X-ray spectroscopy on the active ion in laser crystals
- The active ions in typical laser crystals were studied with Resonant Inelastic X-ray Scattering (RIXS) and Partial Fluorescence Yield X-ray Absorption (PFY-XAS) spectroscopies as solid state model systems for dilute active centers. We analyzed Ti3+ and Cr3+ in alpha-Al2O3:Ti3+ and LiCaAlF6:Cr3+, respectively. The comparison of experimental data with semi-empirical multiplet calculations provides insights into the electronic structure and shows how measured crystal field energies are related across different spectroscopies.
| Author details: | P. S. Miedema, Rolf MitznerORCiDGND, S. Ganschow, Alexander FöhlischORCiDGND, Martin BeyeORCiDGND |
|---|---|
| DOI: | https://doi.org/10.1039/c7cp03026f |
| ISSN: | 1463-9076 |
| ISSN: | 1463-9084 |
| Pubmed ID: | https://pubmed.ncbi.nlm.nih.gov/28783180 |
| Title of parent work (English): | Physical chemistry, chemical physics : a journal of European Chemical Societies |
| Publisher: | Royal Society of Chemistry |
| Place of publishing: | Cambridge |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2017 |
| Publication year: | 2017 |
| Release date: | 2020/04/20 |
| Volume: | 19 |
| Number of pages: | 7 |
| First page: | 21800 |
| Last Page: | 21806 |
| Funding institution: | Volkswagenstiftung |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie |
| Peer review: | Referiert |
