The effect of delocalization on the exchange energy in meta- and para-linked Pt-containing carbazole polymers and monomers
- A series of novel platinum-containing carbazole monomers and polymers was synthesized and fully characterized by UV-VIS absorption, luminescence, and photoinduced absorption studies. In these compounds, a carbazole unit is incorporated into the main chain via either a para- or a meta-linkage. We discuss the effects of linkage and polymerization on the energy levels of S-1, T-1, and T-n. The S-1-T-1 splitting observed for the meta-linked monomer (0.4 eV) is only half of that in the para-linked monomer (0.8 eV). Upon polymerization, the exchange energy in the para- linked compound reduces, yet still remains larger than in the meta-linked polymer. We attribute the difference in exchange energy to the difference in wave function overlap between electron and hole in these compounds. (c) 2006 American Institute of Physics
Verfasserangaben: | Ning Zhang, Anna Hayer, Mohammed K. Al-Suti, Rayya A. Al-Belushi, Muhammad S. Khan, Anna Köhler |
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URL: | http://scitation.aip.org/getpdf/servlet/ GetPDFServlet?filetype=pdf&id=JCPSA6000124000024244701000001&idtype=cvips&doi=10.1063/1.2200351&prog=normal |
DOI: | https://doi.org/10.1063/1.2200351 |
Publikationstyp: | Wissenschaftlicher Artikel |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2006 |
Erscheinungsjahr: | 2006 |
Datum der Freischaltung: | 24.03.2017 |
Quelle: | Journal of chemical physics. - 124 (2006), 24, Artn 244701 |
Organisationseinheiten: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie |
Peer Review: | Referiert |
Name der Einrichtung zum Zeitpunkt der Publikation: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik |