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Southern Patagonia is a prime example of ongoing oceanic ridge collision and slab-window formation sustained over several million years. The impact of these phenomena on the thermal structure and exhumation of the crust have been mainly assessed with low-temperature thermochronology of bedrock samples. Here, we infer thermal histories from new and existing thermochronological data from the region of most recent ridge collision. In particular, we evaluate the potential far-reaching thermal effects of the evolving slab window, which have previously been considered responsible for patterns of late Miocene reheating associated with back-arc alkaline volcanism. Our model results define protracted cooling since similar to 15 Ma and stepwise exhumation since the late Miocene. The pattern of stepwise exhumation closely matches the onset of Patagonian glaciation at 7 Ma and the successive pulse of glacial incision coeval with neotectonic activity since 3-4 Ma that are also documented by independent geological and geomorphological evidence in the region. Importantly, our findings challenge the recently suggested lack of glacial erosion and incision since 5 Ma in this region. Furthermore, in contrast to previous modelling studies, we find that the available data do not evidence a previously proposed northward-propagating heating event associated with alkaline volcanism. We hypothesize that the anomalous alkaline volcanism in the Patagonian back-arc might be related to trench-orthogonal tears aligned with transform faults in the subducting plate. The substantial differences from the previous modelling procedure on some of the same samples is demonstrated to result from an important lack of convergence in model runs. (C) 2019 Elsevier B.V. All rights reserved.
The intermontane Humahuaca Basin in the Eastern Cordillera of the northwest Argentine Andes lies leeward of an orographic barrier to easterly derived moisture. An average of >2000 mm/yr of rainfall along the eastern flanks of the barrier contrasts with <200 mm/yr in the orogen interior. Paleoenvironmental reconstructions suggest that the basin became disconnected from the foreland during the Miocene-Pliocene by the growth of fault-bounded mountain ranges. Fossil records, sedimentology, and stable isotope data imply that rerouting of the fluvial network by 4.2 Ma and reduced rainfall by ca. 3 Ma were consequences of that range uplift. Here, we present cosmogenic nuclide-derived (Be-10) paleodenudation rates from 6 to 2 Ma fluvial deposits collected from the Humahuaca Basin. Despite increased tectonic activity, our Be-10 data show a tenfold decrease in denudation rates at ca. 3 Ma, documenting a link between uplift-induced semiarid conditions and decreasing hillslope denudation rates. This new data set thus demonstrates the influence of hydrological change on spatiotemporal denudation patterns in tectonically active mountain areas.
The Central Pontides of N Turkey represents a mobile orogenic belt of the southern Eurasian margin that experienced several phases of exhumation associated with the consumption of different branches of the Neo-Tethys Ocean and the amalgamation of continental domains. Our new low-temperature thermochronology data help to constrain the timing of these episodes, providing new insights into associated geodynamic processes. In particular, our data suggest that exhumation occurred at (1) similar to 110 to 90Ma, most likely during tectonic accretion and exhumation of metamorphic rocks from the subduction zone; (2) from similar to 60 to 40Ma, during the collision of the Kirehir and Anatolide-Tauride microcontinental domains with the Eurasian margin; (3) from similar to 0 to 25Ma, either during the early stages of the Arabia-Eurasia collision (soft collision) when the Arabian passive margin reached the trench, implying 70 to 530km of subduction of the Arabian passive margin, or during a phase of trench advance predating hard collision at similar to 20Ma; and (4) similar to 11Ma to the present, during transpression associated with the westward motion of Anatolia. Our findings document the punctuated nature of fault-related exhumation, with episodes of fast cooling followed by periods of slow cooling or subsidence, the role of inverted normal faults in controlling the Paleogene exhumation pattern, and of the North Anatolian Fault in dictating the most recent pattern of exhumation.
