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Fe K-edge X-ray absorption near edge structure (XANES) and Mossbauer spectra were collected on synthetic glasses of basaltic composition and of glasses on the sodium oxide-silica binary to establish a relation between the pre- edge of the XANES at the K-edge and the Fe oxidation state of depolymerised glasses. Charges of sample material were equilibrated at ambient pressure, superliquidus temperatures and oxygen fugacities that were varied over a range of about 15 orders of magnitude. Most experiments were carried out in gas-flow furnaces, either with pure oxygen, air, or different CO/CO2 mixtures. For the most reduced conditions, the samples charges were enclosed together with a pellet of the IQF oxygen buffer in an evacuated silica glass ampoule. Fe3+/SigmaFe x 100 of the samples determined by Mossbauer spectroscopy range between 0% and 100%. Position and intensity of the pre-edge centroid position vary strongly depending on the Fe oxidation state. The pre-edge centroid position and the Fe oxidation state determined by Mossbauer spectroscopy are nonlinearly related and have been fitted by a quadratic polynomial. Alternatively, the ratio of intensities measured at positions sensitive to Fe2+ and Fe3+, respectively, provides an even more sensitive method. Pre- edge intensities of the sample suite indicate average Fe co-ordination between 4 and 6 for all samples regardless of oxidation state. A potential application of the calibration given here opens the possibility of determining Fe oxidation state in glasses of similar compositions with high spatial resolution by use of a Micro-XANES setup (e.g., glass inclusions in natural minerals). (C) 2004 Elsevier B.V. All rights reserved
We remelted and analyzed crystallized silicate melt inclusions in quartz from a porphyritic albitezinnwaldite microgranite dike to determine the composition of highly evolved, shallowly intruded, Li- and F-rich granitic magma and to investigate the role of crystal fractionation and aqueous fluid exsolution in causing the extreme extent of magma differentiation. This dike is intimately associated with tin- and tungsten-mineralized granites of Zinnwald, Erzgebirge, Germany. Prior research on Zinnwald granite geochemistry was limited by the effects of strong and pervasive greisenization and alkali-feldspar metasomatism of the rocks. These melt inclusions, however, provide important new constraints on magmatic and mineralizing processes in Zinnwald magmas. The mildly peraluminous granitic melt inclusions are strongly depleted in CAFEMIC constituents (e.g., CaO, FeO, MgO, TiO2), highly enriched in lithophile trace elements, and highly but variably enriched in F and Cl. The melt inclusions contain up to several thousand ppm Cl and nearly 3 wt% F, on average; several inclusions contain more than 5 wt% F. The melt inclusions are geochemically similar to the corresponding whole-rock sample, except that the former contain much more F and less CaO, FeO, Zr, Nb, Sr, and Ba. The Sr and Ba abundances are very low implying the melt inclusions represent magma that was more evolved than that represented by the bulk rock. Relationships involving melt constituents reflect increasing lithophile-element and halogen abundances in residual melt with progressive magma differentiation. Modeling demonstrates that differentiation was dominated by crystal fractionation involving quartz and feldspar and significant quantities of topaz and F-rich zinnwaldite. The computed abundances of the latter phases greatly exceed their abundances in the rocks, suggesting that the residual melt was separated physically from phenocrysts during magma movement and evolution. Interactions of aqueous fluids with silicate melt were also critical to magma evolution. To better understand the role of halogen-charged, aqueous fluids in magmatic differentiation and in subsequent mineralization and metasomatism of the Zinnwald granites, Cl-partitioning experiments were conducted with a F-enriched silicate melt and aqueous fluids at 2,000 bar (200 MPa). The results of the experimentally determined partition coefficients for Cl and F, the compositions of fluid inclusions in quartz and other phenocrysts, and associated geochemical modeling point to an important role of magmatic-hydrothermal fluids in influencing magma geochemistry and evolution. The exsolution of halogen-charged fluids from the Li- and F- enriched Zinnwald granitic magma modified the Cl, alkali, and F contents of the residual melt, and may have also sequestered Li, Sri, and W from the melt. Many of these fluids contained strongly elevated F concentrations that were equivalent to or greater than their Cl abundances. The exsolution of F-, Cl-, Li-, +/- W- and Sn-bearing hydrothermal fluids from Zinnwald granite magmas was important in effecting the greisenizing and alkali-feldspathizing metasomatism of the granites and the concomitant mineralization
