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Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity
(2013)
Mondal, Suvendu Sekhar
;
Bhunia, Asamanjoy
;
Baburin, Igor A.
;
Jäger, Christian
;
Kelling, Alexandra
;
Schilde, Uwe
;
Seifert, Gotthard
;
Janiak, Christoph
;
Holdt, Hans-Jürgen
A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N-2 and CH4 gases.
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