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Mechanical behaviors of granite after thermal treatment under loading and unloading conditions
(2021)
Understanding the mechanical behaviors of granite after thermal treatment under loading and unloading conditions is of utmost relevance to deep geothermal energy recovery. In the present study, a series of loading and unloading triaxial compression tests (20, 40 and 60 MPa) on granite specimens after exposure to different temperatures (20, 200, 300, 400, 500 and 600 degrees C) was carried out to quantify the combined effects of thermal treatment and loading/unloading stress conditions on granite strength and deformation. Changes in the microstructure of granite exposed to high temperatures were revealed by optical microscopy. The experimental results indicate that both, thermal treatment and loading/unloading stress conditions, degrade the mechanical behaviors and further decrease the carrying capacity of granite. The gradual degradation of the mechanical characteristics of granite after thermal treatment is mainly associated with the evolution of thermal micro-cracks based on optical microscopy observations. The unloading stress state induces the extension of tension cracks parallel to the axial direction, and thus, the mechanical properties are degraded. Temperatures above 400 degrees C have a more significant influence on the mechanical characteristics of granite than the unloading treatment, whereby 400 degrees C can be treated as a threshold temperature for the delineation of significant deterioration. This study is expected to support feasibility and risk assessments by means of providing data for analytical calculations and numerical simulations on granite exposed to high temperatures during geothermal energy extraction.
It is widely recognized that collisional mountain belt topography is generated by crustal thickening and lowered by river bedrock erosion, linking climate and tectonics(1-4). However, whether surface processes or lithospheric strength control mountain belt height, shape and longevity remains uncertain. Additionally, how to reconcile high erosion rates in some active orogens with long-term survival of mountain belts for hundreds of millions of years remains enigmatic. Here we investigate mountain belt growth and decay using a new coupled surface process(5,6) and mantle-scale tectonic model(7). End-member models and the new non-dimensional Beaumont number, Bm, quantify how surface processes and tectonics control the topographic evolution of mountain belts, and enable the definition of three end-member types of growing orogens: type 1, non-steady state, strength controlled (Bm > 0.5); type 2, flux steady state(8), strength controlled (Bm approximate to 0.4-0.5); and type 3, flux steady state, erosion controlled (Bm < 0.4). Our results indicate that tectonics dominate in Himalaya-Tibet and the Central Andes (both type 1), efficient surface processes balance high convergence rates in Taiwan (probably type 2) and surface processes dominate in the Southern Alps of New Zealand (type 3). Orogenic decay is determined by erosional efficiency and can be subdivided into two phases with variable isostatic rebound characteristics and associated timescales. The results presented here provide a unified framework explaining how surface processes and lithospheric strength control the height, shape, and longevity of mountain belts.
In this study, we analyzed a large seismological dataset from temporary and permanent networks in the southern and eastern Alps to establish high-precision hypocenters and 1-D V-P and V-P/V-S models. The waveform data of a subset of local earthquakes with magnitudes in the range of 1-4.2 M-L were recorded by the dense, temporary SWATH-D network and selected stations of the AlpArray network between September 2017 and the end of 2018. The first arrival times of P and S waves of earthquakes are determined by a semi-automatic procedure. We applied a Markov chain Monte Carlo inversion method to simultaneously calculate robust hypocenters, a 1-D velocity model, and station corrections without prior assumptions, such as initial velocity models or earthquake locations. A further advantage of this method is the derivation of the model parameter uncertainties and noise levels of the data. The precision estimates of the localization procedure is checked by inverting a synthetic travel time dataset from a complex 3-D velocity model and by using the real stations and earthquakes geometry. The location accuracy is further investigated by a quarry blast test. The average uncertainties of the locations of the earthquakes are below 500m in their epicenter and similar to 1.7 km in depth. The earthquake distribution reveals seismicity in the upper crust (0-20 km), which is characterized by pronounced clusters along the Alpine frontal thrust, e.g., the Friuli-Venetia (FV) region, the Giudicarie-Lessini (GL) and Schio-Vicenza domains, the Austroalpine nappes, and the Inntal area. Some seismicity also occurs along the Periadriatic Fault. The general pattern of seismicity reflects head-on convergence of the Adriatic indenter with the Alpine orogenic crust. The seismicity in the FV and GL regions is deeper than the modeled frontal thrusts, which we interpret as indication for southward propagation of the southern Alpine deformation front (blind thrusts).
