global model data is used to describe and quantify each effect. Within the reduction process, model errors and uncertainties propagate into the residual, the result of the reduction. The focus of this part of the thesis is quantifying the resulting, propagated uncertainty for each individual correction. Different superconducting gravimeter installations were evaluated with respect to their topography, distance to the ocean and the climate regime. Furthermore, different time periods of aggregated gravity observation data were assessed, ranging from 1 hour up to 12 months. It was found that uncertainties were highest for a frequency of 6 months and smallest for hourly frequencies. Distance to the ocean influences the uncertainty of the non-tidal ocean loading component, while geographical latitude affects uncertainties of the global hydrological component. It is important to highlight that the resulting correction-induced uncertainties in the residual have the potential to mask the signal of interest, depending on the signal magnitude and its frequency. These findings can be used to assess the value of gravity data across a range of applications and geographic settings.
In an overarching synthesis all results and findings are discussed with a general focus on their added value for bringing hydrogravimetric field research to a new level. The conceptual and applied methodological benefits for hydrological studies are highlighted. Within an outlook for future setups and study designs, it was once again shown what enormous potential is offered by gravimeters as hydrological field tools.
The Andean Cordillera is a mountain range located at the western South American margin and is part of the Eastern- Circum-Pacific orogenic Belt. The ~7000 km long mountain range is one of the longest on Earth and hosts the second largest orogenic plateau in the world, the Altiplano-Puna plateau. The Andes are known as a non-collisional subduction-type orogen which developed as a result of the interaction between the subducted oceanic Nazca plate and the South American continental plate. The different Andean segments exhibit along-strike variations of morphotectonic provinces characterized by different elevations, volcanic activity, deformation styles, crustal thickness, shortening magnitude and oceanic plate geometry. Most of the present-day elevation can be explained by crustal shortening in the last ~50 Ma, with the shortening magnitude decreasing from ~300 km in the central (15°S-30°S) segment to less than half that in the southern part (30°S-40°S). Several factors were proposed that might control the magnitude and acceleration of shortening of the Central Andes in the last 15 Ma. One important factor is likely the slab geometry. At 27-33°S, the slab dips horizontally at ~100 km depth due to the subduction of the buoyant Juan Fernandez Ridge, forming the Pampean flat-slab. This horizontal subduction is thought to influence the thermo-mechanical state of the Sierras Pampeanas foreland, for instance, by strengthening the lithosphere and promoting the thick-skinned propagation of deformation to the east, resulting in the uplift of the Sierras Pampeanas basement blocks. The flat-slab has migrated southwards from the Altiplano latitude at ~30 Ma to its present-day position and the processes and consequences associated to its passage on the contemporaneous acceleration of the shortening rate in Central Andes remain unclear. Although the passage of the flat-slab could offer an explanation to the acceleration of the shortening, the timing does not explain the two pulses of shortening at about 15 Ma and 4 Ma that are suggested from geological observations. I hypothesize that deformation in the Central Andes is controlled by a complex interaction between the subduction dynamics of the Nazca plate and the dynamic strengthening and weakening of the South American plate due to several upper plate processes. To test this hypothesis, a detailed investigation into the role of the flat-slab, the structural inheritance of the continental plate, and the subduction dynamics in the Andes is needed. Therefore, I have built two classes of numerical thermo-mechanical models: (i) The first class of models are a series of generic E-W-oriented high-resolution 2D subduction models thatinclude flat subduction in order to investigate the role of the subduction dynamics on the temporal variability of the shortening rate in the Central Andes at Altiplano latitudes (~21°S). The shortening rate from the models was then validated with the observed tectonic shortening rate in the Central Andes. (ii) The second class of models are a series of 3D data-driven models of the present-day Pampean flat-slab configuration and the Sierras Pampeanas (26-42°S). The models aim to investigate the relative contribution of the present-day flat subduction and inherited structures in the continental lithosphere on the strain localization. Both model classes were built using the advanced finite element geodynamic code ASPECT.
The first main finding of this work is to suggest that the temporal variability of shortening in the Central Andes is primarily controlled by the subduction dynamics of the Nazca plate while it penetrates into the mantle transition zone. These dynamics depends on the westward velocity of the South American plate that provides the main crustal shortening force to the Andes and forces the trench to retreat. When the subducting plate reaches the lower mantle, it buckles on it-self until the forced trench retreat causes the slab to steepen in the upper mantle in contrast with the classical slab-anchoring model. The steepening of the slab hinders the trench causing it to resist the advancing South American plate, resulting in the pulsatile shortening. This buckling and steepening subduction regime could have been initiated because of the overall decrease in the westwards velocity of the South American plate. In addition, the passage of the flat-slab is required to promote the shortening of the continental plate because flat subduction scrapes the mantle lithosphere, thus weakening the continental plate. This process contributes to the efficient shortening when the trench is hindered, followed by mantle lithosphere delamination at ~20 Ma. Finally, the underthrusting of the Brazilian cratonic shield beneath the orogen occurs at ~11 Ma due to the mechanical weakening of the thick sediments covered the shield margin, and due to the decreasing resistance of the weakened lithosphere of the orogen.
The second main finding of this work is to suggest that the cold flat-slab strengthens the overriding continental lithosphere and prevents strain localization. Therefore, the deformation is transmitted to the eastern front of the flat-slab segment by the shear stress operating at the subduction interface, thus the flat-slab acts like an indenter that “bulldozes” the mantle-keel of the continental lithosphere. The offset in the propagation of deformation to the east between the flat and steeper slab segments in the south causes the formation of a transpressive dextral shear zone. Here, inherited faults of past tectonic events are reactivated and further localize the deformation in an en-echelon strike-slip shear zone, through a mechanism that I refer to as “flat-slab conveyor”. Specifically, the shallowing of the flat-slab causes the lateral deformation, which explains the timing of multiple geological events preceding the arrival of the flat-slab at 33°S. These include the onset of the compression and of the transition between thin to thick-skinned deformation styles resulting from the crustal contraction of the crust in the Sierras Pampeanas some 10 and 6 Myr before the Juan Fernandez Ridge collision at that latitude, respectively.
At the beginning of 2020, with COVID-19, courts of justice worldwide had to move online to continue providing judicial service. Digital technologies materialized the court practices in ways unthinkable shortly before the pandemic creating resonances with judicial and legal regulation, as well as frictions. A better understanding of the dynamics at play in the digitalization of courts is paramount for designing justice systems that serve their users better, ensure fair and timely dispute resolutions, and foster access to justice. Building on three major bodies of literature —e-justice, digitalization and organization studies, and design research— Designing for Digital Justice takes a nuanced approach to account for human and more-than-human agencies.
Using a qualitative approach, I have studied in depth the digitalization of Chilean courts during the pandemic, specifically between April 2020 and September 2022. Leveraging a comprehensive source of primary and secondary data, I traced back the genealogy of the novel materializations of courts’ practices structured by the possibilities offered by digital technologies. In five (5) cases studies, I show in detail how the courts got to 1) work remotely, 2) host hearings via videoconference, 3) engage with users via social media (i.e., Facebook and Chat Messenger), 4) broadcast a show with judges answering questions from users via Facebook Live, and 5) record, stream, and upload judicial hearings to YouTube to fulfil the publicity requirement of criminal hearings. The digitalization of courts during the pandemic is characterized by a suspended normativity, which makes innovation possible yet presents risks. While digital technologies enabled the judiciary to provide services continuously, they also created the risk of displacing traditional judicial and legal regulation.
Contributing to liminal innovation and digitalization research, Designing for Digital Justice theorizes four phases: 1) the pre-digitalization phase resulting in the development of regulation, 2) the hotspot of digitalization resulting in the extension of regulation, 3) the digital innovation redeveloping regulation (moving to a new, preliminary phase), and 4) the permanence of temporal practices displacing regulation. Contributing to design research Designing for Digital Justice provides new possibilities for innovation in the courts, focusing at different levels to better address tensions generated by digitalization. Fellow researchers will find in these pages a sound theoretical advancement at the intersection of digitalization and justice with novel methodological references. Practitioners will benefit from the actionable governance framework Designing for Digital Justice Model, which provides three fields of possibilities for action to design better justice systems. Only by taking into account digital, legal, and social factors can we design better systems that promote access to justice, the rule of law, and, ultimately social peace.
The shallow Earth’s layers are at the interplay of many physical processes: some being driven by atmospheric forcing (precipitation, temperature...) whereas others take their origins at depth, for instance ground shaking due to seismic activity. These forcings cause the subsurface to continuously change its mechanical properties, therefore modulating the strength of the surface geomaterials and hydrological fluxes. Because our societies settle and rely on the layers hosting these time-dependent properties, constraining the hydro-mechanical dynamics of the shallow subsurface is crucial for our future geographical development. One way to investigate the ever-changing physical changes occurring under our feet is through the inference of seismic velocity changes from ambient noise, a technique called seismic interferometry. In this dissertation, I use this method to monitor the evolution of groundwater storage and damage induced by earthquakes. Two research lines are investigated that comprise the key controls of groundwater recharge in steep landscapes and the predictability and duration of the transient physical properties due to earthquake ground shaking. These two types of dynamics modulate each other and influence the velocity changes in ways that are challenging to disentangle. A part of my doctoral research also addresses this interaction. Seismic data from a range of field settings spanning several climatic conditions (wet to arid climate) in various seismic-prone areas are considered. I constrain the obtained seismic velocity time-series using simple physical models, independent dataset, geophysical tools and nonlinear analysis. Additionally, a methodological development is proposed to improve the time-resolution of passive seismic monitoring.
Soil is today considered a non-renewable resource on societal time scale, as the rate of soil loss is higher than the one of soil formation.
Soil formation is complex, can take several thousands of years and is influenced by a variety of factors, one of them is time. Oftentimes, there is the assumption of constant and progressive conditions for soil and/or profile development (i.e., steady-state). In reality, for most of the soils, their (co-)evolution leads to a complex and irregular soil development in time and space characterised by “progressive” and “regressive” phases.
Lateral transport of soil material (i.e., soil erosion) is one of the principal processes shaping the land surface and soil profile during “regressive” phases and one of the major environmental problems the world faces.
Anthropogenic activities like agriculture can exacerbate soil erosion. Thus, it is of vital importance to distinguish short-term soil redistribution rates (i.e., within decades) influenced by human activities differ from long-term natural rates. To do so, soil erosion (and denudation) rates can be determined by using a set of isotope methods that cover different time scales at landscape level.
