Investigations on mobility of carbon colloid supported nanoscale zero-valent iron (nZVI) in a column experiment and a laboratory 2D-aquifer test system
- Nanoscale zero-valent iron (nZVI) has recently gained great interest in the scientific community as in situ reagent for installation of permeable reactive barriers in aquifer systems, since nZVI is highly reactive with chlorinated compounds and may render them to harmless substances. However, nZVI has a high tendency to agglomerate and sediment; therefore it shows very limited transport ranges. One new approach to overcome the limited transport of nZVI in porous media is using a suited carrier colloid. In this study we tested mobility of a carbon colloid supported nZVI particle "Carbo-Iron Colloids" (CIC) with a mean size of 0.63 mu m in a column experiment of 40 cm length and an experiment in a two-dimensional (2D) aquifer test system with dimensions of 110x40x5 cm. Results show a breakthrough maximum of 82 % of the input concentration in the column experiment and 58 % in the 2D-aquifer test system. Detected residuals in porous media suggest a strong particle deposition in the first centimeters and few depositions in the porous mediaNanoscale zero-valent iron (nZVI) has recently gained great interest in the scientific community as in situ reagent for installation of permeable reactive barriers in aquifer systems, since nZVI is highly reactive with chlorinated compounds and may render them to harmless substances. However, nZVI has a high tendency to agglomerate and sediment; therefore it shows very limited transport ranges. One new approach to overcome the limited transport of nZVI in porous media is using a suited carrier colloid. In this study we tested mobility of a carbon colloid supported nZVI particle "Carbo-Iron Colloids" (CIC) with a mean size of 0.63 mu m in a column experiment of 40 cm length and an experiment in a two-dimensional (2D) aquifer test system with dimensions of 110x40x5 cm. Results show a breakthrough maximum of 82 % of the input concentration in the column experiment and 58 % in the 2D-aquifer test system. Detected residuals in porous media suggest a strong particle deposition in the first centimeters and few depositions in the porous media in the further travel path. Overall, this suggests a high mobility in porous media which might be a significant enhancement compared to bare or polyanionic stabilized nZVI.…
| Verfasserangaben: | Jan Philip Busch, Tobias Meissner, Annegret Potthoff, Sascha Eric OswaldORCiDGND |
|---|---|
| DOI: | https://doi.org/10.1007/s11356-014-3049-7 |
| ISSN: | 0944-1344 |
| ISSN: | 1614-7499 |
| Pubmed ID: | https://pubmed.ncbi.nlm.nih.gov/24859704 |
| Titel des übergeordneten Werks (Englisch): | Environmental science and pollution research : official organ of the EuCheMS Division for Chemistry and the Environment, EuCheMS DCE |
| Verlag: | Springer |
| Verlagsort: | Heidelberg |
| Publikationstyp: | Wissenschaftlicher Artikel |
| Sprache: | Englisch |
| Jahr der Erstveröffentlichung: | 2014 |
| Erscheinungsjahr: | 2014 |
| Datum der Freischaltung: | 27.03.2017 |
| Freies Schlagwort / Tag: | Aquifer systems; Carbon colloid; Nanoscale zero-valent iron (nZVI) |
| Band: | 21 |
| Ausgabe: | 18 |
| Seitenanzahl: | 9 |
| Erste Seite: | 10908 |
| Letzte Seite: | 10916 |
| Fördernde Institution: | German Ministry for Education and Research (Bundesministerium fur Bildung und Forschung, BMBF) |
| Organisationseinheiten: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Geowissenschaften |
| Peer Review: | Referiert |
| Name der Einrichtung zum Zeitpunkt der Publikation: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Erd- und Umweltwissenschaften |
