Extern
Refine
Has Fulltext
- yes (204)
Year of publication
Document Type
- Postprint (204) (remove)
Keywords
- Germany (7)
- Demokratie (4)
- China (3)
- Realpolitik (3)
- cluster expansion (3)
- democracy (3)
- infinite-dimensional Brownian diffusion (3)
- transatlantic relations (3)
- EU (2)
- European foreign policy (2)
- Fluoreszenz-Resonanz-Energie-Transfer (2)
- G8 (2)
- German foreign policy (2)
- Immunoassay (2)
- Iraq war (2)
- Lumineszenz (2)
- N400 (2)
- PUFA (2)
- Türkei (2)
- US foreign policy (2)
- common foreign and security policy (2)
- entropy (2)
- ethnicity (2)
- fatty acid (2)
- food quality (2)
- predictability (2)
- 315 nm (1)
- 46 (3) 2009 (1)
- 473 nm (1)
- 946 nm (1)
- ACIDIFICATION (1)
- AMNET (1)
- Abrüstung (1)
- Absorption (1)
- Absorptionsspektroskopie (1)
- Akan (1)
- Allantoin (1)
- Amphiphiles (1)
- Anaphylatoxin (1)
- Anatomy (1)
- Animal (1)
- Animal personality (1)
- Arbeit (1)
- Auftragsabwicklung (1)
- Auftragsabwicklungssysteme (1)
- Außenpolitik (1)
- Biochemical analysis (1)
- Biophotonik (1)
- Bryophytes (1)
- Bundesnachrichtendienst (1)
- Carbo-Iron (1)
- Catecholamine (1)
- Chemistry of fresh water (1)
- Chlamydomonas (1)
- Climate Change (1)
- Color vision Aging (1)
- Common Foreign and Security Policy (1)
- Complement system (1)
- Confluence (1)
- Daphnia (1)
- Diversity (1)
- Doblin (1)
- Doeblin (1)
- Dreissena polymorpha (1)
- Döblin (1)
- EROSION (1)
- ERPs (1)
- EVENTS (1)
- Energietransfer (1)
- Energy expenditure (1)
- Entwicklung (1)
- Ethnien (1)
- Europe (1)
- European Alps (1)
- European hare (1)
- Experimental study (1)
- Exploration (1)
- Flow-Erleben (1)
- Flow-experience (1)
- Fluoreszenzspektroskopie (1)
- Fontane, Theodor (1)
- Freizeit (1)
- Förster Resonanz Energie Transfer (1)
- Galactosides (1)
- Gemeinsame Außen- und Sicherheitspolitik (1)
- Geopolitik (1)
- German Foreign Policy (1)
- Gesellschaft (1)
- Gibbs field (1)
- Gibbs measure (1)
- Globalisisierung (1)
- Globalization (1)
- Glucagon (1)
- Glycoconjugates (1)
- Glycopeptides (1)
- Glück/Zufriedenheit (1)
- Grenzüberschreitende Flüsse (1)
- Grundwassersanierung (1)
- HYDROGRAPH SEPARATION (1)
- Hepatic artery (1)
- Hepatic glucose balance (1)
- Hepatic hemodynamics (1)
- Hepatic lactate balance (1)
- Hepatic nerve (1)
- Huminstoffe (1)
- India (1)
- Indien (1)
- Indonesia (1)
- Industrieunternehmen (1)
- Information Processing (1)
- Innenpolitik (1)
- Inter-individual differences (1)
- Interacting Diffusion Processes (1)
- International Organisations (1)
- International Relations (1)
- International law (1)
- Internationale Organisationen (1)
- Internationaler Pakt über bürgerliche und politische Rechte (1)
- Iran (1)
- Iraq crisis (1)
- Islam (1)
- Isotopie (1)
- JH-III-specific carrier protein (1)
- Jurkat cells (1)
- Juvenile hormone (1)
- KINETIC-ENERGY (1)
- Kaukasus (1)
- Klimawandel (1)
- Kolmogorov-Gleichung (1)
- Kooperation (1)
- LC/HRMS (1)
- Lake Constance (1)
- Langevin Dynamics (1)
- Lanthanoide (1)
- Leptinotarsa decemlineata (1)
- Lichtstreuung (1)
- MESOSCALE CONVECTIVE COMPLEXES (1)
- MIXTURE (1)
- Macular pigment (1)
- Malliavin calculus (1)
- Massenvernichtungswaffen (1)
- Medialisierung (1)
- Medien (1)
- Menschenrechtsbeschwerde (1)
- Mexico (1)
- MiSpEx (1)
- Microsaccades (1)
- Microsaccadic Inhibition (1)
- Middle East (1)
- Mobile learning (1)
- Monolayers (1)
- Movement ecology (1)
- Multilateralismus (1)
- NGOs (1)
- Nanoeisen (1)
- Nanopartikel (1)
- Neodym-YAG-Laser (1)
- Nitrogen deposition (1)
- ODBA (1)
- Optode (1)
- Osteuropa (1)
- P300 (1)
- P300Psychophysiology (1)
- Partial Little Square (1)
- Partizipation (1)
- Perfusion (1)
- Poland (1)
- Politisches System (1)
- Portal vein (1)
- Presse (1)
- Privatisierung (1)
- Prozesskontrolle (1)
- Quantenpunkt (1)
- Quantitative Trait Locus (1)
- Quantitative Trait Locus analysis (1)
- Random Field Ising Model (1)
- Rat (1)
- Ratgeber (1)
- Regelkreismechanismus (1)
- Regionalmacht (1)
- Runoff and streamflow (1)
- Russland (1)
- S. 635-644 (1)
- SAK (1)
- SOILWATER END-MEMBERS (1)
- STREAMWATER CHEMISTRY (1)
- Sauerstoff (1)
- Sensorik (1)
- Sicherheit (1)
- Social Identity Theory (1)
- Space-Time Cluster Expansions (1)
- Species richness (1)
- Steroid esters (1)
- Stochastische Analysis (1)
- Succession (1)
- Summenparameter (1)
- Süd- und Mittelamerika (1)
- TRACERS (1)
- Team Composition (1)
- Team Development (1)
- Technique (1)
- Terrorismus (1)
- UNITED-STATES (1)
- UV-detection (1)
