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Beziehungen zwischen Texturen und Molekülpackung in Monoschichten an der Luft/Wasser-Grenzfläche
(1997)
The pendant drop technique was used to determine p/A isotherms of docosanic acid spread on the drop surface of an aqueous polymer solution. Two water soluble polymers were used, poly(dimethyl-diallyl-ammoniumchloride) and sodium poly(styrene sulfonate-b-ethylethylene). By fast changes of the drop volume, the monolayers were compressed and dilated. The stress relaxation was monitored and surface rheological dilation parameters were obtained. It is shown that the fatty acid monolayer can be mechanically stabilized by both interacting anionic and cationic polymers. In the case of the anionic polymer, the interaction becomes more pronounced in the presence of salts in the subphase (counterions). Brewster angle microscopy shows that the typical tilt-orientation of crystalline domains of the fatty acid monolayers transforms into a more uniform and fluid-like structure caused by the polymer/monolayer interaction. The surface rheological behavior is dramatically influenced by the polymer binding. The interaction results in surface dilational viscoelastic properties and show that there is a strong resistance against expansion of the complex fatty acid/polymer layer.
High pressure X-ray diffraction, absorption, luminescence and Raman scattering study of Cs2MoS4
(1997)
Characterization of InGaAs single quantum wells buried in GaAs[001] by grazing incidence diffraction
(1997)
Thermally induced rearrangement of fatty acid salt molecules in Langmuir-Blodgett multilayers
(1997)
Spectral analyses of central of planetary nebulae of early WC-type / NGC 6751 and Sanduleak 3
(1997)
Untersuchungen kinematischer und dynamisch konsistenter Dynamomodelle in sphärischer Geometrie
(1997)
Reconstruction of nonlinear time delay models from data by the use of optimal transformations
(1997)
Weak gravitational lensing by large-scale structure affects the determination of the cosmological deceleration parameter q0. We find that the lensing induced dispersions on truly standard candles are 0.04 and 0.02 mag at redshift z = 1 and z = 0.5, respectively, in a COBE-normalized cold dark matter universe with Omega 0 = 0.40, Lamda 0 = 0.6, H = 65 km s-1 Mpc-1, and sigma 8 = 0.79. It is shown that one would observe q0 = -0.395^{+0.125}_{-0.095} and q0 = - 0.398^{+0.048}_{-0.077} (the error bars are 2 sigma limits) with standard candles with zero intrinsic dispersion at redshift z = 1 and z = 0.5, respectively, compared to the truth of q0 = -0.400. A standard COBE normalized Omega 0 = 1 CDM model would produce three times as much variance and a mixed (hot and cold) dark matter model would lead to an intermediate result. One unique signature of this dispersion effect is its non-Gaussianity. Although the lensing induced dispersion at lower redshift is still significantly smaller than the currently best observed (total) dispersion of 0.12 mag in a sample of type Ia supernovae, selected with the multicolor light curve shape method, it becomes significant at higher redshift. We show that there is an optimal redshift, in the range z ~ 0.5--2.0 depending on the amplitude of the intrinsic dispersion of the standard candles, at which q0 can be most accurately determined.
Fluoreszenzuntersuchungen an flüssigkristallinen Polymeren mit Benzanilid- und Biphenylseitengruppen
(1997)
Langmuir-Blodgett films of zinc 11,18,25-tri(tert-butyl)-4-sulfo-phthalocyanine (ZNPctSO3Na) have been deposited onto hydrophilic and hydrophobic silicon wafers. Y-type films were formed on both types of substrate, and the transfer ratio was very close to unity. The organization of the films on the molecular level was probed by X-ray specular reflectivity.
The molecular in-plane structure of uranyl arachidate Langmuir-Blodgett (LB) films formed at different subphase pH values was analysed by means of X-ray grazing-incidence diffraction. For multilayers formed at low subphase pH a reorganisation of the arachidic acid film structure is confirmed. At appropriate subphase pH values, reorganisation of the film structure, e.g. via the formation of three-dimensional crystallites, is prevented by the presence of the uranyl ions and by the subsequent introduction of conformational disorder (gauche defects) in the alkyl chains. The observation of a macroscopic flow-induced in-plane texture in these uranyl arachidate LB films has profound implications for the design of ordered, supramolecular structures by the Langmuir-Blodgett technique.
The thermal treatment of Y-type Langmuir-Blodgett (LB) films formed from the amphiphilic derivative of 2,5- diphenyl-1,3,4-oxadiazole 1 results in changes of the molecular packing. These changes have been analysed by a combination of X-ray specular reflectivity data, X-ray grazing incidence diffraction data and scanning force microscopy images, On the basis of these experimental data we have simulated possible supramolecular structures, These simulations provide insight into the intermolecular interactions giving rise to the observed structural transitions. The crystalline structure induced by thermal treatment of the LB films is characterized by a uniaxial texture, which is correlated with the dipping direction during deposition of the LB film.
The complexation of highly ordered fatty acid monolayers with polyelectrolytes is expected to yield well- ordered Langmuir films suitable for the formation of Langmuir-Blodgett multilayers with improved long-term stability. Studies of the surface pressure-area isotherms and of the surface potential kinetics yield detailed information regarding the influence of these polymeric counterions on the monolayer properties. The injection of bivalent metal salts into the subphase after the complexation was used to improve the order and stability of the mono- and multilayers. The corresponding Langmuir-Blodgett films were investigated by means of X-ray reflectivity measurements and scanning force microscopy. The polyion complex multilayers show a strongly increased mechanical stability compared with films of fatty acid salts formed with bivalent metal ions. These structures are expected to be suitable as ultrathin separation layer for gas separation or ultrafiltration membranes.
This paper describes the formation and structure investigation of Langmuir monolayers and Langmuir-Blodgett multilayers formed from amphiphilic derivatives of 2,5-diphenyl-1,3,4-oxadiazole. The 2,5-diphenyl-1,3,4-oxadiazole group as a functional unit with interesting physical and chemical properties is maintained, while the head group, the length of the alkyl chain and the structure of the coupling unit between aromatic and aliphatic part of these linear short-chain amphiphiles is systematically varied in order to explore the influence of this change on the film forming properties and the stability of Langmuir and Langmuir-Blodgett films. Molecular mechanics simulations are shown by these systematic variations to be suitable for the prediction of optimal chemical structures allowing for a stable stratified molecular packing. The combination of a detailed structure investigation of the multilayers based on scanning force microscopy and X-ray data with molecular mechanics simulations yields an insight into the packing of the molecules and the intermolecular interactions.