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Schröder, Rolf ; Warlo, Irene ; Herrmann, Harald ; VanDerVen, Peter F. M ; Klasen, Christian ; Blümke, Ingmar ; Mundegar, Rustam R. ; Fürst, Dieter Oswald ; Göbel, Hans H. ; Magin, Thomas
Altenbach, Alexander V. ; Pflaum, U. ; Scheibel, Thomas R. ; Thies, A. ; Timm, M. ; Trauth, Martin H.
Parezanović, Vladimir ; Cordier, Laurent ; Spohn, Andreas ; Duriez, Thomas ; Noack, Bernd R. ; Bonnet, Jean-Paul ; Segond, Marc ; Abel, Markus ; Brunton, Steven L.
Many previous studies have shown that the turbulent mixing layer under periodic forcing tends to adopt a lock-on state, where the major portion of the fluctuations in the flow are synchronized at the forcing frequency. The goal of this experimental study is to apply closed-loop control in order to provoke the lock-on state, using information from the flow itself. We aim to determine the range of frequencies for which the closed-loop control can establish the lock-on, and what mechanisms are contributing to the selection of a feedback frequency. In order to expand the solution space for optimal closed-loop control laws, we use the genetic programming control (CPC) framework. The best closed-loop control laws obtained by CPC are analysed along with the associated physical mechanisms in the mixing layer flow. The resulting closed-loop control significantly outperforms open-loop forcing in terms of robustness to changes in the free-stream velocities. In addition, the selection of feedback frequencies is not locked to the most amplified local mode, but rather a range of frequencies around it.
Twort, Victoria G. ; Dennis, Alice B. ; Park, Duckchul ; Lomas, Kathryn F. ; Newcomb, Richard D. ; Buckley, Thomas R.
Animal reproductive proteins, especially those in the seminal fluid, have been shown to have higher levels of divergence than non-reproductive proteins and are often evolving adaptively. Seminal fluid proteins have been implicated in the formation of reproductive barriers between diverging lineages, and hence represent interesting candidates underlying speciation. RNA-seq was used to generate the first male reproductive transcriptome for the New Zealand tree weta species Hemideina thoracica and H. crassidens. We identified 865 putative reproductive associated proteins across both species, encompassing a diverse range of functional classes. Candidate gene sequencing of nine genes across three Hemideina, and two Deinacrida species suggests that H. thoracica has the highest levels of intra-specific genetic diversity. Non-monophyly was observed in the majority of sequenced genes indicating that either gene flow may be occurring between the species, or that reciprocal monophyly at these loci has yet to be attained. Evidence for positive selection was found for one lectin-related reproductive protein, with an overall omega of 7.65 and one site in particular being under strong positive selection. This candidate gene represents the first step in the identification of proteins underlying the evolutionary basis of weta reproduction and speciation.
Moser, Othmar ; Mueller, Alexander ; Tschakert, Gerhard ; Koehler, Gerd ; Lawrence, Jimmy B. ; Groeschl, Werner ; Pieber, Thomas R. ; Bracken, Richard M. ; Hofmann, Peter
Toy, Virginia Gail ; Sutherland, Rupert ; Townend, John ; Allen, Michael J. ; Becroft, Leeza ; Boles, Austin ; Boulton, Carolyn ; Carpenter, Brett ; Cooper, Alan ; Cox, Simon C. ; Daube, Christopher ; Faulkner, D. R. ; Halfpenny, Angela ; Kato, Naoki ; Keys, Stephen ; Kirilova, Martina ; Kometani, Yusuke ; Little, Timothy ; Mariani, Elisabetta ; Melosh, Benjamin ; Menzies, Catriona D. ; Morales, Luiz ; Morgan, Chance ; Mori, Hiroshi ; Niemeijer, Andre ; Norris, Richard ; Prior, David ; Sauer, Katrina ; Schleicher, Anja Maria ; Shigematsu, Norio ; Teagle, Damon A. H. ; Tobin, Harold ; Valdez, Robert ; Williams, Jack ; Yeo, Samantha ; Baratin, Laura-May ; Barth, Nicolas ; Benson, Adrian ; Boese, Carolin ; Célérier, Bernard ; Chamberlain, Calum J. ; Conze, Ronald ; Coussens, Jamie ; Craw, Lisa ; Doan, Mai-Linh ; Eccles, Jennifer ; Grieve, Jason ; Grochowski, Julia ; Gulley, Anton ; Howarth, Jamie ; Jacobs, Katrina ; Janku-Capova, Lucie ; Jeppson, Tamara ; Langridge, Robert ; Mallyon, Deirdre ; Marx, Ray ; Massiot, Cécile ; Mathewson, Loren ; Moore, Josephine ; Nishikawa, Osamu ; Pooley, Brent ; Pyne, Alex ; Savage, Martha K. ; Schmitt, Doug ; Taylor-Offord, Sam ; Upton, Phaedra ; Weaver, Konrad C. ; Wiersberg, Thomas ; Zimmer, Martin
During the second phase of the Alpine Fault, Deep Fault Drilling Project (DFDP) in the Whataroa River, South Westland, New Zealand, bedrock was encountered in the DFDP-2B borehole from 238.5–893.2 m Measured Depth (MD). Continuous sampling and meso- to microscale characterisation of whole rock cuttings established that, in sequence, the borehole sampled amphibolite facies, Torlesse Composite Terrane-derived schists, protomylonites and mylonites, terminating 200–400 m above an Alpine Fault Principal Slip Zone (PSZ) with a maximum dip of 62°. The most diagnostic structural features of increasing PSZ proximity were the occurrence of shear bands and reduction in mean quartz grain sizes. A change in composition to greater mica:quartz + feldspar, most markedly below c. 700 m MD, is inferred to result from either heterogeneous sampling or a change in lithology related to alteration. Major oxide variations suggest the fault-proximal Alpine Fault alteration zone, as previously defined in DFDP-1 core, was not sampled.
Volcanic activities triggered or inhibited by resonance of volcanic edifices to large earthquakes
(2018)
Namiki, Atsuko ; Rivalta, Eleonora ; Woith, Heiko ; Willey, Timothy ; Parolai, Stefano ; Walter, Thomas R.
