Base catalysed decomposition of anthracene endoperoxide
- Catalytic amounts of a weak base are sufficient to induce the decomposition of anthracene endoperoxides to anthraquinone. The mechanism has been elucidated by isolation of intermediates in combination with DFT calculations. The whole process is suitable for the convenient generation of hydrogen peroxide under very mild conditions.
| Author details: | Matthias Klaper, Pablo WessigORCiDGND, Torsten LinkerORCiDGND |
|---|---|
| DOI: | https://doi.org/10.1039/c5cc08606j |
| ISSN: | 1359-7345 |
| ISSN: | 1364-548X |
| Pubmed ID: | https://pubmed.ncbi.nlm.nih.gov/26608846 |
| Title of parent work (English): | Chemical communications |
| Publisher: | Royal Society of Chemistry |
| Place of publishing: | Cambridge |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2016 |
| Publication year: | 2016 |
| Release date: | 2020/03/22 |
| Volume: | 52 |
| Number of pages: | 4 |
| First page: | 1210 |
| Last Page: | 1213 |
| Funding institution: | University of Potsdam |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer review: | Referiert |
