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Ancient evaporite deposits are geological archives of depositional environments characterized by a long‐term negative precipitation balance and bear evidence for global ocean element mass balance calculations. Here, Cretaceous selenite pseudomorphs from western Anatolia (‘Rosetta Marble’) — characterized by their exceptional morphological preservation — and their ‘marine’ geochemical signatures are described and interpreted in a process‐oriented context. These rocks recorded Late Cretaceous high‐pressure/low‐temperature, subduction‐related metamorphism with peak conditions of 1·0 to 1·2 GPa and 300 to 400°C. Metre‐scale, rock‐forming radiating rods, now present as fibrous calcite marble, clearly point to selenitic gypsum as the precursor mineral. Stratigraphic successions are recorded along a reconstructed proximal to distal transect. The cyclical alternation of selenite beds and radiolarian ribbon‐bedded cherts in the distal portions are interpreted as a two type of seawater system. During arid intervals, shallow marine brines cascaded downward into basinal settings and induced precipitation. During more humid times, upwelling‐induced radiolarian blooms caused the deposition of radiolarite facies. Interestingly, there is no comparable depositional setting known from the Cenozoic world. Meta‐selenite geochemical data (δ13C, δ18O and 87Sr/86Sr) plot within the range of reconstructed middle Cretaceous seawater signatures. Possible sources for the 13C‐enriched (mean 2·2‰) values include methanogenesis, gas hydrates and cold seep fluid exhalation. Spatially resolved component‐specific analysis of a rock slab displays isotopic variances between meta‐selenite crystals (mean δ13C 2·2‰) and host matrix (mean δ13C 1·3‰). The Cretaceous evaporite‐pseudomorphs of Anatolia represent a basin wide event coeval with the Aptian evaporites of the Proto‐Atlantic and the pseudomorphs share many attributes, including lateral distribution of 600 km and stratigraphic thickness of 1·5 to 2·0 km, with the evaporites formed during the younger Messinian salinity crisis. The Rosetta Marble of Anatolia may represent the best‐preserved selenite pseudomorphs worldwide and have a clear potential to act as a template for the study of meta‐selenite in deep time.
A new occurrence of eclogites was found in the Kesandere valley in the eastern most part of the Bitlis complex, SE Anatolia. These high-pressure (HP) relics were preserved in calc-arenitic metasediments within the high-grade metamorphic basement of the Bitlis complex. The eclogitic parageneses were strongly overprinted during decompression and heating. These new eclogites locality complements the evidence of blueschist-facies metamorphism documented recently in the meta-sedimentary cover sequence of this part of the Bitlis complex. Thermodynamic calculations suggest peak conditions of ca. 480-540 degrees C/1.9-2.4GPa. New U/Pb dates of 84.4 +/-.9 and 82.4 +/-.9Ma were obtained on zircons from two Kesandere eclogite samples. On the basis of geochemical criteria, these dates are interpreted to represent zircon crystallization during the eclogitic peak stage. Kesandere eclogites differ from those previously described in the western Bitlis complex (Mt. Gablor locality) in terms of lithologic association, protolithic origin, and peak P-T conditions (600-650 degrees C/1.0-2.0GPa, respectively). On the other hand, eclogitic metamorphism of Kesandere metasediments occurred shortly before blueschist-facies metamorphism of the sedimentary cover (79-74Ma Ar-40/Ar-39 white mica). Therefore, the exhumation of Kesandere eclogites started between ca. 82 and 79Ma, while the meta-sedimentary cover was being buried. During this short time span, Kesandere eclogite were likely uplifted from similar to 65 to 35km depth, indicating a syn-subduction exhumation rate of similar to 4.3mm/a. Subsequently, eclogite- and blueschist-facies rocks were likely retrogressed contemporarily during collision-type metamorphism (around 72-69Ma). The Bitlis HP rocks thus sample a subduction zone that separated the Bitlis-Puturge (Bistun?) block from the South-Armenian block, further north. To the south, Eocene metasediments of the Urse formation are imbricated below the Bitlis complex. They contain (post Eocene) blueschists, testifying separation from the Arabian plate and southward migration of the subduction zone. The HT overprint of Kesandere eclogites can be related to the asthenospheric flow provoked by subducting slab retreat or break off.
The Menderes Massif, exposed in western Anatolia, is a metamorphic complex cropping out in the Alpine orogenic belt. The metamorphic rock succession of the Massif is made up of a Precambrian basement and overlying Paleozoic-early Tertiary cover series. The Pan-African basement is composed of late Proterozoic metasedimentary rocks consisting of partially migmatized paragneisses and conformably overlying medium- to high-grade mica schists, intruded by orthogneisses and metagabbros. Along the southern flank of the southern submassif, we recognized well-preserved primary contact relationship between biotite and leucocratic tourmaline orthogneisses and country rocks as the orthogneisses represent numerous large plutons, stocks and vein rocks intruded into a basement of garnet mica schists. Based on the radiometric data, the primary deposition age of the precursors of the country rocks, garnet mica schist, can be constrained between 600 and 550 Ma (latest Neoproterozoic). The North Africa-Arabian-Nubian Shield in the Mozambique Belt can be suggested as the possible provenance of these metaclastics. The intrusion ages of the leucocratic tourmaline orthogneisses and biotite orthogneisses were dated at 550-540 Ma (latest Neoproterozoic-earliest Cambrian) by zircon U/Pb and Pb/Pb geochronology. These granitoids represent the products of the widespread Pan-African acidic magmatic activity, which can be attributed to the closure of the Mozambique Ocean during the final collision of East and West Gondwana. Detrital zircon ages at about 550 Ma in the Paleozoic muscovite-quartz schists show that these Pan-African granitoids in the basement form the source rocks of the cover series of the Menderes Massif.
