Referiert
Refine
Year of publication
- 2018 (74) (remove)
Language
- English (74)
Is part of the Bibliography
- yes (74)
Keywords
- Euglyphida (2)
- Europe (2)
- LiDAR (2)
- Maritime Alps (2)
- adaptation (2)
- biogenic silica (2)
- catchment (2)
- climate change (2)
- knickpoint (2)
- radiative forcing (2)
Institute
- Institut für Umweltwissenschaften und Geographie (74) (remove)
In this study transmission X-ray microscopy (TXM) was tested as a method to investigate the chemistry and structure of corroded silicate glasses at the nanometer scale. Three different silicate glasses were altered in static corrosion experiments for 1-336 hours at temperatures between 60 degrees C and 85 degrees C using a 25% HCl solution. Thin lamellas were cut perpendicular to the surface of corroded glass monoliths and were analysed with conventional TEM as well as with TXM. By recording optical density profiles at photon energies around the Na and O K-edges, the shape of the corrosion rim/pristine glass interfaces and the thickness of the corrosion rims has been determined. Na and O near-edge X-ray absorption fine-structure spectra (NEXAFS) were obtained without inducing irradiation damage and have been used to detect chemical changes in the corrosion rims. Spatially resolved NEXAFS spectra at the O K-edge provided insight to structural changes in the corrosion layer on the atomic scale. By comparison to O K-edge spectra of silicate minerals and (hydrous) albite glass as well as to O K-edge NEXAFS of model structures simulated with ab initio calculations, evidence is provided that changes of the fine structure at the O K-edge are assigned to the formation of siloxane groups in the corrosion rim.
Urbanization as an inexorable global trend stresses the need to identify cities which are eco-efficient. These cities enable socioeconomic development with lower environmental burden, both being multidimensional concepts. Based on this approach, we benchmark 88 European cities using (i) an advanced version of regression residual ranking and (ii) Data Envelopment Analysis (DEA). Our results show that Stockholm, Munich and Oslo perform well irrespective of the benchmarking method. Furthermore, our results indicate that larger European cities are eco-efficient given the socioeconomic benefits they offer compared to smaller cities. In addition, we analyze correlations between a subjective public perception ranking and our objective eco-efficiency rankings for a subset of 45 cities. This exercise revealed three insights: (1) public perception about quality of life in a city is not merely confined to the socioeconomic well-being but rather to its combination with a lower environmental burden; (2) public perception correlates well with both formal ranking outcomes, corroborating the choice of variables; and (3) the advanced regression residual method appears to be more adequate to fit the urbanites' perception ranking (correlation coefficient about 0.6). This can be interpreted as an indication that urbanites' perception reflects the typical eco-efficiency performance and is less influenced by exceptionally performing cities (in the latter case, DEA should have better correlation coefficient). This study highlights that the socioeconomic growth in cities should not be environmentally detrimental as this might lead to significant discontent regarding perceived quality of urban life.
The West Bohemia/Vogtland region, characterized by the intersection of the Eger (Ohre) Rift and the Marianske Lazne fault, is a geodynamically active area exhibiting repeated occurrence of earthquake swarms, massive CO2 emanations and mid Pleistocene volcanism. The Eger Rift is the only known intra-continental region in Europe where such deep seated, active lithospheric processes currently take place. We present an image of electrical resistivity obtained from two-dimensional inversion of magnetotelluric (MT) data acquired along a regional profile crossing the Eger Rift. At the near surface, the Cheb basin and the aquifer feeding the mofette fields of Bublak and Hartousov have been imaged as part of a region of very low resistivity. The most striking resistivity feature, however, is a deep reaching conductive channel which extends from the surface into the lower crust spatially correlated with the hypocentres of the seismic events of the Novy Kostel Focal Zone. This channel has been interpreted as imaging a pathway from a possible mid-crustal fluid reservoir to the surface. The resistivity model reinforces the relation between the fluid circulation along deep-reaching faults and the generation of the earthquakes. Additionally, a further conductive channel has been revealed to the south of the profile. This other feature could be associated to fossil hydrothermal alteration related to Mytina and/or Neualbenreuth Maar structures or alternatively could be the signature of a structure associated to the suture between the Saxo-Thuringian and Tepla-Barrandian zones, whose surface expression is located only a few kilometres away.
