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Jochen Pahl un de Subrekter
(2012)
Detlev von Liliencron
(2012)
Charakterisierung und Bewertung des Schaffens Detlevs von Liliencron und Überlegungen zu dessen Rezeption. Es werden Liliencrons Liebe zu Schleswig-Holstein, die Unmöglichkeit, ihn einer Schule zuzuordnen sowie die synästhetischen Qualitäten seines innovativen Werkes von dem Synästhetiker Peters hervorgehoben. Auch Humor und Menschlichkeit Liliencrons finden Erwähnung.
Am alten Markt
(2012)
Weihnacht 1914 in Issoudun
(2012)
F. E. Peters wurde 1914 als junger Lehrer eingezogen und an der Marne von den Franzosen gefangengenommen. In seinen Kriegserinnerungen ("Kriegsgefangener in Frankreich (1914-1920)")beschreibt er die Zeit seiner Gefangenschaft und auch seine Freundschaft mit dem Schauspieler Willi Lohmann. In dieser Erzählung organisieren Kriegsgefangene ein Weihnachtsfest wider den Willen der Franzosen.
Der Herr Major
(2012)
Ein alter Major stößt zu einer Reisegesellschaft, die sich auf einem Dampfer nach Hallig Hooge befindet. Durch seine verbalen Ausfälle und seine Trunksucht verspielt der Major allmählich die Achtung, die ihm anfangs entgegengebracht wurde. Eine genaue Beobachtung von gesellschaftlicher Gruppendynamik und unterschiedlichen Rollenverhalten in der Konfrontation mit einem Außenseiter.
Der Gewaltige und der Poet
(2012)
Das Opfer
(2012)
Der alte Timm Wieben sieht die natürliche gottgewollte Ordnung durch den Fortschritt, d. h. den Bau eines Bahndammes in seinem Dorf, gefährdet. Er prophezeit die Notwendigkeit eines Menschenopfers, das die Erde besänftigen soll: "Es muss etwas Lebiges in die Grund". Daraufhin ereignet sich ein schwerer Unfall. Der aus dem Nachlass veröffentlichte Text gehört eindeutig zu dem Umfeld der "Baasdörper Krönk". Er kontrastiert Aberglaube und aufgeklärtes Denken, , ohne in Schwarz-Weiß-Malerei zu verfallen. In Peters' Autobiographie Preis der guten Mächte (1940) erscheint der Großvater als ein Fürsprecher des Rationalismus und, wie Hans Lohse in der Erzählung, als ein Gegenentwurf zu Timm Wieben ("Dat geiht all natürlich to"). Aber auch er erkennt trotz allem die Macht des Übernatürlichen an. Für Peters löst sich der Gegensatz zwischen Licht und Dunkel, Aufklärung und Dämonie in der Religion auf: "Und wenn wir auch den beschränkten Geltungsbereich unserer Leuchte erkennen, so haben wir dennoch die Pflicht, sie ins Dunkel hinauszutragen bis an den alleräußersten Rand unseres Vermögens. Wer aber vor dem letzten, undurchleuchtbaren Dunkel steht, der suche seine Zuflucht nicht bei verdächtigen Mächten des Zaubers, sondern fasse die Hand Gottes, die sich ihm aus der deutschen Bibel Martin Luthers hilfreich entgegenstreckt." (Ausgewählte Werke, Bd II, Hamburg, Hoffmann und Campe, S. 111)
"Hinnerk Pick und der Steernkieker" ist ein poetischer Text, der sich mit dem Astronomen J. J. Sievers, der an der Altonaer Sternwarte tätig war, befasst. J. J. Sievers (1804-1881) stammte aus Stafstedt (Kreis Rendsburg-Eckernförde), einem Dorf in der Nähe von Luhnstedt, dem Heimatdorf von F. E. Peters. Er wird beschrieben als märchenhaft geheimnisvolle Gestalt und zugleich liebenswerter Sonderling, in dessen Augen sich eine Pascalsche Scheu vor der Unendlichkeit des Raumes widerspiegelt. "Immer aber wird mir der Steernkieker teuer bleiben als ein Zeugnis dafür, dass aus der Enge eines holsteinischen Dorfes zum Geist geführt werden kann, wen der Geist gerufen hat. Am Ende ist eines Menschen Drang ins Weite doch vergeblich, wenn er sie nach unruhigen Jahren des Suchens nicht findet in sich selbst." In den Mund des Astronomen Sievers ("de ool Steernkieker", "de ool Klooksnacker") legt Peters am Anfang der "Baasdörper Krönk" die berühmte Beschreibung von Baasdorp und der Anlage des Dorfes in drei sozial definierte konzentrische Kreise (reiche Bauern; Halbhufner und kleine Bauern; schließlich Handwerker und Katenbauern).
