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Resonant inelastic scattering spectra of free molecules with vibrational resolution

  • Inelastic x-ray scattering spectra excited at the 1s(-1) pi* resonance of gas phase O-2 have been recorded with an overall energy resolution that allows for well-resolved vibrational progressions. The nuclear wave packet dynamics in the intermediate state is reflected in vibrational excitations of the electronic ground state, and by fine-tuning the excitation energy the dissociation dynamics in the predissociative B' (3) Pi(g) final state is controlled.

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Author details:Franz Hennies, Annette PietzschORCiD, Martin Berglund, Alexander FöhlischORCiDGND, Thorsten Schmitt, Vladimir Strocov, Hans O. Karlsson, Joakim Andersson, Jan-Erik Rubensson
URL:http://prl.aps.org/
DOI:https://doi.org/10.1103/Physrevlett.104.193002
ISSN:0031-9007
Publication type:Article
Language:English
Year of first publication:2010
Publication year:2010
Release date:2017/03/25
Source:Physical review letters. - ISSN 0031-9007. - 104 (2010), 19, Art. 193002
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie
Peer review:Referiert
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