With the aim to unravel the co-evolution of weathering, soil profile development and lateral redistribution on a landscape level, we used Pluthonium-239+240 (239+240Pu), Beryllium-10 (10Be, in situ and meteoric) and Radiocarbon (14C) to calculate short- and long-term erosion rates in two settings, i.e., a natural and an anthropogenic environment in the hummocky ground moraine landscape of the Uckermark, North-eastern Germany. The main research questions were:
1. How do long-term and short-term rates of soil redistributing processes differ?
2. Are rates calculated from in situ 10Be comparable to those of using meteoric 10Be?
3. How do soil redistribution rates (short- and long-term) in an agricultural and in a natural landscape compare to each other?
4. Are the soil patterns observed in northern Germany purely a result of past events (natural and/or anthropogenic) or are they imbedded in ongoing processes?
Erosion and deposition are reflected in a catena of soil profiles with no or almost no erosion on flat positions (hilltop), strong erosion on the mid-slope and accumulation of soil material at the toeslope position. These three characteristic process domains were chosen within the CarboZALF-D experimental site, characterised by intense anthropogenic activities. Likewise, a hydrosequence in an ancient forest was chosen for this study and being regarded as a catena strongly influenced by natural soil transport.
The following main results were obtained using the above-mentioned range of isotope methods available to measure soil redistribution rates depending on the time scale needed (e.g., 239+240Pu, 10Be, 14C):
1. Short-term erosion rates are one order of magnitude higher than long-term rates in agricultural settings.
2. Both meteoric and in situ 10Be are suitable soil tracers to measure the long-term soil redistribution rates giving similar results in an anthropogenic environment for different landscape positions (e.g., hilltop, mid-slope, toeslope)
3. Short-term rates were extremely low/negligible in a natural landscape and very high in an agricultural landscape – -0.01 t ha-1 yr-1 (average value) and -25 t ha-1 yr-1 respectively. On the contrary, long-term rates in the forested landscape are comparable to those calculated in the agricultural area investigated with average values of -1.00 t ha-1 yr-1 and -0.79 t ha-1 yr-1.
4. Soil patterns observed in the forest might be due to human impact and activities started after the first settlements in the region, earlier than previously postulated, between 4.5 and 6.8 kyr BP, and not a result of recent soil erosion.
5. Furthermore, long-term soil redistribution rates are similar independently from the settings, meaning past natural soil mass redistribution processes still overshadow the present anthropogenic erosion processes.
Overall, this study could make important contributions to the deciphering of the co-evolution of weathering, soil profile development and lateral redistribution in North-eastern Germany. The multi-methodological approach used can be challenged by the application in a wider range of landscapes and geographic regions.
The collaboration-based professional development approach Lesson Study (LS), which has its roots in the Japanese education system, has gained international recognition over the past three decades and spread quickly throughout the world. LS is a collaborative method to professional development (PD) that incorporates multiple characteristics that have been identified in the research literature as key to effective PD. Specifically, LS is a long-term process that consists of subsequent inquiry cycles, it is site-based and integrated in teachers’ practice, it encourages collaboration and reflection, places a strong emphasis on student learning, and it typically involves external experts that support the process or offer additional insights.
As LS integrates all these characteristics, it has rapidly gained international popularity since the turn of the 21st century and is currently being practiced in over 40 countries around the world. This international borrowing of the idea of LS to new national contexts has given rise to a research field that aims to investigate the effectiveness of LS on teacher learning as well as the circumstances and mechanisms that make LS effective in various settings around the world. Such research is important, as borrowing educational innovations and adapting them to new contexts can be a challenging process. Educational innovations that fail to deliver the expected outcomes tend to be abandoned prematurely and before they have been completely understood or a substantial research base has been established.
In order to prevent LS from early abandonment, Lewis and colleagues outlined three critical research needs in 2006, not long after LS was initially introduced to the United States. These research needs included (1) developing a descriptive knowledge base on LS, (2) examining the mechanisms by which teachers learn through LS, and (3) using design-based research cycles to analyze and improve LS.
This dissertation set out to take stock of the progress that has been made on these research needs over the past 20 years. The scoping review conducted for the framework of this dissertation indicates that, while a large and international knowledge base has been developed, the field has not yet produced reliable evidence of the effectiveness of LS. Based on the scoping review, this dissertation makes the case that Lewis et al.’s (2006) critical research needs should be updated. In order to do so, a number of limitations to the current knowledge base on LS need to be addressed. These limitations include (1) the frequent lack of comparable and replicable descriptions of the LS intervention in publications, (2) the incoherent use or lack of use of theoretical frameworks to explain teacher learning through LS, (3) the inconsistent use of terminology and concepts, and (4) the lack of scientific rigor in research studies and of established ways or tools to measure the effectiveness of LS.
This dissertation aims to advance the critical research needs in the field by examining the extent and nature of these limitations in three research studies. The focus of these studies lies on the LS stages of observation and reflection, as these stages have a high potential to facilitate teacher learning. The first study uses a mixed-method design to examine how teachers at German primary schools reflect critically together. The study derives a theory-based definition of critical and collaborative reflection in order to re-frame the reflection element in LS.
The second study, a systematic review of 129 articles on LS, assess how transparent research articles are in reporting how teachers observed and reflected together. In addition, it is investigated whether these articles provide any kind of theorization for the stages of observation and reflection.
The third study proposes a conceptual model for the field of LS that is based on existing models of continuous professional development and research findings on team effectiveness and collaboration. The model describes the dimensions of input, mediating mechanisms, and outcomes in order to provide a conceptual grid to teachers’ continuous professional development through LS.
Carbonates carried in subducting slabs may play a major role in sourcing and storing carbon in the deep Earth’s interior. Current estimates indicate that between 40 to 66 million tons of carbon per year enter subduction zones, but it is uncertain how much of it reaches the lower mantle. It appears that most of this carbon might be extracted from subducting slabs at the mantle wedge and only a limited amount continues deeper and eventually reaches the deep mantle. However, estimations on deeply subducted carbon broadly range from 0.0001 to 52 million tons of carbon per year. This disparity is primarily due to the limited understanding of the survival of carbonate minerals during their transport to deep mantle conditions. Indeed, carbon has very low solubility in mantle silicates, therefore it is expected to be stored primarily in accessory phases such as carbonates. Among those carbonates, magnesite (MgCO3), as a single phase, is the most stable under all mantle conditions. However, experimental investigation on the stability of magnesite in contact with SiO2 at lower mantle conditions suggests that magnesite is stable only along a cold subducted slab geotherm. Furthermore, our understanding of magnesite’s stability when interacting with more complex mantle silicate phases remains incomplete. In the first part of this dissertation, laser-heated diamond anvil cells and multi-anvil apparatus experiments were performed to investigate the stability of magnesite in contact with iron-bearing mantle silicates. Sub-solidus reactions, melting, decarbonation and diamond formation were examined from shallow to mid-lower mantle conditions (25 to 68 GPa; 1300 to 2000 K). Multi-anvil experiments at 25 GPa show the formation of carbonate-rich melt, bridgmanite, and stishovite with melting occurring at a temperature corresponding to all geotherms except the coldest one. In situ X-ray diffraction, in laser-heating diamond anvil cells experiments, shows crystallization of bridgmanite and stishovite but no melt phase was detected in situ at high temperatures. To detect decarbonation phases such as diamond, Raman spectroscopy was used. Crystallization of diamonds is observed as a sub-solidus process even at temperatures relevant and lower than the coldest slab geotherm (1350 K at 33 GPa). Data obtained from this work suggest that magnesite is unstable in contact with the surrounding peridotite mantle in the upper-most lower mantle. The presence of magnesite instead induces melting under oxidized conditions and/or foster diamond formation under more reduced conditions, at depths ∼700 km. Consequently, carbonates will be removed from the carbonate-rich slabs at shallow lower mantle conditions, where subducted slabs can stagnate. Therefore, the transport of carbonate to deeper depths will be restricted, supporting the presence of a barrier for carbon subduction at the top of the lower mantle. Moreover, the reduction of magnesite, forming diamonds provides additional evidence that super-deep diamond crystallization is related to the reduction of carbonates or carbonated-rich melt.
The second part of this dissertation presents the development of a portable laser-heating system optimized for X-ray emission spectroscopy (XES) or nuclear inelastic scattering (NIS) spectroscopy with signal collection at near 90◦. The laser-heated diamond anvil cell is the only static pressure device that can replicate the pressure and temperatures of the Earth’s lower mantle and core. The high temperatures are reached by using high-powered lasers focused on the sample contained between the diamond anvils. Moreover, diamonds’ transparency to X-rays enables in situ X-ray spectroscopy measurements that can probe the sample under high-temperature and high-pressure conditions. Therefore, the development of portable laser-heating systems has linked high-pressure and temperature research with high-resolution X-ray spectroscopy techniques to synchrotron beamlines that do not have a dedicated, permanent, laser-heating system. A general description of the system is provided, as well as details on the use of a parabolic mirror as a reflective imaging objective for on-axis laser heating and radiospectrometric temperature measurements with zero attenuation of incoming X-rays. The parabolic mirror improves the accuracy of temperature measurements free from chromatic aberrations in a wide spectral range and its perforation permits in situ X-rays measurement at synchrotron facilities. The parabolic mirror is a well-suited alternative to refractive objectives in laser heating systems, which will facilitate future applications in the use of CO2 lasers.
In model-driven engineering, the adaptation of large software systems with dynamic structure is enabled by architectural runtime models. Such a model represents an abstract state of the system as a graph of interacting components. Every relevant change in the system is mirrored in the model and triggers an evaluation of model queries, which search the model for structural patterns that should be adapted. This thesis focuses on a type of runtime models where the expressiveness of the model and model queries is extended to capture past changes and their timing. These history-aware models and temporal queries enable more informed decision-making during adaptation, as they support the formulation of requirements on the evolution of the pattern that should be adapted. However, evaluating temporal queries during adaptation poses significant challenges. First, it implies the capability to specify and evaluate requirements on the structure, as well as the ordering and timing in which structural changes occur. Then, query answers have to reflect that the history-aware model represents the architecture of a system whose execution may be ongoing, and thus answers may depend on future changes. Finally, query evaluation needs to be adequately fast and memory-efficient despite the increasing size of the history---especially for models that are altered by numerous, rapid changes.