The existence of a causal link between large earthquakes and volcanic unrest is widely accepted. Recent observations have also revealed counterintuitive negative responses of volcanoes to large earthquakes, including decreased gas emissions and subsidence in volcanic areas. In order to explore the mechanisms that could simultaneously explain both the positive and negative responses of volcanic activity to earthquakes, we here focus on the role played by topography. In the laboratory, we shook a volcanic edifice analogue, made of gel, previously injected with a buoyant fluid. We find that shaking triggers rapid migration of the buoyant fluid upward, downward, or laterally, depending on the fluid’s buoyancy and storage depth; bubbly fluids stored at shallow depth ascend, while low-buoyancy fluids descend or migrate laterally. The migration of fluids induced by shaking is two orders of magnitude faster than without shaking. Downward or lateral fluid migration may decrease volcanic gas emissions and cause subsidence as a negative response, while upward migration is consistent both with an increase in volcanic activity and immediate unrest (deformation and seismicity) after large earthquakes. The fluid migration is more efficient when the oscillation frequency is close to the resonance frequency of the edifice. The resonance frequency for a 30-km-wide volcanic mountain range, such as those where subsidence was observed, is ∼0.07 Hz. Only large earthquakes are able to cause oscillation at such low frequencies.
Fujihara, Kenji M. ; Zhang, Bonnie Z. ; Jackson, Thomas D. ; Ogunkola, Moses ; Nijagal, Brunda ; Milne, Julia V. ; Sallman, David A. ; Ang, Ching-Seng ; Nikolic, Iva ; Kearney, Conor J. ; Hogg, Simon J. ; Cabalag, Carlos S. ; Sutton, Vivien R. ; Watt, Sally ; Fujihara, Asuka T. ; Trapani, Joseph A. ; Simpson, Kaylene J. ; Stojanovski, Diana ; Leimkühler, Silke ; Haupt, Sue ; Phillips, Wayne A. ; Clemons, Nicholas J.
The mechanism of action of eprenetapopt (APR-246, PRIMA-1MET) as an anticancer agent remains unresolved, al-though the clinical development of eprenetapopt focuses on its reported mechanism of action as a mutant-p53 reactivator. Using unbiased approaches, this study demonstrates that eprenetapopt depletes cellular antioxidant glutathione levels by increasing its turnover, triggering a nonapoptotic, iron-dependent form of cell death known as ferroptosis. Deficiency in genes responsible for supplying cancer cells with the substrates for de novo glutathione synthesis (SLC7A11, SHMT2, and MTHFD1L), as well as the enzymes required to synthesize glutathione (GCLC and GCLM), augments the activity of eprenetapopt. Eprenetapopt also inhibits iron-sulfur cluster biogenesis by limit-ing the cysteine desulfurase activity of NFS1, which potentiates ferroptosis and may restrict cellular proliferation. The combination of eprenetapopt with dietary serine and glycine restriction synergizes to inhibit esophageal xenograft tumor growth. These findings reframe the canonical view of eprenetapopt from a mutant-p53 reactivator to a ferroptosis inducer.
Devarapalli, Shanti Priya ; Jagirdar, Rukmini ; Prasad, Manjunath R. ; Thomas, Vineet S. ; Ahmed, Syed Aslam ; Gralapally, Raghavendra ; Das, Jesmin Permala Lohy
A comprehensive photometric and spectroscopic analysis of the variable TYC 5532-1333-1 (TYC) along with an investigation of its orbital period variation is presented for the first time. The B- and V-band photometric study indicates that TYC is an intermediate contact binary with degree of contact and mass ratio of 34 per cent and similar to 0.24, respectively. The derived equivalent widths from the spectroscopic study of H alpha and Na-I lines reveal phase-dependent variation and mutual correlation. Using the available times of minimum light, an investigation of orbital period variation shows a long-term decrease at a rate of 3.98 x 10(-6) d yr(-1). Expected causes for such decline in the orbital period could be angular momentum loss and a quasi-sinusoidal variation due to light-time effect probably caused by a third-body companion. The minimum mass of the third body (M-3) was derived to be 0.65 M-circle dot. Our presented study is an attempt to evaluate and understand the evolutionary state of above-mentioned neglected contact binary.
Childhood obesity is one of the most serious public health challenges of the twenty-first century. While small-scale experiments change behaviors among adults in the short run, we know little about the effectiveness of large-scale policies or the longer-run impacts. To nudge primary school children into a long-term habit of exercising, the German state of Saxony distributed sports club membership vouchers among all 33,000 third graders in 2009. In 2018, we carried out a register-based survey to evaluate the policy. Even after a decade, awareness of the voucher program was significantly higher in the treatment group. We also find that youth received and redeemed the vouchers. However, we do not find significant short- or long-term effects on sports club membership, physical activity, overweightness, or motor skills. Apparently, membership vouchers for children are not a strong enough policy tool to overcome barriers to exercise regularly.
SpiderMAEn
(2019)
Herold, Heike M. ; Aigner, Tamara Bernadette ; Grill, Carolin E. ; Krüger, Stefanie ; Taubert, Andreas ; Scheibel, Thomas R.
A growing energy demand requires new and preferably renewable energy sources. The infinite availability of solar radiation makes its conversion into storable and transportable energy forms attractive for research as well as for the industry. One promising example of a transportable fuel is hydrogen (H-2), making research into eco-friendly hydrogen production meaningful. Here, a hybrid system was developed using newly designed recombinant spider silk protein variants as a template for mineralization with inorganic titanium dioxide and gold. These bioinspired organic/inorganic hybrid materials allow for hydrogen production upon light irradiation. To begin with, recombinant spider silk proteins bearing titanium dioxide and gold-binding moieties were created and processed into structured films. These films were modified with gold and titanium dioxide in order to produce a photocatalyst. Subsequent testing revealed hydrogen production as a result of light-induced hydrolysis of water. Therefore, the novel setup presented here provides access to a new principle of generating advanced hybrid materials for sustainable hydrogen production and depicts a promising platform for further studies on photocatalytic production of hydrogen, the most promising future fuel.
