Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal–organic frameworks with flexible ethoxy substituent
- A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas-sorption behavior of both materials for H2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect.
Author details: | Suvendu Sekhar MondalORCiDGND, Subarna Dey, Igor A. Baburin, Alexandra Kelling, Uwe SchildeORCiDGND, Gotthard Seifert, Christoph Janiak, Hans-Jürgen HoldtORCiD |
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URN: | urn:nbn:de:kobv:517-opus4-94360 |
Publication series (Volume number): | Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (234) |
Publication type: | Postprint |
Language: | English |
Date of first publication: | 2013/10/08 |
Publication year: | 2013 |
Publishing institution: | Universität Potsdam |
Release date: | 2016/08/11 |
Tag: | adsorption; behavior; carbon-dioxide; crystals; gases; ligand; pressure; selectivity; temperature; zinc |
First page: | 9394 |
Last Page: | 9399 |
Source: | CrystEngComm (2013) Nr. 15, S. 9394-9399. - DOI: 10.1039/C3CE41632A |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
DDC classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Peer review: | Referiert |
Publishing method: | Open Access |
License (German): | Keine öffentliche Lizenz: Unter Urheberrechtsschutz |