Terrestrial cosmogenic nuclide (TCN) concentrations in fluvial sediment, from which denudation rates are commonly inferred, can be affected by hillslope processes. TCN concentrations in gravel and sand may differ if localized, deep-excavation processes (e.g. landslides, debris flows) affect the contributing catchment, whereas the TCN concentrations of sand and gravel tend to be more similar when diffusional processes like soil creep and sheetwash are dominant. To date, however, no study has systematically compared TCN concentrations in different detrital grain-size fractions with a detailed inventory of hillslope processes from the entire catchment. Here we compare concentrations of the TCN Be-10 in 20 detrital sand samples from the Quebrada del Toro (southern Central Andes, Argentina) to a hillslope-process inventory from each contributing catchment. Our comparison reveals a shift from low-slope gullying and scree production in slowly denuding, low-slope areas to steep-slope gullying and landsliding in fast-denuding, steep areas. To investigate whether the nature of hillslope processes (locally excavating or more uniformly denuding) may be reflected in a comparison of the Be-10 concentrations of sand and gravel, we define the normalized sand-gravel index (NSGI) as the Be-10-concentration difference between sand and gravel divided by their summed concentrations. We find a positive, linear relationship between the NSGI and median slope, such that our NSGI values broadly reflect the shift in hillslope processes from low-slope gullying and scree production to steep-slope gullying and landsliding. Higher NSGI values characterize regions affected by steep-slope gullying or landsliding. We relate the large scatter in the relationship, which is exhibited particularly in low-slope areas, to reduced hillslope-channel connectivity and associated transient sediment storage within those catchments. While high NSGI values in well-connected catchments are a reliable signal of deep-excavation processes, hillslope excavation processes may not be reliably recorded by NSGI values where sediment experiences transient storage. (c) 2018 John Wiley & Sons, Ltd.
The Vicuna Pampa volcanic complex, at the SE edge of the arid Puna Plateau of the Central Andes, records the interplay between volcanic construction and degra-dational processes. The low-sloping Vicuna Pampa volcanic complex, with a 1200-m-deep, southeastward-opening depression, was previously interpreted as a collapse caldera based on morphological considerations. However, characteristic features associated with collapse calderas do not exist, and close inspection instead suggests that the Vicuna Pampa volcanic complex is a strongly eroded, broad, massif-type composite volcano of mainly basaltic to trachyandesitic composition. Construction of the Vicuna Pampa volcanic complex occurred during two distinct cycles separated by the development of the depression. The first and main cycle took place at ca. 12 Ma and was dominated by lava flows and subordinate scoria cones and domes. The second cycle, possibly late Miocene in age, affected the SW portion of the depression with the emplacement of domes. We interpret the central depression as the result of a possible sector collapse and subsequent intense fluvial erosion during middle to late Miocene time, facilitated by faulting, steepened topography, and wetter climate conditions compared to today. We estimate that similar to 65% of the initial edifice of similar to 240 km(3) was degraded. The efficiency of degradation processes for removing mass from the Vicuna Pampa volcanic complex is surprising, considering that today the region is arid, and the stream channels within the complex are predominantly transport limited, forming a series of coalesced, aggraded alluvial fans and eolian infill. Hence, the Vicuna Pampa volcanic complex records the effects of past degradation efficiency that differs substantially from that of today.
Fluvial fill terraces in intermontane basins are valuable geomorphic archives that can record tectonically and/or climatically driven changes of the Earth-surface process system. However, often the preservation of fill terrace sequences is incomplete and/or they may form far away from their source areas, complicating the identification of causal links between forcing mechanisms and landscape response, especially over multi-millennial timescales. The intermontane Toro Basin in the southern Central Andes exhibits at least five generations of fluvial terraces that have been sculpted into several-hundred-meter-thick Quaternary valley-fill conglomerates. New surface-exposure dating using nine cosmogenic Be-10 depth profiles reveals the successive abandonment of these terraces with a 100 kyr cyclicity between 75 +/- 7 and 487 +/- 34 ka. Depositional ages of the conglomerates, determined by four Al-26/Be-10 burial samples and U-Pb zircon ages of three intercalated volcanic ash beds, range from 18 +/- 141 to 936 +/- 170 ka, indicating that there were multiple cut-and-fill episodes. Although the initial onset of aggradation at similar to 1 Ma and the overall net incision since ca. 500 ka can be linked to tectonic processes at the narrow basin outlet, the superimposed 100 kyr cycles of aggradation and incision are best explained by eccentricity-driven climate change. Within these cycles, the onset of river incision can be correlated with global cold periods and enhanced humid phases recorded in paleoclimate archives on the adjacent Bolivian Altiplano, whereas deposition occurred mainly during more arid phases on the Altiplano and global interglacial periods. We suggest that enhanced runoff during global cold phases - due to increased regional precipitation rates, reduced evapotranspiration, or both - resulted in an increased sediment-transport capacity in the Toro Basin, which outweighed any possible increases in upstream sediment supply and thus triggered incision. Compared with two nearby basins that record precessional (21-kyr) and long-eccentricity (400-kyr) forcing within sedimentary and geomorphic archives, the recorded cyclicity scales with the square of the drainage basin length. (C) 2017 Elsevier B.V. All rights reserved.
