"Caffeine Doping" of Carbon/Nitrogen-Based Organic Catalysts: Caffeine as a Supramolecular Edge Modifier for the Synthesis of Photoactive Carbon Nitride Tubes
- An alternative method for the structure tuning of carbon nitride materials by using a supramolecular approach in combination with caffeine as lining-agent is described. The self-assembly of the precursor complex consisting of melamine and cyanuric acid can be controlled by this doping molecule in terms of morphology, electronic, and photophysical properties. Caffeine is proposed to insert as an edge-molecule eventually leading to hollow tube-like carbon nitride structures with improved efficiency of charge formation. Compared to the bulk carbon nitride, the caffeine-doped analogue possesses a higher photocatalytic activity for the degradation of rhodamineB dye. Furthermore, this approach is also shown to be suitable for the modification of carbon nitride electrodes.
Verfasserangaben: | Thomas JordanORCiDGND, Nina FechlerGND, Jingsan Xu, Thomas J. K. Brenner, Markus AntoniettiORCiDGND, Menny Shalom |
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DOI: | https://doi.org/10.1002/cctc.201500343 |
ISSN: | 1867-3880 |
ISSN: | 1867-3899 |
Titel des übergeordneten Werks (Englisch): | ChemCatChem : heterogeneous & homogeneous & bio- & nano-catalysis ; a journal of ChemPubSoc Europe |
Verlag: | Wiley-VCH |
Verlagsort: | Weinheim |
Publikationstyp: | Wissenschaftlicher Artikel |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2015 |
Erscheinungsjahr: | 2015 |
Datum der Freischaltung: | 27.03.2017 |
Freies Schlagwort / Tag: | caffeine; carbon nitride; films; photocatalysis; supramolecular chemistry |
Band: | 7 |
Ausgabe: | 18 |
Seitenanzahl: | 5 |
Erste Seite: | 2826 |
Letzte Seite: | 2830 |
Organisationseinheiten: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie |
Peer Review: | Referiert |