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Ostracod distribution and habitat relationships in the Kunlun Mountains, northern Tibetan Plateau
(2013)
Surface sediment samples were collected from the lakes Heihai, Kusai, Haiding Nuur and Yan Hu, and from streams and ponds in the Kunlun Mountains at the northern margin of the Tibetan Plateau to investigate the sub-fossil ostracod (micro-crustacean) fauna of the region. Among 65 collected samples, 46 ostracod shell-rich samples were used to study the relationship between the ostracod distribution and specific conductivity (SC) of the water, which ranged from 0.6 to 53.0 mS cm(-1). A total of eleven ostracod species was identified from this region, with about half of the species restricted to the Tibetan Plateau and its adjacent mountain areas, and the other half representing Holarctic taxa. Tonnacypris cf. estonica and Tonnacypris tonnensis are reported from the Tibetan Plateau for the first time. Leucocythere sp. is the dominant species and Ilyocypris cf. bradyi is also relatively abundant. The other seven species were recorded with limited abundances apparently due to lower SC tolerances. Leucocythere sp. was recorded over the full SC range from 0.6 to 53 mS cm(-1). Eucypris mareotica is a typical brackish and saline water species, which was found at sample sites with high SC (2.8-53.0 mS cm(-1)). In contrast, Leucocythere dorsotuberosa, Candona candida and Eucypris afghanistanensis prefer freshwater to slightly oli-gohaline waters with SC < 1.8 mS cm(-1). The SC optimum and tolerance range for each species were determined and compared to earlier reported data from other regions of Central Asia. The results indicate that species assemblage data from fossil ostracod shells have a large potential to provide information on past SC levels and more general climate-determined moisture conditions. (C) 2013 Elsevier Ltd and INQUA. All rights reserved.
Increasingly available high-frequency data during storm events, when hydrological dynamics most likely activate nitrate storage-flux exchanges, reveal insights into catchment nitrate dynamics. In this study, we explored impacts of seasonality and landscape gradients on nitrate concentration-discharge (C-Q) hysteresis patterns in the Selke catchment, central Germany, which has heterogeneous combinations of meteorological, hydrogeological and land use conditions. Three nested gauging stations established along the main Selke River captured flow and nitrate export dynamics from the uppermost subcatchment (mixed forest and arable land), middle subcatchment (pure steep forest) and lowermost subcatchment (arable and urban land). We collected continuous high-frequency (15-min) discharge and nitrate concentration data from 2012 to 2017 and analyzed the 223 events detected at all three stations. A dominant hysteresis pattern in the uppermost and middle subcatchments was counter-clockwise and combined with an accretion effect, indicating many proximal and mobilized distal nitrate sources. However, 66% of all events at the catchment outlet experienced a dilution effect, possibly due to mechanisms that vary seasonally. During wetting/wet periods (October-March), it was combined mainly with a counter-clockwise pattern due to the dominance of event runoff volume from the uppermost and middle subcatchments. During drying/dry periods (April-September), however, it was combined mainly with a clockwise pattern due to occasional quick surface flows from lowland near-stream urban areas. In addition, the clockwise hysteresis occurred mainly from May-October during mostly drying/dry periods at all three sites, indicating little distal nitrate transport in response to the low terrestrial hydrological connectivity, especially in the lowermost dry and flat sub-catchment. This comprehensive analysis (i.e., clockwise vs. counter-clockwise, accretion vs. dilution) enables in-depth analysis of nitrate export mechanisms during certain periods under different landscape conditions. Specific combination of C-Q relationships could identify target locations for agricultural management actions that decrease nitrate output. Therefore, we strongly encourage long-term multisite and high-frequency monitoring strategies in heterogeneous nested catchment(s), which can help understand process mechanisms, generate data for physical-based water-quality modeling and provide guidance for water and agricultural management.
The Gongjue basin from the eastern Qiangtang terrane is located in the transition region where the regional structural lineation curves from east-west-oriented in Tibet to north-south-oriented in Yunnan. In this study, we sampled the red beds in the basin from the lower Gongjue to upper Ranmugou formations for the first time covering the entire stratigraphic profile. The stratigraphic ages are bracketed within 53-43Ma by new detrital zircon U-Pb ages constraining the maximum deposition age to 52.51.5Ma. Rock magnetic and petrographic studies indicate that detrital magnetite and hematite are the magnetic carriers. Positive reversals and fold tests demonstrate that the characteristic remanent magnetization has a primary origin. The Gongjue and Ranmugou formations yield mean characteristic remanent magnetization directions of D-s/I-s=31.0 degrees/21.3 degrees and D-s/I-s=15.9 degrees/22.0 degrees, respectively. The magnetic inclination of these characteristic remanent magnetizations is significantly shallowed compared to the expected inclination for the locality. However, the elongation/inclination correction method does not provide a meaningful correction, likely because of syn-depositional rotation. Rotations relative to the Eurasian apparent polar wander path occurred in three stages: Stage I, 33.33.4 degrees clockwise rotation during the deposition of the Gongjue and lower Ranmugou formations; Stage II, 26.93.7 degrees counterclockwise rotation during deposition of the lower and middle Ranmugou formation; and Stage III, 17.73.3 degrees clockwise rotation after 43Ma. The complex rotation history recorded in the basin is possibly linked to sinistral shear along the Qiangtang block during India indentation into Asia and the early stage of the extrusion of the northwestern Indochina blocks away from eastern Tibet.
Paleogeographic reconstructions of terranes can greatly benefit from the provenance analysis of sediments. A series of Cenozoic basins provide key sedimentary archives for investigating the growth of the Tibetan Plateau, yet the provenance of the sediments in these basins has never been constrained robustly. Here we report sedimentary petrological and detrital zircon geochronological data from the Paleocene-Eocene Nangqian-Xialaxiu and Gongjue basins. Sandstone detrital modes and zircon morphology suggest that the samples collected in these two basins were sourced from recycled orogen. Detrital zircon geochronology indicates that sediments in the Nangqian-Xialaxiu Basin are characterized by two distinct age populations at 220-280 Ma and 405-445 Ma. In contrast, three predominant age populations of 207-256 Ma, 423-445 Ma, and 1851-1868 Ma, and two subordinate age populations of similar to 50 Ma and similar to 2500 Ma, are recognized in the Gongjue Basin. Comparison with detrital zircon ages from the surrounding terranes suggests that sediments in the Nangqian-Xialaxiu Basin come from the neighboring thrust belts, whereas sediments from the Gongjue Basin are predominantly derived from the distant Songpan-Ganzi Terrane with minor contribution from the surrounding areas. A three-stage Cenozoic evolution of the eastern Tibetan Plateau is proposed. During the Paleocene, the Nangqian-Xialaxiu Basin appeared as a set of small intermontane sub-basins and received plentiful sediments from the neighboring mountain belts; during the Eocene, the Gongjue Basin kept a relatively low altitude and was a depression at the edge of a proto-Plateau; since the Oligocene, the Tibetan Plateau further uplifted and the marginal Gongjue Basin was involved in the Tibetan interior orogeny, indicating the eastward propagation of the Tibetan Plateau.
