530 Physik
Refine
Year of publication
Document Type
- Article (884)
- Doctoral Thesis (368)
- Postprint (114)
- Other (48)
- Preprint (25)
- Habilitation Thesis (23)
- Review (10)
- Master's Thesis (9)
- Monograph/Edited Volume (4)
- Course Material (3)
Is part of the Bibliography
- yes (1490) (remove)
Keywords
- diffusion (43)
- anomalous diffusion (33)
- gamma rays: general (20)
- synchronization (19)
- Synchronisation (16)
- organic solar cells (15)
- stochastic processes (15)
- cosmic rays (14)
- ISM: supernova remnants (13)
- data analysis (12)
Institute
- Institut für Physik und Astronomie (1367)
- Extern (38)
- Institut für Chemie (36)
- Interdisziplinäres Zentrum für Dynamik komplexer Systeme (26)
- Mathematisch-Naturwissenschaftliche Fakultät (25)
- Institut für Mathematik (18)
- Institut für Geowissenschaften (14)
- Institut für Biochemie und Biologie (7)
- Institut für Umweltwissenschaften und Geographie (7)
- Potsdam Institute for Climate Impact Research (PIK) e. V. (6)
Isoflux tension propagation (IFTP) theory and Langevin dynamics (LD) simulations are employed to study the dynamics of channel-driven polymer translocation in which a polymer translocates into a narrow channel and the monomers in the channel experience a driving force fc. In the high driving force limit, regardless of the channel width, IFTP theory predicts τ ∝ f βc for the translocation time, where β = −1 is the force scaling exponent. Moreover, LD data show that for a very narrow channel fitting only a single file of monomers, the entropic force due to the subchain inside the channel does not play a significant role in the translocation dynamics and the force exponent β = −1 regardless of the force magnitude. As the channel width increases the number of possible spatial configurations of the subchain inside the channel becomes significant and the resulting entropic force causes the force exponent to drop below unity.
We review recent progress in the field of light responsive soft nano-objects. These are systems the shape, size, surface area and surface energy of which can be easily changed by low-intensity external irradiation. Here we shall specifically focus on microgels, DNA molecules, polymer brushes and colloidal particles. One convenient way to render these objects photosensitive is to couple them via ionic and/or hydrophobic interactions with azobenzene containing surfactants in a non-covalent way. The advantage of this strategy is that these surfactants can make any type of charged object light responsive without the need for possibly complicated (and irreversible) chemical conjugation. In the following, we will exclusively discuss only photosensitive surfactant systems. These contain a charged head and a hydrophobic tail into which an azobenzene group is incorporated, which can undergo reversible photo-isomerization from a trans-to a cis-configuration under UV illumination. These kinds of photo-isomerizations occur on a picosecond timescale and are fully reversible. The two isomers in general possess different polarity, i.e. the trans-state is less polar with a dipole moment of usually close to 0 Debye, while the cis-isomer has a dipole moment up to 3 Debye or more, depending on additional phenyl ring substituents. As part of the hydrophobic tail of a surfactant molecule, the photo-isomerization also changes the hydrophobicity of the molecule as a whole and hence its solubility, surface energy, and strength of interaction with other substances. Being a molecular actuator, which converts optical energy in to mechanical work, the azobenzene group in the shape of surfactant molecule can be utilized in order to actuate matter on larger time and length scale. In this paper we show several interesting examples, where azobenzene containing surfactants play the role of a transducer mediating between different states of size, shape, surface energy and spatial arrangement of various nanoscale soft-material systems.
Dielectric elastomer devices operate on the principle of Maxwell stress and their operating performance significantly rely on the elastomer and compliant electrode's electrical and mechanical properties. This paper reports that performing actuation tests at elevated temperatures resulted in an enhanced performance due to the reduction of Young's modulus and the increase of dielectric permittivity. As a result, considerably higher isometric forces and isotonic strains were achieved above the ambient operating temperature. For actuators made of silicone, polyurethane and acrylic elastomers, 166%, 70% and 266% higher isometric forces and 450%, 250% and 54% higher isotonic strains were observed, respectively, when tested at the temperature of 100 degrees C in comparison to ambient temperature values using the same operating voltages. Values of up to 0.4 J kg(-1) and 3.1 W kg(-1) were achieved for the work and power outputs per mass, respectively, on a silicone elastomer driven with a voltage of 1.5 kV at a temperature of 100 degrees C.
We study generalized diffusion-wave equation in which the second order time derivative is replaced by an integro-differential operator. It yields time fractional and distributed order time fractional diffusion-wave equations as particular cases. We consider different memory kernels of the integro-differential operator, derive corresponding fundamental solutions, specify the conditions of their non-negativity and calculate the mean squared displacement for all cases. In particular, we introduce and study generalized diffusion-wave equations with a regularized Prabhakar derivative of single and distributed orders. The equations considered can be used for modeling the broad spectrum of anomalous diffusion processes and various transitions between different diffusion regimes.
We obtain a generalized diffusion equation in modified or Riemann-Liouville form from continuous time random walk theory. The waiting time probability density function and mean squared displacement for different forms of the equation are explicitly calculated. We show examples of generalized diffusion equations in normal or Caputo form that encode the same probability distribution functions as those obtained from the generalized diffusion equation in modified form. The obtained equations are general and many known fractional diffusion equations are included as special cases.