We provide new insights into the prograde evolution of HP/LT metasedimentary rocks on the basis of detailed petrologic examination, element-partitioning analysis, and thermodynamic modelling of well-preserved Fe-Mg-carpholite- and Fe-Mg-chloritoid-bearing rocks from the Afyon Zone (Anatolia). We document continuous and discontinuous compositional (ferromagnesian substitution) zoning of carpholite (overall X-Mg = 0.27-0.73) and chloritoid (overall X-Mg = 0.07-0.30), as well as clear equilibrium and disequilibrium (i.e., reaction-related) textures involving carpholite and chloritoid, which consistently account for the consistent enrichment in Mg of both minerals through time, and the progressive replacement of carpholite by chloritoid. Mg/Fe distribution coefficients calculated between carpholite and chloritoid vary widely within samples (2.2-20.0). Among this range, only values of 7-11 correlate with equilibrium textures, in agreement with data from the literature. Equilibrium phase diagrams for metapelitic compositions are calculated using a newly modified thermodynamic dataset, including most recent data for carpholite, chloritoid, chlorite, and white mica, as well as further refinements for Fe-carpholite, and both chloritoid end-members, as required to reproduce accurately petrologic observations (phase relations, experimental constraints, Mg/Fe partitioning). Modelling reveals that Mg/Fe partitioning between carpholite and chloritoid is greatly sensitive to temperature and calls for a future evaluation of possible use as a thermometer. In addition, calculations show significant effective bulk composition changes during prograde metamorphism due to the fractionation of chloritoid formed at the expense of carpholite. We retrieve P-T conditions for several carpholite and chloritoid growth stages (1) during prograde stages using unfractionated, bulk-rock XRF analyses, and (2) at peak conditions using compositions fractionated for chloritoid. The P-T paths reconstructed for the Kutahya and Afyon areas shed light on contrasting temperature conditions for these areas during prograde and peak stages.
The Karaburun Peninsula, which is considered part of the Anatolide-Tauride Block of Turkey, contains clastic and carbonate sequences deposited on the northern margin of Gondwana. The Palaeozoic clastic sequence, which is intruded by the Early Triassic granitoid and tectonically overlies a Mesozoic melange sequence, can be divided into three subunits: a lower clastic subunit consisting of a sandstone-shale alternation, an upper clastic subunit consisting of black chert-bearing shales, sandstone and conglomerate, and a Permo-Carboniferous carbonate subunit. The lower Triassic Karaburun I-type granitoid has a high initial Sr-87/Sr-86 ratio (0.709021-0.709168), and low Nd-143/Nd-144 ratio (0.512004-0.512023) and epsilon Nd (-5.34 to -5.70) isotopic values. Geochronological data indicate a crystallization (intrusion) age of 247.1 +/- 2.0 Ma (Scythian). Geochemically, the acidic magmatism reflects a subduction-related continental-arc basin tectonic setting, which can be linked to the opening of the northern branch of Neo-Tethys as a continental back-arc rifting basin on the northern margin of Gondwana. This can be related to the closure through southward subduction of the Palaeotethys Ocean beneath Gondwana.
Afyon Zone, which was derived from the Anatolide-Tauride platform during closure of the Neo-Tethys, is made up of pre-Mesozoic basement and unconformably overlying Triassic-Early Tertiary cover series. The Afyon Zone contains widespread metavolcanic rocks, which are dominated by rhyolite, dacite, and trachyandesite. They form a distinct volcanic succession, which is separated from the underlying Silurian-Lower Carboniferous metacarbonates and meta-siliciclastics by a regional unconformity. Trachyandesitic metavolcanics are made up of massive lava flows, pyroclastics and epiclastics, less frequently, domes and dikes, which were developed on a deeply eroded subaerial landmass. U/Pb and Pb/Pb zircon geochronology yielded Lower Triassic (similar to 250 Ma) ages, which are interpreted as extrusion age of trachyandesitic volcanics. Based on the stratigraphic, geochronological, and geochemical data, we suggest that these Lower Triassic magmatic rocks represent an extensional tectonic setting on the northern active margin of the Gondwana, which led to the development of the northern branch of the Neo-Tethys.