Gamba, Cristina ; Jones, Eppie R. ; Teasdale, Matthew D. ; McLaughlin, Russell L. ; González-Fortes, Gloria M. ; Mattiangeli, Valeria ; Domboroczki, Laszlo ; Kovari, Ivett ; Pap, Ildiko ; Anders, Alexandra ; Whittle, Alasdair ; Dani, Janos ; Raczky, Pal ; Higham, Thomas F. G. ; Hofreiter, Michael ; Bradley, Daniel G. ; Pinhasi, Ron
The Great Hungarian Plain was a crossroads of cultural transformations that have shaped European prehistory. Here we analyse a 5,000-year transect of human genomes, sampled from petrous bones giving consistently excellent endogenous DNA yields, from 13 Hungarian Neolithic, Copper, Bronze and Iron Age burials including two to high (similar to 22x) and seven to similar to 1x coverage, to investigate the impact of these on Europe's genetic landscape. These data suggest genomic shifts with the advent of the Neolithic, Bronze and Iron Ages, with interleaved periods of genome stability. The earliest Neolithic context genome shows a European hunter-gatherer genetic signature and a restricted ancestral population size, suggesting direct contact between cultures after the arrival of the first farmers into Europe. The latest, Iron Age, sample reveals an eastern genomic influence concordant with introduced Steppe burial rites. We observe transition towards lighter pigmentation and surprisingly, no Neolithic presence of lactase persistence.
Mell, Thomas ; Heekeren, Hauke R. ; Marschner, Alexander ; Wartenburger, Isabell ; Villringer, Arno ; Reischies, Friedel M.
The flexible learning of stimulus-reward associations when required by situational context is essential for everyday behavior. Older adults experience a progressive decline in several cognitive functions and show deficiencies in neuropsychological tasks requiring flexible adaptation to external feedback, which could be related to impairments in reward association learning. To study the effect of aging on stimulus-reward association learning 20 young and 20 older adults performed a probabilistic object reversal task (pORT) along with a battery of tests assessing executive functions and general intellectual abilities. The pORT requires learning and reversing associations between actions and their outcomes. Older participants collected fewer points, needed more trials to reach the learning criterion, and completed less blocks successfully compared to young adults. This difference remained statistically significant after correcting for the age effect of other tests assessing executive functions. This suggests that there is an age-related difference in reward association learning as measured using the pORT, which is not closely related to other executive functions with respect to the age effect. In human aging, structural alterations of reward detecting structures and functional changes of the dopaminergic as well as the serotonergic system might contribute to the deficit in reward association learning observed in this study. (C) 2004 Elsevier Ltd. All rights reserved
Marschner, Alexander ; Mell, Thomas ; Wartenburger, Isabell ; Villringer, Arno ; Reischies, Friedel M. ; Heekeren, Hauke R.
Heekeren, Hauke R. ; Wartenburger, Isabell ; Marschner, Alexander ; Mell, Thomas ; Villringer, Arno ; Reischies, Friedel M.
Mell, Thomas ; Wartenburger, Isabell ; Marschner, Alexander ; Villringer, Arno ; Reischies, Friedel M. ; Heekeren, Hauke R.
Normal aging is associated with a decline in different cognitive domains and local structural atrophy as well as decreases in dopamine concentration and receptor density. To date, it is largely unknown how these reductions in dopaminergic neurotransmission affect human brain regions responsible for reward-based decision making in older adults. Using a learning criterion in a probabilistic object reversal task, we found a learning stage by age interaction in the dorsolateral prefrontal cortex (dIPFC) during decision making. While young adults recruited the dlPFC in an early stage of learning reward associations, older adults recruited the dlPFC when reward associations had already been learned. Furthermore, we found a reduced change in ventral striatal BOLD signal in older as compared to younger adults in response to high probability rewards. Our data are in line with behavioral evidence that older adults show altered stimulus-reward learning and support the view of an altered fronto-striatal interaction during reward-based decision making in old age, which contributes to prolonged learning of reward associations.
Starting in 2009, the German state of Saxony distributed sports club membership vouchers among all 33,000 third graders in the state. The policy’s objective was to encourage them to develop a long-term habit of exercising. In 2018, we carried out a large register-based survey among several cohorts in Saxony and two neighboring states. Our difference-in-differences estimations show that, even after a decade, awareness of the voucher program was significantly higher in the treatment group. We also find that youth received and redeemed the vouchers. However, we do not find significant short- or long-term effects on sports club membership, physical activity, overweightness, or motor skills.
Breuer, Lutz ; Willems, Patrick ; Bormann, Helge ; Bronstert, Axel ; Croke, Barry ; Frede, Hans Georg ; Gräff, Thomas ; Hubrechts, Lode ; Kite, Geoffrey ; Lanini, Jordan ; Leavesley, George ; Lettenmaier, Dennis P. ; Lindstroem, Goeran ; Seibert, Jan ; Sivapalan, Mayuran ; Viney, Neil R.
This paper introduces the project on 'Assessing the impact of land use change on hydrology by ensemble modeling (LUCHEM)' that aims at investigating the envelope of predictions on changes in hydrological fluxes due to land use change. As part of a series of four papers, this paper outlines the motivation and setup of LUCHEM, and presents a model intercomparison for the present-day simulation results. Such an intercomparison provides a valuable basis to investigate the effects of different model structures on model predictions and paves the ground for the analysis of the performance of multi-model ensembles and the reliability of the scenario predictions in companion papers. in this study, we applied a set of 10 lumped, semi-lumped and fully distributed hydrological models that have been previously used in land use change studies to the low mountainous Dill catchment. Germany. Substantial differences in model performance were observed with Nash-Sutcliffe efficiencies ranging from 0.53 to 0.92. Differences in model performance were attributed to (1) model input data, (2) model calibration and (3) the physical basis of the models. The models were applied with two sets of input data: an original and a homogenized data set. This homogenization of precipitation, temperature and leaf area index was performed to reduce the variation between the models. Homogenization improved the comparability of model simulations and resulted in a reduced average bias, although some variation in model data input remained. The effect of the physical differences between models on the long-term water balance was mainly attributed to differences in how models represent evapotranspiration. Semi-lumped and lumped conceptual models slightly outperformed the fully distributed and physically based models. This was attributed to the automatic model calibration typically used for this type of models. Overall, however, we conclude that there was no superior model if several measures of model performance are considered and that all models are suitable to participate in further multi-model ensemble set-ups and land use change scenario investigations.
Reference values and validation of the 1-minute sit-to-stand test in healthy 5-16-year-old youth
(2021)
Haile, Sarah R. ; Fühner, Thea Heidi ; Granacher, Urs ; Stocker, Julien ; Radtke, Thomas ; Kriemler, Susi
Objectives:
It is essential to have simple, reliable and valid tests to measure children's functional capacity in schools or medical practice. The 1-minute sit-to-stand (STS) test is a quick fitness test requiring little equipment or space that is increasingly used in both healthy populations and those with chronic disease. We aimed to provide age-specific and sex-specific reference values of STS test in healthy children and adolescents and to evaluate its short-term reliability and construct validity.