The thesis presents a query language and a querying approach for the specification and evaluation of temporal queries. These contributions aim to cope with the challenges of evaluating temporal queries at runtime, a prerequisite for history-aware architectural monitoring and adaptation which has not been systematically treated by prior model-based solutions. The distinguishing features of our contributions are: the specification of queries based on a temporal logic which encodes structural patterns as graphs; the provision of formally precise query answers which account for timing constraints and ongoing executions; the incremental evaluation which avoids the re-computation of query answers after each change; and the option to discard history that is no longer relevant to queries. The query evaluation searches the model for occurrences of a pattern whose evolution satisfies a temporal logic formula. Therefore, besides model-driven engineering, another related research community is runtime verification. The approach differs from prior logic-based runtime verification solutions by supporting the representation and querying of structure via graphs and graph queries, respectively, which is more efficient for queries with complex patterns. We present a prototypical implementation of the approach and measure its speed and memory consumption in monitoring and adaptation scenarios from two application domains, with executions of an increasing size. We assess scalability by a comparison to the state-of-the-art from both related research communities. The implementation yields promising results, which pave the way for sophisticated history-aware self-adaptation solutions and indicate that the approach constitutes a highly effective technique for runtime monitoring on an architectural level.
Layered structures are ubiquitous in nature and industrial products, in which individual layers could have different mechanical/thermal properties and functions independently contributing to the performance of the whole layered structure for their relevant application. Tuning each layer affects the performance of the whole layered system.
Pores are utilized in various disciplines, where low density, but large surfaces are demanded. Besides, open and interconnected pores would act as a transferring channel for guest chemical molecules. The shape of pores influences compression behavior of the material. Moreover, introducing pores decreases the density and subsequently the mechanical strength. To maintain defined mechanical strength under various stress, porous structure can be reinforced by adding reinforcement agent such as fiber, filler or layered structure to bear the mechanical stress on demanded application.
In this context, this thesis aimed to generate new functions in bilayer systems by combining layers having different moduli and/or porosity, and to develop suitable processing techniques to access these structures.
Manufacturing processes of layered structures employ often organic solvents mostly causing environmental pollution. In this regard, the studied bilayer structures here were manufactured by processes free of organic solvents.
In this thesis, three bilayer systems were studied to answer the individual questions.
First, while various methods of introducing pores in melt-phase are reported for one-layer constructs with simple geometry, can such methods be applied to a bilayer structure, giving two porous layers?
This was addressed with Bilayer System 1. Two porous layers were obtained from melt-blending of two different polyurethanes (PU) and polyvinyl alcohol (PVA) in a co-continuous phase followed by sequential injection molding and leaching the PVA phase in deionized water. A porosity of 50 ± 5% with a high interconnectivity was obtained, in which the pore sizes in both layers ranged from 1 µm to 100 µm with an average of 22 µm in both layers. The obtained pores were tailored by applying an annealing treatment at relevant high temperatures of 110 °C and 130 °C, which allowed the porosity to be kept constant. The disadvantage of this system is that a maximum of 50% porosity could be reached and removal of leaching material in the weld line section of both layers is not guaranteed. Such a construct serves as a model for bilayer porous structure for determining structure-property relationships with respect to the pore size, porosity and mechanical properties of each layer. This fabrication method is also applicable to complex geometries by designing a relevant mold for injection molding.
Secondly, utilizing scCO2 foaming process at elevated temperature and pressure is considered as a green manufacturing process. Employing this method as a post-treatment can alter the history orientation of polymer chains created by previous fabrication methods. Can a bilayer structure be fabricated by a combination of sequential injection molding and scCO2 foaming process, in which a porous layer is supported by a compact layer?
Such a construct (Bilayer System 2) was generated by sequential injection molding of a PCL (Tm ≈ 58 °C) layer and a PLLA (Tg ≈ 58 °C) layer. Soaking this structure in the autoclave with scCO2 at T = 45 °C and P = 100 bar led to the selective foaming of PCL with a porosity of 80%, while the PLA layer was kept compact. The scCO2 autoclave led to the formation of a porous core and skin layer of the PCL, however, the degree of crystallinity of PLLA layer increased from 0 to 50% at the defined temperature and pressure. The microcellular structure of PCL as well as the degree of crystallinity of PLLA were controlled by increasing soaking time.
Thirdly, wrinkles on surfaces in micro/nano scale alter the properties, which are surface-related. Wrinkles are formed on a surface of a bilayer structure having a compliant substrate and a stiff thin film. However, the reported wrinkles were not reversible. Moreover, dynamic wrinkles in nano and micro scale have numerous examples in nature such as gecko foot hair offering reversible adhesion and an ability of lotus leaves for self-cleaning altering hydrophobicity of the surface. It was envisioned to imitate this biomimetic function on the bilayer structure, where self-assembly on/off patterns would be realized on the surface of this construct.
In summary, developing layered constructs having different properties/functions in the individual layer or exhibiting a new function as the consequence of layered structure can give novel insight for designing layered constructs in various disciplines such as packaging and transport industry, aerospace industry and health technology.
Most machine learning methods provide only point estimates when being queried to predict on new data. This is problematic when the data is corrupted by noise, e.g. from imperfect measurements, or when the queried data point is very different to the data that the machine learning model has been trained with. Probabilistic modelling in machine learning naturally equips predictions with corresponding uncertainty estimates which allows a practitioner to incorporate information about measurement noise into the modelling process and to know when not to trust the predictions. A well-understood, flexible probabilistic framework is provided by Gaussian processes that are ideal as building blocks of probabilistic models. They lend themself naturally to the problem of regression, i.e., being given a set of inputs and corresponding observations and then predicting likely observations for new unseen inputs, and can also be adapted to many more machine learning tasks. However, exactly inferring the optimal parameters of such a Gaussian process model (in a computationally tractable manner) is only possible for regression tasks in small data regimes. Otherwise, approximate inference methods are needed, the most prominent of which is variational inference.
In this dissertation we study models that are composed of Gaussian processes embedded in other models in order to make those more flexible and/or probabilistic. The first example are deep Gaussian processes which can be thought of as a small network of Gaussian processes and which can be employed for flexible regression. The second model class that we study are Gaussian process state-space models. These can be used for time-series modelling, i.e., the task of being given a stream of data ordered by time and then predicting future observations. For both model classes the state-of-the-art approaches offer a trade-off between expressive models and computational properties (e.g. speed or convergence properties) and mostly employ variational inference. Our goal is to improve inference in both models by first getting a deep understanding of the existing methods and then, based on this, to design better inference methods. We achieve this by either exploring the existing trade-offs or by providing general improvements applicable to multiple methods.
We first provide an extensive background, introducing Gaussian processes and their sparse (approximate and efficient) variants. We continue with a description of the models under consideration in this thesis, deep Gaussian processes and Gaussian process state-space models, including detailed derivations and a theoretical comparison of existing methods.
Then we start analysing deep Gaussian processes more closely: Trading off the properties (good optimisation versus expressivity) of state-of-the-art methods in this field, we propose a new variational inference based approach. We then demonstrate experimentally that our new algorithm leads to better calibrated uncertainty estimates than existing methods.
Next, we turn our attention to Gaussian process state-space models, where we closely analyse the theoretical properties of existing methods.The understanding gained in this process leads us to propose a new inference scheme for general Gaussian process state-space models that incorporates effects on multiple time scales. This method is more efficient than previous approaches for long timeseries and outperforms its comparison partners on data sets in which effects on multiple time scales (fast and slowly varying dynamics) are present.
Finally, we propose a new inference approach for Gaussian process state-space models that trades off the properties of state-of-the-art methods in this field. By combining variational inference with another approximate inference method, the Laplace approximation, we design an efficient algorithm that outperforms its comparison partners since it achieves better calibrated uncertainties.
With the recent growth of sensors, cloud computing handles the data processing of many applications. Processing some of this data on the cloud raises, however, many concerns regarding, e.g., privacy, latency, or single points of failure. Alternatively, thanks to the development of embedded systems, smart wireless devices can share their computation capacity, creating a local wireless cloud for in-network processing. In this context, the processing of an application is divided into smaller jobs so that a device can run one or more jobs.
The contribution of this thesis to this scenario is divided into three parts. In part one, I focus on wireless aspects, such as power control and interference management, for deciding which jobs to run on which node and how to route data between nodes. Hence, I formulate optimization problems and develop heuristic and meta-heuristic algorithms to allocate wireless and computation resources. Additionally, to deal with multiple applications competing for these resources, I develop a reinforcement learning (RL) admission controller to decide which application should be admitted. Next, I look into acoustic applications to improve wireless throughput by using microphone clock synchronization to synchronize wireless transmissions.
In the second part, I jointly work with colleagues from the acoustic processing field to optimize both network and application (i.e., acoustic) qualities. My contribution focuses on the network part, where I study the relation between acoustic and network qualities when selecting a subset of microphones for collecting audio data or selecting a subset of optional jobs for processing these data; too many microphones or too many jobs can lessen quality by unnecessary delays. Hence, I develop RL solutions to select the subset of microphones under network constraints when the speaker is moving while still providing good acoustic quality. Furthermore, I show that autonomous vehicles carrying microphones improve the acoustic qualities of different applications. Accordingly, I develop RL solutions (single and multi-agent ones) for controlling these vehicles.
In the third part, I close the gap between theory and practice. I describe the features of my open-source framework used as a proof of concept for wireless in-network processing. Next, I demonstrate how to run some algorithms developed by colleagues from acoustic processing using my framework. I also use the framework for studying in-network delays (wireless and processing) using different distributions of jobs and network topologies.
Species are adapted to the environment they live in. Today, most environments are subjected to rapid global changes induced by human activity, most prominently land cover and climate changes. Such transformations can cause adjustments or disruptions in various eco-evolutionary processes. The repercussions of this can appear at the population level as shifted ranges and altered abundance patterns. This is where global change effects on species are usually detected first.
To understand how eco-evolutionary processes act and interact to generate patterns of range and abundance and how these processes themselves are influenced by environmental conditions, spatially-explicit models provide effective tools. They estimate a species’ niche as the set of environmental conditions in which it can persist. However, the currently most commonly used models rely on static correlative associations that are established between a set of spatial predictors and observed species distributions. For this, they assume stationary conditions and are therefore unsuitable in contexts of global change. Better equipped are process-based models that explicitly implement algorithmic representations of eco-evolutionary mechanisms and evaluate their joint dynamics. These models have long been regarded as difficult to parameterise, but an increased data availability and improved methods for data integration lessen this challenge. Hence, the goal of this thesis is to further develop process-based models, integrate them into a complete modelling workflow, and provide the tools and guidance for their successful application.
