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Production, characterization, and biogas application of magnetic hydrochar from cellulose

  • Hydrothermal carbonization (HTC) produces carbon-rich nano-micro size particles. In this study, magnetic hydrochar (MHC) was prepared from model compound cellulose by simply adding ferrites during HTC. The effects of ferrites on HTC were evaluated by characterizing solid MHC and corresponding process liquid. Additionally, magnetic stability of MHC was tested by magnetic susceptibility method. Finally, MHC was used as support media for anaerobic films in anaerobic digestion (AD). Ash-free mass yield was around 50% less in MHC than hydrochar produced without ferrites at any certain HTC reaction condition, where organic part of MHC is mainly carbon. In fact, amorphous hydrochar was growing on the surface of inorganic ferrites. MHC maintained magnetic susceptibility regardless of reaction time at reaction temperature 250 degrees C. Pronounced inhibitory effects of magnetic hydrochar occurred during start-up of AD but diminished with prolong AD times. Visible biofilms were observed on the MHC by laser scanning microscope after AD. (C) 2015Hydrothermal carbonization (HTC) produces carbon-rich nano-micro size particles. In this study, magnetic hydrochar (MHC) was prepared from model compound cellulose by simply adding ferrites during HTC. The effects of ferrites on HTC were evaluated by characterizing solid MHC and corresponding process liquid. Additionally, magnetic stability of MHC was tested by magnetic susceptibility method. Finally, MHC was used as support media for anaerobic films in anaerobic digestion (AD). Ash-free mass yield was around 50% less in MHC than hydrochar produced without ferrites at any certain HTC reaction condition, where organic part of MHC is mainly carbon. In fact, amorphous hydrochar was growing on the surface of inorganic ferrites. MHC maintained magnetic susceptibility regardless of reaction time at reaction temperature 250 degrees C. Pronounced inhibitory effects of magnetic hydrochar occurred during start-up of AD but diminished with prolong AD times. Visible biofilms were observed on the MHC by laser scanning microscope after AD. (C) 2015 Elsevier Ltd. All rights reserved.zeige mehrzeige weniger

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Metadaten
Verfasserangaben:M. Toufiq Reza, Erwin Rottler, Rainer Tölle, Maja Werner, Patrice Ramm, Jan Mumme
DOI:https://doi.org/10.1016/j.biortech.2015.03.044
ISSN:0960-8524
ISSN:1873-2976
Pubmed ID:https://pubmed.ncbi.nlm.nih.gov/25804500
Titel des übergeordneten Werks (Englisch):Bioresource technology : biomass, bioenergy, biowastes, conversion technologies, biotransformation, production technologies
Verlag:Elsevier
Verlagsort:Oxford
Publikationstyp:Wissenschaftlicher Artikel
Sprache:Englisch
Jahr der Erstveröffentlichung:2015
Erscheinungsjahr:2015
Datum der Freischaltung:27.03.2017
Freies Schlagwort / Tag:Anaerobic digestion; Cellulose; Hydrothermal carbonization; Magnetic hydrochar; Magnetic susceptibility
Band:186
Seitenanzahl:10
Erste Seite:34
Letzte Seite:43
Fördernde Institution:Bioenergy program delegated from the German Federal Ministry of Research and Education; Western Sun Grant Initiatives [C0432G-C]
Organisationseinheiten:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Geowissenschaften
Peer Review:Referiert
Name der Einrichtung zum Zeitpunkt der Publikation:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Erd- und Umweltwissenschaften
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