The present work is devoted to establishing of a new generation of self-healing anti-corrosion coatings for protection of metals. The concept of self-healing anticorrosion coatings is based on the combination of the passive part, represented by the matrix of conventional coating, and the active part, represented by micron-sized capsules loaded with corrosion inhibitor. Polymers were chosen as the class of compounds most suitable for the capsule preparation. The morphology of capsules made of crosslinked polymers, however, was found to be dependent on the nature of the encapsulated liquid. Therefore, a systematic analysis of the morphology of capsules consisting of a crosslinked polymer and a solvent was performed. Three classes of polymers such as polyurethane, polyurea and polyamide were chosen. Capsules made of these polymers and eight solvents of different polarity were synthesized via interfacial polymerization. It was shown that the morphology of the resulting capsules is specific for every polymer-solvent pair. Formation of capsules with three general types of morphology, such as core-shell, compact and multicompartment, was demonstrated by means of Scanning Electron Microscopy. Compact morphology was assumed to be a result of the specific polymer-solvent interactions and be analogues to the process of swelling. In order to verify the hypothesis, pure polyurethane, polyurea and polyamide were synthesized; their swelling behavior in the solvents used as the encapsulated material was investigated. It was shown that the swelling behavior of the polymers in most cases correlates with the capsules morphology. Different morphologies (compact, core-shell and multicompartment) were therefore attributed to the specific polymer-solvent interactions and discussed in terms of “good” and “poor” solvent. Capsules with core-shell morphology are formed when the encapsulated liquid is a “poor” solvent for the chosen polymer while compact morphologies are formed when the solvent is “good”. Multicompartment morphology is explained by the formation of infinite networks or gelation of crosslinked polymers. If gelation occurs after the phase separation in the system is achieved, core-shell morphology is present. If gelation of the polymer occurs far before crosslinking is accomplished, further condensation of the polymer due to the crosslinking may lead to the formation of porous or multicompartment morphologies. It was concluded that in general, the morphology of capsules consisting of certain polymer-solvent pairs can be predicted on the basis of polymer-solvent behavior. In some cases, the swelling behavior and morphology may not match. The reasons for that are discussed in detail in the thesis. The discussed approach is only capable of predicting capsule morphology for certain polymer-solvent pairs. In practice, the design of the capsules assumes the trial of a great number of polymer-solvent combinations; more complex systems consisting of three, four or even more components are often used. Evaluation of the swelling behavior of each component pair of such systems becomes unreasonable. Therefore, exploitation of the solubility parameter approach was found to be more useful. The latter allows consideration of the properties of each single component instead of the pair of components. In such a manner, the Hansen Solubility Parameter (HSP) approach was used for further analysis. Solubility spheres were constructed for polyurethane, polyurea and polyamide. For this a three-dimensional graph is plotted with dispersion, polar and hydrogen bonding components of solubility parameter, obtained from literature, as the orthogonal axes. The HSP of the solvents are used as the coordinates for the points on the HSP graph. Then a sphere with a certain radius is located on a graph, and the “good” solvents would be located inside the sphere, while the “poor” ones are located outside. Both the location of the sphere center and the sphere radius should be fitted according to the information on polymer swelling behavior in a number of solvents. According to the existing correlation between the capsule morphology and swelling behavior of polymers, the