Design setting and participants:
Cross-sectional convenience sample from six public schools and one science fair in central Europe. Overall, 587 healthy participants aged 5-16 years were recruited and divided into age groups of 3 years each.
Outcomes:
1-minute STS. To evaluate short-term reliability, some children performed the STS test twice. To evaluate construct validity, some children also performed a standing long jump (SLJ) and a maximal incremental exercise test.
Results:
Data from 547 youth aged 5-16 years were finally included in the analyses. The median number of repetitions in 1 min in males (females) ranged from 55 [95% CI: 38 to 72] (53 [95% CI: 35 to 76]) in 14-16-year olds to 59 [95% CI: 41 to 77] (60 [95% CI: 38 to 77]) in 8-10-year olds. Children who repeated STS showed a learning effect of on average 4.8 repetitions more than the first test (95% limits of agreement: -6.7 to 16.4). Moderate correlations were observed between the STS and the SLJ (r=0.48) tests and the maximal exercise test (r=0.43).
Conclusions:
The reported STS reference values can be used to interpret STS test performance in children and adolescents. The STS appears to have good test- retest reliability, but a learning effect of about 10%. The association of STS with other measures of physical fitness should be further explored in a larger study and technical standards for its conduct are needed.
The proportion of elderly people in societies of western industrialized countries is continuously rising. Biologic aging induces deficits in balance and muscle strength/power in old age, which is responsible for an increased prevalence of falls. Therefore, nationwide and easy-to-administer fall prevention programs have to be developed in order to contribute to the autonomy and quality of life in old age and to help reduce the financial burden on the public health care system due to the treatment of fall-related injuries. This narrative (qualitative) literature review deals with a) the reasons for an increased prevalence of falls in old age, b) important clinical tests for fall-risk assessment, and c) evidence-based intervention/training programs for fall prevention in old age. The findings of this literature review are based on a cost-free practice guide that is available to the public (via the internet) and that was created by an expert panel (i.e., geriatricians, exercise scientists, physiotherapists, geriatric therapists). The present review provides the scientific foundation of the practice guide.
Breuer, Lutz ; Bormann, Helge ; Bronstert, Axel ; Croke, Barry F. W. ; Frede, Hans-Georg ; Gräff, Thomas ; Hubrechts, Lode ; Kite, Geoffrey ; Lanini, Jordan ; Leavesley, George ; Lettenmaier, Dennis P. ; Lindstroem, Goeran ; Seibert, Jan ; Sivapalan, Mayuran ; Viney, Neil R. ; Willems, Patrick
An ensemble of 10 hydrological models was applied to the same set of land use change scenarios. There was general agreement about the direction of changes in the mean annual discharge and 90% discharge percentile predicted by the ensemble members, although a considerable range in the magnitude of predictions for the scenarios and catchments under consideration was obvious. Differences in the magnitude of the increase were attributed to the different mean annual actual evapotranspiration rates for each land use type. The ensemble of model runs was further analyzed with deterministic and probabilistic ensemble methods. The deterministic ensemble method based on a trimmed mean resulted in a single somewhat more reliable scenario prediction. The probabilistic reliability ensemble averaging (REA) method allowed a quantification of the model structure uncertainty in the scenario predictions. It was concluded that the use of a model ensemble has greatly increased our confidence in the reliability of the model predictions.
Zheng, Ju-Sheng ; Luan, Jian'an ; Sofianopoulou, Eleni ; Imamura, Fumiaki ; Stewart, Isobel D. ; Day, Felix R. ; Pietzner, Maik ; Wheeler, Eleanor ; Lotta, Luca A. ; Gundersen, Thomas E. ; Amiano, Pilar ; Ardanaz, Eva ; Chirlaque, Maria-Dolores ; Fagherazzi, Guy ; Franks, Paul W. ; Kaaks, Rudolf ; Laouali, Nasser ; Mancini, Francesca Romana ; Nilsson, Peter M. ; Onland-Moret, N. Charlotte ; Olsen, Anja ; Overvad, Kim ; Panico, Salvatore ; Palli, Domenico ; Ricceri, Fulvio ; Rolandsson, Olov ; Spijkerman, Annemieke M. W. ; Sanchez, Maria-Jose ; Schulze, Matthias Bernd ; Sala, Nuria ; Sieri, Sabina ; Tjonneland, Anne ; Tumino, Rosario ; van der Schouw, Yvonne T. ; Weiderpass, Elisabete ; Riboli, Elio ; Danesh, John ; Butterworth, Adam S. ; Sharp, Stephen J. ; Langenberg, Claudia ; Forouhi, Nita G. ; Wareham, Nicholas J.
OBJECTIVE: Higher plasma vitamin C levels are associated with lower type 2 diabetes risk, but whether this association is causal is uncertain. To investigate this, we studied the association of genetically predicted plasma vitamin C with type 2 diabetes.
RESEARCH DESIGN AND METHODS: We conducted genome-wide association studies of plasma vitamin C among 52,018 individuals of European ancestry to discover novel genetic variants. We performed Mendelian randomization analyses to estimate the association of genetically predicted differences in plasma vitamin C with type 2 diabetes in up to 80,983 case participants and 842,909 noncase participants. We compared this estimate with the observational association between plasma vitamin C and incident type 2 diabetes, including 8,133 case participants and 11,073 noncase participants.
RESULTS: We identified 11 genomic regions associated with plasma vitamin C (P < 5 x 10(-8)), with the strongest signal at SLC23A1, and 10 novel genetic loci including SLC23A3, CHPT1, BCAS3, SNRPF, RER1, MAF, GSTA5, RGS14, AKT1, and FADS1. Plasma vitamin C was inversely associated with type 2 diabetes (hazard ratio per SD 0.88; 95% CI 0.82, 0.94), but there was no association between genetically predicted plasma vitamin C (excluding FADS1 variant due to its apparent pleiotropic effect) and type 2 diabetes (1.03; 95% CI 0.96, 1.10).
