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Six N-alkylpyridinium salts [CnPy](2)[MCl4] (n = 4 or 12 and M = Co, Cu, Zn) were synthesized, and their structure and thermal properties were studied. The [C4Py](2)[MCl4] compounds are monoclinic and crystallize in the space group P2(1)/n. The crystals of the longer chain analogues [C12Py](2)[MCl4] are triclinic and crystallize in the space group P (1) over bar. Above the melting temperature, all compounds are ionic liquids (ILs). The derivatives with the longer C12 chain exhibit liquid crystallinity and the shorter chain compounds only show a melting transition. Consistent with single-crystal analysis, electron paramagnetic resonance spectroscopy suggests that the [CuCl4](2-) ions in the Cu-based ILs have a distorted tetrahedral geometry.
This case study evaluates the suitability of radar-based quantitative precipitation estimates (QPEs) for the simulation of streamflow in the Marikina River Basin (MRB), the Philippines. Hourly radar-based QPEs were produced from reflectivity that had been observed by an S-band radar located about 90 km from the MRB. Radar data processing and precipitation estimation were carried out using the open source library wradlib. To assess the added value of the radar-based QPE, we used spatially interpolated rain gauge observations (gauge-only (GO) product) as a benchmark. Rain gauge observations were also used to quantify rainfall estimation errors at the point scale. At the point scale, the radar-based QPE outperformed the GO product in 2012, while for 2013, the performance was similar. For both periods, estimation errors substantially increased from daily to the hourly accumulation intervals. Despite this fact, both rainfall estimation methods allowed for a good representation of observed streamflow when used to force a hydrological simulation model of the MRB. Furthermore, the results of the hydrological simulation were consistent with rainfall verification at the point scale: the radar-based QPE performed better than the GO product in 2012, and equivalently in 2013. Altogether, we could demonstrate that, in terms of streamflow simulation, the radar-based QPE can perform as good as or even better than the GO product - even for a basin such as the MRB which has a comparatively dense rain gauge network. This suggests good prospects for using radar-based QPE to simulate and forecast streamflow in other parts of the Philippines where rain gauge networks are not as dense.
The 11 July 1889 Chilik earthquake (M-w 8.0-8.3) forms part of a remarkable sequence of large earthquakes in the late nineteenth and early twentieth centuries in the northern Tien Shan. Despite its importance, the source of the 1889 earthquake remains unknown, though the macroseismic epicenter is sited in the Chilik valley, similar to 100 km southeast of Almaty, Kazakhstan (similar to 2 million population). Several short fault segments that have been inferred to have ruptured in 1889 are too short on their own to account for the estimated magnitude. In this paper we perform detailed surveying and trenching of the similar to 30 km long Saty fault, one of the previously inferred sources, and find that it was formed in a single earthquake within the last 700 years, involving surface slip of up to 10 m. The scarp-forming event, likely to be the 1889 earthquake, was the only surface-rupturing event for at least 5000 years and potentially for much longer. From satellite imagery we extend the mapped length of fresh scarps within the 1889 epicentral zone to a total of similar to 175 km, which we also suggest as candidate ruptures from the 1889 earthquake. The 175 km of rupture involves conjugate oblique left-lateral and right-lateral slip on three separate faults, with step overs of several kilometers between them. All three faults were essentially invisible in the Holocene geomorphology prior to the last slip. The recurrence interval between large earthquakes on any of these faults, and presumably on other faults of the Tien Shan, may be longer than the timescale over which the landscape is reset, providing a challenge for delineating sources of future hazard.
