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We studied FeCO3 using Fe K-edge X-ray absorption near-edge structure (XANES) spectroscopy at pressures up to 54 GPa and temperatures above 2000 K. First-principles calculations of Fe at the K-edge in FeCO3 were performed to support the interpretation of the XANES spectra. The variation of iron absorption edge features with pressure and temperature in FeCO3 matches well with recently reported observations on FeCO3 at extreme conditions, and provides new insight into the stability of Fe-carbonates in Earth's mantle. Here we show that at conditions of the mid-lower mantle, ~50 GPa and ~2200 K, FeCO3 melts and partially decomposes to high-pressure Fe3O4. Carbon (diamond) and oxygen are also inferred products of the reaction. We constrained the thermodynamic phase boundary between crystalline FeCO3 and melt to be at 51(1) GPa and ~1850 K. We observe that at 54(1) GPa, temperature-induced spin crossover of Fe2+ takes place from low to high spin such that at 1735(100) K, all iron in FeCO3 is in the high-spin state. A comparison between experiment and theory provides a more detailed understanding of FeCO3 decomposition observed in X-ray absorption spectra and helps to explain spectral changes due to pressure-induced spin crossover in FeCO3 at ambient temperature.
Identifying the provenance signature and geodynamic setting on which sedimentary basins at convergent margins grow is challenging since they result from coupled erosional and tectonic processes, which shape the evolution of source areas and the stress regime. The Early Cretaceous evolution of the northern Andes of Colombia is characterized by extensional tectonics and the subsequent formation of a marginal basin. The Abejorral Formation and coeval volcano-sedimentary rocks are exposed along the western flank and axis of the Central Cordillera. They comprise an Early Cretaceous transgressive sequence initially accumulated in fluvial deltaic environments, which switched towards a deep-marine setting, and are interpreted as the infilling record of a marginal back-arc basin. Available provenance data suggest that Permian-Triassic metamorphic and less abundant Jurassic magmatic rocks forming the basement of the Central Cordillera sourced the Abejorral Formation. New detailed volcanic and metamorphic lithics analyses, conventional and varietal study of heavy minerals, detrital rutile mineral chemistry, allowed us to document changes in the source areas defined by the progressive appearance of both higher-grade and more distal low-grade metamorphic sources, which switched from pelitic to dominantly mafic in composition. Crystallochemical indexes of clay minerals of fine-grained rocks of the Abejorral Formation suggest that samples located close to the Romeral Fault System show characteristics of low-medium P-T low-grade metamorphism, whereas rocks located farther to the northeast preserve primary diagenetic features, which suggest a high heat-flow accumulation setting. We interpret that the Abejorral Formation records the progressive unroofing of the Central Cordillera basement that was being rapidly exhumed, as well as the incorporation of distal subduction-related metamorphic complexes to the west in response either to the widening of extensional front or the reactivation of fault structures on the oceanward margin of the basin. Although the deformational record of the Abejorral Formation would have resulted from over-imposed episodes, our new geochronological constraints suggest that this sedimentary sequence must have been deformed before the Paleocene due to the presence of arc-related intrusive non-deformed magmatic rocks with a crystallization age of ca. 60 Ma.
The paper presents a historical long-distance communication system based on beacon fires in one of the most dynamic and rugged mountain ranges of the world, the Hindu Kush-Karakoram-Himalayas. It was deployed as an early warning system for glacial lake outburst floods, which caused devastating impacts on settlement zones and infrastructure until the middle of the twentieth century. The study revealed that the beacon fire systems were operated in distinct valleys spread over the entire Hindu Kush-Karakoram Region. The remarkable fact is the establishment of fire posts in highly difficult accessible mountain environments with communication distances of several hundred kilometres for individual beacon lines. The warning system was a cooperative natural hazard management, which was operated even across distinct ethnic groups. Distant societies, formerly perceived as isolated villages by physical barriers of the high mountain relief, were in historical times connected not only by challenging trade routes but also by a fast working optical communication system. The findings are discussed in the context of a future sustainable natural hazard management.
