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Many methods have been proposed for the stabilization of higher index differential-algebraic equations (DAEs). Such methods often involve constraint differentiation and problem stabilization, thus obtaining a stabilized index reduction. A popular method is Baumgarte stabilization, but the choice of parameters to make it robust is unclear in practice. Here we explain why the Baumgarte method may run into trouble. We then show how to improve it. We further develop a unifying theory for stabilization methods which includes many of the various techniques proposed in the literature. Our approach is to (i) consider stabilization of ODEs with invariants, (ii) discretize the stabilizing term in a simple way, generally different from the ODE discretization, and (iii) use orthogonal projections whenever possible. The best methods thus obtained are related to methods of coordinate projection. We discuss them and make concrete algorithmic suggestions.
A Hamiltonian system in potential form (formula in the original abstract) subject to smooth constraints on q can be viewed as a Hamiltonian system on a manifold, but numerical computations must be performed in Rn. In this paper methods which reduce "Hamiltonian differential algebraic equations" to ODEs in Euclidean space are examined. The authors study the construction of canonical parameterizations or local charts as well as methods based on the construction of ODE systems in the space in which the constraint manifold is embedded which preserve the constraint manifold as an invariant manifold. In each case, a Hamiltonian system of ordinary differential equations is produced. The stability of the constraint invariants and the behavior of the original Hamiltonian along solutions are investigated both numerically and analytically.
Many methods have been proposed for the simulation of constrained mechanical systems. The most obvious of these have mild instabilities and drift problems. Consequently, stabilization techniques have been proposed A popular stabilization method is Baumgarte's technique, but the choice of parameters to make it robust has been unclear in practice. Some of the simulation methods that have been proposed and used in computations are reviewed here, from a stability point of view. This involves concepts of differential-algebraic equation (DAE) and ordinary differential equation (ODE) invariants. An explanation of the difficulties that may be encountered using Baumgarte's method is given, and a discussion of why a further quest for better parameter values for this method will always remain frustrating is presented. It is then shown how Baumgarte's method can be improved. An efficient stabilization technique is proposed, which may employ explicit ODE solvers in case of nonstiff or highly oscillatory problems and which relates to coordinate projection methods. Examples of a two-link planar robotic arm and a squeezing mechanism illustrate the effectiveness of this new stabilization method.
The prepaparation of amorphous, homogeneous blends of zwitterionic polymers and transition metal salts was investigated. Homogeneous miscibility was achieved in many cases up to equimolar amounts of salt, depending on the anion and cation chosen. Various analytical techniques point to a solid state solution of the inorganic ions in the polymer matrix.
Throughfall measurements were made under primary terra firme rainforest in the Rio Pichis valley, in the Upper Amazon Basin of Peru. Based on 214 precipitation events over nearly 18 months, throughfall was estimated to be 83.1±8.8% of gross precipitation. Regression analysis of all events revealed that gross precipitation is the only significant explanatory variable; the use of one-burst events does not significantly improve the regression relationship. Gross precipitation is, however, a poor predictor of throughfall for small rainfall events. The two forest structure parameters, canopy capacity, S, and free throughfall coefficient, p, were determined to be 1.3±0.2 mm and 0.32±0.18 mm. Rainfall intensity was found to influence these parameters. New methods which attempt to minimize the influence of meteorologic variables are used to estimate the potential values of these canopy parameters.
Solubilization by polysoaps
(1994)
The aqueous solubilization power of several series of micellar homopolymers and copolymers (polysoaps) is investigated. Using five insoluble or poorly water-soluble dyes, comparisons of the capacities are made with respect ot the influence of structural variables such as the polymer backbone, the polymer geometry, the comonomer content, and the charge of the hydrophilic group. Some guidelines for polysoap structures suited for efficient solubilization are established. Noteworthy is that the solubilization capacities of the polysoaps are neither linked to the ability to reduce the surface tension of water, nor to the polarity of the solubilization sites deduced from spectroscopic probes.
In this paper, we show that symplectic partitioned Runge-Kutta methods conserve momentum maps corresponding to linear symmetry groups acting on the phase space of Hamiltonian differential equations by extended point transformation. We also generalize this result to constrained systems and show how this conservation property relates to the symplectic integration of Lie-Poisson systems on certain submanifolds of the general matrix group GL(n).
In cultured rat hepatocytes the key gluconeogenic enzyme phosphoenolpyruvate carboxykinase (PCK) is known to be induced by glucagon via an elevation of cAMP. Prostaglandin E₂ has been shown to antagonize the glucagon-activated cAMP formation, glycogen phosphorylase activity and glucose output in hepatocytes. It was the purpose of the current investigation to study the potential of PGE₂ to inhibit the glucagon-induced expression of PCK on the level of mRNA and enzyme activity. PCK mRNA and enzyme activity were increased by 0.1 nM glucagon to a maximum after 2 h and 4 h, respectively. This increase was completely inhibited if 10 μM PGE2 was added concomitantly with glucagon. This inhibition by PGE₂ of glucagon-induced PCK activity was abolished by pertussis toxin treatment. When added at the maximum of PCK mRNA at 2 h, PGE₂ accelerated the decay of mRNA and reduced enzyme activity. This effect was not reversed by pertussis toxin treatment. Since in liver PGE₂ is derived from Kupffer cells, which play a key role in the local inflammatory response, the present data imply that during inflammation PGE₂ may reduce the hepatic gluconeogenic capacity via a Gᵢ-linked signal chain.
Rat hepatocytes have previously been reported to possess prostaglandin E₂ receptors of the EP₃-type (EP₃-receptors) that inhibit glucagonstimulated glycogenolysis by decreasing cAMP. Here, the isolation of a functional EP₃ϐ receptor cDNA clone from a rat hepatocyte cDNA library is reported. This clone can be translated into a 362-amino-acid protein, that displays over 95% homology to the EP₃ϐ receptor from mouse mastocytoma. The amino- and carboxy-terminal region of the protein are least conserved. Transiently transfected HEK 293 cells expressed a single binding site for PGE₂ with an apparent Kd of 15 nM. PGE₂ > PGF₂α > PGD₂ competed for [³H]PGE₂ binding sites as did the EP₃ receptor agonists M&B 28767 = sulprostone > misoprostol but not the EP₁ receptor antagonist SC 19220. In stably transfected CHO cells M&B 28767 > sulprostone = PGE₂ > misoprostol > PGF₂α inhibited the forskolin-elicited cAMP formation. Thus, the characteristics of the EP₃ϐ receptor of rat hepatocytes closely resemble those of the EP₃ϐ receptor of mouse mastocytoma.
The site of confluence of the artery and the portal vein in the liver still appears to be controversial. Anatomical studies suggested a presinusoidal or an intrasinusoidal confluence in the first, second or even final third of the sinusoids. The objective of this investigation was to study the problem with functional biochemical techniques. Rat livers were perfused through the hepatic artery and simultaneously either in the orthograde direction from the portal vein to the hepatic vein or in the retrograde direction from the hepatic vein to the portal vein. Arterial how was linearly dependent on arterial pressure between 70 cm H2O and 120 cm H2O at a constant portal or hepatovenous pressure of 18 cm H2O. An arterial pressure of 100 cm H2O was required for the maintenance of a homogeneous orthograde perfusion of the whole parenchyma and of a physiologic ratio of arterial to portal how of about 1:3. Glucagon was infused either through the artery or the portal vein and hepatic vein, respectively, to a submaximally effective ''calculated'' sinusoidal concentration after mixing of 0.1 nmol/L. During orthograde perfusions, arterial and portal glucagon caused the same increases in glucose output. Yet during retrograde perfusions, hepatovenous glucagon elicited metabolic alterations equal to those in orthograde perfusions, whereas arterial glucagon effected changes strongly reduced to between 10% and 50%. Arterially infused trypan blue was distributed homogeneously in the parenchyma during orthograde perfusions, whereas it reached clearly smaller areas of parenchyma during retrograde perfusions. Finally, arterially applied acridine orange was taken up by all periportal hepatocytes in the proximal half of the acinus during orthograde perfusions but only by a much smaller portion of periportal cells in the proximal third of the acinus during retrograde perfusions. These findings suggest that in rat liver, the hepatic artery and the portal vein mix before and within the first third of the sinusoids, rather than in the middle or even last third.
