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Das klinische Tagebuch
(2021)
Zwei mal zwanzig Jahre
(2021)
Background
The anterior cruciate ligament (ACL) rupture can lead to impaired knee function. Reconstruction decreases the mechanical instability but might not have an impact on sensorimotor alterations.
Objective
Evaluation of the sensorimotor function measured with the active joint position sense (JPS) test in anterior cruciate ligament (ACL) reconstructed patients compared to the contralateral side and a healthy control group.
Methods
The databases MEDLINE, CINAHL, EMBASE, PEDro, Cochrane Library and SPORTDiscus were systematically searched from origin until April 2020. Studies published in English, German, French, Spanish or Italian language were included. Evaluation of the sensorimotor performance was restricted to the active joint position sense test in ACL reconstructed participants or healthy controls. The Preferred Items for Systematic Reviews and Meta-Analyses guidelines were followed. Study quality was evaluated using the Quality Assessment Tool for Observational Cohort and Cross-Sectional Studies. Data was descriptively synthesized.
Results
Ten studies were included after application of the selective criteria. Higher angular deviation, reaching significant difference (p < 0.001) in one study, was shown up to three months after surgery in the affected limb. Six months post-operative significantly less error (p < 0.01) was found in the reconstructed leg compared to the contralateral side and healthy controls. One or more years after ACL reconstruction significant differences were inconsistent along the studies.
Conclusions
Altered sensorimotor function was present after ACL reconstruction. Due to inconsistencies and small magnitudes, clinical relevance might be questionable. JPS testing can be performed in acute injured persons and prospective studies could enhance knowledge of sensorimotor function throughout the rehabilitative processes.
Id est figura corporis mei
(2021)
Exendin-4 is a pharmaceutical peptide used in the control of insulin secretion. Structural information on exendin-4 and related peptides especially on the level of quaternary structure is scarce. We present the first published association equilibria of exendin-4 directly measured by static and dynamic light scattering. We show that exendin-4 oligomerization is pH dependent and that these oligomers are of low compactness. We relate our experimental results to a structural hypothesis to describe molecular details of exendin-4 oligomers. Discussion of the validity of this hypothesis is based on NMR, circular dichroism and fluorescence spectroscopy, and light scattering data on exendin-4 and a set of exendin-4 derived peptides. The essential forces driving oligomerization of exendin-4 are helix–helix interactions and interactions of a conserved hydrophobic moiety. Our structural hypothesis suggests that key interactions of exendin-4 monomers in the experimentally supported trimer take place between a defined helical segment and a hydrophobic triangle constituted by the Phe22 residues of the three monomeric subunits. Our data rationalize that Val19 might function as an anchor in the N-terminus of the interacting helix-region and that Trp25 is partially shielded in the oligomer by C-terminal amino acids of the same monomer. Our structural hypothesis suggests that the Trp25 residues do not interact with each other, but with C-terminal Pro residues of their own monomers.
Grochowiaks Haiku-images
(2021)
Obwohl schon viel über kommerzielle Materialien gesagt und geschrieben wurde, ist unser Verständnis sehr begrenzt, wenn es um lokal produzierte (hauseigene, nicht-kommerzielle) Materialien geht, die oft verwendet werden, um bestehende veröffentlichte Materialien zu ersetzen oder zu ergänzen. In diesem Beitrag geben wir einen Überblick über die Literatur zur Darstellung von Geschlecht und Sexualität in kommerziellen Lehrmitteln und unsere Überlegungen zu lokal produzierten Unterrichtsmaterialien, die in einem Englisch-Intensivprogramm an einer Universität in der Türkei mit Englisch als Unterrichtsmedium (EMI) verwendet werden. Wir unterstreichen die Bedeutung von Materialien für die Handlungsfähigkeit von Lehrkräften bei der Schaffung eines sicheren und inklusiven Klassenzimmers und bei der Bekämpfung von systematischer Unterdrückung, Diskriminierung und Ungerechtigkeit im und ausserhalb des Klassenzimmers.
Bezug nehmend auf Rainer E. Zimmermanns Buch "Metaphysik als Grundlegung von Naturdialektik. Zum Sagbaren und Unsagbaren im spekulativen Denken" wird der von Zimmermann entwickelte Ansatz eines transzendentalen Materialismus in der Traditionslinie Schellingscher Dialektik einerseits und dem Spin-Schaum-Ansatz der Quantengravitationstheorie andererseits erörtert. Die Rückführung von Wirklichkeitsstrukturen auf mathematische Strukturen - auf das Prozessieren von Zahlen - wird problematisiert.