The African Humid Period (AHP) between similar to 15 and 5.5 cal. kyr BP caused major environmental change in East Africa, including filling of the Suguta Valley in the northern Kenya Rift with an extensive (similar to 2150 km(2)), deep (similar to 300 m) lake. Interfingering fluvio-lacustrine deposits of the Baragoi paleo-delta provide insights into the lake-level history and how erosion rates changed during this time, as revealed by delta-volume estimates and the concentration of cosmogenic Be-10 in fluvial sand. Erosion rates derived from delta-volume estimates range from 0.019 to 0.03 mm yr(-1). Be-10-derived paleo-erosion rates at similar to 11.8 cal. kyr BP ranged from 0.035 to 0.086 mm yr(-1), and were 2.7 to 6.6 times faster than at present. In contrast, at similar to 8.7 cal. kyr BP, erosion rates were only 1.8 times faster than at present. Because Be-10-derived erosion rates integrate over several millennia; we modeled the erosion-rate history that best explains the 10Be data using established non-linear equations that describe in situ cosmogenic isotope production and decay. Two models with different temporal constraints (15-6.7 and 12-6.7 kyr) suggest erosion rates that were 25 to 300 times higher than the initial erosion rate (pre-delta formation). That pulse of high erosion rates was short (similar to 4 kyr or less) and must have been followed by a rapid decrease in rates while climate remained humid to reach the modern Be-10-based erosion rate of,similar to 0.013 mm yr(-1). Our simulations also flag the two highest Be-10-derived erosion rates at 11.8 kyr BP related to nonuniform catchment erosion. These changes in erosion rates and processes during the AHP may reflect a strong increase in precipitation, runoff, and erosivity at the arid-to-humid transition either at 15 or similar to 12 cal. kyr BP, before the landscape stabilized again, possibly due to increased soil production and denser vegetation.
The subduction of bathymetric anomalies at convergent margins can profoundly affect subduction dynamics, magmatism, and the structural and geomorphic evolution of the overriding plate. The Northern Patagonian Icefield (NPI) is located east of the Chile Triple Junction at similar to 47 degrees S, where the Chile Rise spreading center collides with South America. This region is characterized by an abrupt increase in summit elevations and relief that has been controversially debated in the context of geodynamic versus glacial erosion effects on topography. Here we present geomorphic, thermochronological, and structural data that document neotectonic activity along hitherto unrecognized faults along the flanks of the NPI. New apatite (U-Th)/He bedrock cooling ages suggest faulting since 2-3 Ma. We infer the northward translation of an similar to 140 km long fore-arc sliver-the NPI block-results from enhanced partitioning of oblique plate convergence due to the closely spaced collision of three successive segments of the Chile Rise. In this model, greater uplift occurs in the hanging wall of the Exploradores thrust at the northern leading edge of the NPI block, whereas the Cachet and Liquine-Ofqui dextral faults decouple the NPI block along its eastern and western flanks, respectively. Localized extension possibly occurs at its southern trailing edge along normal faults associated with margin-parallel extension, tectonic subsidence, and lower elevations along the Andean crest line. Our neotectonic model provides a novel explanation for the abrupt topographic variations inland of the Chile Triple Junction and emphasizes the fundamental effects of local tectonics on exhumation and topographic patterns in this glaciated landscape.