Earlier investigations at South Creek in northeastern Queensland established the importance of overland flow as a hydrologic pathway in this tropical rainforest environment. Since this pathway is ‘fast’, transmitting presumably ‘new’ water, its importance should be reflected in the stormflow chemistry of South Creek: the greater the volumentric contribution to the stormflow hydrograph, the more similarity between the chemical composition of streamwater and of overland flow is to be expected. Water samples were taken during two storm events in an ephemeral gully (gully A), an intermittent gully (gully B) and at the South Creek catchment outlet; additional spot checks were made in several poorly defined rills. The chemical composition of ‘old’ water was determined from 45 baseflow samples collected throughout February. The two events differed considerably in their magnitudes, intensities and antecedent moisture conditions. In both events, the stormflow chemistry in South Creek was characterized by a sharp decrease in Ca, Mg, Na, Si, Cl, EC, ANC, alkalinity and total inorganic carbon. pH remained nearly constant with discharge, whereas K increased sharply, as did sulfate in an ill-defined manner. In event 1, this South Creek stormflow pattern was closely matched by the pattern in gully A, implying a dominant contribution of ‘new’ water. This match was confirmed by the spot samples from rills. Gully B behaved like South Creek itself, but with a dampened ‘new’ water signal, indicating less overland flow generation in its subcatchment. In event 2, which occurred five days later, the initial ‘new’ water signal in gully A was rapidly overwhelmed by a different signal which is attributed to rapid drainage from a perched water table. This study shows that stormflow in this rainforest catchment consists predominantly of ‘new’ water which reaches the stream channel via ‘fast’ pathways. Where the ephemeral gullies delivering overland flow are incised deeply enough to intersect a perched water table, a delayed, ‘old’ water-like signal may be transmitted.
After a review of previous work on the prosody of emotional involvement, data extracts from natural conversations are analyzed in order to argue for the constitution of an 'emphatic (speech) style', which linguistic devices are used to signal heightened emotive involvement. Participants use prosodic cues, in co-occurrence with syntactic and lexical cues, to contextualize turn-constructional units as 'emphatic'. Only realizations of prosodic categories that are marked in relation to surrounding uses of these categories have the power to contextualize units as displaying 'more-than-normal involvement'. In the appropriate context, and in cooccurrence with syntactic and lexical cues and sequential position, the context-sensitive interpretation of this involvement is 'emphasis'. Prosodic marking is used in addition to various unmarked cues that signal and constitute different activity types in conversation. Emphatic style highlights and reinforms particular conversational activities, and makes certain types of recipient responses locally relevant. In particular, switches from non-emphatic to emphatic style are used to contextualize 'peaks of involvement' or 'climaxes' in story-telling. These are shown in the paper to be 'staged' by speakers and treated by recipients as marked activities calling for displays of alignment with respect to the matter at hand. Signals of emphasis are deployable as techniques for locally organizing demonstrations of shared understanding and participant reciprocity in conversational interaction.
A novel atomic beam splitter, using reflection of atoms off an evanescent light wave, is investigated theoretically. The intensity or frequency of the light is modulated in order to create sidebands on the reflected de Broglie wave. The weights and phases of the various sidevands are calculated using three different approaches: the Born approximation, a semiclassical path integral approach, and a numerical solution of the time-dependent Schrdinger equation. We show how this modulated mirror could be used to build practical atomic interferometers.
We present a semiclassical perturbation method for the description of atomic diffraction by a weakly modulated potential. It proceeds in a way similar to the treatment of light diffraction by a thin phase grating, and consists in calculating the atomic wavefunction by means of action integrals along the classical trajectories of the atoms in the absence of the modulated part of the potential. The capabilities and the validity condition of the method are illustrated on the well-known case of atomic diffraction by a Gaussian standing wave. We prove that in this situation the perturbation method is equivalent to the Raman-Nath approximation, and we point out that the usually-considered Raman-Nath validity condition can lead to inaccuracies in the evaluation of the phases of the diffraction amplitudes. The method is also applied to the case of an evanescent wave reflection grating, and an analytical expression for the diffraction pattern at any incidence angle is obtained for the first time. Finally, the application of the method to other situations is briefly discussed.
A detailed theoretical investigation of the reflection of an atomic de Broglie wave at an evanescent wave mirror is presented. The classical and the semiclassical descriptions of the reflection process are reviewed, and a full wave-mechanical approach based on the analytical soution of the corresponding Schrödinger equation is presented. The phase shift at reflection is calculated exactly and interpreted in terms of instantaneous reflection of the atom at an effective mirror. Besides the semiclassical regime of reflection describable by the WKB method, a pure quantum regime of reflection is identified in the limit where the incident de Broglie wavelength is large compared to the evanescent wave decay length.
This study investigated the relation between interest in four different subject areas (mathematics, biology, English, history) and the quality of experience in class. The strength of interest as a predictor of experience was contrasted with that of achievement motivation and scholastic ability. A total of208 highly able freshmen and sophomores completed interest ratings, an achievement motivation questionnaire, and the Preliminary Scholastic Aptitude Test (PSAT). These assessments were followed by one week of experience sampling. In addition, grades were available for the subject areas involved. The results showed that interest was a significant predictor of the experience of potency, intrinsic motivation, self-esteem, and perception of skill. Controlling for ability and achievement motivation did not decrease the strength of these relations. Achievement motivation and ability proved to be considerably weaker predictors of the quality of experience than was interest. In addition, interest contributed significantly to the prediction of grades in mathematics, biology, and history, but not English. The main results and some limitations of the study are discussed, and suggestions for future research are made.
A paradigm for the determination of time-accuracy functions (TAFs) for individual participants is introduced for two pairs of tasks differing in cognitive complexity, that is, word scanning vs cued recognition and figural scanning vs figural reasoning. TAFs can be used to test dissociations of cognitive processes beyond scale-related ambiguities of ordinal interactions. The approach is applied to examine the cognitive-aging hypothesis that a single slowing factor can account for interactions between adult age and cognitive task complexity. Twenty young and 20 old adults participated in 17 sessions. Presentation times required for 75, 87.5, and 100% accuracies were determined for each task with a variant of the psychophysical method of limits. Accuracy was fit by negatively accelerated functions of presentation time. State-trace analyses showed that different slowing factors are required for high- and low-complexity tasks. Relations to speed-accuracy and performance-resource functions are discussed.
Excerpt: The shrill sounds of the now seemingly outdated controversy between Gershom Scholem and Martin Buber at the beginning of the sixties are still in the minds of every student of Hasidic literature and thought. - The "Scholem-community" feels content and the "Buber-community" upset. We can summarize the case in a few words. Martin Buber, the pioneer of Hasidism in the Western World, held the position that whoever would want to understand Hasidism had to turn to Hasidic tale as here, in the tales of the Hasidim, real Hasidic life was to be found. Whereas in the Hasidic homilies we meet mere non-creative tradition especially in the form of Kabbalah. Buber did not totally deny the importance of the Hasidic Midrash but he regarded it just as a commentary, i.e. as secondhand material, whereas, in his view, the tale was a true mirror of real Hasidic life [...]
Several zwitterionic polymers were prepared by radical homopolymerization of surfactant monomers which bear diallyl, diene or vinylcyclopropane moieties. These polymer systems were complemented by alternating copolymers of appropriate zwitterionic vinyl compounds. Thus, polymers with reduced (as compared with simple vinylic homopolymers, or statistical copolymers) and well defined density of surfactant side groups are obtained. The solubilities found for these polymers are dominated by polymer geometry rather than by the balance of hydrophilic and hydrophobic fragments, thus corroborating a main-chain spacer model proposed recently. All water-soluble polymers exhibit characteristic features of classical polysoaps, as shown by surface tension measurements and by solubilization of hydrophobic dyes. In contrast, the water-insoluble copolymers are capable to form stable monolayers at the air-water interface.
This article describes recent achievements in the field of micellar polymers, or polysoaps. Taking advantage of zwitterionic model polymers, systematic variations of the molecular architecture have provided an improved understanding of the relationship between the molecular structure of the polymers and their key properties such as surface activity and solubilization capacity. Useful rules are established, which take into account much of the previous data in the literature.
Increase in prostanoid formation in rat liver macrophages (Kupffer cells) by human anaphylatoxin C3a
(1993)
Human anaphylatoxin C3a increases glycogenolysis in perfused rat liver. This action is inhibited by prostanoid synthesis inhibitors and prostanoid antagonists. Because prostanoids but not anaphylatoxin C3a can increase glycogenolysis in hepatocytes, it has been proposed that prostanoid formation in nonparenchymal cells represents an important step in the C3a-dependent increase in hepatic glycogenolysis. This study shows that (a) human anaphylatoxin C3a (0.1 to 10 mug/ml) dose-dependently increased prostaglandin D2, thromboxane B, and prostaglandin F2alpha formation in rat liver macrophages (Kupffer cells); (b) the C3a-mediated increase in prostanoid formation was maximal after 2 min and showed tachyphylaxis; and (c) the C3a-elicited prostanoid formation could be inhibited specifically by preincubation of C3a with carboxypeptidase B to remove the essential C-terminal arginine or by preincubation of C3a with Fab fragments of a neutralizing monoclonal antibody. These data support the hypothesis that the C3a-dependent activation of hepatic glycogenolysis is mediated by way of a C3a-induced prostanoid production in Kupffer cells.