Metamorphic studies in the cover sequences of the Bitlis complex allow the thermal evolution of the massif to be constrained using metamorphic index minerals. Regionally distributed metamorphic index minerals such as glaucophane, carpholite, relics of carpholite in chloritoid-bearing schists and pseudomorphs after aragonite in marbles record a LT-HP evolution:This demonstrates that the Bitlis complex was subducted and stacked to form a nappe complex during the closure of the Neo-Tethys. During late Cretaceous to Cenozoic evolution the Bitlis complex experienced peak metamorphism of 1.0-1.1 GPa at 350-400 degrees C. During the retrograde evolution temperatures remained below 460 degrees C. Ar-39/Ar-40 dating of white mica in different parageneses from the Bitlis complex reveals a 74-79 Ma (Campanian) date of peak metamorphism and rapid exhumation to an almost isothermal greenschist stage at 67-70 Ma (Maastrichtian). The HP Eocene flysch escaped the greenschist facies stage and were exhumed under very cold conditions. These single stage evolutions contrast with the multistage evolution reported further north from the Amassia-Stepanavan Suture in Armenia. Petrological investigations and isotopic dating show that the collision of Arabia with Eurasia resulted in an assemblage of different blocks derived from the northern as well as from the southern plate and a set of subduction zones producing HP rocks with diverse exhumation histories.
Well-preserved primary contact relationships between a Late Proterozoic metasedimentary and the metagranitic core and Palaeozoic cover series of the Menderes Massif have been recognized in the eastern part of the Cine submassif on a regional-scale. Metaconglomerates occur as laterally discontinuous channel-fill bodies close the base of the metaquartzarenite directly above the basement. The pebbles in the metaconglomerates consist mainly of different types of tourmaline-rich leucocratic granitoids, tourmalinite and schist in a sandy matrix. Petrographic features, geochemical compositions and zircon radiometric ages (549.6 +/- 3.7-552.3 +/- 3.1 Ma) of the diagnostic clasts of the metaconglomerates (e.g. leucocratic granitoids and tourmalinites) show excellent agreement with their in situ equivalents (549.0 +/- 5.4 Ma) occurring in the Pan-African basement as stocks and veins.
The correlation between clasts in the metaconglomerates and granitoids of the basement suggests that the primary contact between the basement and cover series is a regional unconformity (supra-Pan-African Unconformity) representing deep erosion of the Pan-African basement followed by the deposition of the cover series. Hence the usage of 'core-cover' terminology in the Menderes Massif is valid. Consequently, these new data preclude the views that the granitic precursors of the leucocratic orthogneisses are Tertiary intrusions.
This study shows Lu-Hf geochronology of zoned garnet crystals contained in mica schists from the southern Menderes Massif, Turkey. Selected samples are four 3-5 cm large garnet megacrysts of which several consecutive garnet shells have been sampled with a micro-saw and analyzed for dating. The results are used to extract growth rates of garnet, and also to improve the time constraint for Alpine-aged overprint of the Pan-African basement in the Menderes Massif.
The new data provides a precise age determination for prograde Barrovian metamorphism in the southern Menderes Massif, which so far was placed between 63 and 27 Ma on the basis of mica Rb-Sr and Ar-Ar dating. This study provides new constraints crucial to the understanding of the tectonic evolution of southwest Anatolia and the Aegean realm, as it yields a shorter outline for Alpine aged continental collision.
The Alanya Massif, which is located to the south of central Taurides in Turkey, presents a typical nappe pile consisting of thrust sheets with contrasting metamorphic histories. In two thrust sheets, Sugozu and GundogmuAY nappes, HP metamorphism under eclogite (550-567 A degrees C/14-18 kbar) and blueschist facies (435-480 A degrees C/11-13 kbar) conditions have been recognized, respectively. Whereas the rest of the Massif underwent MP metamorphism under greenschist to amphibolite facies (525-555 A degrees C/6.5-7.5 kbar) conditions. Eclogite facies metamorphism in Sugozu nappe, which consists of homogeneous garnet-glaucophane-phengite schists with eclogite lenses is dated at 84.8 +/- A 0.8, 84.7 +/- A 1.5 and 82 +/- A 3 Ma (Santonian-Campanian) by Ar-40/Ar-39 phengite, U/Pb zircon and rutile dating methods, respectively. Similarly, phengites in GundogmuAY nappe representing an accretionary complex yield 82-80 Ma (Campanian) ages for blueschist facies metamorphism. During the exhumation, the retrograde overprint of the HP units under greenschist-amphibolite facies conditions and tectonic juxtaposition with the Barrovian units occurred during Campanian (75-78 Ma). Petrological and geochronological data clearly indicate a similar Late Cretaceous tectonometamorphic evolution for both Alanya (84-75 Ma) and Bitlis (84-72 Ma) Massifs. They form part of a single continental sliver (Alanya-Bitlis microcontinent), which was rifted from the southern part of the Anatolide-Tauride platform. The P-T-t coherence between two Massifs suggests that both Massifs have been derived from the closure of the same ocean (Alanya-Bitlis Ocean) located to the south of the Anatolide-Tauride block by a northward subduction. The boundary separating the autochthonous Tauride platform to the north from both the Alanya and Bitlis Massifs to the south represents a suture zone, the Pamphylian-Alanya-Bitlis suture.