Refine
Year of publication
- 2005 (644) (remove)
Document Type
- Article (644) (remove)
Language
- English (644) (remove)
Keywords
- givenness (2)
- 1829 (1)
- Elektronische Edition (1)
- Frederic Edwin Church (1)
- Google (1)
- Gottfried August Bürger (1)
- Humboldt Digital Library (1)
- Humboldt als Vorbild (1)
- Italienische Reise (1)
- Johann Wolfgang von Goethe (1)
Institute
- Institut für Physik und Astronomie (146)
- Institut für Biochemie und Biologie (97)
- Institut für Geowissenschaften (67)
- Institut für Chemie (58)
- Department Psychologie (40)
- Department Linguistik (34)
- Institut für Mathematik (34)
- Institut für Ernährungswissenschaft (31)
- Institut für Informatik und Computational Science (28)
- Wirtschaftswissenschaften (18)
- Institut für Umweltwissenschaften und Geographie (11)
- Sozialwissenschaften (11)
- Historisches Institut (10)
- Institut für Anglistik und Amerikanistik (9)
- Extern (8)
- Institut für Romanistik (8)
- Philosophische Fakultät (5)
- Department Sport- und Gesundheitswissenschaften (4)
- Institut für Germanistik (4)
- Institut für Slavistik (4)
- Department Erziehungswissenschaft (3)
- Institut für Jüdische Studien und Religionswissenschaft (2)
- Öffentliches Recht (2)
- Bürgerliches Recht (1)
- Institut für Künste und Medien (1)
- Klassische Philologie (1)
- MenschenRechtsZentrum (1)
X-ray diffraction by a crystal in a permanent external electric field : general considerations
(2005)
The variations of X-ray diffraction intensities from a crystal in the presence of a permanent external electric field is modeled analytically using a first-order stationary perturbation theory. The change in a crystal, induced by an external electric field, is separated into two contributions. The first one is related to a pure polarization of an electron subsystem, while the second contribution can be reduced to the displacements of the rigid pseudoatoms from their equilibrium positions. It is shown that a change of the X-ray diffraction intensities mainly originates from the second contribution, while the influence of the pure polarization of a crystal electron subsystem is negligibly small. The quantities restored from an X-ray diffraction experiment in the presence of an external electric field were analyzed in detail in terms of a rigid pseudoatomic model of electron density and harmonic approximation for the atomic thermal motion. Explicit relationships are derived that link the properties of phonon spectra with E-field-induced variations of a structure factor, pseudoatomic displacements and piezoelectric strains. The displacements can be numerically estimated using a model of independent atomic motion if the Debye - Waller factors and pseudoatomic charges are known either from a previous single-crystal X-ray diffraction study or from density functional theory calculations. The above estimations can be used to develop an optimum strategy for a data collection that avoids the measurements of reflections insensitive to the electric-field-induced variations
On the basis of a mete-analysis of pairwise correlations between working memory tasks and cognitive ability measures, P. L. Ackerman. M. E. Beier, and M. O. Boyle (2005) claimed that working memory capacity (WMC) shares less than 25% of its variance with general intelligence (,;) and with reasoning ability. In this comment, the authors argue that this is an underestimation because of several methodological shortcomings and biases. A reanalysis of the data reported in Ackerman et al. using the correct statistical procedures demonstrates that g and WMC are very highly correlated. On a conceptual level. the authors point out that WMC should be regarded as an explanatory construct for intellectual abilities. Theories of working memory do not claim that WMC is isomorphic with intelligence factors but that it is a very strong predictor of reasoning ability and also predicts general fluid intelligence and g.
With the success of wireless technologies in consumer electronics, standard wireless technologies are envisioned for the deployment in industrial environments as well. Industrial applications involving mobile subsystems or just the desire to save cabling make wireless technologies attractive. Nevertheless, these applications often have stringent requirements on reliability and timing. In wired environments, timing and reliability are well catered for by fieldbus systems (which are a mature technology designed to enable communication between digital controllers and the sensors and actuators interfacing to a physical process). When wireless links are included, reliability and timing requirements are significantly more difficult to meet, due to the adverse properties of the radio channels. In this paper we thus discuss some key issues coming up in wireless fieldbus and wireless industrial communication systems:1)fundamental problems like achieving timely and reliable transmission despite channel errors; 2) the usage of existing wireless technologies for this specific field of applications; and 3) the creation of hybrid systems in which wireless stations are included into existing wired systems
Previous research has documented only a modest success rate for imposed sanctions. By contrast, the success rate is higher in cases that are settled at the threat stage. In this article, the authors provide new insights about the circumstances under which sanctions cause behavioral change only after being imposed. First, the target must initially underestimate the impact of sanctions, miscalculate the sender's determination to impose them, or wrongly believe that sanctions will be imposed and maintained whether it yields or not. Second, the target's misperceptions must be corrected after sanctions are imposed. A game-theoretical model with incomplete information is used to develop and clarify the argument