This study explores learning-disabled students' academic and psychosocial adjustment as compared to their non-disabled classmates within the mainstream public education system in Greece. A brief description of the special education services in Greece is also presented. The sample of the study consisted of fifth and sixth grade elementary school students in northern Greece. The learning-disabled students were identified based on teachers' evaluation (N=30). The control group consisted of all classmates of these students (N=307). Teacher-, peer and self-ratings were used and achievement data were obtained. The learning-disabled students were found to exhibit various academic and psychosocial difficulties based on the perceptions of all raters. Implications of the findings are discussed.
In perfused rat livers, infusion of prostaglandin F₂α (PGF₂α) or noradrenaline increased glucose and lactate output and reduced flow. Glucagon increased glucose output and decreased lactate output without influence on flow. Infusion of phorbol 13-myristate 14-acetate (PMA) for 20 min prior to these stimuli strongly inhibited the metabolic and hemodynamic effects of noradrenaline, reduced the metabolic actions of PGF₂α but did not alter the effects of glucagon. In isolated rat hepatocytes PGF₂α, noradrenaline and glucagon activated glycogen phosphorylase but only PGF₂α and noradrenaline increased intracellular inositol 1,4,5-1risphosphalc (InsP₃). The noradrenaline- or PGF₂α-elicited activation of glycogen phosphorylase and increase in InsP₃ were largely reduced after preincubation of the cells for 10 min with PMA, whereas the glucagon-mediated enzyme activation was not affected. In contra\t to PMA, the phorbol ester 4a-phorbol 13,14-didecanoate. which does not activate protein kinase C, did not attenuate the PGF₂α- and noradrenaline-elicited stimulation of glucose output, glycogen phosphorylase and InsP, formation. Stimulation of InsP₃ formation by AlF₄⁻, which activates phospholipase C independently of the receptor, was not attenuated by prior incubation with PMA. Plasma membranes purified from isolated hepatocytes had both a high-capacity, low-affinity and a low-capacity, high-affinity binding site for PGF₂α. The Kd of the high-capacity, low-affinity binding site was close to the concentration of PGF₂α that increased glycogen phosphorylase activity halfmaximally. Binding to the high-capacity, low-affinity binding site was enhanced by guanosine 5'- 0-(3-thio)triphosphate (GTP[S]). This high-capacity, low-affinity site might thus represent the receptor. The Bmax and Kd of the high-capacity site, as well as the enhancement by GTP[S] of PGF₂α binding to this site, remained unaffected by PMA pretreatment. It is concluded that, in hepatocytes, activation of protein kinase C by PMA interrupted the InsP₃-mediated signal pathway from PGF₂α via a PGF₂α receptor and phospholipase C to glycogen phosphorylase at a point distal of the receptor prior to phospholipase C.
Prostaglandin (PG)F₂α has previously been shown to increase glucose output from perfused livers and isolated hepatocytes, where it stimulated glycogen phosphorylase via an inositol-trisphosphatedependent signal pathway. In this study, PGF₂α binding sites on hepatocyte plasma membranes, that might represent the putative receptor, were characterized. Binding studies could not be performed with intact hepatocytes, because PGF₂α accumulated within the cells even at 4°C. The intracellular accumulation was an order of magnitude higher than binding to plasma membranes. Purified hepatocyte plasma membranes had a high-affinity/low-capacity and a low-affinity/highcapacity binding'site for PGF₂α. The respective binding constants for the high-affinity site were Kd = 3 nM and Bmax = 6 fmol/mg membrane protein, and for the low-affinity site Kd = 426 nM and Bmax = 245 fmol/mg membrane protein. Specific PGF₂α binding to the low-affinity site, but not to the high-affinity site, could be enhanced most potently by GTP[γS] followed by GDP[ϐS] and GTP, but not by ATP[γS] or GMP. PGF₂α competed most potently with [³H]PGF₂α for specific binding to hepatocyte plasma membranes, followed by PGD₂ and PGE₂. Since the low-affinity PGF₂α-binding site had a Kd in the concentration range in which PG had previously been shown to be half-maximally active, and since this binding site showed a sensitivity to GTP, it is concluded that it might represent the receptor involved in the PGF₂α signal chain in hepatocytes. A biological function of the high-affinity site is currently not known.
Prostaglandin E₂ has been reported both to stimulate glycogen-phosphorylase activity (glycogenolytic effect) and to inhibit the glucagon-stimulated glycogen-phosphorylase activity (antiglycogenolytic effect) in rat hepatocytes. It was the purpose of this study to resolve this apparent contradiction and to characterize the signalling pathways and receptor subtypes involved in the opposing prostaglandin E₂ actions. Prostaglandin E₂ (10 μM) increased glucose output, glycogen-phosphorylase activity and inositol trisphosphate formation in hepatocyte cell culture andor suspension. In the same systems, prostaglandin E₂ decreased the glucagon-stimulated (1 nM) glycogen-phosphorylase activity and cAMP formation. The signalling pathway leading to the glycogenolytic effect of PGE₂ was interrupted by incubation of the hepatocytes with 4P-phorbol 12-myristate 13-acetate (100 nM) for 10 min, while the antiglycogenolytic effect of prostaglandin E₂ was not attenuated. The signalling pathway leading to the antiglycogenolytic effect of prostaglandin E₂ was interrupted by an incubation of cultured hepatocytes with pertussis toxin (100 ng/ml) for 18 h, whereas the glycogenolytic effect of prostaglandin E₂ was enhanced. The EP₁/EP₃ prostaglandin-E₂-receptor-specific prostaglandin E₂ analogue Sulproston had a stronger glycogenolytic potency than the EP₃ prostaglandin-E₂-receptor-specific prostaglandin E₂ analogue Misoprostol. The antiglycogenolytic potency of both agonists was equal. It is concluded that the glycogenolytic and the antiglycogenolytic effects of prostaglandin E₂ are mediated via different signalling pathways in hepatocytes possibly involving EP₁ and EP₃ prostaglandin E₂ receptors, respectively.
Rainfall erosivities as defined by the R factor from the universal soil loss equation were determined for all events during a two-year period at the station La Cuenca in western Amazonia. Three methods based on a power relationship between rainfall amount and erosivity were then applied to estimate event and daily rainfall erosivities from the respective rainfall amounts. A test of the resulting regression equations against an independent data set proved all three methods equally adequate in predicting rainfall erosivity from daily rainfall amount. We recommend the Richardson model for testing in the Amazon Basin, and its use with the coefficient from La Cuenca in western Amazonia.
Excerpt: The writings from the thirteenth century called by Gershom Scholem the "Writings of the 'lyyun circle" are one of the most intriguing chapters of early kabbalah - this I need not to elaborate on as it is a well known fact to anyone whoever had read these texts or the literature about them. When reading these texts, one gets the impression as if the authors had at hand a box full of terms and phrases into which everybody could just stick his hand and take terms and phrases out of it in order to arrange them according to his own taste, disregarding the meaning they have in the writings of his fellow kabbalists. The result was, that we now have before us a large number of varying mosaic pictures in which we detect again and again the same mosaic pebbles, however composed differently.
This article presents results from a meta-analysis of studies on the relation between subject-matter-related interest and school achievement. For the time period between 1965 and 1990 a total of 21 studies reporting 127 independent correlations (i. e., correlations based on independent samples) were identified. For the overall relation between interestand achievement a mean correlation of .30 was found. Male students exhibited significantly higher interest-achievement correlations than female students. In addition, significant differences among school subjects were observed. Grade level, however, did not produce a significant moderator effect. Finally, the results are discussed on the basis of theories of interest and methodological considerations.
A model for correct recall and intrusions in cued recall of word lists is introduced. Intrusions are false responses that were correct in an earlier list. The model assumes 3 exclusive states for memory traces after encoding: with a list tag (i.e., with information about list origin), without list tags, and missing. Across lists, a trace can lose its list tag or its content. For retrieval, an optimal strategy of response selection was assumed. Younger and older laboratory-trained mnemonists participated in 2 experiments in which recall of permutations of a single word list across a single set of cues was held constant with individually adjusted presentation times. With correct recall equated to younger adults, older adults were more susceptible to intrusions. Age differences were restricted to model parameters estimating the probability of generation of list tags. Alternative accounts of age differences in context memory are discussed.