- Understorey (1)
- Union (1)
- United States (1)
- Urate (1)
- Vascular plants (1)
- Vertrag von Lissabon (1)
- Verträge (1)
- Vincent (1)
- Visual Oddball Paradigm (1)
- Wandlungsfähigkeit (1)
- Wasserkonflikte (1)
- Wasserversorgung (1)
- Weathering (1)
- Welthandel (1)
- Wirtschaft (1)
- Wolfgang (1)
- Word processing (1)
- World Trade (1)
- Zapatistas (1)
- Ziele (1)
- [N]phenylene dyads (1)
- [N]phenylenes (1)
- acclimation (1)
- ad hoc learning (1)
- ad hoc messaging network (1)
- adaptability (1)
- alga (1)
- alpha (1)
- anterior PNP (1)
- area studies (1)
- behaviour (1)
- biophotonics (1)
- canonical discretization schemes (1)
- capillary electrophoresis (1)
- civil war (1)
- climate change (1)
- climate policy (1)
- coherence (1)
- color change (1)
- community (1)
- complement (1)
- composition (1)
- conditioned (1)
- conditioned Feller diffusion (1)
- constrained Hamiltonian systems (1)
- constraint (1)
- consumer (1)
- control loop mechanism (1)
- critical and subcritical Dawson-Watanabe process (1)
- democratisation (1)
- derivational complexity (1)
- differential-algebraic equations (1)
- discotics (1)
- drug delivery (1)
- e-learning platform (1)
- early indicators for SLI (1)
- ecophysiology (1)
- electrochemistry (1)
- enantioselectivity (1)
- energy policy (1)
- enterprise resource planning systems (1)
- ethics (1)
- europe (1)
- european (1)
- feature selection (1)
- feminism (1)
- flexibility (1)
- flood response (1)
- flow (1)
- fluorescence immunoassay (1)
- foreign policy (1)
- future of capitalism (1)
- gender (1)
- gepulster DPSS Laser (1)
- german unification process (1)
- globalization (1)
- glucose (1)
- goals (1)
- grazer (1)
- happiness/satisfaction (1)
- herbivore (1)
- human excised skin (1)
- human rights (1)
- hydrological model (1)
- hydrolysis (1)
- immigration (1)
- immunoassay (1)
- inorganic ions (1)
- integration by parts formula (1)
- intelligence service (1)
- international politics (1)
- international relations (1)
- international security (1)
- internationale Politik (1)
- job characteristics (1)
- lactate output (1)
- language acquisition (1)
- late talker (1)
- leisure time (1)
- life history (1)
- liquid crystals (1)
- long-term effects (1)
- low back pain (1)
- media (1)
- metamorphosis (1)
- mixture of bridges (1)
- monensin (1)
- monosaccharides (1)
- multidisciplinary intervention (1)
- multilaterism (1)
- multitype measure-valued branching processes (1)
- nZVI (1)
- nano zero-valent iron (1)
- nanogels (1)
- nanoparticles (1)
- norms (1)
- optode (1)
- oxygen (1)
- personal initiative (1)
- pervasive learning (1)
- phase synchronization (1)
- photoinduced electron transfer (1)
- photoresponse (1)
- photosynthesis (1)
- physiology (1)
- political economy (1)
- political ideology (1)
- political science (1)
- political system (1)
- political theory (1)
- politische Entwicklungen (1)
- politische Theorie (1)
- polyzyklische aromatische Kohlenwasserstoffe (1)
- posterior P600 (1)
- preferential flow (1)
- probabilistic processing (1)
- processing of phonological details (1)
- prostaglandin-f2-alpha (1)
- pulsed DPSS laser (1)
- reciprocal processes (1)
- reciprocal relationship (1)
- recombinant inbred line (1)
- remediation (1)
- renewable energy (1)
- scale (1)
- selfefficacy (1)
- semantic incongruity (1)
- seston (1)
- skin penetration (1)
- soil analysis (1)
- soziale Bewegungen (1)
- space-time Gibbs field (1)
- spatially explicit model (1)
- stochastic bridge (1)
- stocking capacity (1)
- sustainability (1)
- symplectic methods (1)
- sättigbarer Absorber (1)
- tacrolimus formulation (1)
- terrorism (1)
- theta (1)
- time reversal (1)
- topography (1)
- transatlantic relationship (1)
- transformation of communist states (1)
- transformation products (1)
- transition economy (1)
- veterinary drugs (1)
- war (1)
- welfare state (1)
- wh-ex-situ (1)
- wh-in-situ (1)
- wh-questions (1)
- work (1)
- world order (1)
Institute
- Extern (204) (remove)
Fontanes Medien
(2023)
Theodor Fontane war, im durchaus modernen Sinne, ein Medienarbeiter: Als Presse-Agent in London lernte er die innovativste Presselandschaft seiner Zeit kennen; als Redakteur in Berlin leistete er journalistische Kärrnerarbeit; er schrieb Kritiken über das Theater, die bildende Kunst und die Literatur – und auch seine Romane wie seine Reisebücher sind stets Medienprodukte, als Serien in in Zeitungen und Zeitschriften platziert, bevor sie auf dem Buchmarkt erschienen.