With my thesis, I presented an integrated platform for spatially-explicit eco-evolutionary modelling and provided a workflow for their inverse calibration to observational data. In the first chapter, I introduced RangeShiftR, a software tool that implements an individual-based modelling platform for the statistical programming language R. Its open-source licensing, extensive help pages and available tutorials make it accessible to a wide audience. In the second chapter, I demonstrated a comprehensive workflow for the specification, calibration and validation of RangeShiftR by the example of the red kite in Switzerland. The integration of heterogeneous data sources, such as literature and monitoring data, allowed to successfully calibrate the model. It was then used to make validated, spatio-temporal predictions of future red kite abundance. The presented workflow can be adopted to any study species if data is available. In the third chapter, I extended RangeShiftR to directly link demographic processes to climatic predictors. This allowed me to explore the climate-change responses of eight Swiss breeding birds in more detail. Specifically, the model could identify the most influential climatic predictors, delineate areas of projected demographic suitability, and attribute current population trends to contemporary climate change.
My work shows that the application of complex, process-based models in conservation-relevant contexts is feasible, utilising available tools and data. Such models can be successfully calibrated and outperform other currently used modelling approaches in terms of predictive accuracy. Their projections can be used to predict future abundances or to assess alternative conservation scenarios. They further improve our mechanistic understanding of niche and range dynamics under climate change. However, only fully mechanistic models, that include all relevant processes, allow to precisely disentangle the effects of single processes on observed abundances. In this respect, the RangeShiftR model still has potential for further extensions that implement missing influential processes, such as species interactions.
Dynamic, process-based models are needed to adequately model a dynamic reality. My work contributes towards the advancement, integration and dissemination of such models. This will facilitate numeric, model-based approaches for species assessments, generate ecological insights and strengthen the reliability of predictions on large spatial scales under changing conditions.
Zielsetzung und leitendes Erkenntnisinteresse Als Arbeitsgrundlage soll folgende Definition der Bühnengesellschaft als Ausgangspunkt dienen: Die Bühnengesellschaft wird durch die Gesamtzahl der handelnden Personen einer Posse gebildet, die in einem sozialen, psychologischen und mentalen Beziehungsverhältnis zueinanderstehen. Ihr Umfang ist sowohl von gattungsspezifischen als auch von theaterpraktischen Faktoren abhängig. Die Bühnengesellschaft bildet die Schnittstelle zwischen der fiktionalen Welt der Posse und der Lebenswirklichkeit der Zuschauer. Sie verbindet Spielwelt und Wirklichkeit. Durch diese Brückenfunktion werden beide Elemente aufeinander bezogen. Der so umrissene Blick muss bei der Analyse der Bühnengesellschaft von Nestroys Possen folgende unterschiedlich gewichtete und akzentuierte Schwerpunkte enthalten: 1. Figurenkonzeption Die Konzeption der Figuren der Nestroyschen Bühnengesellschaften wird sowohl im Kontext der historischen Wirklichkeit und den herrschenden kulturellen Konzepten als auch in Bezug zur Gattungstradition analysiert unter der erkenntnisleitenden Fragestellung, wie Zeitwirklichkeit („das konfliktreiche Welttheater“) erfahrbar wird. Der Analyse der „komischen Zentralfigur“ kommt in diesem Zusammenhang eine besondere Bedeutung zu. 2. Bühnengesellschaftliche Beziehungen Eine Analyse der Figurenkonstellation, des Verhältnisses von Haupt- und Nebenfiguren sowie der Bildung von Gruppierungen erhellt ihre dramaturgische Funktion im Kontext der satirischen Intention. 3. Bühnengesellschaft und Theater Der theaterwissenschaftliche Aspekt wird dadurch akzentuiert, dass Theaterorganisation, Bühne und die männlich-weibliche Zusammensetzung des Ensembles in den Blick genommen werden, um die Abhängigkeit des Umfangs und der Zusammensetzung der Bühnengesellschaft von den realen Gegebenheiten des Volkstheaterbetriebs aufzuzeigen. Auf der Grundlage der genannten Schwerpunkte wird für die Untersuchung folgendes leitendes Erkenntnisinteresse formuliert: Die Bühnengesellschaft besitzt eine Schnittstellenfunktion zwischen der fiktionalen Spielwelt der Posse und der Lebenswirklichkeit der Zuschauerschaft. Durch die Analyse der personellen und strukturellen Gestaltung der Bühnengesellschaft wird ihre Brückenfunktion für die ‚Wirksamkeit‘ der satirischen und parodistischen Intention erhellt.
In Forschungsprogrammen werden zahlreiche Akteure mit unterschiedlichen Hintergründen und fachlichen Expertisen in Einzel- oder Verbundvorhaben vereint, die jedoch weitestgehend unabhängig voneinander durchgeführt werden. Vor dem Hintergrund, dass gesamtgesellschaftliche Herausforderungen wie die globale Erwärmung zunehmend disziplinübergreifende Lösungsansätze erfordern, sollten Vernetzungs- und Transferprozesse in Forschungsprogrammen stärker in den Fokus rücken. Mit der Implementierung einer Begleitforschung kann dieser Forderung Rechnung getragen werden. Begleitforschung unterscheidet sich in ihrer Herangehensweise und ihrer Zielvorstellung von den „üblichen“ Projekten und kann in unterschiedlichen theoretischen Reinformen auftreten. Verkürzt dargestellt agiert sie entweder (1) inhaltlich komplementär zu den jeweiligen Forschungsprojekten, (2) auf einer Metaebene mit Fokus auf die Prozesse im Forschungsprogramm oder (3) als integrierende, synthetisierende Instanz, für die die Vernetzung der Projekte im Forschungsprogramm sowie der Wissenstransfer von Bedeutung sind. Zwar sind diese Formen analytisch in theoretische Reinformen trennbar, in der Praxis ergibt sich in der Regel jedoch ein Mix aus allen dreien.
In diesem Zusammenhang schließt die vorliegende Dissertation als ergänzende Studie an bisherige Ansätze zum methodischen Handwerkszeug der Begleitforschung an und fokussiert auf folgende Fragestellungen: Auf welcher Basis kann die Vernetzung der Akteure in einem Forschungsprogramm durchgeführt werden, um diese effektiv zusammenzubringen? Welche weiteren methodischen Elemente sollten daran ansetzen, um einen Mehrwert zu generieren, der die Summe der Einzelergebnisse des Forschungsprogrammes übersteigt? Von welcher Art kann dann ein solcher Mehrwert sein und welche Rolle spielt dabei die Begleitforschung?
Das erste methodische Element bildet die Erhebung und Aufbereitung einer Ausgangsdatenbasis. Durch eine auf semantischer Analyse basierenden Verschlagwortung projektbezogener Texte lässt sich eine umfassende Datenbasis aus den Inhalten der Forschungsprojekte generieren. Die Schlagwörter werden dabei anhand eines kontrollierten Vokabulars in einem Schlagwortkatalog strukturiert. Parallel dazu werden sie wiederum den jeweiligen Projekten zugeordnet, wodurch diese thematische Merkmale erhalten. Um thematische Überschneidungen zwischen Forschungsprojekten sichtbar und interpretierbar zu machen, beinhaltet das zweite Element Ansätze zur Visualisierung. Dazu werden die Informationen in einen Netzwerkgraphen transferiert, der sowohl alle im Forschungsprogramm involvierten Projekte als auch die identifizierten Schlagwörter in Relation zueinander abbilden kann. So kann zum Beispiel sichtbar gemacht werden, welche Forschungsprojekte sich auf Basis ihrer Inhalte „näher“ sind als andere. Genau diese Information wird im dritten methodischen Element als Planungsgrundlage für unterschiedliche Veranstaltungsformate wie Arbeitstagungen oder Transferwerkstätten genutzt. Das vierte methodische Element umfasst die Synthesebildung. Diese gestaltet sich als Prozess über den gesamten Zeitraum der Zusammenarbeit zwischen Begleitforschung und den weiteren Forschungsprojekten hinweg, da in die Synthese unter anderem Zwischen-, Teil- und Endergebnisse der Projekte einfließen, genauso wie Inhalte aus den unterschiedlichen Veranstaltungen. Letztendlich ist dieses vierte Element auch das Mittel, um aus den integrierten und synthetisierten Informationen Handlungsempfehlungen für zukünftige Vorhaben abzuleiten.
Die Erarbeitung der methodischen Elemente erfolgte im laufenden Prozess des Begleitforschungsprojektes KlimAgrar, welches der vorliegenden Dissertation als Fallbeispiel dient und dessen Hintergründe in der Thematik Klimaschutz und Klimaanpassung in der Landwirtschaft im Text ausführlich erläutert werden.
This cumulative dissertation consists of three full empirical investigations based on three separate collections of data dealing with the phenomenon of negotiations in audit processes, which are combined in two research articles. In the first study, I examine internal auditors’ views on negotiation interactions with auditees. My research is based on 23 semi-structured interviews with internal auditors (14 in-house and 9 external service providers) to gain insight into when and about what (RQ1), why (RQ2), and how (RQ3) they negotiate with auditees. By adapting the Gibbins et al. (2001) negotiation framework to the context of internal auditing, I obtain specific process (negotiation issue, auditor-auditee process, and outcome) and context elements that form the basis of my analyses. Through the additional use of inductive procedures, I conclude that internal auditors negotiate when they face professional and non-professional resistance from auditees during the audit process (RQ1). This resistance occurs in a variety of audit types and audit issues. Internal auditors choose negotiations to overcome this resistance primarily out of functional interest, as they cannot simply instruct auditees to acknowledge the findings and implement the required actions (RQ2). I find that the implementation of the required actions is the main goal of the respondents, which is also an important quality factor for internal auditing. Although few respondents interpret these interactions with auditees as negotiations, all respondents use a variety of negotiation strategies to create value (e.g., cost cutting, logrolling, and bridging) and claim value (e.g. positional commitment and threats) (RQ3). Finally, I contribute to empirical research on internal audit negotiations and internal audit quality by shedding light on the black box of internal auditor-auditee interactions. The second study consists of two experiments that examine the effects of tax auditors’ emotion expressions during tax audit negotiations. In the first experiment, we demonstrate that auditors expressing anger obtain more concessions from taxpayers than auditors expressing happiness. This reveals that taxpayers interpret auditors’ emotions strategically and do not respond affectively. In the second experiment, we show that the experience with an auditor who expressed either happiness or anger reduces taxpayers’ post-audit compliance compared to the experience with an emotionally neutral auditor. Apparently, taxpayers use their experience with an emotional auditor to rationalize later noncompliance. Taken together, both experiments show the potentially detrimental effects of positive and negative emotion expressions by the auditor and point to the benefits of avoiding emotion expressions. We find that when auditors avoid emotion expressions this does not result in fewer concessions from taxpayers than when auditors express anger. However, when auditors avoid emotion expressions this leads to a significantly better evaluation of the taxpayer-auditor relationship and significantly reduces taxpayers’ post-audit noncompliance.