We present late Quaternary lake level reconstruction from the high altitude Tso Moriri Lake (NW Indian Himalaya) using a combination of new and published data from shallow and deep water cores, and catchment geomorphology. Our reconstruction indicates two dramatic lake level increases - a late glacial (ca. 16.4-12.6 cal kyr B.P.) rise of 65 m, and a 47 m rise during the early Holocene wet phase (ca. 11.2-8.5 cal kyr B.P.) which are separated by the Younger Dryas (YD) event. We decouple the role of precipitation seasonality and snow melt using a combination of proxies sensitive to the Indian Summer Monsoon (ISM), and a regional spatio-temporal transect that provides information on the eastward penetration of the winter westerlies. A comparison of shallow and deep water cores shows that (i) the first lake level increase (similar to 65 m, ca. 16.4-12.6 cal kyr B.P.) is caused by melt water inflow triggered by the increasing summer insolation; (ii) the second lake level increase (similar to 47 m, 11.2-8.5 cal kyr B.P.) is largely caused by a rise in annual precipitation coupled with reduced summer evaporation; (iii) in contrast to the onset of ISM (Bay of Bengal branch) at ca. 14.7 ka in lower elevations in NE India, the hydroclimatic influence of ISM in the high altitude Himalaya is seen only between 12.7 and 12 cal kyr B.P., though the influence of solar insolation (via increased snowmelt) is visible from 16.4 cal kyr B.P. onwards; (iv) the eastward penetration of westerlies in Indian Himalayas is strongly influenced by the strength of the Siberian High.
Effect of Solid Biological Waste Compost on the Metabolite Profile of Brassica rapa ssp chinensis
(2018)
Large quantities of biological waste are generated at various steps within the food production chain and a great utilization potential for this solid biological waste exists apart from the current main usage for the feedstuff sector. It remains unclear how the usage of biological waste as compost modulates plant metabolites. We investigated the effect of biological waste of the processing of coffee, aronia, and hop added to soil on the plant metabolite profile by means of liquid chromatography in pak choi sprouts. Here we demonstrate that the solid biological waste composts induced specific changes in the metabolite profiles and the changes are depending on the type of the organic residues and its concentration in soil. The targeted analysis of selected plant metabolites, associated with health beneficial properties of the Brassicaceae family, revealed increased concentrations of carotenoids (up to 3.2-fold) and decreased amounts of glucosinolates (up to 4.7-fold) as well as phenolic compounds (up to 1.5-fold).
The management of water resources in a river basin experiencing the expansion of agricultural activities requires a proper understanding of impacts on its hydrologic cycle. This study focused on the analysis of impacts of infield rainwater harvesting (IRWH) and future agricultural expansion as land and water uses change (LWUC) on the hydrologic cycle in the Wami River basin (Tanzania) using the Soil and Water Assessment Tool (SWAT). In the SWAT model, IRWH was implemented by fragmenting rainwater harvesting hydrological response units (HRUs) from cropland HRUs and assigning them as potholes for rainwater impoundment. LWUC was implemented by customizing land cover types and their corresponding model parameters in all original HRUs, and introducing projected water uses in the model. The study thus demonstrated the successful modelling of IRWH and land use change in the SWAT model using HRU fragmentation and customization approaches, respectively. The results indicated that IRWH applications in croplands led to a large increase in evapotranspiration (ET) and the soil water content, and a decrease in percolation, especially in the dry years. However, the average annual streamflow showed negligible changes when IRWH was implemented, even in 50% of current low-coverage croplands in the river basin. Thus, IRWH applications in the river basin are recommended. The results also indicated that LWUC caused huge changes in ET, the soil water content, percolation and the streamflow from the river basin. The average annual streamflow was predicted to decrease by 26% due to LWUC. However, land use change alone without projected water uses was predicted to cause a minor decrease of about 1% in the average annual streamflow. Therefore, further studies on the eco-hydrology of the river basin under various water use scenarios are recommended prior to the expansion of agricultural areas.
AIC-based diffraction stacking for local earthquake locations at the Sumatran Fault (Indonesia)
(2018)
We present a new workflow for the localization of seismic events which is based on a diffraction stacking approach. In order to address the effects from complex source radiation patterns, we suggest to compute diffraction stacking from a characteristic function (CF) instead of stacking the original waveform data. A new CF, which is called in the following mAIC (modified from Akaike Information Criterion) is proposed. We demonstrate that both P- and S-wave onsets can be detected accurately. To avoid cross-talk between P and S waves due to inaccurate velocity models, we separate the P and S waves from the mAIC function by making use of polarization attributes. Then, the final image function is represented by the largest eigenvalue as a result of the covariance analysis between P-and S-image functions. Results from synthetic experiments show that the proposed diffraction stacking provides reliable results. The workflow of the diffraction stacking method was finally applied to local earthquake data from Sumatra, Indonesia. Recordings from a temporary network of 42 stations deployed for nine months around the Tarutung pull-apart basin were analysed. The seismic event locations resulting from the diffraction stacking method align along a segment of the Sumatran Fault. A more complex distribution of seismicity is imaged within and around the Tarutung basin. Two lineaments striking N-S were found in the centre of the Tarutung basin which support independent results from structural geology.