Dryland xeric conditions exert a deterministic effect on microbial communities, forcing life into refuge niches. Deposited rocks can form a lithic niche for microorganisms in desert regions. Mineral weathering is a key process in soil formation and the importance of microbial-driven mineral weathering for nutrient extraction is increasingly accepted. Advances in geobiology provide insight into the interactions between microorganisms and minerals that play an important role in weathering processes. In this study, we present the examination of the microbial diversity in dryland rocks from the Tsauchab River banks in Namibia. We paired culture-independent 16S rRNA gene amplicon sequencing with culture-dependent (isolation of bacteria) techniques to assess the community structure and diversity patterns. Bacteria isolated from dryland rocks are typical of xeric environments and are described as being involved in rock weathering processes. For the first time, we extracted extra- and intracellular DNA from rocks to enhance our understanding of potentially rock-weathering microorganisms. We compared the microbial community structure in different rock types (limestone, quartz-rich sandstone and quartz-rich shale) with adjacent soils below the rocks. Our results indicate differences in the living lithic and sublithic microbial communities.
In some catchments, the distribution of annual maximum streamflow shows heavy tail behavior, meaning the occurrence probability of extreme events is higher than if the upper tail decayed exponentially. Neglecting heavy tail behavior can lead to an underestimation of the likelihood of extreme floods and the associated risk. Partly contradictory results regarding the controls of heavy tail behavior exist in the literature and the knowledge is still very dispersed and limited. To better understand the drivers, we analyze the upper tail behavior and its controls for 480 catchments in Germany and Austria over a period of more than 50 years. The catchments span from quickly reacting mountain catchments to large lowland catchments, allowing for general conclusions. We compile a wide range of event and catchment characteristics and investigate their association with an indicator of the tail heaviness of flood distributions, namely the shape parameter of the GEV distribution. Following univariate analyses of these characteristics, along with an evaluation of different aggregations of event characteristics, multiple linear regression models, as well as random forests, are constructed. A novel slope indicator, which represents the relation between the return period of flood peaks and event characteristics, captures the controls of heavy tails best. Variables describing the catchment response are found to dominate the heavy tail behavior, followed by event precipitation, flood seasonality, and catchment size. The pre-event moisture state in a catchment has no relevant impact on the tail heaviness even though it does influence flood magnitudes.
The metastable paragenesis of corundum and quartz is rare in nature but common in laboratory experiments where according to thermodynamic predictions aluminum-silicate polymorphs should form. We demonstrate here that the existence of a hydrous, silicon-bearing, nanometer-thick layer (called "HSNL") on the corundum surface can explain this metastability in experimental studies without invoking unspecific kinetic inhibition. We investigated experimentally formed corundum reaction products synthesized during hydrothermal and piston-cylinder experiments at 500-800 degrees C and 0.25-1.8 GPa and found that this HSNL formed inside and on the corundum crystals, thereby controlling the growth behavior of its host. The HSNL represents a substitution of Al with Si and H along the basal plane of corundum. Along the interface of corundum and quartz, the HSNL effectively isolates the bulk phases corundum and quartz from each other, thus apparently preventing their reaction to the stable aluminum silicate. High temperatures and prolonged experimental duration lead to recrystallization of corundum including the HSNL and to the formation of quartz + fluid inclusions inside the host crystal. This process reduces the phase boundary area between the bulk phases, thereby providing further opportunity to expand their coexistence. In addition to its small size, its transient nature makes it difficult to detect the HSNL in experiments and even more so in natural samples. Our findings emphasize the potential impact of nanometer-sized phases on geochemical reaction pathways and kinetics under metamorphic conditions in one of the most important chemical systems of the Earth's crust.