Natural gas hydrates are ice-like crystalline compounds containing water cavities that trap natural gas molecules like methane (CH4), which is a potent greenhouse gas with high energy density. The Mallik site at the Mackenzie Delta in the Canadian Arctic contains a large volume of technically recoverable CH4 hydrate beneath the base of the permafrost. Understanding how the sub-permafrost hydrate is distributed can aid in searching for the ideal locations for deploying CH4 production wells to develop the hydrate as a cleaner alternative to crude oil or coal. Globally, atmospheric warming driving permafrost thaw results in sub-permafrost hydrate dissociation, releasing CH4 into the atmosphere to intensify global warming. It is therefore crucial to evaluate the potential risk of hydrate dissociation due to permafrost degradation. To quantitatively predict hydrate distribution and volume in complex sub-permafrost environments, a numerical framework was developed to simulate sub-permafrost hydrate formation by coupling the equilibrium CH4-hydrate formation approach with a fluid flow and transport simulator (TRANSPORTSE). In addition, integrating the equations of state describing ice melting and forming with TRANSPORTSE enabled this framework to simulate the permafrost evolution during the sub-permafrost hydrate formation. A modified sub-permafrost hydrate formation mechanism for the Mallik site is presented in this study. According to this mechanism, the CH4-rich fluids have been vertically transported since the Late Pleistocene from deep overpressurized zones via geologic fault networks to form the observed hydrate deposits in the Kugmallit–Mackenzie Bay Sequences. The established numerical framework was verified by a benchmark of hydrate formation via dissolved methane. Model calibration was performed based on laboratory data measured during a multi-stage hydrate formation experiment undertaken in the LArge scale Reservoir Simulator (LARS). As the temporal and spatial evolution of simulated and observed hydrate saturation matched well, the LARS model was therefore validated. This laboratory-scale model was then upscaled to a field-scale 2D model generated from a seismic transect across the Mallik site. The simulation confirmed the feasibility of the introduced sub-permafrost hydrate formation mechanism by demonstrating consistency with field observations. The 2D model was extended to the first 3D model of the Mallik site by using well-logs and seismic profiles, to investigate the geologic controls on the spatial hydrate distribution. An assessment of this simulation revealed the hydraulic contribution of each geological element, including relevant fault networks and sedimentary sequences. Based on the simulation results, the observed heterogeneous distribution of sub-permafrost hydrate resulted from the combined factors of the source-gas generation rate, subsurface temperature, and the permeability of geologic elements. Analysis of the results revealed that the Mallik permafrost was heated by 0.8–1.3 °C, induced by the global temperature increase of 0.44 °C and accelerated by Arctic amplification from the early 1970s to the mid-2000s. This study presents a numerical framework that can be applied to study the formation of the permafrost-hydrate system from laboratory to field scales, across timescales ranging from hours to millions of years. Overall, these simulations deepen the knowledge about the dominant factors controlling the spatial hydrate distribution in sub-permafrost environments with heterogeneous geologic elements. The framework can support improving the design of hydrate formation experiments and provide valuable contributions to future industrial hydrate exploration and exploitation activities.
The East African Rift System (EARS) is a significant example of active tectonics, which provides opportunities to examine the stages of continental faulting and landscape evolution. The southwest extension of the EARS is one of the most significant examples of active tectonics nowadays, however, seismotectonic research in the area has been scarce, despite the fundamental importance of neotectonics. Our first study area is located between the Northern Province of Zambia and the southeastern Katanga Province of the Democratic Republic of Congo. Lakes Mweru and Mweru Wantipa are part of the southwest extension of the EARS. Fault analysis reveals that, since the Miocene, movements along the active Mweru-Mweru Wantipa Fault System (MMFS) have been largely responsible for the reorganization of the landscape and the drainage patterns across the southwestern branch of the EARS. To investigate the spatial and temporal patterns of fluvial-lacustrine landscape development, we determined in-situ cosmogenic 10Be and 26Al in a total of twenty-six quartzitic bedrock samples that were collected from knickpoints across the Mporokoso Plateau (south of Lake Mweru) and the eastern part of the Kundelungu Plateau (north of Lake Mweru). Samples from the Mporokoso Plateau and close to the MMFS provide evidence of temporary burial. By contrast, surfaces located far from the MMFS appear to have remained uncovered since their initial exposure as they show consistent 10Be and 26Al exposure ages ranging up to ~830 ka. Reconciliation of the observed burial patterns with morphotectonic and stratigraphic analysis reveals the existence of an extensive paleo-lake during the Pleistocene. Through hypsometric analyses of the dated knickpoints, the potential maximum water level of the paleo-lake is constrained to ~1200 m asl (present lake lavel: 917 m asl). High denudation rates (up to ~40 mm ka-1) along the eastern Kundelungu Plateau suggest that footwall uplift, resulting from normal faulting, caused river incision, possibly controlling paleo-lake drainage. The lake level was reduced gradually reaching its current level at ~350 ka.
Parallel to the MMFS in the north, the Upemba Fault System (UFS) extends across the southeastern Katanga Province of the Democratic Republic of Congo. This part of our research is focused on the geomorphological behavior of the Kiubo Waterfalls. The waterfalls are the currently active knickpoint of the Lufira River, which flows into the Upemba Depression. Eleven bedrock samples along the Lufira River and its tributary stream, Luvilombo River, were collected. In-situ cosmogenic 10Be and 26Al were used in order to constrain the K constant of the Stream Power Law equation. Constraining the K constant allowed us to calculate the knickpoint retreat rate of the Kiubo Waterfalls at ~0.096 m a-1. Combining the calculated retreat rate of the knickpoint with DNA sequencing from fish populations, we managed to present extrapolation models and estimate the location of the onset of the Kiubo Waterfalls, revealing its connection to the seismicity of the UFS.
Vereine als Gefahr
(2023)
Die von kriminellen oder extremistischen Gruppen ausgehende Gefahr erhöht sich entsprechend ihres Organisationsgrades. Eine Zustandsanalyse des Vereinsrechts zeigt, dass Vereins- und Kennzeichenverbote wirkmächtige präemptive Maßnahmen gegen neue dezentrale oder mehrstufige Vereinigungen bleiben. Bei ihrer Weiterentwicklung lenkt Sandra Lukosek den Blick auf die Auslegung und wechselseitige Zurechnung verbotsrelevanten Verhaltens einzelner Mitglieder zum Verein und der Erstreckung auf gleichrangige Schwestervereine. Anhand des Waffenrechts arbeitet sie umgekehrt die Vereinszugehörigkeit als taugliches Wesensmerkmal der Mitglieder heraus. Sie betrachtet verschiedene Vereinstypen mit zu differenzierenden vereinigungsfreiheitlichen Schutzbereichen. Ein Verbot religiöser islamistisch-extremistischer Vereine unterscheidet sich vom Verbot eines Rocker- oder Reichsbürgervereins. Die Autorin lässt sich auf sicherheitsbehördliche Herausforderungen ein und findet praktikable Reformansätze zur Fortentwicklung des Vereinsrechts.
Air pollution has been a persistent global problem in the past several hundred years. While some industrialized nations have shown improvements in their air quality through stricter regulation, others have experienced declines as they rapidly industrialize. The WHO’s 2021 update of their recommended air pollution limit values reflects the substantial impacts on human health of pollutants such as NO2 and O3, as recent epidemiological evidence suggests substantial long-term health impacts of air pollution even at low concentrations. Alongside developments in our understanding of air pollution's health impacts, the new technology of low-cost sensors (LCS) has been taken up by both academia and industry as a new method for measuring air pollution. Due primarily to their lower cost and smaller size, they can be used in a variety of different applications, including in the development of higher resolution measurement networks, in source identification, and in measurements of air pollution exposure. While significant efforts have been made to accurately calibrate LCS with reference instrumentation and various statistical models, accuracy and precision remain limited by variable sensor sensitivity. Furthermore, standard procedures for calibration still do not exist and most proprietary calibration algorithms are black-box, inaccessible to the public. This work seeks to expand the knowledge base on LCS in several different ways: 1) by developing an open-source calibration methodology; 2) by deploying LCS at high spatial resolution in urban environments to test their capability in measuring microscale changes in urban air pollution; 3) by connecting LCS deployments with the implementation of local mobility policies to provide policy advice on resultant changes in air quality.
In a first step, it was found that LCS can be consistently calibrated with good performance against reference instrumentation using seven general steps: 1) assessing raw data distribution, 2) cleaning data, 3) flagging data, 4) model selection and tuning, 5) model validation, 6) exporting final predictions, and 7) calculating associated uncertainty. By emphasizing the need for consistent reporting of details at each step, most crucially on model selection, validation, and performance, this work pushed forward with the effort towards standardization of calibration methodologies. In addition, with the open-source publication of code and data for the seven-step methodology, advances were made towards reforming the largely black-box nature of LCS calibrations.
With a transparent and reliable calibration methodology established, LCS were then deployed in various street canyons between 2017 and 2020. Using two types of LCS, metal oxide (MOS) and electrochemical (EC), their performance in capturing expected patterns of urban NO2 and O3 pollution was evaluated. Results showed that calibrated concentrations from MOS and EC sensors matched general diurnal patterns in NO2 and O3 pollution measured using reference instruments. While MOS proved to be unreliable for discerning differences among measured locations within the urban environment, the concentrations measured with calibrated EC sensors matched expectations from modelling studies on NO2 and O3 pollution distribution in street canyons. As such, it was concluded that LCS are appropriate for measuring urban air quality, including for assisting urban-scale air pollution model development, and can reveal new insights into air pollution in urban environments.