Der vorliegende Band dokumentiert die Ergebnisse eines internationalen Kongresses, veranstaltet 2019 vom Theodor-Fontane-Archiv in Potsdam. Die ebenso rasante wie umfassende Medialisierung und Vernetzung der Gesellschaft im Laufe des 19. Jahrhunderts wird dabei als produktive Voraussetzung der schriftstellerischen Tätigkeit Fontanes begriffen. Eingebettet in ein weit verzweigtes Netz der Korrespondenz und der postalischen Textzirkulation, vertraut mit den Routinen und Publika der periodischen Massenpresse, für die er sein Leben lang schrieb, und auf vielfältige Weise geprägt von der visuellen Kultur seiner Zeit wird Theodor Fontane als gleichermaßen journalistisch versierter wie ästhetisch sensibler Grenzgänger erkennbar.
Intuitively, strongly constraining contexts should lead to stronger probabilistic representations of sentences in memory. Encountering unexpected words could therefore be expected to trigger costlier shifts in these representations than expected words. However, psycholinguistic measures commonly used to study probabilistic processing, such as the N400 event-related potential (ERP) component, are sensitive to word predictability but not to contextual constraint. Some research suggests that constraint-related processing cost may be measurable via an ERP positivity following the N400, known as the anterior post-N400 positivity (PNP). The PNP is argued to reflect update of a sentence representation and to be distinct from the posterior P600, which reflects conflict detection and reanalysis. However, constraint-related PNP findings are inconsistent. We sought to conceptually replicate Federmeier et al. (2007) and Kuperberg et al. (2020), who observed that the PNP, but not the N400 or the P600, was affected by constraint at unexpected but plausible words. Using a pre-registered design and statistical approach maximising power, we demonstrated a dissociated effect of predictability and constraint: strong evidence for predictability but not constraint in the N400 window, and strong evidence for constraint but not predictability in the later window. However, the constraint effect was consistent with a P600 and not a PNP, suggesting increased conflict between a strong representation and unexpected input rather than greater update of the representation. We conclude that either a simple strong/weak constraint design is not always sufficient to elicit the PNP, or that previous PNP constraint findings could be an artifact of smaller sample size.
Background
Animal personality has emerged as a key concept in behavioral ecology. While many studies have demonstrated the influence of personality traits on behavioral patterns, its quantification, especially in wild animal populations, remains a challenge. Only a few studies have established a link between personality and recurring movements within home ranges, although these small-scale movements are of key importance for identifying ecological interactions and forming individual niches. In this regard, differences in space use among individuals might reflect different exploration styles between behavioral types along the shy-bold continuum.
Methods
We assessed among-individual differences in behavior in the European hare (Lepus europaeus), a characteristic mammalian herbivore in agricultural landscapes using a standardized box emergence test for captive and wild hares. We determined an individuals’ degree of boldness by measuring the latencies of behavioral responses in repeated emergence tests in captivity. During capture events of wild hares, we conducted a single emergence test and recorded behavioral responses proven to be stable over time in captive hares. Applying repeated novel environment tests in a near-natural enclosure, we further quantified aspects of exploration and activity in captive hares. Finally, we investigated whether and how this among-individual behavioral variation is related to general activity and space use in a wild hare population. Wild and captive hares were treated similarly and GPS-collared with internal accelerometers prior to release to the wild or the outdoor enclosure, respectively. General activity was quantified as overall dynamic body acceleration (ODBA) obtained from accelerometers. Finally, we tested whether boldness explained variation in (i) ODBA in both settings and (ii) variation in home ranges and core areas across different time scales of GPS-collared hares in a wild population.
Results
We found three behavioral responses to be consistent over time in captive hares. ODBA was positively related to boldness (i.e., short latencies to make first contact with the new environment) in both captive and wild hares. Space use in wild hares also varied with boldness, with shy individuals having smaller core areas and larger home ranges than bold conspecifics (yet in some of the parameter space, this association was just marginally significant).
Conclusions
Against our prediction, shy individuals occupied relatively large home ranges but with small core areas. We suggest that this space use pattern is due to them avoiding risky, and energy-demanding competition for valuable resources. Carefully validated, activity measurements (ODBA) from accelerometers provide a valuable tool to quantify aspects of animal personality along the shy-bold continuum remotely. Without directly observing—and possibly disturbing—focal individuals, this approach allows measuring variability in animal personality, especially in species that are difficult to assess with experiments. Considering that accelerometers are often already built into GPS units, we recommend activating them at least during the initial days of tracking to estimate individual variation in general activity and, if possible, match them with a simple novelty experiment. Furthermore, information on individual behavioral types will help to facilitate mechanistic understanding of processes that drive spatial and ecological dynamics in heterogeneous landscapes.
Inverted perovskite solar cells still suffer from significant non-radiative recombination losses at the perovskite surface and across the perovskite/C₆₀ interface, limiting the future development of perovskite-based single- and multi-junction photovoltaics. Therefore, more effective inter- or transport layers are urgently required. To tackle these recombination losses, we introduce ortho-carborane as an interlayer material that has a spherical molecular structure and a three-dimensional aromaticity. Based on a variety of experimental techniques, we show that ortho-carborane decorated with phenylamino groups effectively passivates the perovskite surface and essentially eliminates the non-radiative recombination loss across the perovskite/C₆₀ interface with high thermal stability. We further demonstrate the potential of carborane as an electron transport material, facilitating electron extraction while blocking holes from the interface. The resulting inverted perovskite solar cells deliver a power conversion efficiency of over 23% with a low non-radiative voltage loss of 110 mV, and retain >97% of the initial efficiency after 400 h of maximum power point tracking. Overall, the designed carborane based interlayer simultaneously enables passivation, electron-transport and hole-blocking and paves the way toward more efficient and stable perovskite solar cells.