Despite its high-seismogenic potential, the details of the seismogenic processes of Zagros Simply Folded Belt (SFB) remains debated. Three large earthquakes (M-w 7.3, 5.9 and 6.3) struck in the Lurestan arc of the Zagros SFB in 2017 and 2018. The sequence was recorded by seismic stations at regional, and teleseismic distances. Coseismic surface displacements, measured by Sentinel-1A/B satellites, provide additional data and a unique opportunity to study these earthquakes in detail. Here, we complement previous studies of the coseismic slip distribution of the 12 November 2017 M-w 7.3 Ezgeleh earthquake by a detailed analysis of its aftershocks, and we analysed the rupture process of the two interrelated earthquakes (25 August 2018 M-w 5.9 Tazehabad and the 25 November 2018 M-w 6.3 Sarpol-e Zahab earthquakes). We model the surface displacements obtained from Interferometric Synthetic Aperture Radar (InSAR) measurements and seismic records. We conduct non-linear probabilistic optimizations based on joint InSAR and seismic data to obtain finite-fault rupture of these earthquakes. The Lurestan arc earthquakes were followed by a sustained aftershock activity, with 133 aftershocks exceeding M-n 4.0 until 30 December 2019. We rely on the permanent seismic networks of Iran and Iraq to relocate similar to 700 M-n 3 + events and estimate moment tensor solutions for 85 aftershocks down to M-w 4.0. The 2017 Ezgeleh earthquake has been considered to activate a low-angle (similar to 17 degrees) dextral-thrust fault at the depth of 10-20 km. However, most of its aftershocks have shallow centroid depths (8-12 km). The joint interpretation of finite source models, moment tensor and hypocentral location indicate that the 2018 Tazehabad and Sarpol-e Zahab earthquakes ruptured different strike-slip structures, providing evidence for the activation of the sinistral and dextral strike-slip faults, respectively. The deformation in the Lurestan arc is seismically accommodated by a complex fault system involving both thrust and strike-slip faults. Knowledge about the deformation characteristics is important for the understanding of crustal shortening, faulting and hazard and risk assessment in this region.
The release of greenhouse gases from the large organic carbon stock in permafrost deposits in the circumarctic regions may accelerate global warming upon thaw. The extent of this positive climate feedback is thought to be largely controlled by the microbial degradability of the organic matter preserved in these sediments. In addition, weathering and oxidation processes may release inorganic carbon preserved in permafrost sediments as CO2, which is generally not accounted for. We used C-13 and C-14 analysis and isotopic mass balances to differentiate and quantify organic and inorganic carbon released as CO2 in the field from an active retrogressive thaw slump of Pleistocene-age Yedoma and during a 1.5-years incubation experiment. The results reveal that the dominant source of the CO2 released from freshly thawed Yedoma exposed as thaw mound is Pleistocene-age organic matter (48-80%) and to a lesser extent modern organic substrate (3-34%). A significant portion of the CO2 originated from inorganic carbon in the Yedoma (17-26%). The mixing of young, active layer material with Yedoma at a site on the slump floor led to the preferential mineralization of this young organic carbon source. Admixtures of younger organic substrates in the Yedoma thaw mound were small and thus rapidly consumed as shown by lower contributions to the CO2 produced during few weeks of aerobic incubation at 4 degrees C corresponding to approximately one thaw season. Future CO2 fluxes from the freshly thawed Yedoma will contain higher proportions of ancient inorganic (22%) and organic carbon (61-78%) as suggested by the results at the end, after 1.5 years of incubation. The increasing contribution of inorganic carbon during the incubation is favored by the accumulation of organic acids from microbial organic matter degradation resulting in lower pH values and, in consequence, in inorganic carbon dissolution. Because part of the inorganic carbon pool is assumed to be of pedogenic origin, these emissions would ultimately not alter carbon budgets. The results of this study highlight the preferential degradation of younger organic substrates in freshly thawed Yedoma, if available, and a substantial release of CO2 from inorganic sources.