To achieve the last goal of this work, two measurement campaigns were conducted in connection with the implementation of three mobility policies in Berlin. The first involved the construction of a pop-up bike lane on Kottbusser Damm in response to the COVID-19 pandemic, the second surrounded the temporary implementation of a community space on Böckhstrasse, and the last was focused on the closure of a portion of Friedrichstrasse to all motorized traffic. In all cases, measurements of NO2 were collected before and after the measure was implemented to assess changes in air quality resultant from these policies. Results from the Kottbusser Damm experiment showed that the bike-lane reduced NO2 concentrations that cyclists were exposed to by 22 ± 19%. On Friedrichstrasse, the street closure reduced NO2 concentrations to the level of the urban background without worsening the air quality on side streets. These valuable results were communicated swiftly to partners in the city administration responsible for evaluating the policies’ success and future, highlighting the ability of LCS to provide policy-relevant results.
As a new technology, much is still to be learned about LCS and their value to academic research in the atmospheric sciences. Nevertheless, this work has advanced the state of the art in several ways. First, it contributed a novel open-source calibration methodology that can be used by a LCS end-users for various air pollutants. Second, it strengthened the evidence base on the reliability of LCS for measuring urban air quality, finding through novel deployments in street canyons that LCS can be used at high spatial resolution to understand microscale air pollution dynamics. Last, it is the first of its kind to connect LCS measurements directly with mobility policies to understand their influences on local air quality, resulting in policy-relevant findings valuable for decisionmakers. It serves as an example of the potential for LCS to expand our understanding of air pollution at various scales, as well as their ability to serve as valuable tools in transdisciplinary research.
Rainfall-triggered landslides are a globally occurring hazard that cause several thousand fatalities per year on average and lead to economic damages by destroying buildings and infrastructure and blocking transportation networks. For people living and governing in susceptible areas, knowing not only where, but also when landslides are most probable is key to inform strategies to reduce risk, requiring reliable assessments of weather-related landslide hazard and adequate warning. Taking proper action during high hazard periods, such as moving to higher levels of houses, closing roads and rail networks, and evacuating neighborhoods, can save lives. Nevertheless, many regions of the world with high landslide risk currently lack dedicated, operational landslide early warning systems.
The mounting availability of temporal landslide inventory data in some regions has increasingly enabled data-driven approaches to estimate landslide hazard on the basis of rainfall conditions. In other areas, however, such data remains scarce, calling for appropriate statistical methods to estimate hazard with limited data. The overarching motivation for this dissertation is to further our ability to predict rainfall-triggered landslides in time in order to expand and improve warning. To this end, I applied Bayesian inference to probabilistically quantify and predict landslide activity as a function of rainfall conditions at spatial scales ranging from a small coastal town, to metropolitan areas worldwide, to a multi-state region, and temporal scales from hourly to seasonal. This thesis is composed of three studies.
In the first study, I contributed to developing and validating statistical models for an online landslide warning dashboard for the small town of Sitka, Alaska, USA. We used logistic and Poisson regressions to estimate daily landslide probability and counts from an inventory of only five reported landslide events and 18 years of hourly precipitation measurements at the Sitka airport. Drawing on community input, we established two warning thresholds for implementation in the dashboard, which uses observed rainfall and US National Weather Service forecasts to provide real-time estimates of landslide hazard.
In the second study, I estimated rainfall intensity-duration thresholds for shallow landsliding for 26 cities worldwide and a global threshold for urban landslides. I found that landslides in urban areas occurred at rainfall intensities that were lower than previously reported global thresholds, and that 31% of urban landslides were triggered during moderate rainfall events. However, landslides in cities with widely varying climates and topographies were triggered above similar critical rainfall intensities: thresholds for 77% of cities were indistinguishable from the global threshold, suggesting that urbanization may harmonize thresholds between cities, overprinting natural variability. I provide a baseline threshold that could be considered for warning in cities with limited landslide inventory data.
In the third study, I investigated seasonal landslide response to annual precipitation patterns in the Pacific Northwest region, USA by using Bayesian multi-level models to combine data from five heterogeneous landslide inventories that cover different areas and time periods. I quantitatively confirmed a distinctly seasonal pattern of landsliding and found that peak landslide activity lags the annual precipitation peak. In February, at the height of the landslide season, landslide intensity for a given amount of monthly rainfall is up to ten times higher than at the season onset in November, underlining the importance of antecedent seasonal hillslope conditions.
Together, these studies contributed actionable, objective information for landslide early warning and examples for the application of Bayesian methods to probabilistically quantify landslide hazard from inventory and rainfall data.
Residential segregation is a widespread phenomenon that can be observed in almost every major city. In these urban areas, residents with different ethnical or socioeconomic backgrounds tend to form homogeneous clusters. In Schelling’s classical segregation model two types of agents are placed on a grid. An agent is content with its location if the fraction of its neighbors, which have the same type as the agent, is at least 𝜏, for some 0 < 𝜏 ≤ 1. Discontent agents simply swap their location with a randomly chosen other discontent agent or jump to a random empty location. The model gives a coherent explanation of how clusters can form even if all agents are tolerant, i.e., if they agree to live in mixed neighborhoods. For segregation to occur, all it needs is a slight bias towards agents preferring similar neighbors.
Although the model is well studied, previous research focused on a random process point of view. However, it is more realistic to assume instead that the agents strategically choose where to live. We close this gap by introducing and analyzing game-theoretic models of Schelling segregation, where rational agents strategically choose their locations.
As the first step, we introduce and analyze a generalized game-theoretic model that allows more than two agent types and more general underlying graphs modeling the residential area. We introduce different versions of Swap and Jump Schelling Games. Swap Schelling Games assume that every vertex of the underlying graph serving as a residential area is occupied by an agent and pairs of discontent agents can swap their locations, i.e., their occupied vertices, to increase their utility. In contrast, for the Jump Schelling Game, we assume that there exist empty vertices in the graph and agents can jump to these vacant vertices if this increases their utility. We show that the number of agent types as well as the structure of underlying graph heavily influence the dynamic properties and the tractability of finding an optimal strategy profile.
As a second step, we significantly deepen these investigations for the swap version with 𝜏 = 1 by studying the influence of the underlying topology modeling the residential area on the existence of equilibria, the Price of Anarchy, and the dynamic properties. Moreover, we restrict the movement of agents locally. As a main takeaway, we find that both aspects influence the existence and the quality of stable states.
Furthermore, also for the swap model, we follow sociological surveys and study, asking the same core game-theoretic questions, non-monotone singlepeaked utility functions instead of monotone ones, i.e., utility functions that are not monotone in the fraction of same-type neighbors. Our results clearly show that moving from monotone to non-monotone utilities yields novel structural properties and different results in terms of existence and quality of stable states.
In the last part, we introduce an agent-based saturated open-city variant, the Flip Schelling Process, in which agents, based on the predominant type in their neighborhood, decide whether to change their types. We provide a general framework for analyzing the influence of the underlying topology on residential segregation and investigate the probability that an edge is monochrome, i.e., that both incident vertices have the same type, on random geometric and Erdős–Rényi graphs. For random geometric graphs, we prove the existence of a constant c > 0 such that the expected fraction of monochrome edges after the Flip Schelling Process is at least 1/2 + c. For Erdős–Rényi graphs, we show the expected fraction of monochrome edges after the Flip Schelling Process is at most 1/2 + o(1).
Today, point clouds are among the most important categories of spatial data, as they constitute digital 3D models of the as-is reality that can be created at unprecedented speed and precision. However, their unique properties, i.e., lack of structure, order, or connectivity information, necessitate specialized data structures and algorithms to leverage their full precision. In particular, this holds true for the interactive visualization of point clouds, which requires to balance hardware limitations regarding GPU memory and bandwidth against a naturally high susceptibility to visual artifacts.
This thesis focuses on concepts, techniques, and implementations of robust, scalable, and portable 3D visualization systems for massive point clouds. To that end, a number of rendering, visualization, and interaction techniques are introduced, that extend several basic strategies to decouple rendering efforts and data management: First, a novel visualization technique that facilitates context-aware filtering, highlighting, and interaction within point cloud depictions. Second, hardware-specific optimization techniques that improve rendering performance and image quality in an increasingly diversified hardware landscape. Third, natural and artificial locomotion techniques for nausea-free exploration in the context of state-of-the-art virtual reality devices. Fourth, a framework for web-based rendering that enables collaborative exploration of point clouds across device ecosystems and facilitates the integration into established workflows and software systems.
In cooperation with partners from industry and academia, the practicability and robustness of the presented techniques are showcased via several case studies using representative application scenarios and point cloud data sets. In summary, the work shows that the interactive visualization of point clouds can be implemented by a multi-tier software architecture with a number of domain-independent, generic system components that rely on optimization strategies specific to large point clouds. It demonstrates the feasibility of interactive, scalable point cloud visualization as a key component for distributed IT solutions that operate with spatial digital twins, providing arguments in favor of using point clouds as a universal type of spatial base data usable directly for visualization purposes.
Control over spin and electronic structure of MoS₂ monolayer via interactions with substrates
(2023)
The molybdenum disulfide (MoS2) monolayer is a semiconductor with a direct bandgap while it is a robust and affordable material.
It is a candidate for applications in optoelectronics and field-effect transistors.
MoS2 features a strong spin-orbit coupling which makes its spin structure promising for acquiring the Kane-Mele topological concept with corresponding applications in spintronics and valleytronics.
From the optical point of view, the MoS2 monolayer features two valleys in the regions of K and K' points. These valleys are differentiated by opposite spins and a related valley-selective circular dichroism.
In this study we aim to manipulate the MoS2 monolayer spin structure in the vicinity of the K and K' points to explore the possibility of getting control over the optical and electronic properties.
We focus on two different substrates to demonstrate two distinct routes: a gold substrate to introduce a Rashba effect and a graphene/cobalt substrate to introduce a magnetic proximity effect in MoS2.
The Rashba effect is proportional to the out-of-plane projection of the electric field gradient. Such a strong change of the electric field occurs at the surfaces of a high atomic number materials and effectively influence conduction electrons as an in-plane magnetic field. A molybdenum and a sulfur are relatively light atoms, thus, similar to many other 2D materials, intrinsic Rashba effect in MoS2 monolayer is vanishing small. However, proximity of a high atomic number substrate may enhance Rashba effect in a 2D material as it was demonstrated for graphene previously.
Another way to modify the spin structure is to apply an external magnetic field of high magnitude (several Tesla), and cause a Zeeman splitting, the conduction electrons.
However, a similar effect can be reached via magnetic proximity which allows us to reduce external magnetic fields significantly or even to zero. The graphene on cobalt interface is ferromagnetic and stable for MoS2 monolayer synthesis. Cobalt is not the strongest magnet; therefore, stronger magnets may lead to more significant results.