Main group pallasite meteorites are samples of a single early magmatic planetesimal, dominated by metal and olivine but containing accessory chromite, sulfide, phosphide, phosphates, and rare phosphoran olivine. They represent mixtures of core and mantle materials, but the environment of formation is poorly understood, with a quiescent core-mantle boundary, violent core-mantle mixture, or surface mixture all recently suggested. Here, we review main group pallasite data sets and petrologic characteristics, and present new observations on the low-MnO pallasite Brahin that contains abundant fragmental olivine, but also rounded and angular olivine and potential evidence of sulfide-phosphide liquid immiscibility. A reassessment of the literature shows that low-MnO and high-FeO subgroups preferentially host rounded olivine and low-temperature P2O5-rich phases such as the Mg-phosphate farringtonite and phosphoran olivine. These phases form after metal and silicate reservoirs back-react during decreasing temperature after initial separation, resulting in oxidation of phosphorus and chromium. Farringtonite and phosphoran olivine have not been found in the common subgroup PMG, which are mechanical mixtures of olivine, chromite with moderate Al2O3 contents, primitive solid metal, and evolved liquid metal. Lower concentrations of Mn in olivine of the low-MnO PMG subgroup, and high concentrations of Mn in low-Al2O3 chromites, trace the development and escape of sulfide-rich melt in pallasites and the partially chalcophile behavior for Mn in this environment. Pallasites with rounded olivine indicate that the core-mantle boundary of their planetesimal may not be a simple interface but rather a volume in which interactions between metal, silicate, and other components occur.
We investigate the thermal and structural evolution of asymmetric rifted margin using numerical modeling and geological observations derived from the Western Pyrenees. Our numerical model provides a self-consistent physical evolution of the top basement heat flow during asymmetric rifting. The model shows a pronounced thermal asymmetry that is caused by migration of the rift center toward the upper plate. The same process creates a diachronism for the record of maximum heat flow and maximum temperatures (T-max) in basal rift sequences. The Mauleon-Arzacq basin (W-Pyrenees) corresponds to a former mid-Cretaceous asymmetric hyperextended rift basin. New vitrinite reflectance data in addition to existing data sets from this basin reveal an asymmetry in the distribution of peak heat (T-max) with respect to the rift shoulders, where highest values are located at the former upper- to lower-plate transition. This data set from the Arzacq-Mauleon field study confirms for the first time the thermal asymmetry predicted by numerical models. Numerical modeling results also suggest that complexities in synrift thermal architecture could arise when hanging-wall-derived extensional allochthons and related T-max become part of the lower plate and are transported away from the upper- to lower-plate transition. This study emphasizes the limitations of the common approach to integrate punctual thermal data from pre-rift to synrift sedimentary sequences in order to describe the rift-related thermal evolution and paleothermal gradients at the scale of a rift basin or a rifted margin.
The application of electrical resistivity tomography to peatlands supports conventional coring by providing data on the current condition of peatlands, including data on stratigraphy, peat properties and thickness of organic deposits. Data on the current condition of drained peatlands are particularly required to improve estimates of carbon storage as well as losses and emissions from agriculturally used peatlands. However, most of the studies focusing on electrical resistivity tomography surveys have been conducted on natural peatlands with higher groundwater levels. Peatlands drained for agriculture have not often been studied using geophysical techniques. Drained sites are characterized by low groundwater levels and high groundwater fluctuations during the year, which lead to varying levels of water saturation. To validate better electrical resistivity tomography surveys of drained peatlands, the aim of this laboratory study is to investigate the influence of varying water saturation levels on electrical conductivity (reciprocal of resistivity) for a variety of peat and gyttja types, as well as for different degrees of peat decomposition. Results show that different levels of water saturation strongly influence bulk electrical conductivity. Distinct differences in this relationship exist between peat and gyttja substrates and between different degrees of peat decomposition. Peat shows an exponential relationship for all degrees of decomposition, whereas gyttja, in particular organic-rich gyttja, is characterized by a rather unimodal relationship. The slopes for the relationship between electrical conductivity and water content are steeper at high degrees of decomposition than for peat of low degrees of decomposition. These results have direct implications for field electrical resistivity tomography surveys. In drained peatlands that are strongly susceptible to drying, electrical resistivity tomography surveys have a high potential to monitor the actual field water content. In addition, at comparable water saturations, high or low degrees of decomposition can be inferred from electrical conductivity.