The 100 km wide Merida Andes extend from the Colombian/Venezuelan border to the Coastal Cordillera. The mountain chain and its associated major strike-slip fault systems in western Venezuela formed due to oblique convergence of the Caribbean with the South American Plates and the north-eastwards expulsion of the North Andean Block. Due to the limited knowledge of lithospheric structures related to the formation of the Merida Andes research projects have been developed to illuminate this zone with deep geophysical data. In this study, we present three-dimensional inversion of broadband magnetotelluric data, collected along a 240 km long profile crossing the Merida Andes and the Maracaibo and Barinas-Apure foreland basins. The distribution of the stations limits resolution of the model to off-profile features. Combining 3D inversion of synthetic data sets derived from 3D modelling with 3D inversion of measured data, we could derive a 10 to 15 km wide corridor with good lateral resolution to develop hypotheses about the origin of deep-reaching anomalies of high electrical conductivity. The Merida Andes appear generally as electrically resistive structures, separated by anomalies associated with the most important fault systems of the region, the Bocono and Valera faults. Sensitivity tests suggest that the Valera Fault reaches to depths of up to 12 km and the Bocono Fault to more than 35 km depth. Both structures are connected to a sizeable conductor located east of the profile at 12-15 km depth. We propose that the high conductivity associated with this off-profile conductor may be related to the detachment of the Trujillo Block. We also identified a conductive zone that correlates spatially with the location of a gravity low, possibly representing a SE tilt of the Maracaibo Triangular Block under the mountain chain to great depths (>30 km). The relevance of these tectonic blocks in our models at crustal depths seems to be consistent with proposed theories that describe the geodynamics of western Venezuela as dominated by floating blocks or orogens. Our results stress the importance of the Trujillo Block for the current tectonic evolution of western Venezuela and confirm the relevance of the Bocono Fault carrying deformation to the lower crust and upper mantle. The Barinas-Apure and the Maracaibo sedimentary basins are imaged as electrically conductive with depths of 4 to 5 km and 5 to 10 km, respectively. The Barinas-Apure basin is imaged as a simple 1D structure, in contrast to the Maracaibo Basin, where a series of conductive and resistive bodies could be related to active deformation causing the juxtaposition of older geological formations and younger basin sediments.
The Altiplano-Puna plateau, in Central Andes, is the second-largest continental plateau on Earth, extending between 22 degrees and 27 degrees S at an average altitude of 4400 m. The Puna plateau has been formed in consequence of the subduction of the oceanic Nazca Plate beneath the continental South American plate, which has an average crustal thickness of 50 km at this location. A large seismicity cluster, the Jujuy cluster, is observed at depth of 150-250 km beneath the central region of the Puna plateau. The cluster is seismically very active, with hundreds of earthquakes reported and a peak magnitude MW 6.6 on 25th August 2006. The cluster is situated in one of three band of intermediate-depth focus seismicity, which extend parallel to the trench roughly North to South. It has been hypothesized that the Jujuy cluster could be a seismic nest, a compact seismogenic region characterized by a high stationary activity relative to its surroundings. In this study, we collected more than 40 years of data from different catalogs and proof that the cluster meets the three conditions of a seismic nest. Compared to other known intermediate depth nests at Hindu Kush (Afganisthan) or Bucaramanga (Colombia), the Jujuy nest presents an outstanding seismicity rate, with more than 100 M4+ earthquakes per year. We additionally performed a detailed analysis of the rupture process of some of the largest earthquakes in the nest, by means of moment tensor inversion and directivity analysis. We focused on the time period 2017-2018, where the seismic monitoring was the most extended. Our results show that earthquakes in the nest take place within the eastward subducting oceanic plate, but rupture along sub-horizontal planes dipping westward. We suggest that seismicity at Jujuy nest is controlled by dehydration processes, which are also responsible for the generation of fluids ascending to the crust beneath the Puna volcanic region. We use the rupture plane and nest geometry to provide a constraint to maximal expected magnitude, which we estimate as MW -6.7.