Basin formation dynamics of the Tertiary Piedmont Basin (TPB) are here investigated by means of cross-section numerical modelling. Previous works hypothesised that basin subsidence occurred due first to extension (Oligocene) and then to subsequent loading due to back-thrusting (Miocene). However, structural evidence shows that the TPB was mainly under contraction from Oligocene until post Pliocene time while extension played a minor role. Furthermore, thermal indicators strongly call for a cold (flexure-induced) mechanism but are strictly inconsistent with a hot (thermally induced) mechanism. Our new modelling shows that the TPB stratigraphic features can be reproduced by flexure of a visco- elastic plate loaded by backthrusts active in the Western Alps in Oligo-Miocene times. Far-field compression contributed to the TPB subsidence and controlled the basin infill geometry by enhancing basin tilting, forebulge uplift and erosion of the southern margin of the basin. These results suggest that the TPB subsidence is the result of a combination of mechanisms including thrust loading and farfield compressional stresses. (c) 2005 Elsevier B.V. All rights reserved
Potential fields are classically represented on the sphere using spherical harmonics. However, this decomposition leads to numerical difficulties when data to be modelled are irregularly distributed or cover a regional zone. To overcome this drawback, we develop a new representation of the magnetic and the gravity fields based on wavelet frames. In this paper, we first describe how to build wavelet frames on the sphere. The chosen frames are based on the Poisson multipole wavelets, which are of special interest for geophysical modelling, since their scaling parameter is linked to the multipole depth (Holschneider et al.). The implementation of wavelet frames results from a discretization of the continuous wavelet transform in space and scale. We also build different frames using two kinds of spherical meshes and various scale sequences. We then validate the mathematical method through simple fits of scalar functions on the sphere, named 'scalar models'. Moreover, we propose magnetic and gravity models, referred to as 'vectorial models', taking into account geophysical constraints. We then discuss the representation of the Earth's magnetic and gravity fields from data regularly or irregularly distributed. Comparisons of the obtained wavelet models with the initial spherical harmonic models point out the advantages of wavelet modelling when the used magnetic or gravity data are sparsely distributed or cover just a very local zone
This paper is devoted to the digital processing of multicomponent seismograms using wavelet analysis. The goal of this processing is to identify Rayleigh surface elastic waves and determine their properties. A new method for calculating the ellipticity parameters of a wave in the form of a time-frequency spectrum is proposed, which offers wide possibilities for filtering seismic signals in order to suppress or extract the Rayleigh components. A model of dispersion and dissipation of elliptic waves written in terms of wavelet spectra of complex (two-component) signals is also proposed. The model is used to formulate a nonlinear minimization problem that allows for a high-accuracy calculation of the group and phase velocities and the attenuation factor for a propagating elliptic Rayleigh wave. All methods considered in the paper are illustrated with the use of test signals. (c) 2005 Pleiades Publishing, Inc
In silicate glasses and melts, water acts according to two main processes. First, it can be dissolved in high temperature/high pressure melts. Second, it constitutes a weathering agent on the glass surface. A number of in-situ x- ray absorption fine structure (XAFS) studies for Fe, Ni, Zr, Th and U show that the more charged cations (Zr, Nb, Mo, Ta, Sn, Th and U) are little affected by the presence of dissolved water in the melt. In contrast, divalent iron and nickel are highly sensitive to the presence of water, which enhance nucleation processes, for example, of phyllosilicates at the angstrom-scale. Such information provides additional constraints on the role of water deep in the Earth, particularly in magmatology. By contrast, the weathering of glass surfaces by water can be studied from a durability perspective. Experimental weathering experiments Of nuclear waste glasses performed in the laboratory show a variety of surface enrichments (carbon, chlorine, alkalis, iron) after exposure to atmospheric fluids and moisture. Mn-, and Fe-surface enrichments of analogous glasses of the XIVth century are related to the formation of Mn and Fe oxy/ hydroxides on the surface. The impact on the glass darkening is considered in terms of urban pollution and mass tourism
In the light of recent intensity-voltage low energy electron diffraction (LEED-IV) experiments [Surf. Sci. 316, 92 (1994); Surf. Rev. Lett. 10, 487 (2003)], the electronic and geometric structure of a water bilayer adsorbed at the Ru(0001) surface are investigated through first-principles total energy calculations, using periodic slab geometries and gradient-corrected density functional theory (DFT). We consider five possible bilayer structures, all roughly consistent with the LEED-IV analysis (three intact structures and two half-dissociated), and a water single layer at Ru(0001). Adsorption energies and substrate-adsorbate geometry parameters are given and discussed in the light of the experiments. We also give a comparative analysis of the electron density redistribution (Delta rho) and of the dipole moment change (Delta mu) induced by water adsorption on the Ru(0001) surface. In agreement with Feibelman [Science 295, 99 (2002)], the half-dissociated structures are found to be more stable than the intact ones, and their adsorption geometries in better agreement with the LEED-IV data. However, the Delta rho analysis shows that a half-dissociated structure induces a Delta mu>0, which would be incompatible with the experimentally measured decrease of the work function following bilayer adsorption; the latter would be consistent, instead, with the Delta mu < 0 induced by the intact structures. It is the aim of this paper to compare various possible adsorption structures, most of them already considered previously, with one and the same method. For this purpose, thick slabs and restrictive computational parameters are chosen to generally address the accuracy and the limits of DFT in reproducing adsorption energies and bond lengths of water-metal interacting systems