The Upper Cambrian Lower Qiulitag Group in the Tarim Basin, NW China, is overwhelmingly composed of cyclic dolomites. Based on extensive field investigations and facies analysis from four outcrop sections in the Bachu-Keping area, northwestern Tarim Basin, four main types of facies are recognized: open-marine subtidal, restricted shallow subtidal, intertidal, and supratidal facies, and these are further subdivided into ten lithofacies. In general, these facies are vertically arranged into shallowing-upward, metre-scale cycles. These cycles are commonly composed of a thin basal horizon reflecting abrupt deepening, and a thicker upper succession showing gradual shallowing upwards. Based on the vertical facies arrangements and changes across boundary surfaces, two types of cycle: peritidal and shallow subtidal cycle, are further identified. The peritidal cycles, predominating over the lower-middle Lower Qiulitag Group, commence with shallow subtidal to lower intertidal facies and are capped by inter-supratidal facies. In contrast, the shallow subtidal cycles, dominating the upper Lower Qiulitag Group, are capped by shallow-subtidal facies. Based on vertical lithofacies variations, cycle stacking patterns, and accommodation variations revealed by Fischer plots, six larger-scale third-order depositional sequences (Sq1-Sq6) are recognized. These sequences generally consist of a lower transgressive and an upper regressive systems tract. The transgressive tracts are dominated by thicker-than-average cycles, indicating an overall accommodation increase, whereas the regressive tracts are characterized by thinner-than-average peritidal cycles, indicating an overall accommodation decrease. The sequence boundaries are characterized by transitional zones of stacked thinner-than-average cycles, rather than by a single surface. These sequences can further be grouped into lower-order sequence sets: the lower and upper sequence sets. The lower sequence set, including Sq1-Sq3, is characterized by peritidal facies-dominated sequences and a progressive decrease in accommodation space, indicating a longer-term fall in sea level. In contrast, the upper sequence set (Sq4-Sq6) is characterized by subtidal facies-dominated sequences and a progressive increase in accommodation space, indicating a longer-term rise in sea level.
To provide physically based wind modelling for wind erosion research at regional scale, a 3D computational fluid dynamics (CFD) wind model was developed. The model was programmed in C language based on the Navier-Stokes equations, and it is freely available as open source. Integrated with the spatial analysis and modelling tool (SAMT), the wind model has convenient input preparation and powerful output visualization. To validate the wind model, a series of experiments was conducted in a wind tunnel. A blocking inflow experiment was designed to test the performance of the model on simulation of basic fluid processes. A round obstacle experiment was designed to check if the model could simulate the influences of the obstacle on wind field. Results show that measured and simulated wind fields have high correlations, and the wind model can simulate both the basic processes of the wind and the influences of the obstacle on the wind field. These results show the high reliability of the wind model. A digital elevation model (DEM) of an area (3800 m long and 1700 m wide) in the Xilingele grassland in Inner Mongolia (autonomous region, China) was applied to the model, and a 3D wind field has been successfully generated. The clear implementation of the model and the adequate validation by wind tunnel experiments laid a solid foundation for the prediction and assessment of wind erosion at regional scale.
In order to identify the areas in the Xilingele grassland which are sensitive to wind erosion, a computational fluid dynamics model (CFD-WEM) was used to simulate the wind fields over a region of 37 km(2) which contains different topography and land use types. Previous studies revealed the important influences of topography and land use on wind erosion in the Xilingele grassland. Topography influences wind fields at large scale, and land use influences wind fields near the ground. Two steps were designed to implement the CFD wind simulation, and they were respectively to simulate the influence of topography and surface roughness on the wind. Digital elevation model (DEM) and surface roughness length were the key inputs for the CFD simulation. The wind simulation by CFD-WEM was validated by a wind data set which was measured simultaneously at six positions in the field. Three scenarios with different wind velocities were designed based on observed dust storm events, and wind fields were simulated according to these scenarios to predict the sensitive areas to wind erosion. General assumptions that cropland is the most sensitive area to wind erosion and heavily and moderately grazed grasslands are both sensitive etc. can be refined by the modelling of CFD-WEM. Aided by the results of this study, the land use planning and protection measures against wind erosion can be more efficient. Based on the case study in the Xilingele grassland, a method of regional wind erosion assessment aided by CFD wind simulation is summarized. The essence of this method is a combination of CFD wind simulation and determination of threshold wind velocity for wind erosion. Because of the physically-based simulation and the flexibility of the method, it can be generalised to other regions.
The open source computational fluid dynamics (CFD) wind model (CFD-WEM) for wind erosion research in the Xilingele grassland in Inner Mongolia (autonomous region, China) is compared with two open source CFD models Gerris and OpenFOAM. The evaluation of these models was made according to software technology, implemented methods, handling, accuracy and calculation speed. All models were applied to the same wind tunnel data set. Results show that the simplest CFD-WEM has the highest calculation speed with acceptable accuracy, and the most powerful OpenFOAM produces the simulation with highest accuracy and the lowest calculation speed. Gerris is between CFD-WEM and OpenFOAM. It calculates faster than OpenFOAM, and it is capable to solve different CFD problems. CFD-WEM is the optimal model to be further developed for wind erosion research in Inner Mongolia grassland considering its efficiency and the uncertainties of other input data. However, for other applications using CFD technology, Gerris and OpenFOAM can be good choices. This paper shows the powerful capability of open source CFD software in wind erosion study, and advocates more involvement of open source technology in wind erosion and related ecological researches.
Our study presents the results of a moment tensor inversion of 19 microseismic events with M-L between 2.0 and 3.4, associated with the stimulation operation of an enhanced geothermal reservoir in Basel, Switzerland, in 2006. We adopt a three-step procedure to retrieve point source solution parameters based on full waveform inversion. The inversion is performed by fitting displacement amplitude spectra and displacement seismograms in the first and second step, respectively, assuming a double couple source model and thus obtaining focal solutions for all 19 events. Our results are in agreement with focal mechanisms from a previous study, which employed P wave first-motion polarities from more than 40 stations, whereas our solutions are achieved using full waveform data recorded by less than 10 surface stations. In the last step, a full moment tensor inversion is performed. The results from the moment tensor inversion show an improvement on the waveform fitting compared to the double couple models, which is verified by an F-test. We investigate the stability of the moment tensor solutions by employing different velocity models. The isotropic components of the moment tensor solutions of some events are not negligible, suggesting source volume changes due to fluid injection. Events with significant isotropic components occurred mainly during the stimulation phase and close to the injection well. On the other hand, events that occurred in the post-stimulation phase are predominantly pure shear failure and located further away from the well bore. These spatio-temporal patterns can be explained by the influence of pore pressure variations during and after the hydraulic stimulation at the geothermal site. (C) 2014 Elsevier Ltd. All rights reserved.
We use a data set of 35 surface pollen samples from lake sediments, moss polsters and top soils on the north- eastern Tibetan Plateau to explore the relationship between modern pollen assemblages and contemporary vegetation patterns. The surface pollen transect spanned four vegetation zones--alpine meadow, steppe, steppe desert and desert-- under different climatic/elevational conditions. Relative representation (R (rel)) values and Principal Components Analysis (PCA) were used to determine the relationships between modern pollen and vegetation and regional climate gradients. The results show that the main vegetation zones along the regional and elevational transects can be distinguished by their modern pollen spectra. Relative to Poaceae, a high representation of Artemisia, Nitraria and Chenopodiaceae was found, while Cyperaceae and Gentiana showed values in the middle range, and Ranunculaceae, Asteraceae, Ephedra and Fabaceae had low relative representation values. PCA results indicate a high correlation between the biogeoclimatic zones and annual precipitation and annual temperature and July temperature. The Artemisia/ Chenopodiaceae ratio and the Artemisia/Cyperaceae ratio are useful tools for qualitative and semi-quantitative palaeoenvironmental reconstruction on the north-eastern Tibetan Plateau. Surface lake sediments are found to have different palynomorph spectra from moss cushion and soil samples, reflecting the larger pollen source area in the contemporary vegetation for lakes.
The Kp index is a measure of the midlatitude global geomagnetic activity and represents short-term magnetic variations driven by solar wind plasma and interplanetary magnetic field. The Kp index is one of the most widely used indicators for space weather alerts and serves as input to various models, such as for the thermosphere and the radiation belts. It is therefore crucial to predict the Kp index accurately. Previous work in this area has mostly employed artificial neural networks to nowcast Kp, based their inferences on the recent history of Kp and on solar wind measurements at L1. In this study, we systematically test how different machine learning techniques perform on the task of nowcasting and forecasting Kp for prediction horizons of up to 12 hr. Additionally, we investigate different methods of machine learning and information theory for selecting the optimal inputs to a predictive model. We illustrate how these methods can be applied to select the most important inputs to a predictive model of Kp and to significantly reduce input dimensionality. We compare our best performing models based on a reduced set of optimal inputs with the existing models of Kp, using different test intervals, and show how this selection can affect model performance.