This article discusses how Alex Garland’s The Beach (1996) engages with conceptions of utopian islands, nation, and colonialism in modernity and how it, from this basis, develops a different spatiality that reflects on a more deterritorialized form of imperial domination within late twentieth-century globalization, as exercised by the United States. The novel is shown to subvert, but not to abolish, two spatial formations that originated in early modernity: nation and utopia. Building on Jean Baudrillard’s elaborations regarding simulation and simulacra, the article argues that The Beach creates a hyperreal narrative that does away with the idea of isolated, bounded spaces and that in form and content corresponds with the worldwide dominance of the United States at the end of the twentieth century.
Introduction
(2021)
Rochow & Reckahn
(2021)
Gilgul of Meaning
(2021)
Die fünf Sinne der Schrift
(2021)
Experiment Mensch
(2021)
The atrocities that the prisoners in the concentration and extermination camps actually suffered in the 20th century can hardly be understood by outsiders like us today, especially if one takes a closer look at the experiences of the survivors, who offer cruel testimony on the human beast. This is also the case with the concentration camp testimonies in Daniel Krochmalnik’s contribution, which tell of the deadly experiments of the so-called ›Übermensch‹ and how he, inspired by the National Socialist master-race ideology, assumed an almost divine mission to exterminate everything human in his victims, so that death often seemed to be the only salvation. In view of such descriptions, which pervade the entire concentration camp literature, one inevitably has to ask oneself, as the author does, about the human condition and whether one can still place hope in people after all this – because the shocking experiences of the homo carceris in the concentration camps and gulags of the last century fundamentally shake the self-understanding of the human as a moral being, who can in fact transform into an angry beast at any time, especially under the influence of totalitarian systems of thought and rule as that Chapter „Homo homini lupus“ shows. Nevertheless, in the end the author does not want to give up all hope in ‚humanistic moral resources‘, even if the very existence of the „camp man“ seems to contradict this.
Die Frommen Deutschlands
(2021)
Am Anfang war der Holocaust
Am Ende der Geschichte der deutschen Juden wartete der Holocaust, aber er war schon von Anfang an da. Ja, da trifft das Wort noch sicherer ins Schwarze. Juden und auch Judenverfolgungen hat es im Reich schon lange vorher gegeben, doch die traumatischen Ereignisse im Vorfeld des Ersten Kreuzzugs (1096) stellen einen Einschnitt dar und haben den Jüdischen Gemeinden Deutschlands ihr blutiges Siegel aufgedrückt. Vor die Wahl zwischen Taufe oder Tod gestellt, entschieden sich die Gemeinden an Rhein und Donau zum Selbstopfer. Dafür gab es kaum Präzedenzfälle und auch keine halachische Rechtfertigung. Die Halacha verlangt zwar, dass man sich in so einem Fall lieber töten lassen soll, Selbstmord oder gar Mord ist aber nicht erlaubt.
Dreidimensionales Lernen
(2021)
Ex 34,29-35
(2021)
Märkische Dialekte
(2021)
Indices of oscillatory behavior are conveniently obtained by projecting the fields in question into a phase space of a few (mostly just two) dimensions; empirical orthogonal functions (EOFs) or other, more dynamical, modes are typically used for the projection. If sufficiently coherent and in quadrature, the projected variables simply describe a rotating vector in the phase space, which then serves as the basis for predictions. Using the boreal summer intraseasonal oscillation (BSISO) as a test case, an alternative procedure is introduced: it augments the original fields with their Hilbert transform (HT) to form a complex series and projects it onto its (single) dominant EOF. The real and imaginary parts of the corresponding complex pattern and index are compared with those of the original (real) EOF. The new index explains slightly less variance of the physical fields than the original, but it is much more coherent, partly from its use of future information by the HT. Because the latter is in the way of real-time monitoring, the index can only be used in cases with predicted physical fields, for which it promises to be superior. By developing a causal approximation of the HT, a real-time variant of the index is obtained whose coherency is comparable to the noncausal version, but with smaller explained variance of the physical fields. In test cases the new index compares well to other indices of BSISO. The potential for using both indices as an alternative is discussed.
