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A supramolecular Co(II)₁₄-metal–organic cube in a hydrogen-bonded network and a Co(II)–organic framework with a flexible methoxy substituent

  • The reaction of 4,5-dicyano-2-methoxyimidazole (L1) with Co(NO3)2·6H2O under solvothermal conditions in DMF, a MOF, IFP-8 and a hydrogen-bonded network consisting of tetradecanuclear Co(II)14-metal organic cube (1) are achieved. 1 shows the bcu net with 14 cobalt atoms.

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Author:Suvendu Sekhar Mondal, Asamanjoy Bhunia, Alexandra Kelling, Uwe SchildeORCiDGND, Christoph Janiak, Hans-Jürgen Holdt
Series (Serial Number):Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (paper 169)
Document Type:Postprint
Date of first Publication:2014/03/26
Year of Completion:2014
Publishing Institution:Universität Potsdam
Release Date:2015/03/23
First Page:5441
Last Page:5443
Source:Chemical communications, 2014, 50, S. 5441-5443 - DOI: 10.1039/c3cc49698h
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer Review:Referiert
Publication Way:Open Access
Licence (English):License LogoCreative Commons - Attribution 3.0 unported
Notes extern:Bibliographieeintrag der Originalveröffentlichung/Quelle