This article offers a reconstruction of the vegetation and climate of the south-western Siberian Baraba forest-steppe area during the last ca. 8000 years. The analysis of palynological data from the sediment core of Lake Bolshie Toroki using quantitative methods has made it possible to reconstruct changes of the dominant types of vegetation and mean July air temperatures. Coniferous forests grew in the vicinity of the lake, and mean July air temperatures were similar to present-day ones between 7.9 and 7.0 kyr BP. The warmest and driest climate occurred at 7.0-5.0 kyr BP. At that time, the region had open steppe landscapes; birch groves began to spread. A cooling trend is seen after 5.5 kyr BP, when forest-steppe began to emerge. Steppe communities started to dominate again after 1.5 kyr BP. Mean July air temperatures lower than now are reconstructed for the period of 1.9-1 kyr BP, and then the temperatures became similar to present-day ones. Comparing the archaeological data on the types of economy of the population which inhabited the Baraba forest-steppe with the data on changes in the natural environment revealed a connection between the gradual transition from hunting and fishing to livestock breeding and the development of forest-steppe landscapes with a decrease in the area covered by forests. The development of the forest-steppe as an ecotonic landscape starting around 5 kyr BP might have contributed to the coexistence of several archaeological cultures with different types of economy on the same territory. (C) 2017 Elsevier Ltd. All rights reserved.
To what extent cities can be made sustainable under the mega-trends of urbanization and climate change remains a matter of unresolved scientific debate. Our inability in answering this question lies partly in the deficient knowledge regarding pivotal humanenvironment interactions. Regarded as the most well documented anthropogenic climate modification, the urban heat island (UHI) effect – the warmth of urban areas relative to the rural hinterland – has raised great public health concerns globally. Worse still, heat waves are being observed and are projected to increase in both frequency and intensity, which further impairs the well-being of urban dwellers. Albeit with a substantial increase in the number of publications on UHI in the recent decades, the diverse urban-rural definitions applied in previous studies have remarkably hampered the general comparability of results achieved. In addition, few studies have attempted to synergize the land use data and thermal remote sensing to systematically assess UHI and its contributing factors.
Given these research gaps, this work presents a general framework to systematically quantify the UHI effect based on an automated algorithm, whereby cities are defined as clusters of maximum spatial continuity on the basis of land use data, with their rural hinterland being defined analogously. By combining land use data with spatially explicit surface skin temperatures from satellites, the surface UHI intensity can be calculated in a consistent and robust manner. This facilitates monitoring, benchmarking, and categorizing UHI intensities for cities across scales. In light of this innovation, the relationship between city size and UHI intensity has been investigated, as well as the contributions of urban form indicators to the UHI intensity.
This work delivers manifold contributions to the understanding of the UHI, which have complemented and advanced a number of previous studies. Firstly, a log-linear relationship between surface UHI intensity and city size has been confirmed among the 5,000 European cities. The relationship can be extended to a log-logistic one, when taking a wider range of small-sized cities into account. Secondly, this work reveals a complex interplay between UHI intensity and urban form. City size is found to have the strongest influence on the UHI intensity, followed by the fractality and the anisometry. However, their relative contributions to the surface UHI intensity depict a pronounced regional heterogeneity, indicating the importance of considering spatial patterns of UHI while implementing UHI adaptation measures.
Lastly, this work presents a novel seasonality of the UHI intensity for individual clusters in the form of hysteresis-like curves, implying a phase shift between the time series of UHI intensity and background temperatures. Combining satellite observation and urban boundary layer simulation, the seasonal variations of UHI are assessed from both screen and skin levels. Taking London as an example, this work ascribes the discrepancies between the seasonality observed at different levels mainly to the peculiarities of surface skin temperatures associated with the incoming solar radiation. In addition, the efforts in classifying cities according to their UHI characteristics highlight the important role of regional climates in determining the UHI.
This work serves as one of the first studies conducted to systematically and statistically scrutinize the UHI. The outcomes of this work are of particular relevance for the overall spatial planning and regulation at meso- and macro levels in order to harness the benefits of rapid urbanization, while proactively minimizing its ensuing thermal stress.
This paper assesses the seasonality of the urban heat island (UHI) effect in the Greater London area (United Kingdom). Combining satellite-based observations and urban boundary layer climate modeling with the UrbClim model, the authors are able to address the seasonality of UHI intensity, on the basis of both land surface temperature (LST) and 2-m air temperature, for four individual times of the day (0130, 1030, 1330, and 2230 local time) and the daily means derived from them. An objective of this paper is to investigate whether the UHI intensities that are based on both quantities exhibit a similar hysteresis-like trajectory that is observed for LST when plotting the UHI intensity against the background temperature. The results show that the UrbClim model can satisfactorily reproduce both the observed urban rural LSTs and 2-m air temperatures as well as their differences and the hysteresis in the surface UHI. The hysteresis-like seasonality is largely absent in both the observed and modeled 2-m air temperatures, however. A sensitivity simulation of the UHI intensity to incoming solar radiation suggests that the hysteresis of the LST can mainly be attributed to the seasonal variation in incoming solar radiation.
We perform a systematic study of all cities in Europe to assess the Urban Heat Island (UHI) intensity by means of remotely sensed land surface temperature data. Defining cities as spatial clusters of urban land cover, we investigate the relationships of the UHI intensity, with the cluster size and the temperature of the surroundings. Our results show that in Europe, the UHI intensity in summer has a strong correlation with the cluster size, which can be well fitted by an empirical sigmoid model. Furthermore, we find a novel seasonality of the UHI intensity for individual clusters in the form of hysteresis-like curves. We characterize the shape and identify apparent regional patterns.
Urban climate is determined by a variety of factors, whose knowledge can help to attenuate heat stress in the context of ongoing urbanization and climate change. We study the influence of city size and urban form on the Urban Heat Island (UHI) phenomenon in Europe and find a complex interplay between UHI intensity and city size, fractality, and anisometry. Due to correlations among these urban factors, interactions in the multi-linear regression need to be taken into account. We find that among the largest 5,000 cities, the UHI intensity increases with the logarithm of the city size and with the fractal dimension, but decreases with the logarithm of the anisometry. Typically, the size has the strongest influence, followed by the compactness, and the smallest is the influence of the degree to which the cities stretch. Accordingly, from the point of view of UHI alleviation, small, disperse, and stretched cities are preferable. However, such recommendations need to be balanced against e.g. positive agglomeration effects of large cities. Therefore, trade-offs must be made regarding local and global aims.
The Indus Molasse records orogenic sedimentation associated with uplift and erosion of the southern margin of Asia in the course of ongoing India-Eurasia collision. Detailed field investigation clarifies the nature and extent of the depositional contact between this molasse and the underlying basement units. We report the first dataset on detrital zircon U-Pb ages, Hf isotopes and apatite U-Pb ages for the autochthonous molasse in the Indus Suture Zone. A latest Oligocene depositional age is proposed on the basis of the youngest detrital zircon U-Pb age peak and is consistent with published biostratigraphic data. Multiple provenance indicators suggest exclusively northerly derivation with no input from India in the lowermost parts of the section. The results provide constraints on the uplift and erosion history of the Ladakh Range following the initial India-Asia collision.