This paper is mainly based on field work carried out on the Messinian deposits of the Adana Basin ( southern Turkey), as well as on the interpretation of seismic reflection profiles to understand 3D geometries of the basin fill. Chronostratigraphic constraints for the Messinian deposits are from micropaleontological studies on foraminifera, ostracods, and calcareous nannofossils, recently carried out on the Messinian deposits of the Adana Basin. Our results indicate that this basin developed in a marginal area strictly related to the Mediterranean realm. The Messinian deposits of the Adana Basin record all the main steps of the Messinian Salinity Crisis ( MSC) that affected the Mediterranean area at the end of the Miocene. The new stratigraphic model for the Messinian deposits of the Adana Basin provided in this work gives new insights into both the MSC and the Taurus petroleum system. Despite their complete correspondence with the MSC, the Messinian deposits of the Adana Basin show some differences with respect to the current conceptual model for the MSC. For example, in the current conceptual model for the MSC, only one regional erosional surface ( MES) characterizes the MSC deposits. In the Adana Basin, two regional erosional surfaces, named MES1 and MES2, separate the Messinian deposits related to the MSC in Lower Evaporites, Resedimented Lower Evaporites ( RLE), and upper Messinian continental deposits containing a late Lago-Mare ostracod assemblage ( mainly fluvial coarse-grained and fine-grained sediments). In some places, Brecciated Limestones lie just above the MES1 and beneath the RLE. In addition, the RLE are thought to be related to the same step that brought to the Messinian halite deposition throughout the Mediterranean, pointing to a hyperhaline environment. In contrast, the fine-grained deposits of the RLE of the Adana Basin show the occurrence of Parathetyan brackish ostracod fauna ( early Lago-Mare ostracod assemblages), which defines an oligohaline depositional environment for the RLE. In terms of hydrocarbon prospecting, the Messinian evaporites of the Adana Basin have been considered as a perfect seal for the active Taurus petroleum system. Our results show that due to the complex stratigraphic architecture of the basin fill and the occurrence of two regional erosional surfaces ( MES1 and MES2), the Messinian evaporites are discontinuously present both in surface and in the subsurface of the Adana Basin. However, seal properties in the Adana Basin could be found in the Lower Pliocene deep marine clays of the Avadan Formation. This work leads to suggest a new stratigraphical model for the Messinian deposits of the Adana Basin, allowing us to amend the classical scheme with respect to the Messinian, and to officially define some new formations within the stratigraphy of the Adana Basin.
Deciphering the response of sediment routing systems to climatic forcing is fundamental for understanding the impacts of climate change on landscape evolution. In the Kangra Basin (northwest Sub-Himalaya, India), upper Pleistocene to Holocene alluvial fills and fluvial terraces record periodic fluctuations of sediment supply and transport capacity on timescales of 10(3) to 10(5) yr. To evaluate the potential influence of climate change on these fluctuations, we compare the timing of aggradation and incision phases recorded within remnant alluvial fans and terraces with climate archives. New surface-exposure dating of six terrace levels with in-situ cosmogenic Be-10 indicates the onset of incision phases. Two terrace surfaces from the highest level (T1) sculpted into the oldest preserved alluvial fan (AF1) date back to 53.4 +/- 3.2 ka and 43.0 +/- 2.7 ka (1 sigma). T2 surfaces sculpted into the remnants of AF1 have exposure ages of 18.6 +/- 1.2 ka and 15.3 +/- 0.9 ka, while terraces sculpted into the upper Pleistocene-Holocene fan (AF2) provide ages of 9.3 +/- 0.4 ka (T3), 7.1 +/- 0.4 ka (T4), 5.2 +/- 0.4 ka (T5) and 3.6 +/- 0.2 ka (T6). Together with previously published OSL ages yielding the timing of aggradation, we find a correlation between variations in sediment transport with oxygen-isotope records from regions affected by the Indian Summer Monsoon. During periods of increased monsoon intensity and post-Last Glacial Maximum glacial retreat, aggradation occurred in the Kangra Basin, likely due to high sediment flux, whereas periods of weakened monsoon intensity or lower sediment supply coincide with incision. (C) 2016 Elsevier B.V. All rights reserved.
The southernmost thrust of the Himalayan orogenic wedge that separates the foreland from the orogen, the Main Frontal Thrust, is thought to accommodate most of the ongoing crustal shortening in the Sub-Himalaya. Steepened longitudinal river profile segments, terrace offsets, and back-tilted fluvial terraces within the Kangra reentrant of the NW Sub-Himalaya suggest Holocene activity of the Jwalamukhi Thrust (JMT) and other thrust faults that may be associated with strain partitioning along the toe of the Himalayan wedge. To assess the shortening accommodated by the JMT, we combine morphometric terrain analyses with in situ Be-10-based surface-exposure dating of the deformed terraces. Incision into upper Pleistocene sediments within the Kangra Basin created two late Pleistocene terrace levels (T1 and T2). Subsequent early Holocene aggradation shortly before similar to 10ka was followed by episodic reincision, which created four cut-and-fill terrace levels, the oldest of which (T3) was formed at 10.10.9ka. A vertical offset of 445m of terrace T3 across the JMT indicates a shortening rate of 5.60.8 to 7.51.1mma(-1) over the last similar to 10ka. This result suggests that thrusting along the JMT accommodates 40-60% of the total Sub-Himalayan shortening in the Kangra reentrant over the Holocene. We speculate that this out-of-sequence shortening may have been triggered or at least enhanced by late Pleistocene and Holocene erosion of sediments from the Kangra Basin.