Development of chronic pain after a low back pain episode is associated with increased pain sensitivity, altered pain processing mechanisms and the influence of psychosocial factors. Although there is some evidence that multimodal therapy (such as behavioral or motor control therapy) may be an important therapeutic strategy, its long-term effect on pain reduction and psychosocial load is still unclear. Prospective longitudinal designs providing information about the extent of such possible long-term effects are missing. This study aims to investigate the long-term effects of a homebased uni- and multidisciplinary motor control exercise program on low back pain intensity, disability and psychosocial variables. 14 months after completion of a multicenter study comparing uni- and multidisciplinary exercise interventions, a sample of one study center (n = 154) was assessed once more. Participants filled in questionnaires regarding their low back pain symptoms (characteristic pain intensity and related disability), stress and vital exhaustion (short version of the Maastricht Vital Exhaustion Questionnaire), anxiety and depression experiences (the Hospital and Anxiety Depression Scale), and pain-related cognitions (the Fear Avoidance Beliefs Questionnaire). Repeated measures mixed ANCOVAs were calculated to determine the long-term effects of the interventions on characteristic pain intensity and disability as well as on the psychosocial variables. Fifty four percent of the sub-sample responded to the questionnaires (n = 84). Longitudinal analyses revealed a significant long-term effect of the exercise intervention on pain disability. The multidisciplinary group missed statistical significance yet showed a medium sized long-term effect. The groups did not differ in their changes of the psychosocial variables of interest. There was evidence of long-term effects of the interventions on pain-related disability, but there was no effect on the other variables of interest. This may be partially explained by participant's low comorbidities at baseline. Results are important regarding costless homebased alternatives for back pain patients and prevention tasks. Furthermore, this study closes the gap of missing long-term effect analysis in this field.
Organisms often employ ecophysiological strategies to exploit environmental conditions and ensure bio-energetic success. However, the many complexities involved in the differential expression and flexibility of these strategies are rarely fully understood. Therefore, for the first time, using a three-part cross-disciplinary laboratory experimental analysis, we investigated the diversity and plasticity of photoresponsive traits employed by one family of environmentally contrasting, ecologically important phytoflagellates. The results demonstrated an extensive inter-species phenotypic diversity of behavioural, physiological, and compositional photoresponse across the Chlamydomonadaceae, and a multifaceted intra-species phenotypic plasticity, involving a broad range of beneficial photoacclimation strategies, often attributable to environmental predisposition and phylogenetic differentiation. Deceptively diverse and sophisticated strong (population and individual cell) behavioural photoresponses were observed, with divergence from a general preference for low light (and flexibility) dictated by intra-familial differences in typical habitat (salinity and trophy) and phylogeny. Notably, contrasting lower, narrow, and flexible compared with higher, broad, and stable preferences were observed in freshwater vs. brackish and marine species. Complex diversity and plasticity in physiological and compositional photoresponses were also discovered. Metabolic characteristics (such as growth rates, respiratory costs and photosynthetic capacity, efficiency, compensation and saturation points) varied elaborately with species, typical habitat (often varying more in eutrophic species, such as Chlamydomonas reinhardtii), and culture irradiance (adjusting to optimise energy acquisition and suggesting some propensity for low light). Considerable variations in intracellular pigment and biochemical composition were also recorded. Photosynthetic and accessory pigments (such as chlorophyll a, xanthophyll-cycle components, chlorophyll a:b and chlorophyll a:carotenoid ratios, fatty acid content and saturation ratios) varied with phylogeny and typical habitat (to attune photosystem ratios in different trophic conditions and to optimise shade adaptation, photoprotection, and thylakoid architecture, particularly in freshwater environments), and changed with irradiance (as reaction and harvesting centres adjusted to modulate absorption and quantum yield). The complex, concomitant nature of the results also advocated an integrative approach in future investigations. Overall, these nuanced, diverse, and flexible photoresponsive traits will greatly contribute to the functional ecology of these organisms, addressing environmental heterogeneity and potentially shaping individual fitness, spatial and temporal distribution, prevalence, and ecosystem dynamics.
We investigate whether political ideology has an observable effect on decarbonization ambition, renewable power aims, and preferences for power system balancing technologies in four European countries. Based on the Energy Logics framework, we identify ideologically different transition strategies (state-centered, market-centered, grassroots-centered) contained in government policies and opposition party programs valid in 2019. We compare these policies and programs with citizen poll data. We find that ideology has a small effect: governments and political parties across the spectrum have similar, and relatively ambitious, decarbonization and renewables targets. This mirrors citizens' strong support for ambitious action regardless of their ideological self-description. However, whereas political positions on phasing out fossil fuel power are clear across the policy space, positions on phasing in new flexibility options to balance intermittent renewables are vague or non-existent. As parties and citizens agree on strong climate and renewable power aims, the policy ambition is likely to remain high, even if governments change.
Acquiring Syntactic Variability: The Production of Wh-Questions in Children and Adults Speaking Akan
(2020)
This paper investigates the predictions of the Derivational Complexity Hypothesis by studying the acquisition of wh-questions in 4- and 5-year-old Akan-speaking children in an experimental approach using an elicited production and an elicited imitation task. Akan has two types of wh-question structures (wh-in-situ and wh-ex-situ questions), which allows an investigation of children’s acquisition of these two question structures and their preferences for one or the other. Our results show that adults prefer to use wh-ex-situ questions over wh-in-situ questions. The results from the children show that both age groups have the two question structures in their linguistic repertoire. However, they differ in their preferences in usage in the elicited production task: while the 5-year-olds preferred the wh-in-situ structure over the wh-ex-situ structure, the 4-year-olds showed a selective preference for the wh-in-situ structure in who-questions. These findings suggest a developmental change in wh-question preferences in Akan-learning children between 4 and 5 years of age with a so far unobserved u-shaped developmental pattern. In the elicited imitation task, all groups showed a strong tendency to maintain the structure of in-situ and ex-situ questions in repeating grammatical questions. When repairing ungrammatical ex-situ questions, structural changes to grammatical in-situ questions were hardly observed but the insertion of missing morphemes while keeping the ex-situ structure. Together, our findings provide only partial support for the Derivational Complexity Hypothesis.