This paper presents a new methodology for examining the phenomenon of subitizing. Subjects were presented with a standard numerosity-detection task but for a range of presentation times to allow Task-Accuracy Functions to be computed for individual subjects. The data appear to show a continuous change in processing for numerosities from 2 to 5 when the data are aggregated across subjects. At the level of individual subjects, there appear to be qualitative shifts in enumeration processing after 3 or 4 objects. The approach used in this experiment may be used to test the claim that subitizing is a distinct enumeration process that can be used for small numbers of objects.
Sequential and coordinative complexity : age-based processing limitations in figural transformations
(1993)
Dimensions of cognitive complexity in figural transformations were examined in the context of adult age differences. Sequential complexity was manipulated through figural transformations of single objects in a multiple-object array. Coordinative complexity was induced through spatial or nonspatial transformations of the entire array. Results confirmed the prediction that age-related slowing is larger in coordinative complexity than in sequential complexity conditions. The effect was stable across 8 sessions (Experiment 1), was obtained when age groups were equated in accuracy with criterion-referenced testing (Experiment 2), and was corroborated by age-differential probabilities of error types (Experiments 1 and 2). A model is proposed attributing age effects under coordinative complexity to 2 factors: (a) basic-level slowing and (b) time-consuming reiterations through the processing sequence due to age-related working memory failures.
Past research suggests that age differences in measures of cognitive speed contribute to differences in intellectual functioning between young and old adults. To investigate whether speed also predicts age-related differences in intellectual performance beyond age 70 years, tests indicating 5 intellectual abilities—speed, reasoning, memory, knowledge, and fluency—were administered to a close-to-representative, age-stratified sample of old and very old adults. Age trends of all 5 abilities were well described by a negative linear function. The speed-mediated effect of age fully explained the relationship between age and both the common and the specific variance of the other 4 abilities. Results offer strong support for the speed hypothesis of old age cognitive decline but need to be qualified by further research on the reasons underlying age differences in measures of speed.
My analysis of question-word questions in conversational question-answer sequences results in the decomposition of the conversational question into three systems of constitutive cues, which signal and contextualize the particular activity type in conversational interaction: (1) syntactic structure, (2) semantic relation to prior turn, and (3) prosody. These components are used and combined by interlocutors to distinguish between different activity types which (4) sequentially implicate different types of answers by the recipient in the next turn. Prosody is only one cooccurring cue, but in some cases it is the only distinctive one. It is shown that prosody, and in particular intonation, cannot be determined or even systematically related to syntactic sentence structure type or other sentence-grammatical principles, as most former and current theories of intonation postulate. Instead, prosody is an independent, autonomous signalling system, which is used as a contextualization device for the constitution of interactively relevant activity types in conversation.
A set of novel zwitterionic side-chain polyacrylates and polymethacrylates is studied by X-ray scattering. The structural order both in the short-range and long-range scale is investigated. The influence of the polymer backbone, of different locations of the ionic groups in isomeric polymers, of bound water and of added inorganic salts on the bulk structures is studied, and the observed rearrangements are analysed.
Technical and physical systems, especially electronic circuits, are frequently modeled as a system of differential and nonlinear implicit equations. In the literature such systems of equations are called differentialalgebraic equations (DAEs). It turns out that the numerical and analytical properties of a DAE depend on an integer called the index of the problem. For example, the well-known BDF method of Gear can be applied, in general, to a DAE only if the index does not exceed one. In this paper we give a geometric interpretation of higherindex DAEs and indicate problems arising in connection with such DAEs by means of several examples.
The topography of first-order catchments in a region of western Amazonia was found to exhibit distinctive, recurrent features: a steep, straight lower side slope, a flat or nearly flat terrace at an intermediate elevation between valley floor and interfluve, and an upper side slope connecting interfluve and intermediate terrace. A detailed survey of soil-saturated hydraulic conductivity (K sat)-depth relationships, involving 740 undisturbed soil cores, was conducted in a 0.75-ha first-order catchment. The sampling approach was stratified with respect to the above slope units. Exploratory data analysis suggested fourth-root transformation of batches from the 0–0.1 m depth interval, log transformation of batches from the subsequent 0.1 m depth increments, and the use of robust estimators of location and scale. The K sat of the steep lower side slope decreased from 46 to 0.1 mm/h over the overall sampling depth of 0.4 m. The corresponding decrease was from 46 to 0.1 mm/h on the intermediate terrace, from 335 to 0.01 mm/h on the upper side slope, and from 550 to 0.015 mm/h on the interfluve. A depthwise comparison of these slope units led to the formulation of several hypotheses concerning the link between K sat and topography.
4-Phenylphenoxazinones were isolated after biomimetic oxidation, using diphenoloxidases of insect cuticle, mushroom tyrosinase, or after autoxidation of N-acetyldopamine (Image ) in the presence of β-alanine, β-alanine methyl ester or N-acetyl-L-lysine. They are formed presumably by addition of 2-aminoalkyl-5-alkylphenols to the o-quinone of biphenyltetrol which, in turn, arises from oxidative coupling of. The structures of present the first examples for the assembly of reasonably stable intermediates in the rather complex process of chemical modifications of aliphatic amino acid residues by o-quinones.
Mixed monolayers and Langmuir-Blodgett multilayers of functional low molecular weight guest compounds, especially nonlinear optical (NLO) dyes, within the matrix of an amphotropic spacer polymer have been prepared. The polymer matrix enabled the transfer of guest compounds not capable of self-organizing at the air-water interface by themselves. The structure of the LB multilayers and the transfer process were studied by small angle X-ray scattering and UV-visible spectroscopy. Good NLO coefficients were found in the mixed films.
Several types of insect cuticle contain enzymes catalyzing the formation ofof adducts between N-acetyldopamine (NADA) and N-acetylhistidine (NAH). Two such adducts, NAH-NADA-I and NAH NADA-II, have been isolated and their structures determined. In one of the adducts the link connecting the two residues occurs between the I-position (ß-position) in the NADA side chain and the 1-N atom (τ-N) in the imidazole ring of histidine. Diphenoloxidase activity alone is not sufficient for formation of this adduct, whereas extracts containing both diphenoloxidase and o-quinone-p-quinone methide isomerase activities catalyze the coupling reaction. The adduct consists of a mixture of two diastereomers and they are presumably formed by spontaneous reaction between enzymatically produced NADA-p-quinone methide and N-acetylhistidine. The other adduct has been identified as a ring addition product of N-acetylhistidine and NADA. In contrast to the former adduct it can be formed by incubation of the two substrates with mushroom tyrosinase alone. An adduct between N-acetylhistidine and the benzodioxan-type NADA-dimer is produced in vitro, when the N-acetylhistidine-NADA adduct is incubated with NADA and locust cuticle containing a 1,2-dehydro-NADA generating enzyme system. Trimeric NADA-polymerization products of the substituted benzodioxan-type have been obtained from in vivo sclerotized locust cuticle, confirming the ability of cuticle to produce NADA-oligomers. The results indicate that some insect cuticles contain enzymes promoting linkage of oxidized NADA to histidine residues. It is suggested that histidine residues in the cuticular proteins can serve as acceptors for oxidized NADA and that further addition of NADA-residues to the phenolic groups of bound NADA can occur, resulting in formation of protein-linked NADA-oligomers. The coupling reactions identified may be an important step in natural cuticular sclerotization.
School performance and adjustment of Greek remigrant students in the schools of their home country
(1992)
This study explores the adjustment of Greek remigrant students in Greek public schools after their families' return to Greece from the Federal Republic of Germany. Teacher and self-rating instruments were used, and achievement and language competence data were obtained. The sample consisted of 13- to 15-year-old junior high school students in northern Greece. The remigrant students were divided into two groups ("early return" and "late return"), based on the year of return to Greece. The control group consisted of all the local classmates of these students. Remigrant students (mainly late return) were found to experience difficulties mainly in the language/learning domain and less in the interpersonal and intrapersonal behavior domains.
The molecular packing and spatial correlations of two isomeric zwitterionic polymethacrylates and one polyacrylate analog are studied by means of X-ray analysis and conformational calculations. The analysis of the correlation functions and density distribution profiles suggest a double-layered molecular packing which is discussed for the three polymers investigated, with respect to their different chemical structures. Whereas the zwitterionic polymethacrylates studied exhibit liquid-like short-range order, the polyacrylate analog exhibits an ordered double-layered superstructure.
