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"Kontraktmanagement" - Experiences with internal management contracts on German local government
(2000)
Selenides of the type R1Se-EMe3 (E = Si, Ge, Sn, Pb) react with xenon difluoride by cleavage of the Se-E bond to yield the R1Se-F intermediate and the fluorides Me3E-F, whereas the Se-C bond in PhSe-tBu (E = C) is stable against XeF2. The presence of R1Se-F intermediates is confirmed by addition to acetylenes (4-octyne, 3-hexyne). Thus, the fluoroselenenylation of acetylenes gives fluoro(organylseleno)olefins in preparative yields. In the cases of E = Si, Ge, Sn, and Pb, aryl and n-alkyl groups are suitable as the substituent R1. The X-ray crystal structural analysis of (E)-3- (p-carboxyphenylseleno)-4-fluorohex-3-ene - the first example of an uncharged fluoroselenoolefin synthesized from p- EtO2C-C6H4-Se-SnMe3, XeF2, and 3-hexyne followed by an ester hydrolysis - shows that the addition of the selenenylfluoride intermediate to the acetylene proceeds via a trans-addition, as is known for the R2Se2-XeF2 reagents.
A dust cloud around Ganymede Maintained by hypervelocity impacts of interplanetary micrometeoroids
(2000)
An algal culture medium was developed which reflects the extreme chemical conditions of acidic mining lakes (pH 2.7, high concentrations of iron and sulfate) and remains stable without addition of organic carbon sources. It enables controlled experiments e.g. on the heterotrophic potential of pigmented flagellates in the laboratory. Various plankton organisms isolated from acidic lakes were successfully cultivated in this medium. The growth rates of an Chlamydomonas- isolate from acidic mining lakes were assessed by measuring cell densities under pure autotrophic and heterotrophic conditions (with glucose as organic C-source) and showed values of 0.74 and 0.40, respectively.
An asymptotic analysis and improvement of AdaBoost in the binary classification case (in Japanese)
(2000)
An integrated analysis of industrial policies and social security systems in countries in transition
(2000)
Approximation numbers of linear operators are a very useful tool in order to understand the structure and the numerical behaviour of the operators. In this paper, this concept is extended to polynomials on Banach spaces and the approximation numbers of diagonal polynomials are estimated. As a main tool the rank of polynomials as a graduation of finite type polynomials is introduced and studied.
The equilibrium states of electrically conducting fluids or plasmas have been a subject of intense study for a long time, motivated in particular by the interest in controlled thermonuclear fusion, as well as that in space and astrophysical phenomena such as plasma loops in the solar corona. If high temperatures prohibit solid walls, a conducting fluid can be held together by the action of an electric current passing through it with the pressure gradients being balanced by the Lorentz force. The resultant configuration is known as a pinch. In this paper we report on studies of the pinch in the geometry of a plane sheet.
A numerical bifurcation analysis of the electrically driven plane sheet pinch is presented. The electrical conductivity varies across the sheet such as to allow instability of the quiescent basic state at some critical Hartmann number. The most unstable perturbation is the two-dimensional tearing mode. Restricting the whole problem to two spatial dimensions, this mode is followed up to a time-asymptotic steady state, which proves to be sensitive to three- dimensional perturbations even close to the point where the primary instability sets in. A comprehensive three- dimensional stability analysis of the two-dimensional steady tearing-mode state is performed by varying parameters of the sheet pinch. The instability with respect to three-dimensional perturbations is suppressed by a sufficiently strong magnetic field in the invariant direction of the equilibrium. For a special choice of the system parameters, the unstably perturbed state is followed up in its nonlinear evolution and is found to approach a three-dimensional steady state.
We consider entanglement-assisted remote quantum state manipulation of bipartite mixed states. Several aspects are addressed: we present a class of mixed states of rank two that can be transformed into another class of mixed states under entanglement-assisted local operations with classical communication, but for which such a transformation is impossible without assistance. Furthermore, we demonstrate enhancement of the efficiency of purification protocols with the help of entanglement-assisted operations. Finally, transformations from one mixed state to mixed target states which are sufficiently close to the source state are contrasted with similar transformations in the pure-state case.