The Puna Plateau, adjacent Eastern Cordillera and the Sierras Pampeanas of the central Andes are largely characterized by thick-skinned, basement-involved deformation. The Puna Plateau hosts similar to N-S trending bedrock ranges bounded by deep-seated reverse faults and sedimentary basins. We contribute to the understanding of thick-skinned dynamics in the Puna Plateau by constraining regional kinematics of the poorly understood southern Puna Plateau through a multidisciplinary approach. On the southeastern plateau, sandstone modal composition and detrital zircon U-Pb and apatite fission-track data from Cenozoic strata indicate basin accumulation during the late Eocene to early Oligocene (similar to 38-28 Ma). Provenance analysis reveals the existence of a regional-scale basin covering the southern Puna Plateau during late Eocene to early Oligocene time (similar to 38-28 Ma) that was sourced from both the western plateau and the eastern plateau margin and had a depocenter located to the west. Petrographic and detrital zircon U-Pb data reveal erosion of proximal western and eastern sources after 12 Ma, in mid-late Miocene time. This indicates that the regional basin was compartmentalized into small-scale depocenters by the growth of basement-cored ranges continuing into the late Miocene (similar to 12-8 Ma). We suggest that the Cenozoic history of the southern Puna Plateau records the formation of a regional basin that was possibly driven by lithospheric flexure during the late Eocene to early Oligocene, before the growth of distributed basement-cored ranges starting as early as the late Oligocene. (C) 2015 Elsevier B.V. All rights reserved.
Barite concretions and bands are widely distributed in black shale-chert horizons in the Yurtus Formation of Lower Cambrian in Aksu area, northwestern Tarim Basin, NW China. They mainly consist of coarse-grained anhedral to euhedral barite crystals with minor dolomites and pyrites. Petrological features indicate these concretions grew from the porewater in unconsolidated sediments at shallow burial below sediment-water interface. The slight deviation of Sr-87/Sr-86 ratios (0.7083 to 0.7090) and significant elevated delta S-34 values (56.8-76.4 parts per thousand CDT) of barite samples with respect to those of the Early Cambrian seawater further support that barite deposits precipitated from the enclosed porewater in sediment column, which evolved from the penecontemporaneous seawater with weak interaction with the host fine-grained siliciclastic sediments and highly-depleted sulfate in response to prolonged strong bacterial sulfate reduction without necessary renewal. The abundant organic matters in the basal Yurtus Formation should have facilitated developing sulfate-depleted methanogenesis zone and sulfate-methane transition zone (SMTZ) slightly after deposition. Therefore, barite deposits in the Yurtus Formation most likely resulted from diagenetic barium cycling and persistently grew from the porewater in the static SMTZ with a low sedimentation rate in the Early Cambrian. In comparison with the distribution of sedimentary barites in geological records, we tentatively proposed that a transition in diagenetic barium cycling and associated mineralization may have occurred from the Precambrian to Cambrian periods; this scenario may be causally linked to the changes in marine ecology (the advent of mesozooplankton and associated faecal pellet) and geochemistry (the increase of seawater sulfate concentration). Thus, the occurrence of diagenetic barite deposits in the Yurtus Formation implies that diagenetic barium cycling and more effective scavenging of barium from CH4- and Ba-rich porewaters within sediments might have become an nonnegligible process in continental margin areas, at least, since the earliest Cambrian, which could have significantly impacted the marine barium cycling. (C) 2015 Elsevier B.V. All rights reserved.
The within-site variability in site response is the randomness in site response at a given site from different earthquakes and is treated as aleatory variability in current seismic hazard/risk analyses.
In this study, we investigate the single-station variability in linear site response at K-NET and KiK-net stations in Japan using a large number of earthquake recordings.
We found that the standard deviation of the horizontal-to-vertical Fourier spectral ratio at individual sites, that is single-station horizontal-to-vertical spectral ratio (HVSR) sigma sigma(HV,s), approximates the within-site variability in site response quantified using surface-to-borehole spectral ratios (for oscillator frequencies higher than the site fundamental frequency) or empirical ground-motion models.
Based on this finding, we then utilize the single-station HVSR sigma as a convenient tool to study the site-response variability at 697 KiK-net and 1169 K-NET sites.
Our results show that at certain frequencies, stiff, rough and shallow sites, as well as small and local events tend to have a higher sigma(HV,s).
However, when being averaged over different sites, the single-station HVSR sigma, that is sigma(HV), increases gradually with decreasing frequency. In the frequency range of 0.25-25 Hz, sigma(HV) is centred at 0.23-0.43 in ln scales (a linear scale factor of 1.26-1.54) with one standard deviation of less than 0.1. sigma(HV) is quite stable across different tectonic regions, and we present a constant, as well as earthquake magnitude- and distance-dependent sigma(HV) models.
In the Next Generation Attenuation West2 (NGA-West2) project, a 3D subsurface structure model (Japan Seismic Hazard Information Station [J-SHIS]) was queried to establish depths to 1.0 and 2.5 km/s velocity isosurfaces for sites without depth measurement in Japan. In this article, we evaluate the depth parameters in the J-SHIS velocity model by comparing them with their corresponding site-specific depth measurements derived from selected KiK-net velocity profiles. The comparison indicates that the J-SHIS model underestimates site depths at shallow sites and overestimates depths at deep sites. Similar issues were also identified in the southern California basin model. Our results also show that these underestimations and over-estimations have a potentially significant impact on ground-motion prediction using NGA-West2 ground-motion models (GMMs). Site resonant period may be considered as an alternative to depth parameter in the site term of a GMM.
In this investigation, we examine the uncertainties using the horizontal-to-vertical spectral ratio (HVSR) technique on earthquake recordings to detect site resonant frequencies at 207 KiK-net sites. Our results show that the scenario dependence of response (pseudospectral acceleration) spectral ratio could bias the estimates of resonant frequencies for sites having multiple significant peaks with comparable amplitudes. Thus, the Fourier amplitude spectrum (FAS) should be preferred in computing HVSR. For more than 80% of the investigated sites, the first peak (in the frequency domain) on the average HVSR curve over multiple sites coincides with the highest peak. However, for sites with multiple peaks, the highest peak frequency (f(p)) is less susceptible to the selection criteria of significant peaks and the extent of smoothing to spectrum than the first peak frequency (f(0)). Meanwhile, in comparison to the surface-to-borehole spectral ratio, f(0) tends to underestimate the predominant frequency (at which the largest amplification occurs) more than f(p). In addition, in terms of characterizing linear site response, f(p) shows a better overall performance than f(0). Based on these findings, we thus recommend that seismic network operators provide f(p) on the average HVSRFAS curve as a priority, ideally together with the average HVSRFAS curve in site characterization.
This study aims to identify the best-performing site characterization proxy alternative and complementary to the conventional 30 m average shear-wave velocity V-S30, as well as the optimal combination of proxies in characterizing linear site response. Investigated proxies include T-0 (site fundamental period obtained from earthquake horizontal-to-vertical spectral ratios), V-Sz (measured average shear-wave velocities to depth z, z = 5, 10, 20 and 30 m), Z(0.8) and Z(1.0) (measured site depths to layers having shear-wave velocity 0.8 and 1.0 km/s, respectively), as well as Z(x-infer) (inferred site depths from a regional velocity model, x = 0.8 and 1.0, 1.5 and 2.5 km/s). To evaluate the performance of a site proxy or a combination, a total of 1840 surface-borehole recordings is selected from KiK-net database. Site amplifications are derived using surface-to-borehole response-, Fourier- and cross-spectral ratio techniques and then are compared across approaches. Next, the efficacies of 7 single-proxies and 11 proxy-pairs are quantified based on the site-to-site standard deviation of amplification residuals of observation about prediction using the proxy or the pair. Our results show that T-0 is the best-performing single-proxy among T-0, Z(0.8), Z(1.0) and V-Sz. Meanwhile, T-0 is also the best-performing proxy among T-0, Z(0.8), Z(1.0) and Z(x-infer) complementary to V-S30 in accounting for the residual amplification after V-S30-correction. Besides, T-0 alone can capture most of the site effects and should be utilized as the primary site indicator. Though (T-0, V-S30) is the best-performing proxy pair among (V-S30, T-0), (V-S30, Z(0.8)), (V-S30, Z(1.0)), (V-S30, Z(x-infer)) and (T-0, V-Sz), it is only slightly better than (T-0, V-S20). Considering both efficacy and engineering utility, the combination of T-0 (primary) and V-S20 (secondary) is recommended. Further study is needed to test the performances of various proxies on sites in deep sedimentary basins.