Orthopyroxenes of a high temperature protomylonite of the Ivrea Zone, Northern Italy show twin like polysynthetic lamellae parallel to {210} of the hypersthene host. The transformation is caused by plastic deformation under high metamorphic conditions which has resulted in dynamic recrystallization of pyroxene and plagioclase. The lamellae consist of clinohypersthene. The twin plane and the lamellar clino-orthoinversion of hypersthene due to natural deformation have not been described hitherto.
Content: 1 Persons and Situations: Cornerstones of Modern Personality Psychology 2 The Issue of Consistency in Personality:Sixty Years of Controversy 3 In Defence of Traits: New (and Revived) Perspectives 4 Modern Interactionism: An Alternative Framework for Personality Research 5 Implementing the Interactionist Programme:Three Exemplary Areas of Research 6 Improving Personality Measurement:The Nomothetic Road to the Study of Consistency 7 Personality Psychology is about Individuals:Rediscovering the Idiographic Legacy 8 The Role of the Situation in Personality Research 9 Personality Psychology in the Nineties: An Outlook
Content: Synopsis The Attitudes toward Rape Victims Scale: Psychometric Data from 14 Countries Scale Construction and Validation - Study One: Preliminary Analyses - Study Two: Test-Retest Reliability - Study Three: Construct Validity Cross-cultural Extensions - United States - United Kingdom - Germany - New Zealand - Canada - West Indies - Israel - Turkey - India - Hong Kong - Malaysia - Zimbabwe - Mexico - Metric Equivalence Discussion
Content: Introduction: Do the Arts Really Matter? Aesthetic Cognition and Human Development The Significance of Arts in Everyday Life: Evidence from Case StudiesArts and Quality of Experience: A Systematic Analysis The Conditions of Optimal Experience The Representation of Experience in Personality Consequences for Teaching the Arts
Personality and language
(1992)
Using a testing-the-limits paradigm, the authors investigated the modulation (attenuation) o f negative adult age differences in imagery-based memory performance as a function of professional expertise. Six older graphic designers, 6 normal older adults, 6 younger graphic design students, and 6 normal younger students participated in a 19-session program with a cued-recall variant of the Method of Loci. Older graphic designers attained higher levels o f mnemonic performance than normal older adults but were not able to reach younger adults' level of performance; a perfect separation of age groups was achieved. Spatial visualization was a good predictor of mnemonic performance. Results suggest that negative adult age differences in imagery-based memory are attenuated but not eliminated by the advantages associated with criterion-relevant ability (talent) and experience.
Earlier testing-the-limits research on age differences in cognitive plasticity of a memory skill was extended by 18 additional assessment and training sessions to explore whether older adults were able to catch up with additional practice and improved training conditions. The focus was on the method of loci, which requires mental imagination to encode and retrieve lists of words from memory in serial order. Of the original 37 subjects, 35 (16 young, ranging from 20 to 30 years of age, and 19 older adults, ranging from 66 to 80 years of age) participated in the follow-up study. Older adults showed sizable performance deficits when compared with young adults and tested for limits of reserve capacity. The negative age difference was substantial, resistant to extensive practice, and applied to all subjects studied. The primary origin for this negative age difference may be a loss in the production and use of mental imagination for operations of the mind.
The use of preformed polymers for the preparation of Langmuir-Blodgett (LB) multilayers is reviewed. Principles for polymer self-organization are outlined and the appropriate molecular designs are discussed. Recent developments in the different classes of polymers for LB multilayers are presented, and their outstanding properties highlighted.
1) During orthograde perfusion of rat liver human anaphylatoxin C3a caused an increase in glucose and lactate output and reduction of flow. These effects could be enhanced nearly twofold by co-infusion of the carboxypeptidase inhibitor MERGETPA, which reduced inactivation of C3a to C3adesArg. 2) During retrograde perfusion C3a caused a two- to threefold larger increase in glucose and lactate output and reduction of flow than in orthograde perfusions. These actions tended to be slightly enhanced by MERGETPA. 3) The elimination of C3a plus C3adesArg immunoreactivity during a single liver passage was around 67%, irrespective of the perfusion direction and the presence of the carboxypeptidase inhibitor MERGETPA; however, less C3adesArg and more intact C3a appeared in the perfusate in the presence of MERGETPA in orthograde and retrogade perfusions It is concluded that rat liver inactivated human anaphylatoxin C3a by conversion to C3adesArg and moreover eliminated it by an additional process. The inactivation to C3adesArg seemed to be located predominantly in the proximal periportal region of the liver sinusoid, since C3a was less effective in orthograde perfusions, when C3a first passed the proximal periportal region before reaching the predominant mass of parenchyma as its site of action, than in retrograde perfusions, when it first passed the perivenous area. These data may be evidence for a periportal scavenger mechanism, by which the liver protects itself from systemically released mediators of inflammation that interfere with the local regulation of liver metabolism and hemodynamics.
Rat serum, in which the complement sytem had been activated by incubation with zymosan, increased the glucose and lactate output, and reduced and redistributed the flow in isolated perfused rat liver clearly more than the control serum. Heat inactivation of the rat serum prior to zymosan incubation abolished this difference. Metabolic and hemodynamic alterations caused by the activated serum were dose dependent. They were almost completely inhibited by the cyclooxygenase inhibitor indomethacin and by the thromboxane antagonist 4-[2-(4-chlorobenzenesulfonamide)-ethyl]-benzene-acetica cid (BM 13505), but clearly less efficiently by the 5’-lipoxygenase inhibitor nordihydroguaiaretic acid and the leukotriene antagonist N-{3-[3-(4-acetyl-3-hydroxy-2-propyl-phenoxy)-propoxy]-4-chlorine-6-methyl-phenyl}-1H-tetrazole-5-carboxamide sodium salt (CGP 35949 B). Control serum and to a much larger extent complement-activated serum, caused an overflow of thromboxane B₂ and prostaglandin F₂α into the hepatic vein. It is concluded that the activated complement system of rat serum can influence liver metabolism and hemodynamics via release from nonparenchymal liver cells of thromboxane and prostaglandins, the latter of which can in turn act on the parenchymal cells.
An existence and uniqueness theory is developed for general nonlinear and nonautonomous differential-algebraic equations (DAEs) by exploiting their underlying differential-geometric structure. A DAE is called regular if there is a unique nonautonomous vector field such that the solutions of the DAE and the solutions of the vector field are in one-to-one correspondence. Sufficient conditions for regularity of a DAE are derived in terms of constrained manifolds. Based on this differential-geometric characterization, existence and uniqueness results are stated for regular DAEs. Furthermore, our not ons are compared with techniques frequently used in the literature such as index and solvability. The results are illustrated in detail by means of a simple circuit example.
Cationic and zwitterionic polymerizable surfactants bearing tri- and tetraethyleneglycol spacer groups between the polymerizable moiety and the surfactant structure were prepared and polymerized. Monomers and polymers were investigated with respect to their aggregation behavior in aqueous systems and compared to analogous monomers and polymers lacking spacer groups. In the case of the monomeric surfactants, the spacer groups depress both the Kraffttemperature and the critical micelle concentration. the area occupied per molecule at the air-water interface is substantially enlarged by the spacers, whereas the depression of surface tension is nearly constant. Although the monomers with and without spacers are true surfactants, all the polymers are water-insoluble, but form monomolecular layers at the air-water interface. In analogy to the monomer behavior, the incorporation of the spacer groups increases the area occupied per repeat unit at the air-water interface substantially, but hardly affects the surface activity.
Recent research related to the concept of interest is reviewed. It is argued that current constructs of motivation fail to include crucial aspects of the meaning of interest emphasized by classical American and German educational theorists. In contrast with many contemporary concepts (e.g., intrinsic learning orientation), interest is defined as a content-specific motivational characteristic composed of intrinsic feeling-related and value-related valences. Results from a number of studies are presented that indicate the importance of interest for the depth of text comprehension, the use of learning strategies, and the quality of the emotional experience while learning. The implications of these results and possible directions for future research are discussed.