Thermokarst lakes cover nearly one fourth of ice-rich permafrost lowlands in the Arctic. Sediments from an athalassic subsaline thermokarst lake on Herschel Island (69°36′N; 139°04′W, Canadian Arctic) were used to understand regional changes in climate and in sediment transport, hydrology, nutrient availability and permafrost disturbance. The sediment record spans the last ~ 11,700 years and the basal date is in good agreement with the Holocene onset of thermokarst initiation in the region. Electrical conductivity in pore water continuously decreases, thus indicating desalinization and continuous increase of lake size and water level. The inc/coh ratio of XRF scans provides a high-resolution organic-carbon proxy which correlates with TOC measurements. XRF-derived Mn/Fe ratios indicate aerobic versus anaerobic conditions which moderate the preservation potential of organic matter in lake sediments. The coexistence of marine, brackish and freshwater ostracods and foraminifera is explained by (1) oligohaline to mesohaline water chemistry of the past lake and (2) redeposition of Pleistocene specimens found within upthrusted marine sediments around the lake. Episodes of catchment disturbance are identified when calcareous fossils and allochthonous material were transported into the lake by thermokarst processes such as active-layer detachments, slumping and erosion of ice-rich shores. The pollen record does not show major variations and the pollen-based climate record does not match well with other summer air temperature reconstructions from this region. Local vegetation patterns in small catchments are strongly linked to morphology and sub-surface permafrost conditions rather than to climate. Multidisciplinary studies can identify the onset and life cycle of thermokarst lakes as they play a crucial role in Arctic freshwater ecosystems and in the global carbon cycle of the past, present and future.
In this study, we analyzed 10 yrs of seismicity in central Italy from 2008 to 2017, a period witnessing more than 1400 earthquakes in the magnitude range 2.5≤Mw≤6.5. The data set includes the main sequences that have occurred in the area, including those associated with the 2009 Mw 6.3 L'Aquila earthquake and the 2016–2017 sequence (Mw 6.2 Amatrice, Mw 6.1 Visso, and Mw 6.5 Norcia earthquakes). We calibrated a local magnitude scale, investigating the impact of changing the reference distance at which the nonparametric attenuation is tied to the zero‐magnitude attenuation function for southern California. We also developed an attenuation model to compute the radiated seismic energy (Es) from the time integral of the squared ground‐motion velocity. Seismic moment (M0) and stress drop (Δσ) were estimated for each earthquake by fitting a ω‐square model to the source spectra obtained by applying a nonparametric spectral inversion. The Δσ‐values vary over three orders of magnitude from about 0.1 to 10 MPa, the larger values associated with the mainshocks. The Δσ‐values describe a lognormal distribution with mean and standard deviation equal to log(Δσ)=(−0.25±0.45) (i.e., the mean Δσ is 0.57 MPa, with a 95% confidence interval from 0.08 to 4.79 MPa). The Δσ variability introduces a spread in the distribution of seismic energy versus moment, with differences in energy up two orders of magnitudes for earthquakes with the same moment. The variability in the high‐frequency spectral levels is captured by the local magnitude (ML), which scales with radiated energy as ML=(−1.59+0.52logEs) for logEs≤10.26 and ML=(−1.38+0.50logEs) otherwise. As the peak ground velocity increases with increasing Δσ, local and energy magnitudes perform better than moment magnitude as predictors for the shaking potential. The availability of different magnitude scales and source parameters for a large earthquake population will help characterize the between‐event ground‐motion variability in central Italy.
Ice-wedge polygons are widespread periglacial features and influence landscape hydrology and carbon storage. The influence of climate and topography on polygon development is not entirely clear, however, giving high uncertainties to projections of permafrost development. We studied the mid- to late Holocene development of modern ice-wedge polygon sites to explore drivers of change and reasons for long-term stability. We analyzed organic carbon, total nitrogen, stable carbon isotopes, grain size composition and plant macrofossils in six cores from three polygons. We found that ail sites developed from aquatic to wetland conditions. In the mid-Holocene, shallow lakes and partly submerged ice-wedge polygons existed at the studied sites. An erosional hiatus of ca 5000 years followed, and ice-wedge polygons re-initiated within the last millennium. Ice-wedge melt and surface drying during the last century were linked to climatic warming. The influence of climate on ice-wedge polygon development was outweighed by geomorphology during most of the late Holocene. Recent warming, however, caused ice-wedge degradation at all sites. Our study showed that where waterlogged ground was maintained, low-centered polygons persisted for millennia. Ice-wedge melt and increased drainage through geomorphic disturbance, however, triggered conversion into high-centered polygons and may lead to self-enhancing degradation under continued warming.