Climatic controls on debris-flow activity and sediment aggradation: The Del Medio fan, NW Argentina
(2016)
In the Central Andes, several studies on alluvial terraces and valley fills have linked sediment aggradation to periods of enhanced sediment supply. However, debate continues over whether tectonic or climatic factors are most important in triggering the enhanced supply. The Del Medio catchment in the Humahuaca Basin (Eastern Cordillera, NW Argentina) is located within a transition zone between subhumid and arid climates and hosts the only active debris-flow fan within this intermontane valley. By combining Be-10 analyses of boulder and sediment samples within the Del Medio catchment, with regional morphometric measurements of nearby catchments, we identify the surface processes responsible for aggradation in the Del Medio fan and their likely triggers. We find that the fan surface has been shaped by debris flows and channel avulsions during the last 400 years. Among potential tectonic, climatic, and autogenic factors that might influence deposition, our analyses point to a combination of several favorable factors that drive aggradation. These are in particular the impact of occasional abundant rainfall on steep slopes in rock types prone to failure, located in a region characterized by relatively low rainfall amounts and limited transport capacity. These characteristics are primarily associated with the climatic transition zone between the humid foreland and the arid orogen interior, which creates an imbalance between sediment supply and sediment transfer. The conditions and processes that drive aggradation in the Del Medio catchment today may provide a modern analog for the conditions and processes that drove aggradation in other nearby tributaries in the past.
Fluvial fill terraces preserve sedimentary archives of landscape responses to climate change, typically over millennial timescales. In the Humahuaca Basin of NW Argentina (Eastern Cordillera, southern Central Andes), our 29 new optically stimulated luminescence ages of late Pleistocene fill terrace sediments demonstrate that the timing of past river aggradation occurred over different intervals on the western and eastern sides of the valley, despite their similar bedrock lithology, mean slopes, and precipitation. In the west, aggradation coincided with periods of increasing precipitation, while in the east, aggradation coincided with decreasing precipitation or more variable conditions. Erosion rates and grain size dependencies in our cosmogenic Be-10 analyses of modern and fill terrace sediments reveal an increased importance of landsliding compared to today on the west side during aggradation, but of similar importance during aggradation on the east side. Differences in the timing of aggradation and the Be-10 data likely result from differences in valley geometry, which causes sediment to be temporarily stored in perched basins on the east side. It appears as if periods of increasing precipitation triggered landslides throughout the region, which induced aggradation in the west, but blockage of the narrow bedrock gorges downstream from the perched basins in the east. As such, basin geometry and fluvial connectivity appear to strongly influence the timing of sediment movement through the system. For larger basins that integrate subbasins with differing geometries or degrees of connectivity (like Humahuaca), sedimentary responses to climate forcing are likely attenuated.
The idea that climatically modulated erosion may impact orogenic processes has challenged geoscientists for decades. Although modeling studies and physical calculations have provided a solid theoretical basis supporting this interaction, to date, field-based work has produced inconclusive results. The central-western Alborz Mountains in the northern sectors of the Arabia-Eurasia collision zone constitute a promising area to explore these potential feedbacks. This region is characterized by asymmetric precipitation superimposed on an orogen with a history of spatiotemporal changes in exhumation rates, deformation patterns, and prolonged, km-scale base-level changes. Our analysis suggests that despite the existence of a strong climatic gradient at least since 17.5 Ma, the early orogenic evolution (from similar to 36 to 9-6 Ma) was characterized by decoupled orographic precipitation and tectonics. In particular, faster exhumation and sedimentation along the more arid southern orogenic flank point to a north-directed accretionary flux and underthrusting of Central Iran. Conversely, from 6 to 3 Ma, erosion rates along the northern orogenic flank became higher than those in the south, where they dropped to minimum values. This change occurred during a similar to 3-Myr-long, km-scale base-level lowering event in the Caspian Sea. We speculate that mass redistribution processes along the northern flank of the Alborz and presumably across all mountain belts adjacent to the South Caspian Basin and more stable areas of the Eurasian plate increased the sediment load in the basin and ultimately led to the underthrusting of the Caspian Basin beneath the Alborz Mountains. This underthrusting in turn triggered a new phase of northward orogenic expansion, transformed the wetter northern flank into a new pro-wedge, and led to the establishment of apparent steady-state conditions along the northern orogenic flank (i.e., rock uplift equal to erosion rates). Conversely, the southern mountain front became the retro-wedge and experienced limited tectonic activity. These observations overall raise the possibility that mass-distribution processes during a pronounced erosion phase driven by base-level changes may have contributed to the inferred regional plate-tectonic reorganization of the northern Arabia-Eurasia collision during the last similar to 5 Ma. (C) 2015 Elsevier B.V. All rights reserved.