The study investigates police officers' definitions of different rape situations. On the basis of the concept of 'cognitive prototypes' a methodology is developed which elicits consensual feature lists describing six rape situations: the typical, i.e. most common rape, the credible, dubious, and false rape complaints as weil as the rape experiences that are particularly hard vs. relatively easy for the victim to cope with. Qualitative analysis of the data allows the identification of the characteristic features defining the prototype of each rape situation, as weil as comparisons between the situations in terms of their common and distinctive features. It is shown that police officers, while sharing some of the widely held stereotypes about rape, generally perceive rape as a serious crime with long-term negative consequences for the victim. The quantitative analysis of prototype similarity between the six situations corroborates this conclusion by demonstrating a high similarity between the prototypes of the typical and the credible rape situation: In addition, subjects' general attitude towards rape victims is measured to compare the prototypes provided by respondents holding a positive vs. negative attitude towards rape victims. Findings for the two groups, however, reveal more similarities than differences in their descriptions of rape prototypes. The paper concludes with a discussion of the feasibility of the prototype approach presented in this study as a strategy for investigating implicit or common-sense theories of rape.
The chapter presents a social psychological approach to the study of rape and sexual assault. Two issues are at the core of this approach: identifying the critical variables that affect attributions of responsibility to victims of rape. and exploring people's subjective definitions of rape, which may differ markedly from legal definitions. Following a review of the American evidence, a series of studies conductcd in two European countries is presented to address these issues.
We investigated the role of training-induced knowledge Schemas and encoding time on adult age differences in recall. High-plausible (schema coherent) words were recalled better than lowplausible (schema discrepant) words in both age groups. This difference was larger for old-adults than for young adults for presentation times ranging from 3 s to 11 s per word. After equating participants in overall recall (i.e., at 50% correct) by dynamic adjustment of presentation time, old adults again showed a stronger plausibility effect than young adults when recall was above criterion. In a second experiment with self-paced encoding, old adults used more time than young adults only for low-plausible pairs, yet they still remembered fewer of them. In a third experiment, both age groups preferred to imagine high- rather than low-plausible words, but this effect was more pronounced in old adults. The results indicate that, compared with young adults, old adults find it particularly difficult to form elaborative mental images of schema-discrepant information under a wide variety of time constraints during encoding. Results are discussed in relation to explanations based on age-related mental slowing.
Elderly adults (N = 116; average age = 73 years) were randomly assigned to one of four treatment groups varying in the amount of training and testing on fluid intelligence tests. They were compared before and after treatment on self-efficacy and utility beliefs for intelligence tests and everyday competence. Although both ability training and extended retest practice resulted in significant gains in objective test performance (Baltes, Kliegl, & Dittmann-Kohli, 1988), only ability training resulted in positive changes in self-efficacy. However, these changes were restricted to testrelated self-efficacy. Training had no impact on perceived utility or on everyday self-efficacy beliefs. Implications of the results are discussed with regard to interventions to increase intellectual self-efficacy in elderly persons.
The subject of this paper is the relation of differential-algebraic equations (DAEs) to vector fields on manifolds. For that reason, we introduce the notion of a regular DAE as a DAE to which a vector field uniquely corresponds. Furthermore, a technique is described which yields a family of manifolds for a given DAE. This socalled family of constraint manifolds allows in turn the formulation of sufficient conditions for the regularity of a DAE. and the definition of the index of a regular DAE. We also state a method for the reduction of higher-index DAEs to lowsr-index ones that can be solved without introducing additional constants of integration. Finally, the notion of realizability of a given vector field by a regular DAE is introduced, and it is shown that any vector field can be realized by a regular DAE. Throughout this paper the problem of path-tracing is discussed as an illustration of the mathematical phenomena.
The influence of topic interest, prior knowledge, and cognitive capabilities on text comprehension
(1990)
The present study investigated the influence of topic interest on the comprehension of texts. The primary goals of the study were as follows: (1) to formulate a new definition of the concept "topic interest", (2) to control for cognitive capabilities (intelligence, short-term memory) and prior knowledge, and(3) to assess different levels of comprehension. A total of 53 male students, majoring in computer science, took part in the study. Subjects were presented with a text on "Psychology of Emotion". Prior to reading the text, they were asked to indicate their level of interest in the topic. After reading the text, subjects were given a test of comprehension involving open-ended questions. The questions were designed to represent different levels of comprehension. The results show that the effect of topic interest on text comprehension is especially pronounced when a deeper level of understanding is required. Surprisingly, prior knowledge had no effect on the level of comprehension. Verbal intelligence, on the other hand, showed a clear effect on comprehension, especially in answering questions of simple knowledge. The effects of interest and verbal intelligence could be shown to be independent of one another.
This volume reexamines the long-standing controversy about consistency in personality from a social psychological perspective. Barabara Krahé reconsiders the concept of consistency in terms of the systematic coherence of situation cognition and behaviour across situations. In the first part of the volume she undertakes an examination of recent social psychological models of situation cognition for their ability to clarify the principles underlying the perception of situational similarities. She then advances an individual-centred methedology in which nomothetic hypotheses about cross-situational coherence are tested on the basis of idiogrphic measurement of situation cognition and behaviour. In the second part of the volume, a series of empirical studies is reported which apply the individual-centred framework to the analysis of cross-situational coherence in the domain of anxiety-provoking situations. These studies are distinctive in that they extend over several months and use free-response data; they are based on idiographic sampling; and they employ explicit theoretical models to capture the central features of situation perception. The results demonstrate the benefits of integrating idiographic and nomothetic research strategies and exploiting the advantages of both perspectives.
The focus of this study was on developmental reserve capacity in old age as revealed by testing-thelimits. We examined (a) the time course of training-related magnification of age differences in serial word recall and (b) predictability of training gains by pretest individual differences in cognitive abilities. In 20 sessions, young (n = 18) and old (n = 19) adults were taught to recall lists of 30 words using the Method of Loci. Age differences were magnified early in practice at long presentation times (20 s and 15 s per word) and later at 5 s per word. Regression of posttraining scores on various pretraining abilities revealed significant effects of digit symbol substitution. Also, consistent with the assumption of age-related decline in developmental reserve capacity, the unique variance in serial word recall associated with age group became more salient as the training unfolded.
Aus dem Inhalt: Melanins are complex polyphenolic polymers. They are usually formed in nature by enzyme-catalyzed oxidative polymerization of o-diphenols. The deep black eumelanins, derived from Dopa 1 or dopamine 3, are distinguished from the yellow to brown phaeomelanins obtained from Dopa in the presence of cysteine. Characteristic of eumelanins are the indole units, which are formed from catecholamines by intramolecular addition of the amino groups to the oxidatively generated o-quinones. [...]
Content: 1. Introduction 2. The notion of speech style: from a dependent variable to contextualization cue 3. Speech styles in conversation from a German Sozialamt 3.1 Extracts from conversation 3.2 Speech style constituting cues 3.3 Choice and alternation of speech styles in conversation 4. Summary and conclusions
The complement fragments C3a and C5a were purified from zymosan-activated human serum by column chromatographic procedures after the bulk of the proteins had been removed by acidic polyethylene glycol precipitation. In the isolated in situ perfused rat liver C3a increased glucose and lactate output and reduced flow. Its effects were enhanced in the presence of the carboxypeptidase inhibitor DL-mercaptomethyl-3-guanidinoethylthio-propanoic acid (MERGETPA) and abolished by preincubation of the anaphylatoxin with carboxypeptidase B or with Fab fragments of an anti-C3a monoclonal antibody. The C3a effects were partially inhibited by the thromboxane antagonist BM13505. C5a had no effect. It is concluded that locally but not systemically produced C3a may play an important role in the regulation of local metabolism and hemodynamics during inflammatory processes in the liver.
Langmuir-Blodgett multilayers of hydrocarbon and fluorocarbon polymers with hydrophilic spacer, lipid-polyelectrolyte complexes and mesogenic polymers have been prepared. The thermal behaviour of the multilayers was studied by small angle X-ray scattering, IR and UV—visible spectroscopy. Good thermal stabilities were found for the various classes of polymers. In addition, for both complexed multilayers and mesogenic polymer films, reorientation processes were observed.
Contents: 1. Discotic Liquid Crystals 2. Monolayers and Langmuir-Blodgett Multilayers 3. Theoretical Considerations on the Molecular Packing of Discotic LCs in Monolayers and Multilayers 4. Spreading Experiments with Discotic LCs 5. LB-Multilayers of Discotic LCs 6. Polymeric Discotic LCs 7. Summary
The piezoelectric and pyroelectric properties of oriented films possessing dipole moments are increasingly being used in pressure, acoustic, thermal and optical devices. The performance of these devices in many applications may be enhanced by thin-film technology.The developing Langmuir-Blodgett thin-film deposition technique offers the opportunity to obtain highly oriented and uniform organic-based films in the 10–5000 nm thickness range. Special techniques must be used, however, to assemble these molecules in such a way as to result in polar multilayer films. Several possible deposition techniques are investigated, with one resulting in a polar and pyroelectric film about 50 nm thick.