The knowledge of transformation pathways and identification of transformation products (TPs) of veterinary drugs is important for animal health, food, and environmental matters. The active agent Monensin (MON) belongs to the ionophore antibiotics and is widely used as a veterinary drug against coccidiosis in broiler farming. However, no electrochemically (EC) generated TPs of MON have been described so far. In this study, the online coupling of EC and mass spectrometry (MS) was used for the generation of oxidative TPs. EC-conditions were optimized with respect to working electrode material, solvent, modifier, and potential polarity. Subsequent LC/HRMS (liquid+ chromatography/high resolution mass spectrometry) and MS/MS experiments were performed to identify the structures of derived TPs by a suspected target analysis. The obtained EC-results were compared to TPs observed in metabolism tests with microsomes and hydrolysis experiments of MON. Five previously undescribed TPs of MON were identified in our EC/MS based study and one TP, which was already known from literature and found by a microsomal assay, could be confirmed. Two and three further TPs were found as products in microsomal tests and following hydrolysis, respectively. We found decarboxylation, O-demethylation and acid-catalyzed ring-opening reactions to be the major mechanisms of MON transformation
Dermal Delivery of the High-Molecular-Weight Drug Tacrolimus by Means of Polyglycerol-Based Nanogels
(2019)
Polyglycerol-based thermoresponsive nanogels (tNGs) have been shown to have excellent skin hydration properties and to be valuable delivery systems for sustained release of drugs into skin. In this study, we compared the skin penetration of tacrolimus formulated in tNGs with a commercial 0.1% tacrolimus ointment. The penetration of the drug was investigated in ex vivo abdominal and breast skin, while different methods for skin barrier disruption were investigated to improve skin permeability or simulate inflammatory conditions with compromised skin barrier. The amount of penetrated tacrolimus was measured in skin extracts by liquid chromatography tandem-mass spectrometry (LC-MS/MS), whereas the inflammatory markers IL-6 and IL-8 were detected by enzyme-linked immunosorbent assay (ELISA). Higher amounts of tacrolimus penetrated in breast as compared to abdominal skin or in barrier-disrupted as compared to intact skin, confirming that the stratum corneum is the main barrier for tacrolimus skin penetration. The anti-proliferative effect of the penetrated drug was measured in skin tissue/Jurkat cells co-cultures. Interestingly, tNGs exhibited similar anti-proliferative effects as the 0.1% tacrolimus ointment. We conclude that polyglycerol-based nanogels represent an interesting alternative to paraffin-based formulations for the treatment of inflammatory skin conditions.
The use of nano zerovalent iron (nZVI) for environmental remediation is a promising new technique for in situ remediation. Due to its high surface area and high reactivity, nZVI is able to dechlorinate organic contaminants and render them harmless. Limited mobility, due to fast aggregation and sedimentation of nZVI, limits the capability for source and plume remediation. Carbo-Iron is a newly developed material consisting of activated carbon particles (d50 = 0,8 µm) that are plated with nZVI particles. These particles combine the mobility of activated carbon and the reactivity of nZVI. This paper presents the first results of the transport experiments.
There has been a substantial increase in the percentage for publications with co-authors located in departments from different countries in 12 major journals of psychology. The results are evidence for a remarkable internationalization of psychological research, starting in the mid 1970s and increasing in rate at the beginning of the 1990s. This growth occurs against a constant number of articles with authors from the same country; it is not due to a concomitant increase in the number of co-authors per article. Thus, international collaboration in psychology is obviously on the rise.
Eye fixation durations during normal reading correlate with processing difficulty but the specific cognitive mechanisms reflected in these measures are not well understood. This study finds support in German readers’ eyefixations for two distinct difficulty metrics: surprisal, which reflects the change in probabilities across syntactic analyses as new words are integrated, and retrieval, which quantifies comprehension difficulty in terms of working memory constraints. We examine the predictions of both metrics using a family of dependency parsers indexed by an upper limit on the number of candidate syntactic analyses they retain at successive words. Surprisal models all fixation measures and regression probability. By contrast, retrieval does not model any measure in serial processing. As more candidate analyses are considered in parallel at each word, retrieval can account for the same measures as surprisal. This pattern suggests an important role for ranked parallelism in theories of sentence comprehension.
Parafoveal Load of Word N+1 Modulates Preprocessing Effectivenessof Word N+2 in Chinese Reading
(2010)
Preview benefits (PBs) from two words to the right of the fixated one (i.e., word N+2)and associated parafoveal-on-foveal effects are critical for proposals of distributed lexical processing during reading. This experiment examined parafoveal processing during reading of Chinese sentences, using a boundary manipulation of N+2-word preview with low- and high-frequency words N+1. The main findings were (a) an identity PB for word N+2 that was (b) primarily observed when word N+1 was of high frequency (i.e., an interaction between frequency of word N+1 and PB for word N+2), and (c) a parafoveal-on-foveal frequency effect of word N+1 for fixation durations on word N. We discuss implications for theories of serial attention shifts and parallel distributed processing of words during reading.