Evaluation of a novel application of earthquake HVSR in site-specific amplification estimation
(2020)
Ground response analyses (GRA) model the vertical propagations of SH waves through flat-layered media (1DSH) and are widely carried out to evaluate local site effects in practice. Horizontal-to-vertical spectral ratio (HVSR) technique is a cost-effective approach to extract certain site-specific information, e.g., site fundamental frequency (f(0)), but HVSR values cannot be directly used to approximate the levels of S-wave amplifications. Motivated by the work of Kawase et al. (2019), we propose a procedure to correct earthquake HVSR amplitudes for direct amplification estimations. The empirical correction compensates HVSR by generic vertical amplification spectra categorized by the vertical fundamental frequency (f(0v)) via kappa-means clustering. In this investigation, we evaluate the effectiveness of the corrected HVSR in approximating observed linear amplifications in comparison with 1DSH modellings. We select a total of 90 KiK-net (Kiban Kyoshin network) surface-downhole sites which are found to have no velocity contrasts below their boreholes and thus of which surface-to-borehole spectral ratios (SBSRs) can be taken as their empirical transfer functions (ETFs). 1DSH-based theoretical transfer functions (TTFs) are computed in the linear domain considering uncertainties in Vs profiles through randomizations. Five goodness-of-fit metrics are adopted to gauge the closeness between observed (ETF) and predicted (i.e., TTF and corrected HVSR) amplifications in both amplitude and spectral shape over frequencies from f(0) to 25 Hz. We find that the empirical correction to HVSR is highly effective and achieves a "good match" in both spectral shape and amplitude at the majority of the 90 KiK-net sites, as opposed to less than one-third for the 1DSH modelling. In addition, the empirical correction does not require a velocity model, which GRAs require, and thus has great potentials in seismic hazard assessments.
In this paper we report a rare and fortunate event of fast magnetosonic (MS, also called equatorial noise) waves modulated by compressional ultralow frequency (ULF) waves measured by Van Allen Probes. The characteristics of MS waves, ULF waves, proton distribution, and their potential correlations are analyzed. The results show that ULF waves can modulate the energetic ring proton distribution and in turn modulate the MS generation. Furthermore, the variation of MS intensities is attributed to not only ULF wave activities but also the variation of background parameters, for example, number density. The results confirm the opinion that MS waves are generated by proton ring distribution and propose a new modulation phenomenon.
Whistler mode exohiss are the structureless hiss waves observed outside the plasma pause with featured equatorward Poynting flux. An event of the amplification of exohiss as well as chorus waves was recorded by Van Allen Probes during the recovery phase of a weak geomagnetic storm. Amplitudes of both types of the waves showed a significant increase at the regions of electron density enhancements. It is found that the electrons resonant with exohiss and chorus showed moderate pitch angle anisotropies. The ratio of the number of electrons resonating with exohiss to total electron number presented in-phase correlation with density variations, which suggests that exohiss can be amplified due to electron density enhancement in terms of cyclotron instability. The calculation of linear growth rates further supports above conclusion. We suggest that exohiss waves have potential to become more significant due to the background plasma fluctuation.
Mechanical behaviors of granite after thermal treatment under loading and unloading conditions
(2021)
Understanding the mechanical behaviors of granite after thermal treatment under loading and unloading conditions is of utmost relevance to deep geothermal energy recovery. In the present study, a series of loading and unloading triaxial compression tests (20, 40 and 60 MPa) on granite specimens after exposure to different temperatures (20, 200, 300, 400, 500 and 600 degrees C) was carried out to quantify the combined effects of thermal treatment and loading/unloading stress conditions on granite strength and deformation. Changes in the microstructure of granite exposed to high temperatures were revealed by optical microscopy. The experimental results indicate that both, thermal treatment and loading/unloading stress conditions, degrade the mechanical behaviors and further decrease the carrying capacity of granite. The gradual degradation of the mechanical characteristics of granite after thermal treatment is mainly associated with the evolution of thermal micro-cracks based on optical microscopy observations. The unloading stress state induces the extension of tension cracks parallel to the axial direction, and thus, the mechanical properties are degraded. Temperatures above 400 degrees C have a more significant influence on the mechanical characteristics of granite than the unloading treatment, whereby 400 degrees C can be treated as a threshold temperature for the delineation of significant deterioration. This study is expected to support feasibility and risk assessments by means of providing data for analytical calculations and numerical simulations on granite exposed to high temperatures during geothermal energy extraction.
Understanding the geologic evolution of Northern Tibetan Plateau with multiple thermochronometers
(2018)
The early onset of deformation following the India-Asia collision, Neogene expanse of uplift, and complex systems that comprise strike-slip faults, thrust faults, and intermontane basins characterize the Cenozoic tectonism of Northern Tibetan Plateau and raise two prominent questions in orogenic geodynamics: 1) What mechanism(s) control(s) the transfer of stress related to the India-Asia collision across the distance of >2000 km; and 2) Why the development of high topography was delayed in the Northern Tibetan Plateau and what does it reveal about how the internal forces and external boundary conditions evolved. To address these two questions, we reconstruct a holistic spatial-temporal deformation history of the Northern Tibetan Plateau by using a range of thermochronometers, with closure temperature spanning from 350 degrees C to-60-70 degrees C. This multi-thermochronometer study reveals three stages of faulting related cooling, in the early Cretaceous, in Paleocene-Eocene and in middle-late Miocene. We observe that Paleocene-Eocene deformation was spatially restricted and mostly occurred on reactivated Cretaceous structures, indicating a control of pre-existing weakness on early Cenozoic deformation. Extensive Neogene deformation contrasts with restricted Paleocene-Eocene deformation and relatively quiescent shortening during the Oligocene-early Miocene, which implies a change in the regional tectonics regime. Global plate reconstructions show that this tectonic reorganization is coeval with an increase in Pacific-Asia plate convergence rates. We argue that this change in regional tectonics is a result of increasing constrictive environment of the eastern plate boundary, which changed the behavior of the Altyn Tagh fault the boundary fault of Northern Tibetan Plateau, causing it to change from feeding slip into structures out of the plateau to feeding slip into structures at plateau margins.
QuestionHow important is the effect of micro-relief and vegetation type on the characteristics of vascular plants and bryophytes in low-centred polygons? LocationSiberian Arctic, Russia. MethodsEight low-centred polygons in northern Siberia were surveyed for vegetation along transects running from the rim to the pond via the rim-pond transition of each polygon and across a vegetation type gradient from open forest to tundra. ResultsThe cover of vascular plants and bryophytes displays no significant differences between the rim and rim-pond transition but is significantly lower in the pond section of the polygons. Alpha-diversity of vascular plants decreases strongly from rim to pond, whereas bryophyte diversity in pond plots is significantly distinct from the rim and the rim-pond transition. There is no clear trend in cover for either plant group along the vegetation type transect and only a weak trend in -diversity. However, both gradients are reflected in the compositional turnover. The applied indicator species analysis identified taxa characteristic of certain environmental conditions. Among others, we found vascular plants primarily characteristic of the rim and bryophyte taxa characteristic of each micro-relief level and vegetation type. ConclusionsThe observed gradual pattern in -diversity and composition of polygonal vegetation suggests that micro-relief is the main driver of changes in the vegetation composition, while vegetation type and the related forest cover change are of subordinate importance for polygonal vegetation patterns along the Siberian tree line.