CONCLUSIONS: These findings indicate discordance between biochemically measured and genetically predicted plasma vitamin C levels in the association with type 2 diabetes among European populations. The null Mendelian randomization findings provide no strong evidence to suggest the use of vitamin C supplementation for type 2 diabetes prevention.
Landfester, Katharina ; Montenegro, Rivelino V. D. ; Scherf, Ullrich ; Günter, R. ; Asawapirom, Udom ; Patil, S. ; Neher, Dieter ; Kietzke, Thomas
Eibl, Eva P. S. ; Hainzl, Sebastian ; Vesely, Nele I. K. ; Walter, Thomas R. ; Jousset, Philippe ; Hersir, Gylfi Pall ; Dahm, Torsten
Geysers are hot springs whose frequency of water eruptions remain poorly understood. We set up a local broadband seismic network for 1 year at Strokkur geyser, Iceland, and developed an unprecedented catalog of 73,466 eruptions. We detected 50,135 single eruptions but find that the geyser is also characterized by sets of up to six eruptions in quick succession. The number of single to sextuple eruptions exponentially decreased, while the mean waiting time after an eruption linearly increased (3.7 to 16.4 min). While secondary eruptions within double to sextuple eruptions have a smaller mean seismic amplitude, the amplitude of the first eruption is comparable for all eruption types. We statistically model the eruption frequency assuming discharges proportional to the eruption multiplicity and a constant probability for subsequent events within a multituple eruption. The waiting time after an eruption is predictable but not the type or amplitude of the next one. <br /> Plain Language Summary Geysers are springs that often erupt in hot water fountains. They erupt more often than volcanoes but are quite similar. Nevertheless, it is poorly understood how often volcanoes and also geysers erupt. We created a list of 73,466 eruption times of Strokkur geyser, Iceland, from 1 year of seismic data. The geyser erupted one to six times in quick succession. We found 50,135 single eruptions but only 1 sextuple eruption, while the mean waiting time increased from 3.7 min after single eruptions to 16.4 min after sextuple eruptions. Mean amplitudes of each eruption type were higher for single eruptions, but all first eruptions in a succession were similar in height. Assuming a constant heat inflow at depth, we can predict the waiting time after an eruption but not the type or amplitude of the next one.
Dahm, Torsten ; Becker, Dirk ; Bischoff, Monika ; Cesca, Simone ; Dost, B. ; Fritschen, R. ; Hainzl, Sebastian ; Klose, C. D. ; Kuhn, D. ; Lasocki, S. ; Meier, Thomas ; Ohrnberger, Matthias ; Rivalta, Eleonora ; Wegler, Ulrich ; Husen, Stephan
Various techniques are utilized by the seismological community, extractive industries, energy and geoengineering companies to identify earthquake nucleation processes in close proximity to engineering operation points. These operations may comprise fluid extraction or injections, artificial water reservoir impoundments, open pit and deep mining, deep geothermal power generations or carbon sequestration. In this letter to the editor, we outline several lines of investigation that we suggest to follow to address the discrimination problem between natural seismicity and seismic events induced or triggered by geoengineering activities. These suggestions have been developed by a group of experts during several meetings and workshops, and we feel that their publication as a summary report is helpful for the geoscientific community. Specific investigation procedures and discrimination approaches, on which our recommendations are based, are also published in this Special Issue (SI) of Journal of Seismology.
Eibl, Eva P. S. ; Müller, Daniel ; Walter, Thomas R. ; Allahbakhshi, Masoud ; Jousset, Philippe ; Hersir, Gylfi Páll ; Dahm, Torsten
The eruption frequency of geysers can be studied easily on the surface. However, details of the internal structure including possible water and gas filled chambers feeding eruptions and the driving mechanisms often remain elusive. We used a multidisciplinary network of seismometers, video cameras, water pressure sensors and one tiltmeter to study the eruptive cycle, internal structure, and mechanisms driving the eruptive cycle of Strokkur geyser in June 2018. An eruptive cycle at Strokkur always consists of four phases: (1) Eruption, (2) post-eruptive conduit refilling, (3) gas filling of the bubble trap, and (4) regular bubble collapse at shallow depth in the conduit. For a typical single eruption 19 +/- 4 bubble collapses occur in Phase 3 and 8 +/- 2 collapses in Phase 4 at a mean spacing of 1.52 +/- 0.29 and 24.5 +/- 5.9 s, respectively. These collapses release latent heat to the fluid in the bubble trap (Phase 3) and later to the fluid in the conduit (Phase 4). The latter eventually reaches thermodynamic conditions for an eruption. Single to sextuple eruptions have similar spacings between bubble collapses and are likely fed from the same bubble trap at 23.7 +/- 4.4 m depth, 13-23 m west of the conduit. However, the duration of the eruption and recharging phase linearly increases likely due to a larger water, gas and heat loss from the system. Our tremor data provides documented evidence for a bubble trap beneath a pool geyser.
Lacroix, André ; Mühlbauer, Thomas ; Gschwind, Y. J. ; Pfenninger, B. ; Kressig, R. W. ; Brügger, O. ; Granacher, Urs
Viney, Neil R. ; Bormann, Helge ; Breuer, Lutz ; Bronstert, Axel ; Croke, Barry F. W. ; Frede, Hans-Georg ; Gräff, Thomas ; Hubrechts, Lode ; Huisman, Johan A. ; Jakeman, Anthony J. ; Kite, Geoffrey W. ; Lanini, Jordan ; Leavesley, George ; Lettenmaier, Dennis P. ; Lindstroem, Goeran ; Seibert, Jan ; Sivapalan, Murugesu ; Willems, Patrick
This paper reports on a project to compare predictions from a range of catchment models applied to a mesoscale river basin in central Germany and to assess various ensemble predictions of catchment streamflow. The models encompass a large range in inherent complexity and input requirements. In approximate order of decreasing complexity, they are DHSVM, MIKE-SHE, TOPLATS, WASIM-ETH, SWAT, PRMS, SLURP, HBV, LASCAM and IHACRES. The models are calibrated twice using different sets of input data. The two predictions from each model are then combined by simple averaging to produce a single-model ensemble. The 10 resulting single-model ensembles are combined in various ways to produce multi-model ensemble predictions. Both the single-model ensembles and the multi-model ensembles are shown to give predictions that are generally superior to those of their respective constituent models, both during a 7-year calibration period and a 9- year validation period. This occurs despite a considerable disparity in performance of the individual models. Even the weakest of models is shown to contribute useful information to the ensembles they are part of. The best model combination methods are a trimmed mean (constructed using the central four or six predictions each day) and a weighted mean ensemble (with weights calculated from calibration performance) that places relatively large weights on the better performing models. Conditional ensembles. in which separate model weights are used in different system states (e.g. summer and winter, high and low flows) generally yield little improvement over the weighted mean ensemble. However a conditional ensemble that discriminates between rising and receding flows shows moderate improvement. An analysis of ensemble predictions shows that the best ensembles are not necessarily those containing the best individual models. Conversely, it appears that some models that predict well individually do not necessarily combine well with other models in multi-model ensembles. The reasons behind these observations may relate to the effects of the weighting schemes, non- stationarity of the climate series and possible cross-correlations between models.