Purpose:
Soil erosion by water yields sediment to surface reservoirs, reducing their storage capacities, changing their geometry, and degrading water quality. Sediment reuse, i.e., fertilization of agricultural soils with the nutrient-enriched sediment from reservoirs, has been proposed as a recovery strategy. However, the sediment needs to meet certain criteria. In this study, we characterize sediments from the densely dammed semiarid Northeast Brazil by VNIR-SWIR spectroscopy and assess the effect of spectral resolution and spatial scale on the accuracy of N, P, K, C, electrical conductivity, and clay prediction models.
Methods
Sediment was collected in 10 empty reservoirs, and physical and chemical laboratory analyses as well as spectral measurements were performed. The spectra, initially measured at 1 nm spectral resolution, were resampled to 5 and 10 nm, and samples were analysed for both high and low spectral resolution at three spatial scales, namely (1) reservoir, (2) catchment, and (3) regional scale.
Results
Partial least square regressions performed from good to very good in the prediction of clay and electrical conductivity from reservoir (<40 km(2)) to regional (82,500 km(2)) scales. Models for C and N performed satisfactorily at the reservoir scale, but degraded to unsatisfactory at the other scales. Models for P and K were more unstable and performed from unsatisfactorily to satisfactorily at all scales. Coarsening spectral resolution by up to 10 nm only slightly degrades the models' performance, indicating the potential of characterizing sediment from spectral data captured at lower resolutions, such as by hyperspectral satellite sensors.
Conclusion:
By reducing the costly and time-consuming laboratory analyses, the method helps to promote the sediment reuse as a practice of soil and water conservation.
Urban surface runoff management via best management practices (BMP) and low impact development (LID) has earned significant recognition owing to positive environmental and ecological impacts. However, due to the complexity of the parameters involved, the estimation of LID efficiency in attenuating the urban surface runoff at the watershed scale is challenging. A planning analysis of employing Green Roofs and Infiltration Trenches as BMPs/LIDs practices for urban surface runoff control is presented in this study. A multi-objective optimization decision-making framework is established by coupling SWMM (Storm Water Management Model) with NSGA-II models to check the performance of BMPs/LIDs concerning the cost-benefit analysis of LID at the watershed scale. Two urbanized areas belonging to Central Delhi in India were used as case studies. The results showed that the SWMM model is useful in simulating optimization problems for managing urban surface runoff. The optimum scenarios efficiently minimized the urban runoff volume while maintaining the BMPs/LIDs implementation costs and size. With BMPs/LIDs implementation, the reduction in runoff volume increases as expenses increase initially; however, there is no noticeable reduction in flood volume after a certain threshold. Contrasted with the haphazard arrangement of BMPs/LIDs, the proposed approach demonstrates 22%-24% runoff reductions for the same expenditures in watershed 1 and 23%-26% in watershed 2. The result of the study provides insights into planning and management of the urban surface runoff control with LID practices. The proposed framework assists the hydrologists in optimum selection and placements of BMPs/LIDs practices to acquire the most extreme ecological advantages with the least expenses.