The spatial and temporal variability of a low-centred polygon on the eastern floodplain area of the lower Anabar River (72.070 degrees N, 113.921 degrees E; northern Yakutia, Siberia) has been investigated using a multi-method approach. The present-day vegetation in each square metre was analysed, revealing a community of Larix, shrubby Betula, and Salix on the polygon rim, a dominance of Carex and Andromeda polifolia in the rim-to-pond transition zone, and a predominantly monospecific Scorpidium scorpioides coverage within the pond. The total organic carbon (TOC) content, TOC/TN (total nitrogen) ratio, grain size, vascular plant macrofossils, moss remains, diatoms, and pollen were analysed for two vertical sections and a sediment core from a transect across the polygon. Radiocarbon dating indicates that the formation of the polygon started at least 1500 yr ago; the general positions of the pond and rim have not changed since that time. Two types of pond vegetation were identified, indicating two contrasting development stages of the polygon. The first was a well-established moss association, dominated by submerged or floating Scorpidium scorpioides and/or Drepanocladus spp. and overgrown by epiphytic diatoms such as Tabellaria flocculosa and Eunotia taxa. This stage coincides temporally with a period in which the polygon was only drained by lateral subsurface water flow, as indicated by mixed grain sizes. A different moss association occurred during times of repeated river flooding (indicated by homogeneous medium-grained sand that probably accumulated during the annual spring snowmelt), characterized by an abundance of Meesia triquetra and a dominance of benthic diatoms (e. g. Navicula vulpina), indicative of a relatively high pH and a high tolerance of disturbance. A comparison of the local polygon vegetation (inferred from moss and macrofossil spectra) with the regional vegetation (inferred from pollen spectra) indicated that the moss association with Scorpidium scorpioides became established during relatively favourable climatic conditions, while the association dominated by Meesia triquetra occurred during periods of harsh climatic conditions. Our study revealed a strong riverine influence (in addition to climatic influences) on polygon development and the type of peat accumulated.
Applying conservation of energy to estimate earthquake frequencies from strain rates and stresses
(2020)
Estimating earthquake occurrence rates from the accumulation rate of seismic moment is an established tool of seismic hazard analysis. We propose an alternative, fault-agnostic approach based on the conservation of energy: the Energy-Conserving Seismicity Framework (ENCOS). Working in energy space has the advantage that the radiated energy is a better predictor of the damage potential of earthquake waves than the seismic moment release. In a region, ENCOS balances the stationary power available to cause earthquakes with the long-term seismic energy release represented by the energy-frequency distribution's first moment. Accumulation and release are connected through the average seismic efficiency, by which we mean the fraction of released energy that is converted into seismic waves. Besides measuring earthquakes in energy, ENCOS differs from moment balance essentially in that the energy accumulation rate depends on the total stress in addition to the strain rate tensor. To validate ENCOS, we exemplarily model the energy-frequency distribution around Southern California. We estimate the energy accumulation rate due to tectonic loading assuming poroelasticity and hydrostasis. Using data from the World Stress Map and assuming the frictional limit to estimate the stress tensor, we obtain a power of 0.8 GW. The uncertainty range, 0.3-2.0GW, originates mainly from the thickness of the seismogenic crust, the friction coefficient on preexisting faults, and models of Global Positioning System (GPS) derived strain rates. Based on a Gutenberg-Richter magnitude-frequency distribution, this power can be distributed over a range of energies consistent with historical earthquake rates and reasonable bounds on the seismic efficiency.
Information on the contemporary in-situ stress state of the earth’s crust is essential for geotechnical applications and physics-based seismic hazard assessment. Yet, stress data records for a data point are incomplete and their availability is usually not dense enough to allow conclusive statements. This demands a thorough examination of the in-situ stress field which is achieved by 3D geomechanicalnumerical models. However, the models spatial resolution is limited and the resulting local stress state is subject to large uncertainties that confine the significance of the findings. In addition, temporal variations of the in-situ stress field are naturally or anthropogenically induced. In my thesis I address these challenges in three manuscripts that investigate (1) the current crustal stress field orientation, (2) the 3D geomechanical-numerical modelling of the in-situ stress state, and (3) the phenomenon of injection induced temporal stress tensor rotations. In the first manuscript I present the first comprehensive stress data compilation of Iceland with 495 data records. Therefore, I analysed image logs from 57 boreholes in Iceland for indicators of the orientation of the maximum horizontal stress component. The study is the first stress survey from different kinds of stress indicators in a geologically very young and tectonically active area of an onshore spreading ridge. It reveals a distinct stress field with a depth independent stress orientation even very close to the spreading centre. In the second manuscript I present a calibrated 3D geomechanical-numerical modelling approach of the in-situ stress state of the Bavarian Molasse Basin that investigates the regional (70x70x10km³) and local (10x10x10km³) stress state. To link these two models I develop a multi-stage modelling approach that provides a reliable and efficient method to derive from the larger scale model initial and boundary conditions for the smaller scale model. Furthermore, I quantify the uncertainties in the models results which are inherent to geomechanical-numerical modelling in general and the multi-stage approach in particular. I show that the significance of the models results is mainly reduced due to the uncertainties in the material properties and the low number of available stress magnitude data records for calibration. In the third manuscript I investigate the phenomenon of injection induced temporal stress tensor rotation and its controlling factors. I conduct a sensitivity study with a 3D generic thermo-hydro-mechanical model. I show that the key control factors for the stress tensor rotation are the permeability as the decisive factor, the injection rate, and the initial differential stress. In particular for enhanced geothermal systems with a low permeability large rotations of the stress tensor are indicated. According to these findings the estimation of the initial differential stress in a reservoir is possible provided the permeability is known and the angle of stress rotation is observed. I propose that the stress tensor rotations can be a key factor in terms of the potential for induced seismicity on pre-existing faults due to the reorientation of the stress field that changes the optimal orientation of faults.
Rotations of the principal stress axes are observed as a result of fluid injection into reservoirs. We use a generic, fully coupled 3-D thermo-hydro-mechanical model to investigate systematically the dependence of this stress rotation on different reservoir properties and injection scenarios. We find that permeability, injection rate, and initial differential stress are the key factors, while other reservoir properties only play a negligible role. In particular, we find that thermal effects do not significantly contribute to stress rotations. For reservoir types with usual differential stress and reservoir treatment the occurrence of significant stress rotations is limited to reservoirs with a permeability of less than approximately 10(-12)m(2). Higher permeability effectively prevents stress rotations to occur. Thus, according to these general findings, the observed principal stress axes rotation can be used as a proxy of the initial differential stress provided that rock permeability and fluid injection rate are known a priori.
Iceland is located on the Mid-Atlantic Ridge which is the plate boundary between the Eurasian and the North American plates. It is one of the few places on earth where an active spreading centre is located onshore but the stress pattern has not been extensively investigated so far. In this paper we present a comprehensive compilation of the orientation of maximum horizontal stress (S-Hmax). In particular we interpret borehole breakouts and drilling induced fractures from borehole image logs in 57 geothermal wells onshore Iceland. The borehole results are combined with other stress indicators including earthquake focal mechanism solutions, geological information and overcoring measurements resulting in a dataset with 495 data records for the S-Hmax orientation. The reliability of each indicator is assessed according to the quality criteria of the World Stress Map project The majority of S-Hmax orientation data records in Iceland is derived from earthquake focal mechanism solutions (35%) and geological fault slip inversions (26%). 20% of the data are borehole related stress indicators. In addition minor shares of S-Hmax orientations are compiled, amongst others, from focal mechanism inversions and the alignment of fissure eruptions. The results show that the S-Hmax orientations derived from different depths and stress indicators are consistent with each other.
The resulting pattern of the present-day stress in Iceland has four distinct subsets of S-Hmax orientations. The S-Hmax orientation is parallel to the rift axes in the vicinity of the active spreading regions. It changes from NE-SW in the South to approximately N-S in central Iceland and NNW-SSE in the North. In the Westfjords which is located far away from the ridge the regional S-Hmax rotates and is parallel to the plate motion. (C) 2016 Elsevier B.V. All rights reserved.