Am 8. August 2008 richtete sich alle mediale Aufmerksamkeit schlagartig von Beijing und den Olympischen Spielen auf den Kaukasus – genauer: auf Georgien. Unvorbereitet traf die Meldung über den Krieg im Kaukasus aber nur diejenigen, die glaubten, die „eingefrorenen Konflikte“ im Süden des Gebirgszuges seien beigelegt. Seit den Kriegen um die „abtrünnigen Teilrepubliken“ Georgiens, Südossetien und Abchasien, in den frühen 1990er Jahren sind diese jedoch nie zur Ruhe gekommen.
Wie beständig ist der Mythos „Barack Obama“? Klar ist: Der neue Präsident tritt ein schweres Erbe an. Herausforderungen wie die Wirtschaftskrise, schwierige außen- und sicherheitspolitische Gegebenheiten und die Beziehungen zu Russland warten auf ihn. Der Autor, ein exzellenter Kenner der USA und ehemaliger Diplomat, beleuchtet die Situation der Vereinigten Staaten nach der Wahl.
Prediction of hybrid biomass in Arabidopsis thaliana by selected parental SNP and metabolic markers
(2009)
A recombinant inbred line (RIL) population, derived from two Arabidopsis thaliana accessions, and the corresponding testcrosses with these two original accessions were used for the development and validation of machine learning models to predict the biomass of hybrids. Genetic and metabolic information of the RILs served as predictors. Feature selection reduced the number of variables (genetic and metabolic markers) in the models by more than 80% without impairing the predictive power. Thus, potential biomarkers have been revealed. Metabolites were shown to bear information on inherited macroscopic phenotypes. This proof of concept could be interesting for breeders. The example population exhibits substantial mid-parent biomass heterosis. The results of feature selection could therefore be used to shed light on the origin of heterosis. In this respect, mainly dominance effects were detected.
Microsaccades are very small, involuntary flicks in eye position that occur on average once or twice per second during attempted visual fixation. Microsaccades give rise to EMG eye muscle spikes that can distort the spectrum of the scalp EEG and mimic increases in gamma band power. Here we demonstrate that microsaccades are also accompanied by genuine and sizeable cortical activity, manifested in the EEG. In three experiments, high-resolution eye movements were corecorded with the EEG: during sustained fixation of checkerboard and face stimuli and in a standard visual oddball task that required the counting of target stimuli. Results show that microsaccades as small as 0.15° generate a field potential over occipital cortex and midcentral scalp sites 100 –140 ms after movement onset, which resembles the visual lambda response evoked by larger voluntary saccades. This challenges the standard assumption of human brain imaging studies that saccade-related brain activity is precluded by fixation, even when fully complied with. Instead, additional cortical potentials from microsaccades were present in 86% of the oddball task trials and of similar amplitude as the visual response to stimulus onset. Furthermore, microsaccade probability varied systematically according to the proportion of target stimuli in the oddball task, causing modulations of late stimulus-locked event-related potential (ERP) components. Microsaccades present an unrecognized source of visual brain signal that is of interest for vision research and may have influenced the data of many ERP and neuroimaging studies.
We examined individual differences in masked repetition priming by re-analyzing item-level response-time (RT) data from three experiments. Using a linear mixed model (LMM) with subjects and items specified as crossed random factors, the originally reported priming and word-frequency effects were recovered. In the same LMM, we estimated parameters describing the distributions of these effects across subjects. Subjects’ frequency and priming effects correlated positively with each other and negatively with mean RT. These correlation estimates, however, emerged only with a reciprocal transformation of RT (i.e., -1/RT), justified on the basis of distributional analyses. Different correlations, some with opposite sign, were obtained (1) for untransformed or logarithmic RTs or (2) when correlations were computed using within-subject analyses. We discuss the relevance of the new results for accounts of masked priming, implications of applying RT transformations, and the use of LMMs as a tool for the joint analysis of experimental effects and associated individual differences.
It has recently been demonstrated that the presentation of a rare target in a visual oddball paradigm induces a prolonged inhibition of microsaccades. In the field of electrophysiology, the amplitude of the P300 component in event-related potentials (ERP) has been shown to be sensitive to the stimulus category (target vs. non target) of the eliciting stimulus, its overall probability, and the preceding stimulus sequence. In the present study we further specify the functional underpinnings of the prolonged microsaccadic inhibition in the visual oddball task, showing that the stimulus category, the frequency of a stimulus and the preceding stimulus sequence influence microsaccade rate. Furthermore, by co-recording ERPs and eye-movements, we were able to demonstrate that, despite being largely sensitive to the same experimental manipulation, the amplitude of P300 and the microsaccadic inhibition predict each other very weakly, and thus constitute two independent measures of the brain’s response to rare targets in the visual oddball paradigm.
The effect of moderate rates of nitrogen deposition on ground floor vegetation is poorly predicted by uncontrolled surveys or fertilization experiments using high rates of nitrogen (N) addition. We compared the temporal trends of ground floor vegetation in permanent plots with moderate (7–13 kg ha−1 year−1) and lower bulk N deposition (4–6 kg ha−1 year−1) in southern Sweden during 1982–1998. We examined whether trends differed between growth forms (vascular plants and bryophytes) and vegetation types (three types of coniferous forest, deciduous forest, and bog). Trends of site-standardized cover and richness varied among growth forms, vegetation types, and deposition regions. Cover in spruce forests decreased at the same rate with both moderate and low deposition. In pine forests cover decreased faster with moderate deposition and in bogs cover decreased faster with low deposition. Cover of bryophytes in spruce forests increased at the same rate with both moderate and low deposition. In pine forests cover decreased faster with moderate deposition and in bogs and deciduous forests there was a strong non-linear increase with moderate deposition. The trend of number of vascular plants was constant with moderate and decreased with low deposition. We found no trend in the number of bryophyte species. We propose that the decrease of cover and number with low deposition was related to normal ecosystem development (increased shading), suggesting that N deposition maintained or increased the competitiveness of some species in the moderate-deposition region. Deposition had no consistent negative effect on vegetation suggesting that it is less important than normal successional processes.
