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Novel porous materials based on oligospiroketals (OSK)
- New porous materials based on covalently connected monomers are presented. The key step of the synthesis is an acetalisation reaction. In previous years we used acetalisation reactions extensively to build up various molecular rods. Based on this approach, investigations towards porous polymeric materials were conducted by us. Here we wish to present the results of these studies in the synthesis of 1D polyacetals and porous 3D polyacetals. By scrambling experiments with 1D acetals we could prove that exchange reactions occur between different building blocks (evidenced by MALDI-TOF mass spectrometry). Based on these results we synthesized porous 3D polyacetals under the same mild conditions.
Author details: | Pablo WessigORCiDGND, Maik Gerngroß, Simon Pape, Philipp Bruhns, Jens Weber |
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URN: | urn:nbn:de:kobv:517-opus4-74466 |
Publication series (Volume number): | Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (paper 175) |
Publication type: | Postprint |
Language: | English |
Date of first publication: | 2014/07/03 |
Publication year: | 2014 |
Publishing institution: | Universität Potsdam |
Release date: | 2015/03/26 |
Tag: | construction; frameworks; membranes; microporous organic polymers; models; molecular rods; sorption |
Number of pages: | 7 |
First page: | 31123 |
Last Page: | 31129 |
Source: | RSC Advances, 59 (2014) 4, S. 31123-31129. - DOI: 10.1039/c4ra04437a |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
DDC classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Peer review: | Referiert |
Publishing method: | Open Access |
License (English): | Creative Commons - Namensnennung 3.0 Unported |
External remark: | Bibliographieeintrag der Originalveröffentlichung/Quelle |