Nowadays most experimental studies on the dichalcogenides (MoS2 included) are performed on encapsulated heterostructures that are produced by mechanical exfoliation.
While mechanical exfoliation (or scotch-tape method) allows to produce a huge variety of structures, the shape and the size of the samples as well as distance between layers in heterostructures are impossible to control reproducibly.
In our study we used molecular beam epitaxy (MBE) methods to synthesise both MoS2/Au(111) and MoS2/graphene/Co systems.
We chose to use MBE, as it is a scalable and reproducible approach, so later industry may adapt it and take over.
We used graphene/cobalt instead of just a cobalt substrate because direct contact of MoS2\ monolayer and a metallic substrate may lead to photoluminescence (PL) quenching in the metallic substrate. Graphene and hexagonal boron nitride monolayer are considered building blocks of a new generation of electronics also commonly used as encapsulating materials for PL studies. Moreover graphene is proved to be a suitable substrate for the MBE growth of transitional metal dichalcogenides (TMDCs).
In chapter 1,
we start with an introduction to TMDCs. Then we focus on MoS2 monolayer state of the art research in the fields of application scenario; synthesis approaches; electronic, spin, and optical properties; and interactions with magnetic fields and magnetic materials.
We briefly touch the basics of magnetism in solids and move on to discuss various magnetic exchange interactions and magnetic proximity effect.
Then we describe MoS2 optical properties in more detail. We start from basic exciton physics and its manifestation in the MoS2 monolayer. We consider optical selection rules in the MoS2 monolayer and such properties as chirality, spin-valley locking, and coexistence of bright and dark excitons.
Chapter 2 contains an overview of the employed surface science methods: angle-integrated, angle-resolved, and spin-resolved photoemission; low energy electron diffraction and scanning tunneling microscopy.
In chapter 3, we describe MoS2 monolayer synthesis details for two substrates: gold monocrystal with (111) surface and graphene on cobalt thin film with Co(111) surface orientation.
The synthesis descriptions are followed by a detailed characterisation of the obtained structures: fingerprints of MoS2 monolayer formation; MoS2 monolayer symmetry and its relation to the substrate below; characterisation of MoS2 monolayer coverage, domain distribution, sizes and shapes, and moire structures.
In chapter~4, we start our discussion with MoS2/Au(111) electronic and spin structure. Combining density functional theory computations (DFT) and spin-resolved photoemission studies, we demonstrate that the MoS2 monolayer band structure features an in-plane Rashba spin splitting. This confirms the possibility of MoS2 monolayer spin structure manipulation via a substrate.
Then we investigate the influence of a magnetic proximity in the MoS2/graphene/Co system on the MoS2 monolayer spin structure.
We focus our investigation on MoS2 high symmetry points: G and K.
First, using spin-resolved measurements, we confirm that electronic states are spin-split at the G point via a magnetic proximity effect. Second, combining spin-resolved measurements and DFT computations for MoS2 monolayer in the K point region, we demonstrate the appearance of a small in-plane spin polarisation in the valence band top and predict a full in-plane spin polarisation for the conduction band bottom.
We move forward discussing how these findings are related to the MoS2 monolayer optical properties, in particular the possibility of dark exciton observation. Additionally, we speculate on the control of the MoS2 valley energy via magnetic proximity from cobalt.
As graphene is spatially buffering the MoS2 monolayer from the Co thin film, we speculate on the role of graphene in the magnetic proximity transfer by replacing graphene with vacuum and other 2D materials in our computations.
We finish our discussion by investigating the K-doped MoS2/graphene/Co system and the influence of this doping on the electronic and spin structure as well as on the magnetic proximity effect.
In summary, using a scalable MBE approach we synthesised
MoS2/Au(111) and MoS2/graphene/Co systems. We found a Rashba effect taking place in MoS2/Au(111) which proves that the MoS2 monolayer in-plane spin structure can be modified. In MoS2/graphene/Co the in-plane magnetic proximity effect indeed takes place which rises the possibility of fine tuning the MoS2 optical properties via manipulation of the the substrate magnetisation.
The work is designed to investigate the impacts and sensitivity of climate change on water resources, droughts and hydropower production in Malawi, the South-Eastern region which is highly vulnerable to climate change. It is observed that rainfall is decreasing and temperature is increasing which calls for the understanding of what these changes may impact the water resources, drought occurrences and hydropower generation in the region. The study is conducted in the Greater Lake Malawi Basin (Lake Malawi and Shire River Basins) and is divided into three projects. The first study is assessing the variability and trends of both meteorological and hydrological droughts from 1970-2013 in Lake Malawi and Shire River basins using the standardized precipitation index (SPI) and standardized precipitation and evaporation Index (SPEI) for meteorological droughts and the lake level change index (LLCI) for hydrological droughts. And later the relationship of the meteorological and hydrological droughts is established.
While the second study extends the drought analysis into the future by examining the potential future meteorological water balance and associated drought characteristics such as the drought intensity (DI), drought months (DM), and drought events (DE) in the Greater Lake Malawi Basin. The sensitivity of drought to changes of rainfall and temperature is also assessed using the scenario-neutral approach. The climate change projections from 20 Coordinated Regional Climate Downscaling Experiment (CORDEX) models for Africa based on two scenarios (RCP4.5 and RCP8.5) for the periods 2021–2050 and 2071–2100 are used. The study also investigates the effect of bias-correction (i.e., empirical quantile mapping) on the ability of the climate model ensemble in reproducing observed drought characteristics as compared to raw climate projections.
The sensitivity of key hydrologic variables and hydropower generation to climate change in Lake Malawi and Shire River basins is assessed in third study. The study adapts the mesoscale Hydrological Model (mHM) which is applied separately in the Upper Lake Malawi and Shire River basins. A particular Lake Malawi model, which focuses on reservoir routing and lake water balance, has been developed and is interlinked between the two basins. Similar to second study, the scenario-neutral approach is also applied to determine the sensitivity of climate change on water resources more particularly Lake Malawi level and Shire River flow which later helps to estimate the hydropower production susceptibility.
Results suggest that meteorological droughts are increasing due to a decrease in precipitation which is exacerbated by an increase in temperature (potential evapotranspiration). The hydrological system of Lake Malawi seems to have a >24-month memory towards meteorological conditions since the 36-months SPEI can predict hydrological droughts ten-months in advance. The study has found the critical lake level that would trigger hydrological drought to be 474.1 m.a.s.l.
Despite the differences in the internal structures and uncertainties that exist among the climate models, they all agree on an increase of meteorological droughts in the future in terms of higher DI and longer events (DM). DI is projected to increase between +25% and +50% during 2021-2050 and between +131% and +388% during 2071-2100. This translates into +3 to +5, and +7 to +8 more drought months per year during both periods, respectively. With longer lasting drought events, DE is decreasing. Projected droughts based on RCP8.5 are 1.7 times more severe than droughts based on RCP4.5.
It is also found that an annual temperature increase of 1°C decreases mean lake level and outflow by 0.3 m and 17%, respectively, signifying the importance of intensified evaporation for Lake Malawi’s water budget. Meanwhile, a +5% (-5%) deviation in annual rainfall changes mean lake level by +0.7 m (-0.6 m). The combined effects of temperature increase and rainfall decrease result in significantly lower flows on Shire River. The hydrological river regime may change from perennial to seasonal with the combination of annual temperature increase and precipitation decrease beyond 1.5°C (3.5°C) and -20% (-15%). The study further projects a reduction in annual hydropower production between 1% (RCP8.5) and 2.5% (RCP4.5) during 2021–2050 and between 5% (RCP4.5) and 24% (RCP8.5) during 2071–2100.
The findings are later linked to global policies more particularly the United Nations Framework Convention on Climate Change (UNFCCC)’s Paris Agreement and the United Nations (UN)’s Sustainable Development Goals (SDGs), and how the failure to adhere the restriction of temperature increase below the global limit of 1.5°C will affect drought and the water resources in Malawi consequently impact the hydropower production. As a result, the achievement of most of the SDGs will be compromised.
The results show that it is of great importance that a further development of hydro energy on the Shire River should take into account the effects of climate change. The information generation is important for decision making more especially supporting the climate action required to fight against climate change. The frequency of extreme climate events due to climate change has reached the climate emergency as saving lives and livelihoods require urgent action.
Reiz der Revolution
(2023)
Die Dissertation untersucht die vielseitigen Verflechtungen und Transfers im Rahmen der deutschen Nicaraguasolidarität der späten 1970er und der 1980er Jahre. Bereits im Vorfeld ihres Machtantritts hatten die Sandinistas in beiden Lagern um ausländische staatliche und zivile Unterstützung geworben. Nun gestalteten sie mit dem sandinistischen Reformstaat zugleich ein internationales Netz an Solidaritätsbeziehungen aus, die zur Finanzierung ihrer sozialreformerischen Programme, aber auch zur Legitimation ihrer Herrschaft dienten.
Allein in der Bundesrepublik entstanden mehrere hundert Solidaritätsgruppen. In der DDR löste die politische Führung eine staatlich gelenkte Solidarisierung mit Nicaragua aus, der sich zehntausende Menschen und unabhängige Basisinitiativen anschlossen. Trotz ihrer Verwurzelung in rivalisierenden Systemen und der Heterogenität ihrer Weltbilder – von christlicher Soziallehre bis zur kritischen Linken – arbeiteten etliche Solidaritätsinitiativen in beiden Ländern am selben Zielobjekt: einem Nicaragua jenseits der Blöcke. Gemeinsam mit ihren nicaraguanischen Projektpartner_innen eröffneten sie auf transnationaler Ebene einen neuen Raum für Kommunikation und stießen dabei auf Differenzen und Auseinandersetzungen über politische Ideen, die beiderseits des Atlantiks neue Praktiken anregten.
Die Forschungsarbeit basiert auf einer umfangreichen Quellenauswertung in insgesamt 13 Archiven, darunter das Archiv der Robert-Havemann-Gesellschaft, das Archiv der BStU, verschiedene westdeutsche Bewegungsarchive und die archivalischen Nachlässe des nicaraguanischen Kulturministeriums.
Pichia pastoris (syn. Komagataella phaffi) is a distinguished expression system widely used in industrial production processes. Recent molecular research has focused on numerous approaches to increase recombinant protein yield in P. pastoris. For example, the design of expression vectors and synthetic genetic elements, gene copy number optimization, or co-expression of helper proteins
(transcription factors, chaperones, etc.). However, high clonal variability of transformants and low screening throughput have hampered significant success.