Krise in Pakistan
(2008)
Atomare, biologische und chemische Waffen bedrohen das Überleben der Menschheit. Friedens- und Konfliktforscher Wolfgang Kötter aus Potsdam untersucht die differenzierten Ergebnisse bei der Beseitigung dieser Gefahr. Während die chemische Abrüstung, wenn auch mit Verzögerungen, voran kommt, fehlt dem Verbot der B-Waffen ein wirksames Kontrollinstrument. Atomare Waffen erleben sogar eine Renaissance und das nukleare Nichtverbreitungsregime droht zu zerbrechen.
Die Zukunft Osteuropas entscheidet sich im Spannungsfeld zwischen Russland und der EU. Die dortigen Staaten lösen sich aus der einseitigen Abhängigkeit eines erstarkten und seine Interessen im postsowjetischen Raum verteidigenden Russland. Ob die EU diese Chance in Osteuropa nutzen kann, hängt davon ab, ob sich die Mitgliedstaaten bereitfinden, ihre wirtschaftlichen und geopolitischen Interessen in der Region gemeinsam zu verfolgen.
Kaukasische Verwicklungen
(2008)
Blattgold : Pole Position
(2008)
A multitype Dawson-Watanabe process is conditioned, in subcritical and critical cases, on non-extinction in the remote future. On every finite time interval, its distribution is absolutely continuous with respect to the law of the unconditioned process. A martingale problem characterization is also given. Several results on the long time behavior of the conditioned mass process - the conditioned multitype Feller branching diffusion - are then proved. The general case is first considered, where the mutation matrix which models the interaction between the types, is irreducible. Several two-type models with decomposable mutation matrices are analyzed too .
Irans zunehmender Einfluss als Regionalmacht wird wegen seines Atomprogramms und seiner antiwestlichen Politik als Störfaktor bewertet. Die offensive Rhetorik Teherans zielt primär darauf ab, möglichen Gefahren entgegenzutreten. Westliche Politik sollte das allseitig bestehende Interesse an regionaler Stabilität nutzen, um seine ausschließlich auf Eindämmung bedachte Politik zu überwinden.
Demokratie, nicht Laizismus um jeden Preis : zu den inneren Auseinandersetzungen in der Türkei
(2008)
Die innergesellschaftlichen Auseinandersetzungen in der Türkei drehen sich nicht darum, ob der Laizismus fortbestehen oder beseitigt werden soll. Stattdessen findet im Land ein politischer Machtkampf statt. Dabei geht es für die alten kemalistischen Eliten ums politische Überleben. Für die Vertreter der neuen bürgerlichen, religiös-konservativen Mittelschicht hingegen geht es um ihre Zukunft in einer globalisierten Welt.
Seit den 1980er Jahren nehmen die neuen sozialen Bewegungen in Lateinamerika an Bedeutung rapide zu. Nachhaltige Transformationsprozesse auszulösen steht dabei seit den 1990er Jahren – in Zeiten neoliberaler Globalisierung und steigender Armut – im Zentrum gesellschaftlichen Handelns. Doch, angesichts der bestehenden globalen Strukturen, wie groß ist das Potenzial der neuen Welle sozialer Kräfte wirklich?
Türkei : Daten und Fakten
(2008)
Small livestock is an important resource for rural human populations in dry climates. How strongly will climate change affect the capacity of the rangeland? We used hierarchical modelling to scale quantitatively the growth of shrubs and annual plants, the main food of sheep and goats, to the landscape extent in the eastern Mediterranean region. Without grazing, productivity increased in a sigmoid way with mean annual precipitation. Grazing reduced productivity more strongly the drier the landscape. At a point just under the stocking capacity of the vegetation, productivity declined precipitously with more intense grazing due to a lack of seed production of annuals. We repeated simulations with precipitation patterns projected by two contrasting IPCC scenarios. Compared to results based on historic patterns, productivity and stocking capacity did not differ in most cases. Thus, grazing intensity remains the stronger impact on landscape productivity in this dry region even in the future.
Mit dem Vertrag von Lissabon verbinden sich hohe Erwartungen hinsichtlich der Effektivität zukünftiger Regelungen zum auswärtigen Handeln der Union. In der Gestaltung dieser Bestimmungen unterliegen die Mitgliedstaaten konstitutionellen Dilemmata, die eine Lösung erschweren. Obwohl im Detail durchaus Verbesserungen erkennbar sind, werden insgesamt zunehmende Konflikte und mangelnde Kohärenz erwartet.
Im Gespräch werden folgende Themen behandelt: WT: Welche politische Bilanz der Präsidentschaft Putins würden Sie ziehen? WT: Wie haben sich die soziale und wirtschafliche Lage sowie das geistige Klima in Russland während dieser Zeit verändert? WT: Wie beurteilen Sie die Persönlichkeit und das politische Konzept des neuen Präsidenten Dimitri Medwedjew? WT: Wie schätzen Sie die sich ankündigende „Tandem“-Variante der Machtausübung im künftigen Russland ein? Wird es einen starken Ministerpräsidenten Putin und einen zu diesem loyalen, sich gewissermaßen selbstbeschränkenden Präsidenten Medwedjew geben? Oder widerspricht das dem Charakter des Institutionensystems in Russland?