Fin du globe
(2021)
This essay argues that Oscar Wilde noticeably contributed to the emerging discourse about world literature, even though his views in this regard have to be unearthed from the margins of his works, from his early and unpublished American lectures and 'between the lines' of his major critical essays. Wilde's implicit ideas around world literature can be understood as being closely related to his broader endeavour of redirecting and revaluing the pejorative discourse around 'decadence' in art and literature. More specifically, the arch-aesthete preferred to use the word 'romance' rather than 'decadence' (a term he hardly used at all in his writings), signalling a sensitivity attuned to what he called the 'love of things impossible'. This reconceptualization of the decadent outlook was to inspire a critical ideal of literature which relied on creatively activating the other as Other, culminating in a vision of intersubjective, transcultural and unlimited literary communication. Wilde's thought can be more specifically understood as anticipating central tenets of Gayatri Chakravorty Spivak's evocations of the planetary, thus preparing the way for an alterity-oriented understanding of literary cosmopolitanism.
The palladium-catalyzed oxidative Heck-reaction, also referred to as Fujiwara-Moritani-reaction, has been investigated for the synthesis of styrenylsulfonyl compounds. Acetanilides and vinylsulfonyl compounds undergo dehydrogenative coupling reactions in moderate to quantitative yields, using benzoquinone as the oxidant of choice. Potassium peroxodisulfate, which had previously been identified as a superior oxidant for the coupling with acrylates, did not provide any coupling products with these olefins. Traceless removal of the catalyst directing group through a deacetylation-diazotation-coupling (DDC) sequence was demonstrated for 2-arylethene sulfones.
This book explores how capitalism shapes the formation of the economic subject in modern European writing. How are subject positions determined by the subject’s relationship to money and work? How fair is a society that predicates social inclusion upon employment? And what happens when full employment is impossible? The volume traces how literary authors and social theorists have answered these questions in different social and historical contexts from the nineteenth century to the present day. The contributions confront the imperatives of productivity, notions of success and failure, the construction of work cultures and environments, the (in)visibility of certain labour groups, and the implications of the body as a productive site.
Introduction
(2021)
People perceive sentences more favourably after hearing or reading them many times. A prominent approach in linguistic theory argues that these types of exposure effects (satiation effects) show direct evidence of a generative approach to linguistic knowledge: only some sentences improve under repeated exposure, and which sentences do improve can be predicted by a model of linguistic competence that yields natural syntactic classes. However, replications of the original findings have been inconsistent, and it remains unclear whether satiation effects can be reliably induced in an experimental setting at all. Here we report four findings regarding satiation effects in wh-questions across German and English. First, the effects pertain to zone of well-formedness rather than syntactic class: all intermediate ratings, including calibrated fillers, increase at the beginning of the experimental session regardless of syntactic construction. Second, though there is satiation, ratings asymptote below maximum acceptability. Third, these effects are consistent across judgments of superiority effects in English and German. Fourth, wh-questions appear to show similar profiles in English and German, despite these languages being traditionally considered to differ strongly in whether they show effects on movement: violations of the superiority condition can be modulated to a similar degree in both languages by manipulating subject-object initiality and animacy congruency of the wh-phrase. We improve on classic satiation methods by distinguishing between two crucial tests, namely whether exposure selectively targets certain grammatical constructions or whether there is a general repeated exposure effect. We conclude that exposure effects can be reliably induced in rating experiments but exposure does not appear to selectively target certain grammatical constructions. Instead, they appear to be a phenomenon of intermediate gradient judgments.
The particle noch (‘still’) can have an additive reading similar to auch (‘also’). We argue that both particles indicate that a previously partially answered QUD is re-opened to add a further answer. The particles differ in that the QUD, in the case of auch, can be re-opened with respect to the same topic situation, whereas noch indicates that the QUD is re-opened with respect to a new topic situation. This account predicts a difference in the accommodation behavior of the two particles. We present an experiment whose results are in line with this prediction.
Previous research has shown that heritage speakers struggle with inflectional morphology. 'Limitations of online resources' for processing a non-dominant language has been claimed as one possible reason for these difficulties. To date, however, there is very little experimental evidence on real-time language processing in heritage speakers. Here we report results from a masked priming experiment with 97 bilingual (Turkish/German) heritage speakers and a control group of 40 non-heritage speakers of Turkish examining regular and irregular forms of the Turkish aorist. We found that, for the regular aorist, heritage speakers use the same morphological decomposition mechanism ('affix stripping') as control speakers, whereas for processing irregularly inflected forms they exhibited more variability (i.e., less homogeneous performance) than the control group. Heritage speakers also demonstrated semantic priming effects. At a more general level, these results indicate that heritage speakers draw on multiple sources of information for recognizing morphologically complex words.