To enhance screening capacities, display-based methodologies inherit the potential for efficient isolation of producer clones via fluorescence-activated cell sorting (FACS). Therefore, this study focused on developing a novel clone selection method that is based on the non-covalent attachment of Fab fragments on the P. pastoris cell surface to be applicable for FACS.
Initially, a P. pastoris display system was developed, which is a prerequisite for the surface capture of secreted Fabs. A Design of Experiments approach was applied to analyze the influence of various genetic elements on antibody fragment display. The combined P. pastoris formaldehyde dehydrogenase promoter (PFLD1), Saccharomyces cerevisiae invertase 2 signal peptide (ScSUC2), - agglutinin (ScSAG1) anchor protein, and the ARS of Kluyveromyces lactis (panARS) conferred highest display levels.
Subsequently, eight single-chain variable fragments (scFv) specific for the constant part of the Fab heavy or light chain were individually displayed in P. pastoris. Among the tested scFvs, the anti-human CH1 IgG domain scFv allowed the most efficient Fab capture detected by flow cytometry.
Irrespective of the Fab sequence, exogenously added as well as simultaneously secreted Fabs were successfully captured on the cell surface. Furthermore, Fab secretion capacities were shown to correlate to the level of surface-bound Fabs as demonstrated for characterized producer clones.
Flow-sorted clones presenting high amounts of Fabs showed an increase in median Fab titers (factor of 21 to 49) compared to unsorted clones when screened in deep-well plates. For selected candidates, improved functional Fab yields of sorted cells vs. unsorted cells were confirmed in an upscaled shake flask production. Since the scFv capture matrix was encoded on an episomal plasmid with inherently unstable autonomously replicating sequences (ARS), efficient plasmid curing was observed after removing the selective pressure. Hence, sorted clones could be immediately used for production without the need to modify the expression host or vector. The resulting switchable display/secretion system provides a streamlined approach for the isolation of Fab producers and subsequent Fab production.
Este trabajo pretende demostrar que en la obra narrativa del escritor Tomás Carrasquilla Naranjo (1858 - 1940) hay un Wahrheitsgehalt (Benjamin, 2012), la concreción temporal de una idea, que se materializa a través de lo que aquí he denominado imagen de la religiosidad popular. Esto quiere decir que la obra del antioqueño estaría construida a la manera de un gran mosaico, en el que pese a los variados y disparejos elementos que la componen, la unión de todos produce una imagen (Bild). En dicha imagen se representa la experiencia histórica de lo moderno en los sectores populares, a partir de la unión fugaz entre los rezagos de tradiciones vetustas y las formas de vida más novedosas. Lejos de las convenciones de su época, donde la pregunta por la experiencia de lo moderno redunda en los ámbitos metropolitanos y el papel del artista, Carrasquilla se pregunta por lo que ocurre en los extensos ámbitos rurales o liminares entre lo citadino y lo rural, y sus respectivos entrecruzamientos. Los sujetos que habitan estos ámbitos, al carecer de herramientas conceptuales que les permita definir esta nueva “experiencia viviente”, esa nueva Structures and Feeling como la denomina Raymond Williams (2019); apelan a lo único que conocen, los vetustos saberes transmitidos oralmente para explicar su ahora.
En este sentido, es posible afirmar que Carrasquilla, valiéndose de esta imagen de la religiosidad popular, intentó establecer un diálogo en el campo de lo literario, desde el que postuló una idea de lo moderno diferencial. En varias ocasiones, el antioqueño manifestó que la literatura debía incorporar las experiencias locales al diálogo de lo universal. Ejemplo de esto es el símil de la literatura con el sistema planetario, pues, según él, las relaciones de jerarquía se establecen cuando los países que producen modas literarias, los planetas (Europa), relegan a los otros a ser simples satélites, es decir, a imitar (Carrasquilla, 1991). Hoy en día, se aprecia en aquella crítica dirigida a sus paisanos, los modernistas antioqueños, una reivindicación de la alteridad. Por lo que aquí se postula, que si bien dichas vivencias, no son similares a las que se dan en los nacientes ámbitos metropolitanos, donde las mercancías representan a los nuevos sustitutos de la fe; en esos extensos ámbitos, en apariencia provincianos y alejados del contacto con otras culturas y saberes, la imagen de religiosidad popular viene a desempeñar el mismo papel que aquellas. En otras palabras, “indem an Dingen ihr Gebrauchswert abstirbt” (utilidad o adoración), la subjetividad del personaje las carga con “Intentionen von Wunsch und Angst” (Benjamin, 2013a.), convirtiéndolas en objetos de contemplación, bien sea portándolas o coleccionándolas. De manera similar Carrasquilla se habría valido del cúmulo de saberes (Wissen) residuales de su hipotético público lector, heredado de diversas áreas culturales -durante el proceso de la colonización-, sus respectivos y heterogéneos tiempos y lenguas particulares (Ette, 2019), para aunarlos a las experiencias profanas actuales. Así, la obra (cuento o novela) representaría artísticamente “formas de vida” popular, a través de las cuales se “experimenta estéticamente” cómo se sobrevive (überleben) (Ette, 2015) a la modernidad en los sectores marginados. Es decir, solo desde lo vetusto y ruinoso de la religiosidad popular, otrora sagrado, es posible explicar la experiencia de lo moderno, su aquí y ahora.
Visual perception is a complex and dynamic process that plays a crucial role in how we perceive and interact with the world. The eyes move in a sequence of saccades and fixations, actively modulating perception by moving different parts of the visual world into focus. Eye movement behavior can therefore offer rich insights into the underlying cognitive mechanisms and decision processes. Computational models in combination with a rigorous statistical framework are critical for advancing our understanding in this field, facilitating the testing of theory-driven predictions and accounting for observed data. In this thesis, I investigate eye movement behavior through the development of two mechanistic, generative, and theory-driven models. The first model is based on experimental research regarding the distribution of attention, particularly around the time of a saccade, and explains statistical characteristics of scan paths. The second model implements a self-avoiding random walk within a confining potential to represent the microscopic fixational drift, which is present even while the eye is at rest, and investigates the relationship to microsaccades. Both models are implemented in a likelihood-based framework, which supports the use of data assimilation methods to perform Bayesian parameter inference at the level of individual participants, analyses of the marginal posteriors of the interpretable parameters, model comparisons, and posterior predictive checks. The application of these methods enables a thorough investigation of individual variability in the space of parameters. Results show that dynamical modeling and the data assimilation framework are highly suitable for eye movement research and, more generally, for cognitive modeling.
Im Rahmen dieser Arbeit wurden Energie induzierte Nanopartikel-Substrat Interaktionen untersucht. Dazu wurden Goldnanopartikelanordnungen (AuNPA) auf verschiedenen Silizium-basierten Substraten hergestellt und der Einfluss eines Energieeintrages, genauer gesagt einer thermischen Behandlung oder des Metall-assistierten chemischen Ätzens (MaCE) getestet. Die Nanopartikelanordnungen, welche für die thermische Behandlung eingesetzt wurden, wurden nass-chemisch in Toluol synthetisiert, mit Thiol-terminiertem Polystyrol funktionalisiert und mittels Schleuderbeschichtung auf verschiedenen Substraten (drei Gläser und ein Siliziumwafer) in quasi-hexagonalen Mustern angeordnet. Diese AuNP-Anordnungen wurden mit Temperaturen zwischen 475 °C – 792 °C über verschiedene Zeiträume thermisch behandelt. Generell sanken die Nanopartikel in die Substrate ein, und es wurde festgestellt, dass mit Erhöhung der Glasübergangstemperatur der Substrate die Einsinktiefe der Nanopartikel abnahm. Die AuNPA auf Siliziumwafern wurden auf Temperaturen von 700 °C – 900 °C erhitzt. Die Goldnanopartikel sanken dabei bis zu 2,5 nm in das Si-Substrat ein. Ein Sintern der Nanopartikel fand ab einer Temperatur über 660 °C statt. Welcher Sintermechanismus der dominante ist konnte abschließend nicht eindeutig geklärt werden.
Für die Untersuchung des Einflusses des zweiten Energieeintrages mittels MaCE wurden AuNPA sowie Goldkern-Silberschale-Anordnungen auf Siliziumsubstraten genutzt. Die AuNPA wurden mit Hilfe von Poly-N-Isopropylacrylamid Mikrogelen und Natriumcitrat-stabilisierten Goldnanopartikeln (Na-AuNP) bzw. Tetrachloridogoldsäure (TCG) präpariert. Es ergaben sich Nanopartikelanordnungen mit hemisphärischen Partikeln (aus Na-AuNP) und zum anderen Nanopartikelanordnungen mit sphärischen Partikeln (aus TCG). Durch eine anschließende Silberwachstumsreaktion konnten dann die dazugehörigen Goldkern-Silberschale Nanopartikelanordnungen erhalten werden. Beim MaCE konnten signifikante Unterschiede im Verhalten dieser vier Nanopartikelanordnungen festgestellt werden, z.B. mussten bei den hemisphärischen Partikelanordnungen höhere Wasserstoffperoxidkonzentrationen (0,70 M – 0,91 M) als bei den sphärischen Partikelanordnungen (0,08 M – 0,32 M) für das Ätzen eingesetzt werden, um ein Einsinken der Nanopartikel in das Substrat zu erreichen.
Als eine der großen Veteranenorganisationen und rechte Sammlungsbewegung war der "Stahlhelm – Bund der Frontsoldaten" ein bedeutender politischer Akteur der Weimarer Republik. Er stand in einem äußerst ambivalenten Verhältnis zum aufstrebenden Nationalsozialismus. Einerseits konkurrierten sie um die Vorherrschaft innerhalb des nationalen Lagers, andererseits erkannten beide Seiten den Nutzen einer Kooperation. Insbesondere den einfachen Stahlhelm-Mitgliedern erschien die NS-Bewegung als attraktive Alternative, die ihre Ziele zu erreichen schien. Die Konkurrenz steigerte sich 1931/32 zur erbitterten Feindschaft. Nach der Eingliederung eines Großteils der Bundesmitglieder in die SA im Jahr 1933 sah sich der Rest-Bund immer heftigeren Repressalien ausgesetzt, bevor er 1935 aufgelöst wurde. 1951 neu gegründet, konnte er nicht an seine früheren Erfolge anknüpfen. Mehrere Spaltungen beschleunigten den Niedergang der Organisation.