solvents located inside the solubility sphere of a polymer give capsules with compact morphologies. The solvents located outside the solubility sphere of the solvent give either core-shell or multicompartment capsules in combination with the chosen polymer. Once the solubility sphere of a polymer is found, the solubility/swelling behavior is approximated to all possible substances. HSP theory allows therefore prediction of polymer solubility/swelling behavior and consequently the capsule morphology for any given substance with known HSP parameters on the basis of limited data. The latter makes the theory so attractive for application in chemistry and technology, since the choice of the system components is usually performed on the basis of a large number of different parameters that should mutually match. Even slight change of the technology sometimes leads to the necessity to find the analogue of this or that solvent in a sense of solvency but carrying different chemistry. Usage of the HSP approach in this case is indispensable. In the second part of the work examples of the HSP application for the fabrication of capsules with on-demand-morphology are presented. Capsules with compact or core-shell morphology containing corrosion inhibitors were synthesized. Thus, alkoxysilanes possessing long hydrophobic tail, combining passivating and water-repelling properties, were encapsulated in polyurethane shell. The mechanism of action of the active material required core-shell morphology of the capsules. The new hybrid corrosion inhibitor, cerium diethylhexyl phosphate, was encapsulated in polyamide shells in order to facilitate the dispersion of the substance and improve its adhesion to the coating matrix. The encapsulation of commercially available antifouling agents in polyurethane shells was carried out in order to control its release behavior and colloidal stability. Capsules with compact morphology made of polyurea containing the liquid corrosion inhibitor 2-methyl benzothiazole were synthesized in order to improve the colloidal stability of the substance. Capsules with compact morphology allow slower release of the liquid encapsulated material compared to the core-shell ones. If the “in-situ” encapsulation is not possible due to the reaction of the oil-soluble monomer with the encapsulated material, a solution was proposed: loading of the capsules should be performed after monomer deactivation due to the accomplishment of the polymerization reaction. Capsules of desired morphologies should be preformed followed by the loading step. In this way, compact polyurea capsules containing the highly effective but chemically active corrosion inhibitors 8-hydroxyquinoline and benzotriazole were fabricated. All the resulting capsules were successfully introduced into model coatings. The efficiency of the resulting “smart” self-healing anticorrosion coatings on steel and aluminium alloy of the AA-2024 series was evaluated using characterization techniques such as Scanning Vibrating Electron Spectroscopy, Electrochemical Impedance Spectroscopy and salt-spray chamber tests.
Zwischen Morgen und Abend
(2012)
Diese tragische Geschichte von einem Jagdunfall, bei dem ein dreizehnjähriger Junge, einziger Sohn seiner Eltern, ums Leben kommt, ist die bekannteste Episode aus der 1975 posthum veröffentlichten Baasdörper Krönk. F.E. Peters hat sie zu Lebzeiten auf Hochdeutsch veröffentlicht. Die Erzählung variiert den Freischütz-Stoff.
F. E. Peters war während des Ersten Weltkriegs Gefangener in Adriers auf dem Hof der Familie G.-P. Zu der Erzählung von Karl Wildermuth und seiner Freundin Germaine hat er sich von Erlebnissen aus dieser Zeit inspirieren lassen. Die warmherzige Geschichte handelt von einem jähzornigen, aber gutmütigen deutschen Gefreiten, der sich in der Gefangenschaft zuerst mit französischen Tieren und zuletzt mit einem kleinen französischen Mädchen anfreundet, das nach Ende des Krieges Frieden stiftet zwischen ihm und dem heimkehrenden Vater, der seinerseits Kriegsgefangener in Deutschland war. F. E. Peters Erinnerungen an die französische Gefangenschaft sind festgehalten in dem Tagebuch „Kriegsgefangener in Frankreich (1914-1920)“.