A study is reported which investigates the fakeability of personality profiles as measured by a standard personality inventory, the Freiburger Persönlichkeitsinventar (FPI). Unlike previous studies investigating laypersons' ability to fake a global good or bad impression, the present study examined individuals' ability to fake a specific personality profile. Four groups of subjects were instructed to fake their FPI scores so as to present themselves as high vs low scorers on the "social orientation" dimension or high vs low scorers on the "achievement orientation" dimension. The results clearly demonstrate that subjects are successful in manipulating their scores on the critical dimensions according to instruction. Moreover, they also fake related scales in a way that corroborates the intended image of a person with a high (or low) achievement (or social) orientation. The overall pattern of results reveals that subjects were able to distort their responses in a way that reflects their intuitive understanding of the dimensional structure of the FPI. The implications of the present findings for the use of personality inventories as valid diagnostic instruments are discussed.
The main points raised by Borkenau against our challenge of the 'intuitive psychometrics' view of personality judgements are discussed, in particular his example of the link between school grades and intelligence. It is argued that the semantic similarity interpretation advanced in our paper is more adequate and more parsimonious than explanations in terms of psychometric reasoning.
Investigated the range and limits of cognitive reserve capacity as a general approach to the understanding of age differences in cognitive functioning. Testing-the-limits is proposed as a research strategy, Data are reported from 2 training studies involving old (65 to 83 years old) and young adults (19 to 29 years old). The training, designed to engineer an expertise in serial word recall, involved instruction and practice in the Method of Loci. Substantial plasticity was evident in pretest to posttest comparisons. Participants raised their serial word recall several times above that of pretest baseline. Age-differential limits in reserve capacity were evident in amount of training gain but not in responses to conditions of increased test difficulty (speeded stimulus presentation). Group differences were magnified by the training to such a degree that age distributions barely overlapped at posttests. Testing-the-limits offers promise in terms of understanding the extent and nature of cognitive plasticity.
Cognitive research on the plasticity of fluid intelligence has demonstrated that older adults benefit markedly from guided practice in cognitive skills and problem-solving strategies. We examined to what degree older adults are capable by themselves of achieving similar practice gains, focusing on the fluid ability of figural relations. A sample of 72 healthy older adults was assigned randomly to three conditions: control, tutor-guided training, self-guided training. Training time and training materials were held constant for the two training conditions. Posttraining performances were analyzed using a transfer of training paradigm in terms of three indicators: correct responses, accuracy, and level of item difficulty. The training programs were effective and produced a significant but narrow band of within-ability transfer. However, there was no difference between the two training groups. Older adults were shown to be capable of producing gains by themselves that were comparable to those obtained following tutor-guided training in the nature of test-relevant cognitive skills.
The role of intonation in the organization of repair and problem handling sequences in conversation
(1988)
Transcripts of repair and/or problem handling sequences from natural conversations are presented and analyzed with special reference to the role of intonation in the interactive organization of these sequences. It is shown that (a) in the initiation of so-called repair or local problem handling sequences, intonation is used as a type-distinctive device, and (b) in the handling of a global problem handling sequence, intonation is systematically used as a means to constitute and control participant cooperation. In general, intonation is analyzed as one contextualization cue cooccurring with specific syntactic, semantic and discourse organizational devices to signal the status of an utterance in conversational context. It is hypothesized that especially in the global problem handling sequence, different categories of intonation, i.e. different accent and contour types, are systematically used to signal and control participants' interactive problem handling in different, indexically relevant ways simultaneously.
In the isolated rat liver perfused in situ, stimulation of the nerve bundles around the hepatic artery and portal vein caused an increase of glucose and lactate output and a reduction of perfusion flow. These changes could be inhibited completely by α-receptor blockers. The possible involvement of inositol phosphates in the intracellular signal transmission was studied. 1. In cell-suspension experiments, which were performed as a positive control, noradrenaline caused an increase in glucose output and, in the presence of 10 mM LiCl, a dose-dependent and time-dependent increase of inositol mono, bis and trisphosphate. 2. In the perfused rat liver 1 μM noradrenaline caused an increase of glucose and lactate output and in the presence of 10 mM LiCl a time-dependent increase of inositol mono, bis and trisphosphate that was comparable to that observed in cell suspensions. 3. In the perfused rat liver stimulation of the nerve bundles around the portal vein and hepatic artery caused a similar increase in glucose and lactate output to that produced by noradrenaline, but in the presence of 10 mM LiCl there was a smaller increase of inositol monophosphate and no increase of inositol bis and trisphosphate. These findings are in line with the proposal that circulating noradrenaline reaches every hepatocyte, causing a clear overall increase of inositol phosphate formation and thus calcium release from the endoplasmic reticulum, while the hepatic nerves reach only a few cells causing there a small local change of inositol phosphate metabolism and thence a propagation of the signal via gap junctions.
Amphiphilic derivatives of octadiene and docosadiene were investigated in monolayers and Langmuir-Blodgett multilayers, with respect to their self-organization and their polymerization behavior. All amphiphiles investigated form monolayers. However, only acid and alcohol derivatives were able to build up multilayers. Those multilayers are rapidly photopolymerized in the layers via a two-step process: Irradiation with long-wavelength UV light yields soluble polymers, whereas additional irradiation with sfiort-wavelength UV light produces insoluble and presumably cross-linked polymers. The reaction meclianism is discussed according to the polymer characterization by UV spectroscopy, small-angle X-ray scattering, NMR spectroscopy, and gel permeation chromatography. All multilayers undergo structural changes during the polymerization; substantial changes result in defects in the polymerized layers as observed by scanning electron microscopy. In contrast to the acids and alcohols, the deposition of monolayers of the aldehyde derivatives did not yield well-ordered multilayers, but rather amorphous films. In this different film structure, the photopolymerization process differs from the one observed in multilayers.
Explaining perceived cross-situational consistency : intuitive psychometrics or semantic mediation?
(1988)
Recent studies at the interface of social cognition and personality theory have stressed lay persons' ability to 'function as intuitive psychometricians' (Epstein and Teraspulsky, 1986). This research argues that lay persons not only show a substantial degree of accuracy in estimating cross-situational generality of behaviour, but also take into account principles of aggregation over time. In contrast, it is argued here that lay persons' perceptions of the degree of relatedness of different behaviours are mediated largely by the decontextualized semantic relationships between behavioural descriptions. This argument finds support in two experimental studies which demonstrate that the main source for subjects' judgments of 'cross-situational consistency' can be found in an abstracted knowledge base which is represented and mediated through language. The implications of the findings are drawn out for personality research. in particular with reference to domain and item selection in questionnaires for research.
Two field studies were conducted lo investigate the influence of observer and victim characteristics on attributions of victim and assailant responsibility in a rape case. In the first study, male and female subjects completed a measure of rape myth acceptance and were presented with a rape account after which they were asked to attribute responsibility to victim and assailant. In the second study, a new sample was asked to attribute responsibility to victim and assailant on the basis of one of two rape accounts in which victim's pre-rape behavior was manipulated. Results showed that both rape myth acceptance and victims' pre-rape behavior in influenced the degree of responsibility attributed to victims and assailants. No significant effects of subject gender were found. A more complex conceptualization is suggested of the link between observer and victim characteristics in social reactions to and evaluations of rape victims.
On the locus of training gains in research on the plasticity of fluid intelligence in old age
(1988)
Cognitive training research has shown that many older adults have a substantial reserve capacity in fluid intelligence. Little is known, however, about the locus of plasticity. Two studies were conducted to examine whether training gains in fluid abilities are critically dependent on experimenter-guided training and/or whether older adults can achieve similar improvements by themselves on the basis of cognitive skills already available in their repertoire. Several comparisons were made: (a) between test performances after trainer-guided training in ability-specific cognitive skills and after self-guided retest practice (without feedback), (b) between performances under speeded and power conditions of assessment, (c) between performances on easy and difficult items, and (d) between the relative numbers of correct and wrong answers. Results suggest that a large share of the training improvement shown by the elderly can plausibly be explained as the result of the activation and practice of cognitive skills already available in their repertoire. The results also have implications for educational practice, pointing to the appropriateness of strategies of self-directed learning for many elderly adults.
The names of God and the celestial powers : their function and meaning in the Hekhalot literature
(1987)
Excerpt: "Names and adjurations are the two main theurgic means found in the Hekhalot literature applied in connect ion with the descent to the Merkhavah and the invocation of angels to come down to earth and to reveal secrets," says Ithamar Gruenwald in his book on the Merkavah literature. He continues and maintains, with Gershom Scholem, that "that particular element in the Hekhalot Literature actually belonged to its very heart and this almost from its beginning." It is very seductive for the student of this literature to go straight to the heart of these texts; but the danger of this approach is as great as the danger of yeridat merkavah itself. Indeed, I feel as if I am passing the gates of the Hekhalot, the watchers of the gates standing on both sides prepared to throw their iron axes at my head. I can only hope that I may present the proper names! [...]