On 27 December 2007, a 1.9 seismic event occurred within a dyke in the deep-level Mponeng Gold Mine, South Africa. From the seismological network of the mine and the one from the Japanese-German Underground Acoustic Emission Research in South Africa (JAGUARS) group, the hypocentral depth (3,509 m), focal mechanism and aftershock location were estimated. Since no mining activity took place in the days before the event, dynamic triggering due to blasting can be ruled out as the cause. To investigate the hypothesis that stress transfer, due to excavation of the gold reef, induced the event, we set up a small-scale high-resolution three-dimensional (3D) geomechanical numerical model. The model consisted of the four different rock units present in the mine: quartzite (footwall), hard lava (hanging wall), conglomerate (gold reef) and diorite (dykes). The numerical solution was computed using a finite-element method with a discretised mesh of approximately elements. The initial stress state of the model is in agreement with in situ data from a neighbouring mine, and the step-wise excavation was simulated by mass removal from the gold reef. The resulting 3D stress tensor and its changes due to mining were analysed based on the Coulomb failure stress changes on the fault plane of the event. The results show that the seismic event was induced regardless of how the Coulomb failure stress changes were calculated and of the uncertainties in the fault plane solution. We also used the model to assess the seismic hazard due to the excavation towards the dyke. The resulting curve of stress changes shows a significant increase in the last in front of the dyke, indicating that small changes in the mining progress towards the dyke have a substantial impact on the stress transfer.
The seismicity of the Kenya rift is characterized by high-frequency low-magnitude events concentrated along the rift axis. Its seismic character is typical for magmatically active continental rifts, where igneous material at a shallow depth causes extensive grid faulting and geothermal activity. Thermal overprinting and dike intrusion prohibit the buildup of large elastic strains, therefore prohibiting the generation of large-magnitude earthquakes. On 6 January 1928, the M-S 6.9 Subukia earthquake occurred on the Laikipia-Marmanet fault, the eastern rift-bounding structure of the central Kenya rift. It is the largest instrumentally recorded seismic event in the Kenya rift, standing in contrast to the current model of the rift's seismic character in which large earthquakes are not anticipated. Furthermore, the proximity of the ruptured fault and the rift axis is intriguing: The rift-bounding structure that ruptured in 1928 remains seismically active, capable of generating large-magnitude earthquakes, even though thermally weakened crust and better oriented structures are present along the rift axis nearby, prohibiting any significant buildup of elastic strain. We excavated the surface rupture of the 1928 Subukia earthquake to find evidence for preceding ground-rupturing earthquakes. We also made a total station survey of the site topography and mapped the site geology. We show that the Laikipia-Marmanet fault was repeatedly activated during the late Quaternary. We found evidence for six ground-rupturing earthquakes, including the 1928 earthquake. The topographic survey around the trench site revealed a degraded fault scarp of approximate to 7.5 m in height, offsetting a small debris slide. Using scarp-diffusion modeling, we estimated an uplift rate of U = 0.09-0.15 mm/yr, constraining the scarp age to 50-85 ka. Assuming an average fault dip of 55 degrees-75 degrees, the preferred uplift rate (0.15 mm/yr) accommodates approximately 10%-20% of the recent rate of extension (0.5 mm/yr) across the Kenya rift.
Questions of identity and provenance of minerals that are parts of masterpieces in museums have become increasingly important in mineralogical and historical studies. Detailed investigations of valuable and unique objects require on-site, nondestructive and noninvasive methods because touching or removing them may cause irreparable damage. A mobile Raman-microprobe has been used to meet these demands for truly in situ mineralogical studies of the large collection of minerals and rocks of the Prussian kings in the Grotto Hall (Grottensaal) of the New Palace (Neues Palais), Park Sanssouci in Potsdam. Minerals on the walls of the Grotto Hall were analyzed to identify them and thereby to complete the data bank of the collection. Fluid and solid inclusions in the interior of a large quartz crystal have been studied to provide evidence of the provenance of the crystal. The fluid inclusions contain aqueous saline solutions, whereas the solid inclusions are needles of anhydrite with a length of about 1.5 mm. The quartz probably originated from an area in the eastern Alps, from the surroundings of Bad Gastein, Austria. This is the first on-site and in situ study of inclusions below the surface of a mineral with a mobile Raman-microprobe outside a laboratory.
Thermobarometrical and mineral-chemical investigations by electron microprobe and LA-ICP-MS on a sillimanite- bearing pegmatoid from the Reinbolt Hills provide important constraints on the P-T-X-age relations of part of East Antarctica during Pan-African tectonism. U-Th-total Pb ages of monazite imply that the pegmatoid of originally Grenvillan age (zircon U-Pb age of ca. 900 Ma) underwent a major, late Pan-African (Cambrian) regional, granulite-facies metamorphism between 500 and 550 Ma. Most of the monazite formed during this event, as result of apatite metasomatism owing to infiltration of high-grade metamorphic fluids. Apatite-biotite and other mineral thermobarometers define the peak metamorphic temperatures and pressures with 850-950 degrees C and 0.8-1.0 GPa. The F-Cl-OH relations in apatite, and biotite, the chemistry of fluid inclusions and the presence of K-feldspar microveins suggest that the metasomatising fluid was a CO2-bearing, diluted KCl brine. The pegmatoid is the first record of monazite-(Ce) formed from fluorapatite that is rich in U (up to 2.6 Wt% UO2) and possesses Th/U ratios <1 (0.09 on average). These chemical signatures are direct reflection of the U and Th concentration patterns in the parental fluorapatite
The 10th edition of the International Congress on the Application of Raman Spectroscopy in Art and Archaeology (RAA2019) was held in Potsdam (Germany) from 3 to 7 September 2019, with eight keynote lectures, 35 oral presentations and 18 Poster Presentations. The number of active participants was 68 delegates from 20 countries among the 236 authors that presented at least one work.
Forests seem to represent low-erosion systems, according to most, but not all, studies of suspended-sediment yield. We surmised that this impression reflects an accidental bias in the selection of monitoring sites towards those with prevailing vertical hydrological flowpaths, rather than a tight causal link between vegetation cover and erosion alone. To evaluate this conjecture, we monitored, over a 2-year period, a 3.3 ha old-growth rainforest catchment prone to frequent and widespread overland flow. We sampled stream flow at two and overland flow at three sites in a nested arrangement on a within-event basis, and monitored the spatial and temporal frequency of overland flow. Suspended-sediment concentrations were modeled with Random Forest and Quantile Regression Forest to be able to estimate the annual yields for the 2 years, which amounted to 1 t ha(-1) and 2 t ha(-1) in a year with below-average and with average precipitation, respectively. These estimates place our monitoring site near the high end of reported suspended-sediment yields and lend credence to the notion that low yields reflect primarily the dominance of vertical flowpaths and not necessarily and exclusively the kind of vegetative cover. Undisturbed forest and surface erosion are certainly no contradiction in terms even in the absence of mass movements.
Saturated hydraulic conductivity (K-s) is an important soil characteristic affecting soil water storage, runoff generation and erosion processes. In some areas where high-intensity rainfall coincides with low K-s values at shallow soil depths, frequent overland flow entails dense drainage networks. Consequently, linear structures such as flowlines alternate with inter-flowline areas. So far, investigations of the spatial variability of K-s mainly relied on isotropic covariance models which are unsuitable to reveal patterns resulting from linear structures. In the present study, we applied two sampling approaches so as to adequately characterize K-s spatial variability in a tropical forest catchment that features a high density of flowlines: A classical nested sampling survey and a purposive sampling strategy adapted to the presence of flowlines. The nested sampling approach revealed the dominance of small-scale variability, which is in line with previous findings. Our purposive sampling, however, detected a strong spatial gradient: surface K-s increased substantially as a function of distance to flowline; 10 m off flowlines, values were similar to the spatial mean of K-s. This deterministic trend can be included as a fixed effect in a linear mixed modeling framework to obtain realistic spatial fields of K-s. In a next step we used probability maps based on those fields and prevailing rainfall intensities to assess the hydrological relevance of the detected pattern. This approach suggests a particularly good agreement between the probability statements of K-s exceedance and observed overland flow occurrence during wet stages of the rainy season.