Aufgrund ihrer komplexitätsreduzierenden Eigenschaften sind Management-Control-Systeme (MCS) ein wichtiges Instrument für die Professionalisierung vonStart-ups. MCS können helfen, Unsicherheit zu vermeiden und das Insolvenzri-siko reduzieren. Dieser Beitrag gibt einen Einblick in die Verwendung von MCS indeutschen Start-ups und untersucht ausgewählte Einflussfaktoren auf die Einfüh-rung von MCS.
This paper argues that land and resource rights are often essential in overcoming colonial inequality and devaluation of indigenous populations and cultures. It thereby criticizes global welfare egalitarians that promote the abolition of national sovereignty over resources in the name of increased equality. The paper discusses two ways in which land and resource rights contribute to decolonization and the eradication of the associated inequality. First, it proposes that land and resource rights have acquired a status-conferring function for (formerly) colonized peoples so that possession of full personhood and relational equality is partially expressed through the possession of land and resource rights. Second, it suggests that successful internal decolonization depends on access to and control over land and resources, especially for indigenous peoples.
Im Zuge der Digitalisierung bietet Business Analytics das Potenzial, die Budgetierung insbesondere durch eine Automatisierung von Prozessschritten der Budgetierung maßgeblich weiterzuentwickeln. Dieser Beitrag zeigt mittels einer empirischen Untersuchung den Status quo des Einsatzes von Business Analytics im Rahmen der Budgetierung in Deutschland und geht auf die Beurteilung einer Automatisierung der Budgetierung durch Unternehmen ein.
Da Sparkassen einen öffentlichen Auftrag erfüllen müssen, der ihr Bestehen gesetzlich legitimiert, zeichnet sich ihr Corporate-Governance-System durch Besonderheiten aus. Diese Besonderheiten wirken sich nicht nur auf die Vorstandstätigkeit, sondern auch auf die Tätigkeit der Kontrollorgane aus, welche eine nachhaltige Erfüllung des öffentlichen Auftrags prüfen und gewährleisten sollen. Nach einer Vorstellung des Corporate-Governance-Systems beschäftigt sich der Beitrag daher mit der Frage, ob und wie allgemeine Herausforderungen, die durch das System bedingt sind, sowie besondere Herausforderungen, die sich aus der langanhaltenden Niedrigzinspolitik ergeben, die Effektivität der Kontrollen beeinflussen.
Background: To handle the competition demands, sparring drills are used for specific technical–tactical training as well as physical–physiological conditioning in combat sports. While the effects of different area sizes and number of within-round sparring partners on physiological and perceptive responses in combats sports were examined in previous studies, technical and tactical aspects were not investigated. This study investigated the effect of different within-round sparring partners number (i.e., at a time; 1 vs. 1, 1 vs. 2, and 1 vs. 4) and area sizes (2 m × 2 m, 4 m × 4 m, and 6 m × 6 m) variation on the technical–tactical aspects of small combat games in kickboxing.
Method: Twenty male kickboxers (mean ± standard deviation, age: 20.3 ± 0.9 years), regularly competing in regional and national events randomly performed nine different kickboxing combats, lasting 2 min each. All combats were video recorded and analyzed using the software Dartfish.
Results: Results showed that the total number of punches was significantly higher in 1 versus 4 compared with 1 versus 1 (p = 0.011, d = 0.83). Further, the total number of kicks was significantly higher in 1 versus 4 compared with 1 versus 1 and 1 versus 2 (p < 0.001; d = 0.99 and d = 0.83, respectively). Moreover, the total number of kick combinations was significantly higher in 1 versus 4 compared with 1 versus 1 and 1 versus 2 (p < 0.001; d = 1.05 and d = 0.95, respectively). The same outcome was significantly lower in 2 m × 2 m compared with 4 m × 4 m and 6 m × 6 m areas (p = 0.010 and d = − 0.45; p < 0.001 and d = − 0.6, respectively). The number of block-and-parry was significantly higher in 1 versus 4 compared with 1 versus 1 (p < 0.001, d = 1.45) and 1 versus 2 (p = 0.046, d = 0.61) and in 2 m × 2 m compared with 4 m × 4 m and 6 × 6 m areas (p < 0.001; d = 0.47 and d = 0.66, respectively). Backwards lean actions occurred more often in 2 m × 2 m compared with 4 m × 4 m (p = 0.009, d = 0.53) and 6 m × 6 m (p = 0.003, d = 0.60). However, the number of foot defenses was significantly lower in 2 m × 2 m compared with 6 m × 6 m (p < 0.001, d = 1.04) and 4 m × 4 m (p = 0.004, d = 0.63). Additionally, the number of clinches was significantly higher in 1 versus 1 compared with 1 versus 2 (p = 0.002, d = 0.7) and 1 versus 4 (p = 0.034, d = 0.45).
