X-ray spectroscopy on the active ion in laser crystals
- The active ions in typical laser crystals were studied with Resonant Inelastic X-ray Scattering (RIXS) and Partial Fluorescence Yield X-ray Absorption (PFY-XAS) spectroscopies as solid state model systems for dilute active centers. We analyzed Ti3+ and Cr3+ in alpha-Al2O3:Ti3+ and LiCaAlF6:Cr3+, respectively. The comparison of experimental data with semi-empirical multiplet calculations provides insights into the electronic structure and shows how measured crystal field energies are related across different spectroscopies.
Author details: | P. S. Miedema, Rolf MitznerORCiDGND, S. Ganschow, Alexander FöhlischORCiDGND, Martin BeyeORCiDGND |
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DOI: | https://doi.org/10.1039/c7cp03026f |
ISSN: | 1463-9076 |
ISSN: | 1463-9084 |
Pubmed ID: | https://pubmed.ncbi.nlm.nih.gov/28783180 |
Title of parent work (English): | Physical chemistry, chemical physics : a journal of European Chemical Societies |
Publisher: | Royal Society of Chemistry |
Place of publishing: | Cambridge |
Publication type: | Article |
Language: | English |
Year of first publication: | 2017 |
Publication year: | 2017 |
Release date: | 2020/04/20 |
Volume: | 19 |
Number of pages: | 7 |
First page: | 21800 |
Last Page: | 21806 |
Funding institution: | Volkswagenstiftung |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie |
Peer review: | Referiert |