"Staken und Bretter"
(2012)
Eine aus der 1975 posthum veröffentlichten "Baasdörper Krönk" entwickelte Geschichte, die F.E. Peters in hochdeutscher Sprache veröffentlicht hat. Es geht um die Liebesgeschichte, aber auch den kleinen Machtkampf zwischen einem verwitweten Bauern mit vier Kindern und seiner Haushälterin, die für den Geschmack des angehenden Ehemannes zu viel Wert auf Äußerlichkeiten legt. „Staken und Bretter dienen dazu, das Fassungsvermögen eines Leiterwagens zu steigern.“ Der Ausdruck wird in Baasdorf im übertragenen Sinn für Anzeichen eines übertriebenen Geltungsbedürfnisses gebraucht. Berühmt ist die zu der Erzählung gehörende Episode aus der "Baasdörper Krönk" wegen des Ausspruchs von Johann-Detlef: „Dar fohrt Puls [hier: Thun] mit Tante längs.“ (Krönk, S. 67, Staken und Bretter, S. 8). In der "Krönk" folgen sprachsoziologisch interessante Ausführungen des Erzählers zu den vier Gründen, warum der Ausspruch von Johann-Detlef, der die Geziertheit der Haushälterin parodiert, im Dorf zu einem Lacherfolg wird. Nach Baasdorfer Meinung heißt es „föhrt“ und nicht „fahrt“, außerdem „lang“ und nicht „längs“. Zu allem Überfluss lässt sich die Haushälterin von den Kindern „Tante“ nennen, „wat ok dumm Tüüch weer“ und schließlich nennt sie Hansjörn Puls (hier: Ehler Thun) beim Nachnamen. Johann-Detlef macht also mit seinem Spott mobil gegen die Haushälterin, denn der Gebrauch des Hochdeutschen wird in Baasdorf als ein Zeichen von Hochnäsigkeit gewertet: „So’n Lö, de – mit een Woort geseggt – ümmer höger schieten wüllt, as se den Mors hebbt, de nehmt wi erst mal en betjen in’e Maak; de mööt erstmal wat ümlehren.“ (Krönk, S. 67). In der "Krönk" geht der sich später fortsetzende eheliche Kampf um „Staken und Bretter“ anders und weniger harmonisch aus als in der Erzählung.
Rundfunkhörer in Form
(2012)
Das ewige Bündnis
(2012)
Current climate warming is affecting arctic regions at a faster rate than the rest of the world. This has profound effects on permafrost that underlies most of the arctic land area. Permafrost thawing can lead to the liberation of considerable amounts of greenhouse gases as well as to significant changes in the geomorphology, hydrology, and ecology of the corresponding landscapes, which may in turn act as a positive feedback to the climate system. Vast areas of the east Siberian lowlands, which are underlain by permafrost of the Yedoma-type Ice Complex, are particularly sensitive to climate warming because of the high ice content of these permafrost deposits. Thermokarst and thermal erosion are two major types of permafrost degradation in periglacial landscapes. The associated landforms are prominent indicators of climate-induced environmental variations on the regional scale. Thermokarst lakes and basins (alasses) as well as thermo-erosional valleys are widely distributed in the coastal lowlands adjacent to the Laptev Sea. This thesis investigates the spatial distribution and morphometric properties of these degradational features to reconstruct their evolutionary conditions during the Holocene and to deduce information on the potential impact of future permafrost degradation under the projected climate warming. The methodological approach is a combination of remote sensing, geoinformation, and field investigations, which integrates analyses on local to regional spatial scales. Thermokarst and thermal erosion have affected the study region to a great extent. In the Ice Complex area of the Lena River Delta, thermokarst basins cover a much larger area than do present thermokarst lakes on Yedoma uplands (20.0 and 2.2 %, respectively), which indicates that the conditions for large-area thermokarst development were more suitable in the past. This is supported by the reconstruction of the development of an individual alas in the Lena River Delta, which reveals a prolonged phase of high thermokarst activity since the Pleistocene/Holocene transition that created a large and deep basin. After the drainage of the primary thermokarst lake during the mid-Holocene, permafrost aggradation and degradation have occurred in parallel and in shorter alternating stages within the alas, resulting in a complex thermokarst landscape. Though more dynamic than during the first phase, late Holocene thermokarst activity in the alas was not capable of degrading large portions of Pleistocene