Srikhirin, T. ; Cimrova, V. ; Schiewe, B. ; Tzolov, M. ; Hagen, R. ; Kostromine, S. ; Bieringer, Thomas ; Neher, Dieter
Photoaddressable alignment layers for fluorescent polymers in polarized electroluminescence devices
(2002)
Sianova, D. ; Zen, Achmad ; Nothofer, Heinz-Georg ; Asawapirom, Udom ; Scherf, Ullrich ; Hagen, R. ; Bieringer, Thomas ; Kostromine, S. ; Neher, Dieter
Via the reaction of diexo-oxanorbornanedicarboxylic anhydride with toluene, the diexo-aroylcarboxylic acid (3a) was prepared, which exists partly as the tautomeric lactol (3b). With bifunctional reagents, 3a yields fused heterocycles containing three-six rings. Thus, alkylenediamines result in imidazole- and 1,3-diazepine-fused oxygen- bridged isoindolones (6a,b), alkanolamines form the oxazole- and 1,3-oxazine-fused oxanorbornene derivatives (7a-c), and o-phenylenediamine undergoes cyclization to furnish the condensed benzimidazole (8). The reaction of 3a with diexo- aminonorbornanecarbohydrazide yields a pyrimidopyridazine containing six condensed rings (9). In a similar reaction with diendo-aminonorbornenecarbohydrazide, cyclopentadiene cleaves off to give the tricyclic retro Diels-Alder product (10). The structures, and particulary the configurations at the oxanorbornane ring systems and the position of the aryl substituent, were established by means of 1D- and 2D-NMR spectroscopy and, for 3b and 7c, also by X-Ray measurements
Alqahtani, Obaid ; Babics, Maxime ; Gorenflot, Julien ; Savikhin, Victoria ; Ferron, Thomas ; Balawi, Ahmed H. ; Paulke, Andreas ; Kan, Zhipeng ; Pope, Michael ; Clulow, Andrew J. ; Wolf, Jannic ; Burn, Paul L. ; Gentle, Ian R. ; Neher, Dieter ; Toney, Michael F. ; Laquai, Frederic ; Beaujuge, Pierre M. ; Collins, Brian A.
The interplay between nanomorphology and efficiency of polymer-fullerene bulk-heterojunction (BHJ) solar cells has been the subject of intense research, but the generality of these concepts for small-molecule (SM) BHJs remains unclear. Here, the relation between performance; charge generation, recombination, and extraction dynamics; and nanomorphology achievable with two SM donors benzo[1,2-b:4,5-b]dithiophene-pyrido[3,4-b]-pyrazine BDT(PPTh2)(2), namely SM1 and SM2, differing by their side-chains, are examined as a function of solution additive composition. The results show that the additive 1,8-diiodooctane acts as a plasticizer in the blends, increases domain size, and promotes ordering/crystallinity. Surprisingly, the system with high domain purity (SM1) exhibits both poor exciton harvesting and severe charge trapping, alleviated only slightly with increased crystallinity. In contrast, the system consisting of mixed domains and lower crystallinity (SM2) shows both excellent exciton harvesting and low charge recombination losses. Importantly, the onset of large, pure crystallites in the latter (SM2) system reduces efficiency, pointing to possible differences in the ideal morphologies for SM-based BHJ solar cells compared with polymer-fullerene devices. In polymer-based systems, tie chains between pure polymer crystals establish a continuous charge transport network, whereas SM-based active layers may in some cases require mixed domains that enable both aggregation and charge percolation to the electrodes.
Andreev, Andrei ; Raschke, Elena ; Biskaborn, Boris ; Vyse, Stuart Andrew ; Courtin, Jérémy ; Böhmer, Thomas ; Stoof-Leichsenring, Kathleen R. ; Kruse, Stefan ; Pestryakova, Luidmila Agafyevna ; Herzschuh, Ulrike
This paper presents two new pollen records and quantitative climate reconstructions from northern Chukotka documenting environmental changes over the last 27.9 ka. Open tundra- and steppe-like habitats dominated between 27.9 and 18.7 cal. ka BP. Betula and Alnus shrubs might have grown in sheltered microhabitats but disappeared after 18.7 cal. ka BP. Although the climate was rather harsh, local herb-dominated communities supported herbivores as is evident by the presence of coprophilous spores in the sediments. The increase in Salix and Cyperaceae similar to 16.1 cal. ka BP suggests climate amelioration. Shrub Betula appeared similar to 15.9 cal. ka BP, and became dominant after similar to 15.52 cal. ka BP, whilst typical steppe communities drastically reduced. Very high presence of Botryococcus in the Lateglacial sediments reflects widespread shallow habitats, probably due to lake level increase. Shrub Alnus became common after similar to 13 cal. ka BP reflecting further climate amelioration. Simultaneously, herb communities gradually decreased in the vegetation reaching a minimum similar to 11.8 cal. ka BP. A gradual decrease of algae remains suggests a reduction of shallow-water habitats. Shrubby and graminoid tundra was dominant similar to 11.8-11.1 cal. ka BP, later Salix stands significantly decreased. The forest-tundra ecotone established in the Early Holocene, shortly after 11.1 cal. ka BP. Low contents of green algae in the Early Holocene sediments likely reflect deeper aquatic conditions. The most favourable climate conditions were between similar to 10.6 and 7 cal. ka BP. Vegetation became similar to the modern after similar to 7 cal. ka BP but Pinus pumila came to the Ilirney area at about 1.2 cal. ka BP. It is important to emphasize that the study area provided refugia for Betula and Alnus during MIS 2. It is also notable that our records do not reflect evidence of Younger Dryas cooling, which is inconsistent with some regional environmental records but in good accordance with some others.