Van Allen Probes measurements revealed the presence of the most unusual structures in the ultra-relativistic radiation belts. Detailed modeling, analysis of pitch angle distributions, analysis of the difference between relativistic and ultra-realistic electron evolution, along with theoretical studies of the scattering and wave growth, all indicate that electromagnetic ion cyclotron (EMIC) waves can produce a very efficient loss of the ultra-relativistic electrons in the heart of the radiation belts. Moreover, a detailed analysis of the profiles of phase space densities provides direct evidence for localized loss by EMIC waves. The evolution of multi-MeV fluxes shows dramatic and very sudden enhancements of electrons for selected storms. Analysis of phase space density profiles reveals that growing peaks at different values of the first invariant are formed at approximately the same radial distance from the Earth and show the sequential formation of the peaks from lower to higher energies, indicating that local energy diffusion is the dominant source of the acceleration from MeV to multi-MeV energies. Further simultaneous analysis of the background density and ultra-relativistic electron fluxes shows that the acceleration to multi-MeV energies only occurs when plasma density is significantly depleted outside of the plasmasphere, which is consistent with the modeling of acceleration due to chorus waves.
We present two new empirical models of radiation belt electron flux at geostationary orbit. GOES-15 measurements of 0.8 MeV electrons were used to train a Nonlinear Autoregressive with Exogenous input (NARX) neural network for both modeling GOES-15 flux values and an upper boundary condition scaling factor (BF). The GOES-15 flux model utilizes an input and feedback delay of 2 and 2 time steps (i.e., 5 min time steps) with the most efficient number of hidden layers set to 10. Magnetic local time, Dst, Kp, solar wind dynamic pressure, AE, and solar wind velocity were found to perform as predicative indicators of GOES-15 flux and therefore were used as the exogenous inputs. The NARX-derived upper boundary condition scaling factor was used in conjunction with the Versatile Electron Radiation Belt (VERB) code to produce reconstructions of the radiation belts during the period of July-November 1990, independent of in-situ observations. Here, Kp was chosen as the sole exogenous input to be more compatible with the VERB code. This Combined Release and Radiation Effects Satellite-era reconstruction showcases the potential to use these neural network-derived boundary conditions as a method of hindcasting the historical radiation belts. This study serves as a companion paper to another recently published study on reconstructing the radiation belts during Solar Cycles 17-24 (Saikin et al., 2021, ), for which the results featured in this paper were used.
Regional flood frequency analysis (RFFA) is a powerful method for interrogating hydrological series since it combines observational time series from several sites within a region to estimate risk-relevant statistical parameters with higher accuracy than from single-site series. Since RFFA extreme value estimates depend on the shape of the selected distribution of the data-generating stochastic process, there is need for a suitable goodness-of-distributional-fit measure in order to optimally utilize given data. Here we present a novel, least-squares-based measure to select the optimal fit from a set of five distributions, namely Generalized Extreme Value (GEV), Generalized Logistic, Gumbel, Log-Normal Type III and Log-Pearson Type III. The fit metric is applied to annual maximum discharge series from six hydrological stations along the Sava River in South-eastern Europe, spanning the years 1961 to 2020. Results reveal that (1) the Sava River basin can be assessed as hydrologically homogeneous and (2) the GEV distribution provides typically the best fit. We offer hydrological-meteorological insights into the differences among the six stations. For the period studied, almost all stations exhibit statistically insignificant trends, which renders the conclusions about flood risk as relevant for hydrological sciences and the design of regional flood protection infrastructure.