Several polymerizable lipids were synthesized and polymerized to amphiphilic homopolymers and to copolymers with the help of hydrophilic comonomers. The self-organization of these polymeric lipids was investigated in monolayers and Langmuir-Blodgett multilayers. The self-organization of these polymers in model membranes is due to hydrophilic spacer groups in the amphiphilic side groups as well as to hydrophilic spacer groups in the polymer backbone. Thus, highly ordered monolayers and LB-multilayers are easily obtained.
A system of descriptive categories for the notation and analysis of intonation in natural conversation is presented and discussed in relation to other systems currently suggested for incorporation in discourse analysis, The categories are based on purely auditive criteria. They differ from e.g. tonetic approaches by relying more on transcribers' and analysts' perception of the form and internal cohesiveness of contours, especially with respect to rhythmicality and/or pitch contour (gestalt). Intonation is conceived of as a relational phenomenon; the role of intonation in conversational utterances can only be analyzed by considering its co-occurrence with other properties of utterances like syntactic, semantic and discourse organizational structures and devices. In general, intonation is viewed as one signalling system contributing to the contextualization of utterances in their conversational context. A broad functional differentiation between different types of intonation categories seems plausible: Local categories like accents might fulfill mainly semantic functions, while global categories like different contour types might fulfill primarily functions with respect to the interactive coordination of activities in conversation.
In the isolated rat liver perfused in situ stimulation of the nerve bundles around the portal vein and the hepatic artery caused an increase of urate formation that was inhibited by the α1-blocker prazosine and the xanthine oxidase inhibitor allopurinol. Moreover, nerve stimulation increased glucose and lactate output and decreased perfusion flow. Infusion of noradrenaline had similar effects. Compared to nerve stimulation infusion of glucagon led to a less pronounced increase of urate formation and a twice as large increase in glucose output but a decrease in lactate release without affecting the flow rate. Insulin had no effect on any of the parameters studied.
The inhibitory effect of sinefungin on juvenile hormone biosynthesis and development in locusts
(1987)
The antibiotic fungal metabolite sinefungin is a potent inhibitor of S-adenosylmethionine-acceptor methyltransferases. Its effect on insect metabolism and especially on corpora allata farnesoic acid methyltransferase, which catalyzes the penultimate step of juvenile hormone biosynthesis, was investigated in Locusta migratoria. Injection of sinefungin results in a delay of imaginal molt and in suppression of ovary development. Isolated corpora allata are unable to synthesize juvenile hormone III in the presence of more than 1.0 mM sinefungin. In a cell-free system containing the S-adenosylmethionine-dependent farnesoic acid methyltransferase from corpora allata sinefungin is a competitive inhibitor of the synthesis of methylfarnesoate with Ki of 1 μM.
Motivational conditions have been thus far largely neglected by contemporary theoretical approaches in knowledge psychology. The present article attempts to demonstrate the necessity for the greater integration of both. Suggestions are made regarding the choice and conceptualization of relevant motivational factors. Two possible groups of factors can be distinguished: (1) motivational factors of personality, and (2) motivational effects of action. Available theoretical approaches (e.g., the "levels of processing" approach) and examples are used to clarify the potential effects of these factors on the acquisition and representation of knowledge. Finally, a review is made of empirical studies allowing confirmatory allegations about the posited relationships between motivational factors and processes related to knowledge. This review reveals substantial research deficits on this topic.
Two studies are reported which examine the availability of scientific propositions of personality in lay conceptions of personality. It is argued from a social constructivist perspective that models of personality must derive from and refer to lay conceptions of persons. Eysenck's trait-type model of introversion-extroversion, containing specific propositions about phenotypic and genotypic differences between extraverts and introverts, was utilized as the scientific model of personality and its availability in lay conceptions of personality was examined in two studies. In the first study, subjects were presented with a genotypic characterization of either an introvert or an extravert target person and asked to infer corresponding phenotypic differences. In the second study, the inference process was reversed with subjects being asked to infer genotypic characteristics of introverts versus extraverts on the basis of phenotypic target person descriptions of the two types. Results from both studies show a high degree of accuracy in subjects' inferences, suggesting that laypersons have well-formed conceptions about personality containing 'higher-order' psychogenetic propositions corresponding to Eysenck's trait-type model. The implications of the findings for theory construction are discussed.
Content: 1 Introduction 2 Theoretical background - Expertise and Reserve Capacity - Testing-the-Limits and Research on Expertise - Cognitive Processes and Knowledge - Age Comparisons of Peak Performance - Advantages of Constructed Versus Naturally Acquired Expertise - Hypotheses Related to Aging and Expertise: Toward Magnification and Identification of Age Differences and Aging-Sensitive Components 3 Theory-guided synthesis of memory expertise - Theoretical Framework - Procedure - Subjects - Results 4 Adaptivity testing of expert memory - Increasing Task Difficulty Within an Extant System - Selective Componential Interference - Toward the Study of Compensatory Processes 5 Conclusions
This article outlines a research strategy for investigating, in a laboratory setting, the acquisition and the "limits" of a cognitive skill. Expert digit memory is used as an illustration. Two participants with initial average digit- and word-span memory were trained to memorize and reproduce strings of 80 to 90 digits presented at 10- to 1-sec rates. The instruction and training program, based on a theory of skilled memory, focused on three components: (a) acquisition of a mnemonic system (i.e., recoding digits into historical dates or concrete nouns), (b) use of a long-term memory retrieval structure (i.e., instruction in the Method of Loci), and (c) improvement in processing speed. After 86 experimental sessions, one participant recalled 90 random digits presented at a 1-sec rate. The digits were, however, constrained to be compatible with the participant's historical knowledge. The second participant recalled 80 random digits presented at a 5-sec rate after 70 sessions. Speed of encoding and retrieval processing was the only component that required extensive practice for skilled digit-memory acquisition.
The optical density of human macular pigment was measured for 50 observers ranging in age from 10 to 90 years. The psychophysical method required adjusting the radiance of a 1°, monochromatic light (400–550 nm) to minimize flicker (15 Hz) when presented in counterphase with a 460 nm standard. This test stimulus was presented superimposed on a broad-band, short-wave background. Macular pigment density was determined by comparing sensitivity under these conditions for the fovea, where macular pigment is maximal, and 5° temporally. This difference spectrum, measured for 12 observers, matched Wyszecki and Stiles's standard density spectrum for macular pigment. To study variation in macular pigment density for a larger group of observers, measurements were made at only selected spectral points (460, 500 and 550 nm). The mean optical density at 460 nm for the complete sample of 50 subjects was 0.39. Substantial individual differences in density were found (ca. 0.10–0.80), but this variation was not systematically related to age.
Cinnamic acid moieties were incorporated into amphiphilic compounds containing one and two alkyl chains. These lipid-like compounds with photoreactive units undergo self-organization to form monolayers at the gas-water interface and bilayer structures (vesicles) in aqueous solutions. The photoreaction of the cinnamic acid moiety induced by 254 nm UV light was investigated in the crystalline state, in monolayers, in vesicles and in solution in organic solvents. The single-chain amphiphiles undergo dimerization to yield photoproducts with twice the molecular weight of the corresponding monomers in organized systems. The photoreaction of amphiphiles containing two cinnamic acid groups occurs via two mechanisms: The intramolecular dimerization produces bicycles, with retention of the molecular weight of the corresponding monomer. The intermolecular reaction leads to oligomeric and polymeric photoproducts. In contrast to the single-chain amphiphiles, photodimerization processes of lipoids containing two cinnamic acid moieties also occur in solution in organic solvents.
Monolayers of rod-shaped and disc-shaped liquid crystalline compounds at the air-water interface
(1986)
Calamitic (rod-shaped) and discotic (disc-shaped) thermotropic liquid crystalline (LC) compounds were spread at the air-water interface, and their ability to form monolayers was studied. The calamitic LCs investigated were found to form monolayers which behave analogously to conventional amphiphiles such as fatty acids. The spreading of the discotic LCs produced monolayers as well, but with a behaviour different from classical amphiphiles. The areas occupied per molecule are too small to allow the contact of all hydrophilic groups with the water surface and the packing of all hydrophobic chains. Various molecular arrangements of the discotics at the water surface to fit the spreading data are discussed.