Conclusions: This study provides practical insights into how to manipulate within-round sparring partners’ number and/or area size to train specific kickboxing technical–tactical fundamentals.
Sansevieria pfennigii, which to date has been a doubtful species, is confirmed as extant by a recent collection from the Lindi Region in southern Tanzania. The original description of the species, which is based on herbarium material only, is here emended based on additional observations recorded from living plants, including fruits that were previously unknown. Sansevieria pfennigii distinguishes from S. canaliculata, to which it was repeatedly assigned, by its capitate instead of elongate inflorescence, rough rather than smooth leaves, non-pungent instead of pungent leaf tips, dull green leaf colour, more delicate overall appearance, alongside other traits. The difference in inflorescence architecture indicates that these species belong to different groups within Sansevieria and are not closely related; the closest relatives of S. pfennigii are probably S. fischeri and S. stuckyi. Sansevieria pfennigii occurs on well-drained soil in forests, close to S. canaliculata populations. According to the extent of the population seen and the species' overall rarity, it is tentatively assessed as critically endangered.
As overconsumption has negative effects on ecological balance, social equality, and individual well-being, reducing consumption levels among the materially affluent is an emerging strategy for sustainable development. Today's youth form a crucial target group for intervening in unsustainable overconsumption habits and for setting the path and ideas on responsible living. This article explores young people's motivations for engaging in three behavioural patterns linked to anti-consumption (voluntary simplicity, collaborative consumption, and living within one's means) in relation to sustainability. Applying a qualitative approach, laddering interviews reveal the consequences and values behind the anti-consumption behaviours of young people of ages 14 to 24 according to a means-end chains analysis. The findings highlight potential for and the challenges involved in motivating young people to reduce material levels of consumption for the sake of sustainability. Related consumer policy tools from the fields of education and communication are identified. This article provides practical implications for policy makers, activists, and educators. Consumer policies may strengthen anti-consumption among young people by addressing individual benefits, enabling reflection on personal values, and referencing credible narratives. The presented insights can help give a voice to young consumers, who struggle to establish themselves as key players in shaping the future consumption regime.
Spectral analysis is a technique of time-series analysis that decomposes signals into linear combinations of harmonic components. Rooted in the 19th century, spectral analysis gained popularity in palaeoclimatology since the early 1980s. This was partly due to the availability of long time series of past climates, but also the development of new, partly adapted methods and the increasing spread of affordable personal computers. This paper reviews the most important methods of spectral analysis for palaeoclimate time series and discusses the prerequisites for their application as well as advantages and disadvantages. The paper also offers an overview of suitable software, as well as computer code for using the methods on synthetic examples.
Background/Purpose
Muscular reflex responses of the lower extremities to sudden gait disturbances are related to postural stability and injury risk. Chronic ankle instability (CAI) has shown to affect activities related to the distal leg muscles while walking. Its effects on proximal muscle activities of the leg, both for the injured- (IN) and uninjured-side (NON), remain unclear. Therefore, the aim was to compare the difference of the motor control strategy in ipsilateral and contralateral proximal joints while unperturbed walking and perturbed walking between individuals with CAI and matched controls.
Materials and methods
In a cross-sectional study, 13 participants with unilateral CAI and 13 controls (CON) walked on a split-belt treadmill with and without random left- and right-sided perturbations. EMG amplitudes of muscles at lower extremities were analyzed 200 ms after perturbations, 200 ms before, and 100 ms after (Post100) heel contact while walking. Onset latencies were analyzed at heel contacts and after perturbations. Statistical significance was set at alpha≤0.05 and 95% confidence intervals were applied to determine group differences. Cohen’s d effect sizes were calculated to evaluate the extent of differences.
Results
Participants with CAI showed increased EMG amplitudes for NON-rectus abdominus at Post100 and shorter latencies for IN-gluteus maximus after heel contact compared to CON (p<0.05). Overall, leg muscles (rectus femoris, biceps femoris, and gluteus medius) activated earlier and less bilaterally (d = 0.30–0.88) and trunk muscles (bilateral rectus abdominus and NON-erector spinae) activated earlier and more for the CAI group than CON group (d = 0.33–1.09).
