Resonant inelastic scattering spectra of free molecules with vibrational resolution
- Inelastic x-ray scattering spectra excited at the 1s(-1) pi* resonance of gas phase O-2 have been recorded with an overall energy resolution that allows for well-resolved vibrational progressions. The nuclear wave packet dynamics in the intermediate state is reflected in vibrational excitations of the electronic ground state, and by fine-tuning the excitation energy the dissociation dynamics in the predissociative B' (3) Pi(g) final state is controlled.
Author details: | Franz Hennies, Annette PietzschORCiD, Martin Berglund, Alexander FöhlischORCiDGND, Thorsten Schmitt, Vladimir Strocov, Hans O. Karlsson, Joakim Andersson, Jan-Erik Rubensson |
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URL: | http://prl.aps.org/ |
DOI: | https://doi.org/10.1103/Physrevlett.104.193002 |
ISSN: | 0031-9007 |
Publication type: | Article |
Language: | English |
Year of first publication: | 2010 |
Publication year: | 2010 |
Release date: | 2017/03/25 |
Source: | Physical review letters. - ISSN 0031-9007. - 104 (2010), 19, Art. 193002 |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie |
Peer review: | Referiert |