Climate Benefits of Cleaner Energy Transitions in East and South Asia Through Black Carbon Reduction
(2022)
The state of air pollution has historically been tightly linked to how we produce and use energy. Air pollutant emissions over Asia are now changing rapidly due to cleaner energy transitions; however, magnitudes of benefits for climate and air quality remain poorly quantified. The associated risks involve adverse health impacts, reduced agricultural yields, reduced freshwater availability, contributions to climate change, and economic costs. We focus particularly on climate benefits of energy transitions by making first-time use of two decades of high quality observations of atmospheric loading of light-absorbing black carbon (BC) over Kanpur (South Asia) and Beijing (East Asia) and relating these observations to changing energy, emissions, and economic trends in India and China. Our analysis reveals that absorption aerosol optical depth (AAOD) due to BC has decreased substantially, by 40% over Kanpur and 60% over Beijing between 2001 and 2017, and thus became decoupled from regional economic growth. Furthermore, the resultant decrease in BC emissions and BC AAOD over Asia is regionally coherent and occurs primarily due to transitions into cleaner energies (both renewables and fossil fuels) and not due to the decrease in primary energy supply or decrease in use of fossil use and biofuels and waste. Model simulations show that BC aerosols alone contribute about half of the surface temperature change (warming) of the total forcing due to greenhouse gases, natural and internal variability, and aerosols, thus clearly revealing the climate benefits due to a reduction in BC emissions, which would significantly reduce global warming. However, this modeling study excludes responses from natural variability, circulation, and sea ice responses, which cause relatively strong temperature fluctuations that may mask signals from BC aerosols. Our findings show additional benefits for climate (beyond benefits of CO2 reduction) and for several other issues of sustainability over South and East Asia, provide motivation for ongoing cleaner energy production, and consumption transitions, especially when they are associated with reduced emissions of air pollutants. Such an analysis connecting the trends in energy transitions and aerosol absorption loading, unavailable so far, is crucial for simulating the aerosol climate impacts over Asia which is quite uncertain.
In this study, 3-D models of P-wave velocity (Vp) and P-wave and S-wave ratio (Vp/Vs) of the crust and upper mantle in the Eastern and eastern Southern Alps (northern Italy and southern Austria) were calculated using local earthquake tomography (LET). The data set includes high-quality arrival times from well-constrained hypocenters observed by the dense, temporary seismic networks of the AlpArray AASN and SWATH-D. The resolution of the LET was checked by synthetic tests and analysis of the model resolution matrix. The small inter-station spacing (average of similar to 15 km within the SWATH-D network) allowed us to image crustal structure at unprecedented resolution across a key part of the Alps. The derived P velocity model revealed a highly heterogeneous crustal structure in the target area. One of the main findings is that the lower crust is thickened, forming a bulge at 30-50 km depth just south of and beneath the Periadriatic Fault and the Tauern Window. This indicates that the lower crust decoupled both from its mantle substratum as well as from its upper crust. The Moho, taken to be the iso-velocity contour of Vp = 7.25 km/s, agrees with the Moho depth from previous studies in the European and Adriatic forelands. It is shallower on the Adriatic side than on the European side. This is interpreted to indicate that the European Plate is subducted beneath the Adriatic Plate in the Eastern and eastern Southern Alps.
Phase transitions in molecular crystals are often determined by intermolecular interactions. The cage complex of [Co(C12H30N8)](3+) . 3 NO3- is reported to undergo a disorder-order phase transition at T-c1 approximate to 133 K upon cooling. Temperature-dependent neutron and synchrotron diffraction experiments revealed satellite reflections in addition to main reflections in the diffraction patterns below T-c1. The modulation wave vector varies as function of temperature and locks in at T-c3 approximate to 98 K. Here, we demonstrate that the crystal symmetry lowers from hexagonal to monoclinic in the incommensurately modulated phases in T-c1<T<T-c3. Distinctive levels of competitions: trade-off between longer N-H...O and shorter C-H...O hydrogen bonds; steric constraints to dense C-H...O bonds give rise to pronounced modulation of the basic structure. Severely frustrated crystal packing in the incommensurate phase is precursor to optimal balance of intermolecular interactions in the lock-in phase.
In the comment on "Varves of the Dead Sea sedimentary record." Quaternary Science Reviews 215 (Ben Dor et al., 2019): 173-184. by R. Bookman, two recently published papers are suggested to prove that the interpretation of the laminated sedimentary sequence of the Dead Sea, deposited mostly during MIS2 and Holocene pluvials, as annual deposits (i.e., varves) is wrong. In the following response, we delineate several lines of evidence which coalesce to demonstrate that based on the vast majority of evidence, including some of the evidence provided in the comment itself, the interpretation of these sediments as varves is the more likely scientific conclusion. We further discuss the evidence brought up in the comment and its irrelevance and lack of robustness for addressing the question under discussion.