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Metal-containing ionic liquids (ILs) are of interest for a variety of technical applications, e.g., particle synthesis and materials with magnetic or thermochromic properties. In this paper we report the synthesis of, and two structures for, some new tetrabromidocuprates(II) with several “onium” cations in comparison to the results of electron paramagnetic resonance (EPR) spectroscopic analyses. The sterically demanding cations were used to separate the paramagnetic Cu(II) ions for EPR measurements. The EPR hyperfine structure in the spectra of these new compounds is not resolved, due to the line broadening resulting from magnetic exchange between the still-incomplete separated paramagnetic Cu(II) centres. For the majority of compounds, the principal g values (g|| and gK) of the tensors could be determined and information on the structural changes in the [CuBr4]2- anions can be obtained. The complexes have high potential, e.g., as ionic liquids, as precursors for the synthesis of copper bromide particles, as catalytically active or paramagnetic ionic liquids.
Compared to their inorganic counterparts, organic semiconductors suffer from relatively low charge carrier mobilities. Therefore, expressions derived for inorganic solar cells to correlate characteristic performance parameters to material properties are prone to fail when applied to organic devices. This is especially true for the classical Shockley-equation commonly used to describe current-voltage (JV)-curves, as it assumes a high electrical conductivity of the charge transporting material. Here, an analytical expression for the JV-curves of organic solar cells is derived based on a previously published analytical model. This expression, bearing a similar functional dependence as the Shockley-equation, delivers a new figure of merit α to express the balance between free charge recombination and extraction in low mobility photoactive materials. This figure of merit is shown to determine critical device parameters such as the apparent series resistance and the fill factor.
The law of treaties; or, should this book exist? / Vaughan LoweThe law of treaties through the interplay of its different sources / Enzo Cannizzaro -- Regulating treaties: a comparative perspective / Martins Paparinskis -- Theorizing treaties: the consequences of the contractual analogy / Akbar Rasulov -- The effects of treaties in domestic law / André Nollkaemper -- The temporal dimension: non-retroactivity and its discontents / Markus Kotzur -- The spatial dimension: treaties and territory / Marko Milanovic -- The personal dimension: challenges to the pacta tertiis rule / Alexander Proelss -- Formalism versus flexibility in the law of treaties / Jean d'Aspremont -- Integrity versus flexibility in the application of treaties / Katherine del Mar -- Pacta sunt servanda versus flexibility in the suspension and termination of treaties / Sotirios-Ioannis Lekkas and Antonios Tzanakopoulos -- Uniformity versus specialisation (1): the quest for a uniform law of inter-state treaties / Malgosia Fitzmaurice and Panos Merkouris -- Uniformity versus specialisation (2): a uniform regime of treaty interpretation? / Michael Waibel -- Regime-collisions: tensions between treaties (and how to solve them) / Jasper Finke -- Responding to deliberately-created treaty conflicts / Surabhi Ranganathan -- Treaty breaches and responses / Christian J Tams -- Succession to treaties and the inherent limits of international law / Andreas Zimmermann and James G. Devaney -- Treaties and armed conflict / Yael Ronen -- Treaties and international organisations: uneasy analogies / Philippa Webb -- Treaty law and multinational enterprises: more than internationalized contracts? / Markos Karavias -- Treaties and individuals: of beneficiaries, duty-bearers, users, and participants / Ilias Plakokefalos