The mechanisms by which climate and vegetation affect erosion rates over various time scales lie at the heart of understanding landscape response to climate change. Plot-scale field experiments show that increased vegetation cover slows erosion, implying that faster erosion should occur under low to moderate vegetation cover. However, demonstrating this concept over long time scales and across landscapes has proven to be difficult, especially in settings complicated by tectonic forcing and variable slopes. We investigate this problem by measuring cosmogenic Be-10-derived catchment-mean denudation rates across a range of climate zones and hillslope gradients in the Kenya Rift, and by comparing our results with those published from the Rwenzori Mountains of Uganda. We find that denudation rates from sparsely vegetated parts of the Kenya Rift are up to 0.13 mm/yr, while those from humid and more densely vegetated parts of the Kenya Rift flanks and the Rwenzori Mountains reach a maximum of 0.08 mm/yr, despite higher median hillslope gradients. While differences in lithology and recent land-use changes likely affect the denudation rates and vegetation cover values in some of our studied catchments, hillslope gradient and vegetation cover appear to explain most of the variation in denudation rates across the study area. Our results support the idea that changing vegetation cover can contribute to complex erosional responses to climate or land-use change and that vegetation cover can play an important role in determining the steady-state slopes of mountain belts through its stabilizing effects on the land surface.
A valley-filling ignimbrite re-exposed through subsequent river incision at the southern margin of the Andean (Puna) plateau preserves pristine geological evidence of pre-late Miocene palaeotopography in the north western Argentine Andes. Our new Ar-40/(39) Ar dating of the Las Papas Ignimbrites yields a plateau age of 9.24 +/- 0.03 Ma, indicating valley-relief and orographic-barrier conditions comparable to the present-day. A later infill of Plio-Pleistocene coarse conglomerates has been linked to wetter conditions, but resulted in no additional net incision of the Las Papas valley, considering that the base of the ignimbrite remains unexposed in the valley bottom. Our observations indicate that at least 550 m of local plateau margin relief (and likely > 2 km) existed by 9 Ma at the southern Puna margin, which likely aided the efficiency of the orographic barrier to rainfall along the eastern and south eastern flanks of the Puna and causes aridity in the plateau interior.
Sr isotope records from marginal marine basins track the mixing between seawater and local continental runoff, potentially recording the effects of sea level, tectonic, and climate forcing in marine fossils and sediments. Our 110 new Sr-87/Sr-86 analyses on oyster and foraminifera samples from six late Miocene stratigraphic sections in southern Turkey, Crete, and Sicily show that Sr-87/Sr-86 fell below global seawater values in the basins several million years before the Messinian Salinity Crisis, coinciding with tectonic uplift and basin shallowing. 87Sr/86Sr from more centrally located basins (away from the Mediterranean coast) drop below global seawater values only during the Messinian Salinity Crisis. In addition to this general trend, 55 new Sr-87/Sr-86 analyses from the astronomically tuned Lower Evaporites in the central Apennines (Italy) allow us to explore the effect of glacio-eustatic sea level and precipitation changes on Sr-87/Sr-86. Most variation in our data can be explained by changes in sea level, with greatest negative excursions from global seawater values occurring during relative sea level lowstands, which generally coincided with arid conditions in the Mediterranean realm. We suggest that this greater sensitivity to lowered sea level compared with higher runoff could relate to the inverse relationship between Sr concentration and river discharge. Variations in the residence time of groundwater within the karst terrain of the circum-Mediterranean region during arid and wet phases may help to explain the single (robust) occurrence of a negative excursion during a sea level highstand, but this explanation remains speculative without more detailed paleoclimatic data for the region.