Numerous studies investigated the influence of abiotic (meteorological conditions) and biotic factors (tree characteristics) on stemflow generation. Although these studies identified the variables that influence stemflow volumes in simply structured forests, the combination of tree characteristics that allows a robust prediction of stemflow volumes in species-rich forests is not well known. Many hydrological applications, however, require at least a rough estimate of stemflow volumes based on the characteristics of a forest stand. The need for robust predictions of stemflow motivated us to investigate the relationships between tree characteristics and stemflow volumes in a species-rich tropical forest located in central Panama. Based on a sampling setup consisting of ten rainfall collectors, 300 throughfall samplers and 60 stemflow collectors and cumulated data comprising 26 rain events, we derive three main findings. Firstly, stemflow represents a minor hydrological component in the studied 1-ha forest patch (1.0% of cumulated rainfall). Secondly, in the studied species-rich forest, single tree characteristics are only weakly related to stemflow volumes. The influence of multiple tree parameters (e.g. crown diameter, presence of large epiphytes and inclination of branches) and the dependencies among these parameters require a multivariate approach to understand the generation of stemflow. Thirdly, predicting stemflow in species-rich forests based on tree parameters is a difficult task. Although our best model can capture the variation in stemflow to some degree, a critical validation reveals that the model cannot provide robust predictions of stemflow. A reanalysis of data from previous studies in species-rich forests corroborates this finding. Based on these results and considering that for most hydrological applications, stemflow is only one parameter among others to estimate, we advocate using the base model, i.e. the mean of the stemflow data, to quantify stemflow volumes for a given study area. Studies in species-rich forests that wish to obtain predictions of stemflow based on tree parameters probably need to conduct a much more extensive sampling than currently implemented by most studies. Copyright (c) 2015 John Wiley & Sons, Ltd.
estimating mean throughfall
(2016)
The selection of an appropriate spatial extent of a sampling plot is one among several important decisions involved in planning a throughfall sampling scheme. In fact, the choice of the extent may determine whether or not a study can adequately characterize the hydrological fluxes of the studied ecosystem. Previous attempts to optimize throughfall sampling schemes focused on the selection of an appropriate sample size, support, and sampling design, while comparatively little attention has been given to the role of the extent. In this contribution, we investigated the influence of the extent on the representativeness of mean throughfall estimates for three forest ecosystems of varying stand structure. Our study is based on virtual sampling of simulated throughfall fields. We derived these fields from throughfall data sampled in a simply structured forest (young tropical forest) and two heterogeneous forests (old tropical forest, unmanaged mixed European beech forest). We then sampled the simulated throughfall fields with three common extents and various sample sizes for a range of events and for accumulated data. Our findings suggest that the size of the study area should be carefully adapted to the complexity of the system under study and to the required temporal resolution of the throughfall data (i.e. event-based versus accumulated). Generally, event-based sampling in complex structured forests (conditions that favor comparatively long autocorrelations in throughfall) requires the largest extents. For event-based sampling, the choice of an appropriate extent can be as important as using an adequate sample size. (C) 2016 Elsevier B.V. All rights reserved.
A wide range of basic and applied problems in water resources research requires high-quality estimates of the spatial mean of throughfall. Many throughfall sampling schemes, however, are not optimally adapted to the system under study. The application of inappropriate sampling schemes may partly reflect the lack of generally applicable guidelines on throughfall sampling strategies. In this study we conducted virtual sampling experiments using simulated fields which are based on empirical throughfall data from three structurally distinct forests (a 12-year old teak plantation, a 5-year old young secondary forest, and a 130-year old secondary forest). In the virtual sampling experiments we assessed the relative error of mean throughfall estimates for 38 different throughfall sampling schemes comprising a variety of funnel- and trough-type collectors and a large range of sample sizes. Moreover, we tested the performance of each scheme for both event-based and accumulated throughfall data. The key findings of our study are threefold. First, as errors of mean throughfall estimates vary as a function of throughfall depth, the decision on which temporal scale (i.e. event-based versus accumulated data) to sample strongly influences the required sampling effort. Second, given a chosen temporal scale throughfall estimates can vary considerably as a function of canopy complexity. Accordingly, throughfall sampling in simply structured forests requires a comparatively modest effort, whereas heterogeneous forests can be extreme in terms of sampling requirements, particularly if the focus is on reliable data of small events. Third, the efficiency of trough-type collectors depends on the spatial structure of throughfall. Strong, long-ranging throughfall patterns decrease the efficiency of troughs substantially. Based on the results of our virtual sampling experiments, which we evaluated by applying two contrasting sampling approaches simultaneously, we derive readily applicable guidelines for throughfall monitoring. (C) 2014 Elsevier B.V. All rights reserved.
Changes in rainfall interception along a secondary forest succession gradient in lowland Panama
(2013)
Secondary forests are rapidly expanding in tropical regions. Yet, despite the importance of understanding the hydrological consequences of land-cover dynamics, the relationship between forest succession and canopy interception is poorly understood. This lack of knowledge is unfortunate because rainfall interception plays an important role in regional water cycles and needs to be quantified for many modeling purposes. To help close this knowledge gap, we designed a throughfall monitoring study along a secondary succession gradient in a tropical forest region of Panama. The investigated gradient comprised 20 forest patches 3 to 130 yr old. We sampled each patch with a minimum of 20 funnel-type throughfall collectors over a continuous 2month period that had nearly 900 mm of rain. During the same period, we acquired forest inventory data and derived several forest structural attributes. We then applied simple and multiple regression models (Bayesian model averaging, BMA) and identified those vegetation parameters that had the strongest influence on the variation of canopy interception. Our analyses yielded three main findings. First, canopy interception changed rapidly during forest succession. After only a decade, throughfall volumes approached levels that are typical for mature forests. Second, a parsimonious (simple linear regression) model based on the ratio of the basal area of small stems to the total basal area outperformed more complex multivariate models (BMA approach). Third, based on complementary forest inventory data, we show that the influence of young secondary forests on interception in realworld fragmented landscapes might be detectable only in regions with a substantial fraction of young forests. Our re-sults suggest that where entire catchments undergo forest regrowth, initial stages of succession may be associated with a substantial decrease of streamflow generation. Our results further highlight the need to study hydrological processes in all forest succession stages, including early ones.
In the humid tropics, continuing high deforestation rates are seen alongside an increasing expansion of secondary forests. In order to understand and model the consequences of these dynamic land-use changes for regional water cycles, the response of soil hydraulic properties to forest disturbance and recovery has to be quantified.At a site in the Brazilian Amazonia, we annually monitored soil infiltrability and saturated hydraulic conductivity (K-s) at 12.5, 20 cm, and 50 cm soil depth after manual forest conversion to pasture (year zero to four after pasture establishment), and during secondary succession after pasture abandonment (year zero to seven after pasture abandonment). We evaluated the hydrological consequences of the detected changes by comparing the soil hydraulic properties with site-specific rainfall intensities and hydrometric observations. Within one year after grazing started, infiltrability and K-s at 12.5 and 20 cm depth decreased by up to one order of magnitude to levels which are typical for 20-year-old pasture. In the three subsequent monitoring years, infiltrability and K-s remained stable. Land use did not impact on subsoil permeability. Whereas infiltrability values are large enough to allow all rainwater to infiltrate even after the conversion, the sudden decline of near-surface K-s is of hydrological relevance as perched water tables and overland flow occur more often on pastures than in forests at our study site. After pasture abandonment and during secondary succession, seven years of recovery did not suffice to significantly increase infiltrability and K-s at 12.5 depth although a slight recovery is obvious. At 20 cm soil depth, we detected a positive linear increase within the seven-year time frame but annual means did not differ significantly. Although more than a doubling of infiltrability and K-s is still required to achieve pre-disturbance levels, which will presumably take more than a decade, the observed slight increases of K-s might already decrease the probability of perched water table generation and overland flow development well before complete recovery.