We study a distribution of times of the first arrivals to absorbing targets in turbulent diffusion, which is due to a multiplicative noise. Two examples of dynamical systems with a multiplicative noise are studied. The first one is a random process according to inhomogeneous diffusion, which is also known as a geometric Brownian motion in the Black-Scholes model. The second model is due to a random processes on a two-dimensional comb, where inhomogeneous advection is possible only along the backbone, while Brownian diffusion takes place inside the branches. It is shown that in both cases turbulent diffusion takes place as the one-dimensional random process with the log-normal distribution in the presence of absorbing targets, which are characterized by the Levy-Smirnov distribution for the first hitting times.
This publication based thesis, which consists of seven published articles, summarizes my contributions to the research field of laser excited ultrafast structural dynamics. The coherent and incoherent lattice dynamics on microscopic length scales are detected by ultrashort optical and X-ray pulses. The understanding of the complex physical processes is essential for future improvements of technological applications. For this purpose, tabletop soruces and large scale facilities, e.g. synchrotrons, are employed to study structural dynamics of longitudinal acoustic strain waves and heat transport. The investigated effects cover timescales from hundreds of femtoseconds up to several microseconds.
The main part of this thesis is dedicated to the investigation of tailored phonon wave packets propagating in perovskite nanostructures. Tailoring is achieved either by laser excitation of nanostructured bilayer samples or by a temporal series of laser pulses. Due to the propagation of longitudinal acoustic phonons, the out-of-plane lattice spacing of a thin film insulator-metal bilayer sample is modulated on an ultrafast timescale. This leads to an ultrafast modulation of the X-ray diffraction efficiency which is employed as a phonon Bragg switch to shorten hard X-ray pulses emitted from a 3rd generation synchrotron.
In addition, we have observed nonlinear mixing of high amplitude phonon wave packets which originates from an anharmonic interatomic potential. A chirped optical pulse sequence excites a narrow band phonon wave packet with specific momentum and energy. The second harmonic generation of these phonon wave packets is followed by ultrafast X-ray diffraction. Phonon upconversion takes place because the high amplitude phonon wave packet modulates the acoustic properties of the crystal which leads to self steepening and to the successive generation of higher harmonics of the phonon wave packet.
Furthermore, we have demonstrated ultrafast strain in direction parallel to the sample surface. Two consecutive so-called transient grating excitations displaced in space and time are used to coherently control thermal gradients and surface acoustic modes. The amplitude of the coherent and incoherent surface excursion is disentangled by time resolved X-ray reflectivity measurements. We calibrate the absolute amplitude of thermal and acoustic surface excursion with measurements of longitudinal phonon propagation. In addition, we develop a diffraction model which allows for measuring the surface excursion on an absolute length scale with sub-Äangström precision. Finally, I demonstrate full coherent control of an excited surface deformation by amplifying and suppressing thermal and coherent excitations at the surface of a laser-excited Yttrium-manganite sample.
Aims. To gain a realistic picture of the donor star in Vela X-1, we constructed a hydrodynamically consistent atmosphere model describing the wind stratification while properly reproducing the observed donor spectrum. To investigate how X-ray illumination affects the stellar wind, we calculated additional models for different X-ray luminosity regimes. Methods. We used the recently updated version of the Potsdam Wolf-Rayet code to consistently solve the hydrodynamic equation together with the statistical equations and the radiative transfer. Results. The wind flow in Vela X-1 is driven by ions from various elements, with Fe III and S III leading in the outer wind. The model-predicted mass-loss rate is in line with earlier empirical studies. The mass-loss rate is almost unaffected by the presence of the accreting NS in the wind. The terminal wind velocity is confirmed at u(infinity) approximate to 600 km s(-1). On the other hand, the wind velocity in the inner region where the NS is located is only approximate to 100 km s(-1), which is not expected on the basis of a standard beta-velocity law. In models with an enhanced level of X-rays, the velocity field in the outer wind can be altered. If the X-ray flux is too high, the acceleration breaks down because the ionization increases. Conclusions. Accounting for radiation hydrodynamics, our Vela X-1 donor atmosphere model reveals a low wind speed at the NS location, and it provides quantitative information on wind driving in this important HMXB.
Perovskite semiconductors as the active materials in efficient solar cells exhibit free carrier diffusion lengths on the order of microns at low illumination fluxes and many hundreds of nanometers under 1 sun conditions. These lengthscales are significantly larger than typical junction thicknesses, and thus the carrier transport and charge collection should be expected to be diffusion controlled. A consensus along these lines is emerging in the field. However, the question as to whether the built-in potential plays any role is still of matter of some conjecture. This important question using phase-sensitive photocurrent measurements and theoretical device simulations based upon the drift-diffusion framework is addressed. In particular, the role of the built-in electric field and charge-selective transport layers in state-of-the-art p-i-n perovskite solar cells comparing experimental findings and simulation predictions is probed. It is found that while charge collection in the junction does not require a drift field per se, a built-in potential is still needed to avoid the formation of reverse electric fields inside the active layer, and to ensure efficient extraction through the charge transport layers.