Mn(ii) sub-nanometric site stabilization in noble, N-doped carbonaceous materials for electrochemical CO2 reduction
- The preparation of stable and efficient electrocatalysts comprising abundant and non-critical row-materials is of paramount importance for their industrial implementation. Herein, we present a simple synthetic route to prepare Mn(ii) sub-nanometric active sites over a highly N-doped noble carbonaceous support. This support not only promotes a strong stabilization of the Mn(ii) sites, improving its stability against oxidation, but also provides a convenient coordination environment in the Mn(ii) sites able to produce CO, HCOOH and CH3COOH from electrochemical CO2 reduction.
| Author details: | Janina KossmannORCiDGND, Maria Luz Ortiz Sanchez-Manjavacas, Jessica Brandt, Tobias HeilORCiDGND, Nieves López-SalasORCiD, Josep AlberoORCiD |
|---|---|
| DOI: | https://doi.org/10.1039/d2cc00585a |
| ISSN: | 1359-7345 |
| ISSN: | 1364-548X |
| Pubmed ID: | https://pubmed.ncbi.nlm.nih.gov/35348156 |
| Title of parent work (English): | Chemical communications : ChemComm / The Royal Society of Chemistry |
| Publisher: | Royal Society of Chemistry |
| Place of publishing: | Cambridge |
| Publication type: | Article |
| Language: | English |
| Date of first publication: | 2022/03/21 |
| Publication year: | 2022 |
| Release date: | 2023/04/25 |
| Volume: | 58 |
| Issue: | 31 |
| Number of pages: | 5 |
| First page: | 4841 |
| Last Page: | 4844 |
| Funding institution: | Max Planck Society |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| DDC classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Peer review: | Referiert |
| Publishing method: | Open Access / Hybrid Open-Access |
| License (English): |  Creative Commons - Namensnennung 3.0 Unported |
