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Synthesis of star- and block-copolymers using ADMET head-to-tail selectivity during step-growth polymerization

  • Control over molecular architectures obtained via ADMET polymerization is limited by the step-growth nature of this technique. A new approach to this polycondensation method is described allowing for the synthesis of diblock and star-shaped polymers with molecular weight control by using the selectivity of olefin cross-metathesis between acrylates and terminal olefins.

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Author details:Lucas Montero de Espinosa, Michael A. R. Meier
DOI:https://doi.org/10.1039/c0cc04161k
ISSN:1359-7345
Title of parent work (English):Chemical communications
Publisher:Royal Society of Chemistry
Place of publishing:Cambridge
Publication type:Article
Language:English
Year of first publication:2011
Publication year:2011
Release date:2017/03/26
Volume:47
Issue:6
Number of pages:3
First page:1908
Last Page:1910
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Biochemie und Biologie
Peer review:Referiert
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