Parallel A-helices are among the simplest repetitive structural elements in proteins. The folding behavior of A- helix proteins has been studied intensively, also to gain insight on the formation of amyloid fibrils, which share the parallel beta-helix as a central structural motif. An important system for investigating beta-helix folding is the tailspike protein from the Salmonella bacteriophage P22. The central domain of this protein is a right-handed parallel beta-helix with 13 windings. Extensive mutational analyses of the P22 tailspike protein have revealed two main phenotypes: temperature-sensitive-folding (tsf) mutations that reduce the folding efficiency at elevated temperatures, and global suppressor (su) mutations that increase the tailspike folding efficiency. A central question is whether these phenotypes can be understood from changes in the protein stability induced by the mutations. Experimental determination of the protein stability is complicated by the nearly irreversible trimerization of the folded tailspike protein. Here, we present calculations of stability changes with the program FoldX, focusing on a recently published extensive data set of 145 singe-residue alanine mutants. We find that the calculated stability changes are correlated with the experimentally measured in vivo folding efficiencies. In addition, we determine the free-energy landscape of the P22 tailspike protein in a nucleation-propagation model to explore the folding mechanism of this protein, and obtain a processive folding route on which the protein nucleates in the N-terminal region of the helix.
Kaa, Johannes M. ; Sternemann, Christian ; Appel, Karen ; Cerantola, Valerio ; Preston, Thomas R. ; Albers, Christian ; Elbers, Mirko ; Libon, Lelia ; Makita, Mikako ; Pelka, Alexander ; Petitgirard, Sylvain ; Plückthun, Christian ; Roddatis, Vladimir ; Sahle, Christoph J. ; Spiekermann, Georg ; Schmidt, Christian ; Schreiber, Anja ; Sakrowski, Robin ; Tolan, Metin ; Wilke, Max ; Zastrau, Ulf ; Konopkova, Zuzana
The determination of the spin state of iron-bearing compounds at high pressure and temperature is crucial for our understanding of chemical and physical properties of the deep Earth. Studies on the relationship between the coordination of iron and its electronic spin structure in iron-bearing oxides, silicates, carbonates, iron alloys, and other minerals found in the Earth's mantle and core are scarce because of the technical challenges to simultaneously probe the sample at high pressures and temperatures. We used the unique properties of a pulsed and highly brilliant x-ray free electron laser (XFEL) beam at the High Energy Density (HED) instrument of the European XFEL to x-ray heat and probe samples contained in a diamond anvil cell. We heated and probed with the same x-ray pulse train and simultaneously measured x-ray emission and x-ray diffraction of an FeCO3 sample at a pressure of 51 GPa with up to melting temperatures. We collected spin state sensitive Fe K beta(1,3) fluorescence spectra and detected the sample's structural changes via diffraction, observing the inverse volume collapse across the spin transition. During x-ray heating, the carbonate transforms into orthorhombic Fe4C3O12 and iron oxides. Incipient melting was also observed. This approach to collect information about the electronic state and structural changes from samples contained in a diamond anvil cell at melting temperatures and above will considerably improve our understanding of the structure and dynamics of planetary and exoplanetary interiors.
Flóvenz, Ólafur G. ; Wang, Rongjiang ; Hersir, Gylfi Páll ; Dahm, Torsten ; Hainzl, Sebastian ; Vassileva, Magdalena ; Drouin, Vincent ; Heimann, Sebastian ; Isken, Marius Paul ; Gudnason, Egill Á. ; Ágústsson, Kristján ; Ágústsdóttir, Thorbjörg ; Horálek, Josef ; Motagh, Mahdi ; Walter, Thomas R. ; Rivalta, Eleonora ; Jousset, Philippe ; Krawczyk, Charlotte M. ; Milkereit, Claus
Understanding and constraining the source of geodetic deformation in volcanic areas is an important component of hazard assessment. Here, we analyse deformation and seismicity for one year before the March 2021 Fagradalsfjall eruption in Iceland. We generate a high-resolution catalogue of 39,500 earthquakes using optical cable recordings and develop a poroelastic model to describe three pre-eruptional uplift and subsidence cycles at the Svartsengi geothermal field, 8 km west of the eruption site. We find the observed deformation is best explained by cyclic intrusions into a permeable aquifer by a fluid injected at 4 km depth below the geothermal field, with a total volume of 0.11 ± 0.05 km3 and a density of 850 ± 350 kg m–3. We therefore suggest that ingression of magmatic CO2 can explain the geodetic, gravity and seismic data, although some contribution of magma cannot be excluded.
Förstner, Bernd R. ; Tschorn, Mira ; Reinoso-Schiller, Nicolas ; Maričić, Lea Mascarell ; Röcher, Erik ; Kalman, Janos L. ; Stroth, Sanna ; Mayer, Annalina V. ; Schwarz, Kristina ; Kaiser, Anna ; Pfennig, Andrea ; Manook, André ; Ising, Marcus ; Heinig, Ingmar ; Pittig, Andre ; Heinz, Andreas ; Mathiak, Klaus ; Schulze, Thomas G. ; Schneider, Frank ; Kamp-Becker, Inge ; Meyer-Lindenberg, Andreas ; Padberg, Frank ; Banaschewski, Tobias ; Bauer, Michael ; Rupprecht, Rainer ; Wittchen, Hans-Ulrich ; Rapp, Michael A.
This study aimed to build on the relationship of well-established self-report and behavioral assessments to the latent constructs positive (PVS) and negative valence systems (NVS), cognitive systems (CS), and social processes (SP) of the Research Domain Criteria (RDoC) framework in a large transnosological population which cuts across DSM/ICD-10 disorder criteria categories. One thousand four hundred and thirty one participants (42.1% suffering from anxiety/fear-related, 18.2% from depressive, 7.9% from schizophrenia spectrum, 7.5% from bipolar, 3.4% from autism spectrum, 2.2% from other disorders, 18.4% healthy controls, and 0.2% with no diagnosis specified) recruited in studies within the German research network for mental disorders for the Phenotypic, Diagnostic and Clinical Domain Assessment Network Germany (PD-CAN) were examined with a Mini-RDoC-Assessment including behavioral and self-report measures. The respective data was analyzed with confirmatory factor analysis (CFA) to delineate the underlying latent RDoC-structure. A revised four-factor model reflecting the core domains positive and negative valence systems as well as cognitive systems and social processes showed a good fit across this sample and showed significantly better fit compared to a one factor solution. The connections between the domains PVS, NVS and SP could be substantiated, indicating a universal latent structure spanning across known nosological entities. This study is the first to give an impression on the latent structure and intercorrelations between four core Research Domain Criteria in a transnosological sample. We emphasize the possibility of using already existing and well validated self-report and behavioral measurements to capture aspects of the latent structure informed by the RDoC matrix.
