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Stable covalently photo-cross-linked porous poly(ionic liquid) membrane with gradient pore size
(2018)
Porous polyelectrolyte membranes stable in a highly ionic environment are obtained by covalent crosslinking of an imidazolium-based poly(ionic liquid). The crosslinking reaction involves the UV light-induced thiol-ene (click) chemistry, and the phase separation, occurring during the crosslinking step, generates a fully interconnected porous structure in the membrane. The porosity is on the order of the micrometer scale and the membrane shows a gradient of pore size across the membrane cross-section. The membrane can separate polystyrene latex particles of different size and undergoes actuation in contact with acetone due to the asymmetric porous structure.
Monte-Carlo calculations are carried out to simulate the light transport in dense materials. Focus lies on the calculation of diffuse light transmission through films of scattering and absorbing media considering additionally the effect of dependent scattering. Different influences like interaction type between particles, particle size, composition etc. can be studied by this program. Simulations in this study show major influences on the diffuse transmission. Further simulations are carried out to model a sunscreen film and study best compositions of this film and will be presented.