Ice Complex deposits and substantially altering the Yedoma relief. Further thermokarst development in existing alasses is restricted to thin layers of Holocene ice-rich alas sediments, because the Ice Complex deposits underneath the large primary thermokarst lakes have thawed completely and the underlying deposits are ice-poor fluvial sands. Thermokarst processes on undisturbed Yedoma uplands have the highest impact on the alteration of Ice Complex deposits, but will be limited to smaller areal extents in the future because of the reduced availability of large undisturbed upland surfaces with poor drainage. On Kurungnakh Island in the central Lena River Delta, the area of Yedoma uplands available for future thermokarst development amounts to only 33.7 %. The increasing proximity of newly developing thermokarst lakes on Yedoma uplands to existing degradational features and other topographic lows decreases the possibility for thermokarst lakes to reach large sizes before drainage occurs. Drainage of thermokarst lakes due to thermal erosion is common in the study region, but thermo-erosional valleys also provide water to thermokarst lakes and alasses. Besides these direct hydrological interactions between thermokarst and thermal erosion on the local scale, an interdependence between both processes exists on the regional scale. A regional analysis of extensive networks of thermo-erosional valleys in three lowland regions of the Laptev Sea with a total study area of 5,800 km² found that these features are more common in areas with higher slopes and relief gradients, whereas thermokarst development is more pronounced in flat lowlands with lower relief gradients. The combined results of this thesis highlight the need for comprehensive analyses of both, thermokarst and thermal erosion, in order to assess past and future impacts and feedbacks of the degradation of ice-rich permafrost on hydrology and climate of a certain region.
Metals are often used in environments that are conducive to corrosion, which leads to a reduction in their mechanical properties and durability. Coatings are applied to corrosion-prone metals such as aluminum alloys to inhibit the destructive surface process of corrosion in a passive or active way. Standard anticorrosive coatings function as a physical barrier between the material and the corrosive environment and provide passive protection only when intact. In contrast, active protection prevents or slows down corrosion even when the main barrier is damaged. The most effective industrially used active corrosion inhibition for aluminum alloys is provided by chromate conversion coatings. However, their toxicity and worldwide restriction provoke an urgent need for finding environmentally friendly corrosion preventing systems. A promising approach to replace the toxic chromate coatings is to embed particles containing nontoxic inhibitor in a passive coating matrix. This work presents the development and optimization of effective anticorrosive coatings for the industrially important aluminum alloy, AA2024-T3 using this approach. The protective coatings were prepared by dispersing mesoporous silica containers, loaded with the nontoxic corrosion inhibitor 2-mercaptobenzothiazole, in a passive sol-gel (SiOx/ZrOx) or organic water-based layer. Two types of porous silica containers with different sizes (d ≈ 80 and 700 nm, respectively) were investigated. The studied robust containers exhibit high surface area (≈ 1000 m² g-1), narrow pore size distribution (dpore ≈ 3 nm) and large pore volume (≈ 1 mL g-1) as determined by N2 sorption measurements. These properties favored the subsequent adsorption and storage of a relatively large amount of inhibitor as well as its release in response to pH changes induced by the corrosion process. The concentration, position and size of the embedded containers were varied to ascertain the optimum conditions for overall anticorrosion performance. Attaining high anticorrosion efficiency was found to require a compromise between delivering an optimal amount of corrosion inhibitor and preserving the coating barrier properties. This study broadens the knowledge about the main factors influencing the coating anticorrosion efficiency and assists the development of optimum active anticorrosive coatings doped with inhibitor loaded containers.