Schaffenroth, Veronika ; Casewell, Sarah L. ; Schneider, D. ; Kilkenny, David ; Geier, Stephan ; Heber, Ulrich ; Irrgang, Andreas ; Przybilla, Norbert ; Marsh, Thomas R. ; Littlefair, Stuart P. ; Dhillon, Vik S.
Subdwarf B stars are core-helium-burning stars located on the extreme horizontal branch (EHB). Extensive mass loss on the red giant branch is necessary to form them. It has been proposed that substellar companions could lead to the required mass loss when they are engulfed in the envelope of the red giant star. J08205+0008 was the first example of a hot subdwarf star with a close, substellar companion candidate to be found. Here, we perform an in-depth re-analysis of this important system with much higher quality data allowing additional analysis methods. From the higher resolution spectra obtained with ESO-VLT/XSHOOTER, we derive the chemical abundances of the hot subdwarf as well as its rotational velocity. Using the Gaia parallax and a fit to the spectral energy distribution in the secondary eclipse, tight constraints to the radius of the hot subdwarf are derived. From a long-term photometric campaign, we detected a significant period decrease of -3.2(8) x 10(-12) dd(-1). This can be explained by the non-synchronized hot subdwarf star being spun up by tidal interactions forcing it to become synchronized. From the rate of period decrease we could derive the synchronization time-scale to be 4 Myr, much smaller than the lifetime on EHB. By combining all different methods, we could constrain the hot subdwarf to a mass of 0.39-0.50 M-circle dot and a radius of R-sdB = 0.194 +/- 0.008 R-circle dot, and the companion to 0.061-0.071 M-circle dot with a radius of R-comp = 0.092 +/- 0.005 R-circle dot, below the hydrogen-burning limit. We therefore confirm that the companion is most likely a massive brown dwarf.
Adriaans, Jule ; Griese, Florian ; Auspurg, Katrin ; Bledow, Nona ; Bohmann, Sandra ; Busemeyer, Marius R. ; Delhey, Jan ; Goebel, Jan ; Groh-Samberg, Olaf ; Heckhausen, Jutta ; Hinz, Thomas ; Kroh, Martin ; Lengfeld, Holger ; Lersch, Philipp M. ; Liebig, Stefan ; Richter, David ; Sachweh, Patrick ; Schupp, Jürgen ; Schwerdt, Guido ; Verwiebe, Roland
Im Rahmen eines einjährigen Entwicklungsprozesses wurde das Fragebogenmodul "Einstellungen zu sozialer Ungleichheit" unter der Leitung der Infrastruktureinrichtung SOEP entwickelt und in der 38. Welle der Haupterhebung des Sozio-oekonomischen Panels erstmalig erhoben. Das finale Fragebogenmodul umfasst 43 Items zu den Themenbereichen Soziale Vergleiche, Soziale Mobilität, Sozialstaat und Nicht-materielle Ungleichheit. In der Tradition des SOEP als forschungsbasierte Infrastruktureinrichtung erfolgte die Fragebogenentwicklung in enger Zusammenarbeit mit externen Forschenden aus dem Bereich der Einstellungs- und Ungleichheitsforschung. Neben der etablierten Nutzung des SOEP Innovation Samples (SOEP-IS) für quantitative Pretests neu entwickelter Fragen kam erstmals ein kognitiver Pretest zum Einsatz. Der vorliegende Bericht dokumentiert den Entwicklungsprozess von der Konzeption bis zum finalen Fragebogen.
Herrmann, Matthias L. ; Boden, Cindy ; Maurer, Christoph ; Kentischer, Felix ; Mennig, Eva ; Wagner, Sören ; Conzelmann, Lars O. ; Förstner, Bernd R. ; Rapp, Michael A. ; von Arnim, Christine A. F. ; Denkinger, Michael ; Eschweiler, Gerhard W. ; Thomas, Christine
IntroductionPostoperative delirium (POD) is a common and serious adverse event of surgery in older people. Because of its great impact on patients' safety and quality of life, identification of modifiable risk factors could be useful. Although preoperative medication intake is assumed to be an important modifiable risk factor, the impact of anticholinergic drugs on the occurrence of POD seems underestimated in elective surgery. The aim of this study was to investigate the association between preoperative anticholinergic burden and POD. We hypothesized that a high preoperative anticholinergic burden is an independent, potentially modifiable predisposing and precipitating factor of POD in older people. MethodsBetween November 2017 and April 2019, 1,470 patients of 70 years and older undergoing elective orthopedic, general, cardiac, or vascular surgery were recruited in the randomized, prospective, multicenter PAWEL trial. Anticholinergic burden of a sub-cohort of 899 patients, who did not receive a multimodal intervention for preventing POD, was assessed by two different tools at hospital admission: The established Anticholinergic Risk Scale (ARS) and the recently developed Anticholinergic Burden Score (ABS). POD was detected by confusion assessment method (CAM) and a validated post discharge medical record review. Logistic regression analyses were performed to evaluate the association between anticholinergic burden and POD. ResultsPOD was observed in 210 of 899 patients (23.4%). Both ARS and ABS were independently associated with POD. The association persisted after adjustment for relevant confounding factors such as age, sex, comorbidities, preoperative cognitive and physical status, number of prescribed drugs, surgery time, type of surgery and anesthesia, usage of heart-lung-machine, and treatment in intensive care unit. If a patient was taking one of the 56 drugs listed in the ABS, risk for POD was 2.7-fold higher (OR = 2.74, 95% CI = 1.55-4.94) and 1.5-fold higher per additional point on the ARS (OR = 1.54, 95% CI = 1.15-2.02). ConclusionPreoperative anticholinergic drug exposure measured by ARS or ABS was independently associated with POD in older patients undergoing elective surgery. Therefore, identification, discontinuation or substitution of anticholinergic medication prior to surgery may be a promising approach to reduce the risk of POD in older patients.