Thawing of subsea permafrost can impact offshore infrastructure, affect coastal erosion, and release permafrost organic matter. Thawing is usually modeled as the result of heat transfer, although salt diffusion may play an important role in marine settings. To better quantify nearshore subsea permafrost thawing, we applied the CryoGRID2 heat diffusion model and coupled it to a salt diffusion model. We simulated coastline retreat and subsea permafrost evolution as it develops through successive stages of a thawing sequence at the Bykovsky Peninsula, Siberia. Sensitivity analyses for seawater salinity were performed to compare the results for the Bykovsky Peninsula with those of typical Arctic seawater. For the Bykovsky Peninsula, the modeled ice-bearing permafrost table (IBPT) for ice-rich sand and an erosion rate of 0.25m/year was 16.7 m below the seabed 350m offshore. The model outputs were compared to the IBPT depth estimated from coastline retreat and electrical resistivity surveys perpendicular to and crossing the shoreline of the Bykovsky Peninsula. The interpreted geoelectric data suggest that the IBPT dipped to 15-20m below the seabed at 350m offshore. Both results suggest that cold saline water forms beneath grounded ice and floating sea ice in shallow water, causing cryotic benthic temperatures. The freezing point depression produced by salt diffusion can delay or prevent ice formation in the sediment and enhance the IBPT degradation rate. Therefore, salt diffusion may facilitate the release of greenhouse gasses to the atmosphere and considerably affect the design of offshore and coastal infrastructure in subsea permafrost areas.
The sedimentary record of the Dead Sea provides an exceptional high-resolution archive of past climate changes in the drought-sensitive eastern Mediterranean-Levant, a key region for the development of humankind at the boundary of global climate belts. Moreover, it is the only deep hypersaline lake known to have deposited long sequences of finely laminated, annually deposited sediments (i.e. varves) of varied compositions, including aragonite, gypsum, halite and clastic sediments. Vast efforts have been made over the years to decipher the environmental information stored in these evaporitic-clastic sequences spanning from the Pleistocene Lake Amora to the Holocene Dead Sea. A general characterisation of sediment facies has been derived from exposed sediment sections, as well as from shallow- and deep-water sediment cores. During high lake stands and episodes of positive water budget, mostly during glacial times, alternating aragonite and detritus laminae (‘aad’ facies) were accumulated, whereas during low lake stands and droughts, prevailing during interglacials, laminated detritus (‘ld’ facies) and laminated halite (‘lh’ facies) dominate the sequence. In this paper, we (i) review the three types of laminated sediments of the Dead Sea sedimentary record (‘aad’, ‘ld’ and ‘lh’ facies), (ii) discuss their modes of formation, deposition and accumulation, and their interpretation as varves, and (iii) illustrate how Dead Sea varves are utilized for palaeoclimate reconstructions and for establishing floating chronologies.
Rapid local adaptation frequently occurs during the spread of invading species. It remains unclear, however, how consistent, and therefore potentially predictable, such patterns of local adaptation are. One approach to this question is to measure patterns of local differentiation in functional traits and plasticity levels in invasive species in multiple regions. Finding consistent patterns of local differentiation in replicate regions suggests that these patterns are adaptive. Further, this outcome indicates that the invading species likely responds predictably to selection along environmental gradients, even though standing genetic variation is likely to have been reduced during introduction. We studied local differentiation in the invasive annual plant Erodium cicutarium in two invaded regions, California and Chile. We collected seeds from across strong gradients in precipitation and temperature in Mediterranean-climate parts of the two regions (10 populations per region). We grew seeds from maternal families from these populations through two generations and exposed the second generation to contrasting levels of water and nutrient availability. We measured growth, flowering time and leaf functional traits across these treatments to obtain trait means and plasticity measures. We found strong differentiation among populations in all traits. Plants from drier environments flowered earlier, were less plastic in flowering time and reached greater size in all treatments. Correlations among traits within regions suggested a coordinated evolutionary response along environmental gradients associated with growing season length. There was little divergence in traits and trait intercorrelations between regions, but strongly parallel divergence in traits within regions. Similar, statistically consistent patterns of local trait differentiation across two regions suggest that local adaptation to environmental gradients has aided the spread of this invasive species, and that the formation of ecotypes in newly invaded environments has been relatively consistent and predictable.
Ground and space-based geomagnetic data were used in the investigation of the longitudinal, seasonal and lunar phase dependence of the equatorial counter electrojet (CEJ) occurrence in the Peruvian, Brazilian, African, Indian and Philippine sectors during geomagnetically quiet days from the solar cycle 24 (2008 to 2018). We found that CEJ events occur more frequently during the morning (MCEJ) than in the afternoon (ACEJ). The highest MCEJ and ACEJ occurrence rates were observed for the Brazilian sector. Distinct seasonal dependence was found for each longitudinal sector under investigation. The lunar phase dependence was determined for the first time for the Philippine sector (longitude 125 degrees E), and it was shown to be less pronounced than in the Peruvian, Brazilian and African sectors. We demonstrate that differences in CEJ rates derived from ground-based and satellite data can arise from the longitudinal separation between low-latitude and equatorial stations that are used to determine the signal and its consequent time delay in their sunrise/sunset times at ionospheric heights.