Geografie der Ungleichheit
(2008)
Bei N = 101 Arbeitnehmern verschiedener Berufe wurden mit der Experience Sampling Method (ESM) eine Woche lang Daten zum Flow-Erleben, zu Glück/Zufriedenheit und zur Zielausrichtung laufender Aktivitäten erhoben (N = 4603 Messungen). Die Daten wurden mit GLMM-Analysen ausgewertet. Auch bei der jetzt vollständigen Erfassung aller Flow-Komponenten mit der FKS bestätigte sich das „Paradoxon der Arbeit“, wonach während der Arbeit höhere Flow-Werte, aber niedrigere Werte für Glück/Zufriedenheit auftreten als jeweils in der Freizeit. Während der Arbeit waren Aktivitäten häufiger auf die Erreichung von Zielen ausgerichtet als während der Freizeit. Die Zielausrichtung wirkte auf Flow vs. Glück/Zufriedenheit signifikant verschieden. Während der Arbeit hat die Zielausrichtung auf Flow einen stark positiven Effekt, auf Glück/Zufriedenheit jedoch nicht. Im Freizeitbereich war der Effekt von Zielausrichtung auf Glück/Zufriedenheit sogar negativ. Das „Paradoxon der Arbeit“ lässt sich partiell als Effekt der Zielausrichtung verstehen.
Parsing costs as predictors of reading difficulty: An evaluation using the Potsdam Sentence Corpus
(2008)
The surprisal of a word on a probabilistic grammar constitutes a promising complexity metric for human sentence comprehension difficulty. Using two different grammar types, surprisal is shown to have an effect on fixation durations and regression probabilities in a sample of German readers’ eye movements, the Potsdam Sentence Corpus. A linear mixed-effects model was used to quantify the effect of surprisal while taking into account unigram and bigram frequency, word length, and empirically-derived word predictability; the so-called “early” and “late” measures of processing difficulty both showed an effect of surprisal. Surprisal is also shown to have a small but statistically non-significant effect on empirically-derived predictability itself. This work thus demonstrates the importance of including parsing costs as a predictor of comprehension difficulty in models of reading, and suggests that a simple identification of syntactic parsing costs with early measures and late measures with durations of post-syntactic events may be difficult to uphold.
The boundary paradigm (Rayner, 1975) with a novel preview manipulation was used to examine the extent of parafoveal processing of words to the right of fixation. Words n+1 and n+2 had either correct or incorrect previews prior to fixation (prior to crossing the boundary location). In addition, the manipulation utilized either a high or low frequency word in word n+1 location on the assumption that it would be more likely that n+2 preview effects could be obtained when word n+1 was high frequency. The primary findings were that there was no evidence for a preview benefit for word n+2 and no evidence for parafoveal-on-foveal effects when word n+1 is at least four letters long. We discuss implications for models of eye-movement control in reading.
Einerseits führt in Entwicklungsländern die Privatisierung von Wasserbetrieben zu Kostensenkungen. Andererseits verändert sie bisherige Möglichkeiten der Teilnahme. Diese wiederspruchsvollen Entwicklungen diskutiert die Autorin an Beispielen aus Südamerika und Südafrika. Künftige Privatisierungen im Bereich Wasser sollten dauerhafte Formen der Mitwirkung ermöglichen.
Militärmacht Deutschland?
(2007)
Die G8 und Chinas Interessen
(2007)
Die G8 besitzt aus chinesischer Sicht große Entwicklungsmöglichkeiten. Verglichen mit anderen zwischenstaatlichen Organisationen hat die G8 einzigartige Vorteile angesichts ihrer Macht und Flexibilität. Um ihren Einfluss und ihre Kontrolle über die Weltangelegenheiten zu verstärken, sollte die Gruppe reformiert und erweitert werden. China ist gegenwärtig nicht an einem Beitritt zur G8 interessiert, wohl aber an einer engen Zusammenarbeit. Langfristig ist es allerdings nur eine Frage der Zeit, bis China der G8 beitreten wird.
Wider den „euro-atlantischen Internationalismus“ : Berliner Republik und Entgrenzung der Bundeswehr
(2007)
Inhalt: Frieden mit aller Gewalt schaffen? Tatbestand: Staatsterrorismus Das Weißbuch 2006 Bundesverfassungsgericht versus Bundesverwaltungsgericht Weltweites Interventionsrecht Lizenz zum Völkerrechtsbruch „Re-Transformation“ der Bundeswehr Prinzipien für einen sicherheitspolitischen Grundkonsens Breite öffentliche Debatte notwendig
First studies of electron transfer in [N]phenylenes were performed in bimolecular quenching reactions of angular [3]- and triangular [4]phenylene with various electron acceptors. The relation between the quenching rate constants kq and the free energy change of the electron transfer (ΔG0CS ) could be described by the Rehm-Weller equation. From the experimental results, a reorganization energy λ of 0.7 eV was derived. Intramolecular electron transfer reactions were studied in an [N]phenylene bichomophore and a corresponding reference compound. Fluorescence lifetime and quantum yield of the bichromophor display a characteristic dependence on the solvent polarity, whereas the corresponding values of the reference compound remain constant. From the results, a nearly isoenergonic ΔG0CS can be determined. As the triplet quantum yield is nearly independent of the polarity, charge recombination leads to the population of the triplet state.
Indien und die G8
(2007)
Seit 2005 ist Indien als eines der fünf Outreach-Länder in die Diskussionen der G8 eingebunden. Dies geschah wegen seiner Rolle als eine der Kraftquellen der Weltwirtschaft sowie als viertgrößter globaler Markt. Indien betrachtet ein offenes Welthandelregime und einen größeren Kapitalfluss in die Entwicklungsländer als notwendig, um diesen zu helfen, deren Exporte zu steigern, neue Jobs zu schaffen und den Wohlstand ihrer Produzenten zu erhöhen.