Conclusion
Unilateral CAI alters the pattern of the motor control strategy around proximal joints bilaterally. Neuromuscular training for the muscles, which alters motor control strategy because of CAI, could be taken into consideration when planning rehabilitation for CAI.
Janus droplets were prepared by vortex mixing of three non-mixable liquids, i.e., olive oil, silicone oil and water, in the presence of gold nanoparticles (AuNPs) in the aqueous phase and magnetite nanoparticles (MNPs) in the olive oil. The resulting Pickering emulsions were stabilized by a red-colored AuNP layer at the olive oil/water interface and MNPs at the oil/oil interface. The core–shell droplets can be stimulated by an external magnetic field. Surprisingly, an inner rotation of the silicon droplet is observed when MNPs are fixed at the inner silicon droplet interface. This is the first example of a controlled movement of the inner parts of complex double emulsions by magnetic manipulation via interfacially confined magnetic nanoparticles.
Zur Abschaffung des Gutachterverfahrens in der Vertragspsychotherapie – ein Qualitätsverlust?
(2021)
Zielsetzung: Der vorliegende Artikel befasst sich mit der Fragestellung, inwiefern das Gutachterverfahren in der Vertragspsychotherapie ein zuverlässiges Qualitätsinstrument darstellt und ob sich aus der geplanten Abschaffung des Gutachterverfahrens das Risiko einer Qualitätsminderung in der ambulanten Psychotherapie ergibt.
Methodik: Es wurde eine Literaturrecherche durchgeführt. Arbeiten von den Jahren 2000 bis 2020 wurden berücksichtigt, welche sich mit dem Gutachterverfahren als Qualitätsmerkmal der ambulanten Psychotherapie befassen. Um die unterschiedlichen Standpunkte der zitierten Autor_innen zu diskutieren, wurde auch Bezug auf weiterführende Literatur genommen.
Ergebnisse: Das Gutachterverfahren scheint empirisch nicht sicher als zuverlässiges Qualitätsmerkmal der ambulanten Psychotherapie herangezogen werden zu können. Die Annahme, dass sich durch eine gutachterbefreite Vertragspsychotherapie eine Qualitätsminderung der Psychotherapie ergibt, wird durch die hier zusammengefassten Arbeiten insgesamt nicht gestützt.
Mammalian aldehyde oxidases (AOX) are molybdo-flavoenzymes of pharmacological and pathophysiologic relevance that are involved in phase I drug metabolism and, as a product of their enzymatic activity, are also involved in the generation of reactive oxygen species. So far, the physiologic role of aldehyde oxidase 1 in the human body remains unknown. The human enzyme hAOX1 is characterized by a broad substrate specificity, oxidizing aromatic/aliphatic aldehydes into their corresponding carboxylic acids, and hydroxylating various heteroaromatic rings. The enzyme uses oxygen as terminal electron acceptor to produce hydrogen peroxide and superoxide during turnover. Since hAOX1 and, in particular, some natural variants produce not only H2O2 but also high amounts of superoxide, we investigated the effect of both ROS molecules on the enzymatic activity of hAOX1 in more detail. We compared hAOX1 to the high-O-2(.-)-producing natural variant L438V for their time-dependent inactivation with H2O2/O-2(.-) during substrate turnover. We show that the inactivation of the hAOX1 wild-type enzyme is mainly based on the production of hydrogen peroxide, whereas for the variant L438V, both hydrogen peroxide and superoxide contribute to the time-dependent inactivation of the enzyme during turnover. Further, the level of inactivation was revealed to be substrate-dependent: using substrates with higher turnover numbers resulted in a faster inactivation of the enzymes. Analysis of the inactivation site of the enzyme identified a loss of the terminal sulfido ligand at the molybdenum active site by the produced ROS during turnover.
In this paper the development, use, and evaluation of tasks based on the construct of school-related content knowledge are described. The tasks were used in seminars on organic chemistry for bachelor and master preservice chemistry teachers at a German university. For the evaluation a questionnaire with open and closed items was used. The tasks were rated by the preservice chemistry teachers as relevant for their future profession as a chemistry teacher if the content of the tasks is part of the school curriculum. If the content does not belong to the school curriculum, they rated the nature of the tasks still as relevant; they seem to recognize the importance of conceptual knowledge for their future profession. However, the master's preservice teachers argued with this conceptual knowledge more often than the bachelor's preservice teachers. Although the study is cross-sectional, a certain shift from the focus on the content to conceptual knowledge from bachelor's to master's preservice teachers can be observed.