Lamprophyre sind porphyrische, aus Mantelschmelzen gebildete Gesteine, die meist in Form von Gängen auftreten. Sie zeichnen sich durch auffällige und charakteristische texturelle, chemische und mineralogische Eigenschaften aus. Als ehemalige Mantelschmelzen liefern sie Information sowohl über Bedingungen der Schmelzbildung im Mantel als auch über geodynamische Prozesse, die zu metasomatischer Veränderung des Mantels geführt haben. Im Saxothuringikum Mitteleuropas, am Nordrand des Böhmischen Massivs, gibt es zahlreiche Lamprophyrvorkommen, die hier zur Charakterisierung der Mantelentwicklung während der variszischen Orogenese dienen. Die vorliegende Arbeit befaßt sich mit den mineralogischen, geochemischen und isotopischen (Sr-Nd-Pb) Signaturen von spätvariszischen kalkalkalischen Lamprophyren, von postvariszischen ultramafischen Lamprophyren, von Alkalibasalten der Lausitz und, zum Vergleich, von prävariszischen Gabbros. Darüberhinaus nutzt die Arbeit Lithium-Isotopensignaturen kombiniert mit Sr-Nd-Pb–Isotopendaten spätvariszischer kalkalkalischer Lamprophyre aus drei variszischen Domänen (Erzgebirge, Lausitz, Sudeten) zur Erkundung der lokalen Mantelüberprägungen während der variszischen Orogenese.
In order to monitor the seismic activity of Mt. Merapi (Indonesia) over a long period of time, we installed a permanent array of both broadband and short-period seismometers during the summer of 1997. Considering the requirements of an automatic classification and localization system for seismic monitoring and surveillance at active volcanoes, we split this network into three small aperture arrays distributed around the volcano. We introduce here a newly developed method to determine the hypocenters in an automatic, non-linear manner using the coherence of seismic waves observed at the different arrays. To test this method, we analyze a swarm of VT-B events recorded by the network. The first step in this algorithm is based on a modified smoothed coherence transform. In the second step we perform a semblance analysis applied to the 3D problem, evaluating the quality of the estimated relative onset-times. After more than one year of dormancy, Mt. Merapi renewed its activity at the end of June 1998. This gave us the opportunity to analyze all stages of dome growth, collapse and new intrusion of magma using the associated seismicity in a post-processing sense. This also allowed us to calibrate and test our newly developed automatic monitoring system using the more pronounced waveforms of VT-B events. By detecting and classifying different event types automatically, we are able to localize a large number of VT-B events which occurred just before the initial eruption. We are also able to resolve some properties of the wavefield at Mt Merapi which are essential for further interpretations. Finally, the results show that the source region of the VT-B type seismicity just before the 1998 eruption is closely related to the region of subsequent high volcanic activity and therefore may represent a promising tool to forecast future eruptions.
Theories and concepts
(2020)
Urban Change and Citizenship in Times of Crisis addresses the fact that in the beginning of the twenty-first century the majority of the world’s population is urbanised, a social fact that has turned cities more than ever into focal sites of social change. Multiple economic and political strategies, employed by a variety of individual and collective actors, on a number of scales, constitute cities as contested spaces that hold opportunities as well as restrictions for their inhabitants. While cities and urban spaces have long been of central concern for the social sciences, today, classical sociological questions about the city acquire new meaning: Can cities be spaces of emancipation, or does life in the modern city entail a corrosion of citizenship rights? Is the city the focus of societal transformation processes, or do urban environments lose importance in shaping social reality and economic relationships? Furthermore, new questions urgently need to be asked: What is the impact of different historical phenomena such as neo-liberal restructuring, financial and economic crises, or migration flows, as well as their respective counter-movements, on the structure of contemporary cities and on the citizenship rights of city inhabitants? The three volumes address such crucial questions thereby opening up new spaces of debate on both the city and new developments of urbanism.
The contributions to Theories and Concepts offer new theoretical reflections on the city in a philosophical and historical perspective as well as fresh empirical analyses of social life in urban contexts. Chapters not only critically revisit classical and modern philosophical considerations about the nature of cities but no less discuss normative philosophical reflections of urban life and the role of religion in historical processes of the emergence of cities. Composed around the question whether there can be such a thing as a ‘successful city’, this volume addresses issues of urban political subjectivities by considering the city’s role in historical processes of emancipation, the fight for citizenship rights, and today’s challenges and opportunities with regard to promoting social justice, integration, and diversity. Consequentially, theory-driven empirical analyses offer new insight into ways of solving problems in urban contexts and a genuine approach to analyse the Social Quality in cities.