To address one of the central questions of plate tectonics-How do large transform systems work and what are their typical features?-seismic investigations across the Dead Sea Transform (DST), the boundary between the African and Arabian plates in the Middle East, were conducted for the first time. A major component of these investigations was a combined reflection/ refraction survey across the territories of Palestine, Israel and Jordan. The main results of this study are: (1) The seismic basement is offset by 3-5 km under the DST, (2) The DST cuts through the entire crust, broadening in the lower crust, (3) Strong lower crustal reflectors are imaged only on one side of the DST, (4) The seismic velocity sections show a steady increase in the depth of the crust-mantle transition (Moho) from 26 km at the Mediterranean to 39 km under the Jordan highlands, with only a small but visible, asymmetric topography of the Moho under the DST. These observations can be linked to the left-lateral movement of 105 km of the two plates in the last 17 Myr, accompanied by strong deformation within a narrow zone cutting through the entire crust. Comparing the DST and the San Andreas Fault (SAF) system, a strong asymmetry in subhorizontal lower crustal reflectors and a deep reaching deformation zone both occur around the DST and the SAF. The fact that such lower crustal reflectors and deep deformation zones are observed in such different transform systems suggests that these structures are possibly fundamental features of large transform plate boundaries
Along the Southern Himalayan Front (SHF), areas with concentrated precipitation coincide with rapid exhumation, as indicated by young mineral cooling ages. Twenty new, young ( < 1-5 Ma) apatite fission track (AFT) ages have been obtained from the Himalayan Crystalline Core along the Sutlej Valley, NW India. The AFT ages correlate with elevation, but show no spatial relationship to tectonic structures, such as the Main Central Thrust or the Southern Tibetan Fault System. Monsoonal precipitation in this region exerts a strong influence on erosional surface processes. Fluvial erosional unloading along the SHF is focused on high mountainous areas, where the orographic barrier forces out > 80% of the annual precipitation. AFT cooling ages reveal a coincidence between rapid erosion and exhumation that is focused in a similar to 50-70-km-wide sector of the Himalaya, rather than encompassing the entire orogen. Assuming simplified constant exhumation rates, the rocks of two age vs. elevation transects were exhumed at similar to 1.4 +/- 0.2 and similar to 1.1 +/- 0.4 mm/a with an average cooling rate of similar to 40-50degreesC/Ma during Pliocene-Quarternary time. Following other recently published hypotheses regarding the relation between tectonics and climate in the Himalaya, we suggest that this concentrated loss of material was accommodated by motion along a back-stepping thrust to the south and a normal fault zone to the north as part of an extruding wedge. Climatically controlled erosional processes focus on this wedge and suggest that climatically controlled surface processes determine tectonic deformation in the internal part of the Himalaya. (C) 2004 Elsevier B.V. All rights reserved
Fault planes of large earthquakes incorporate inhomogeneous structures. This can be observed in teleseismic studies through the spatial distribution of slip and seismic moment release caused by the mainshock. Both parameters are often concentrated on patches on the fault plane with much higher values for slip and moment release than their adjacent areas. These patches are called asperities which obviously have a strong influence on the mainshock rupture propagation. Condition and properties of structures in the fault plane area, which are responsible for the evolution of such asperities or their significance on damage distributions of future earthquakes, are still not well understood and subject to recent geo-scientific studies. In the presented thesis asperity structures are identified on the fault plane of the Mw=8.0 Antofagasta earthquake in northern Chile which occurred on 30th of July, 1995. It was a thrust-type event in the seismogenic zone between the subducting pacific Nazca plate and the overriding South American plate. In cooperation of the German Task Force for Earthquakes and the CINCA'95 project a network of up to 44 seismic stations was set up to record the aftershock sequence. The seaward extension of the network with 9 OBH stations increased significantly the precision of hypocenter determinations. They were distributed mainly on the fault plane itself around the city of Antofagasta and Mejillones Peninsula. The asperity structures were recognized here by the spatial variations of local seismological parameters; at first by the spatial distribution of the seismic b-value on the fault plane, derived from the magnitude-frequency relation of Gutenberg-Richter. The correlation of this b-value map with other parameters like the mainshock source time function, the gravity isostatic residual anomalies, the aftershock radiated seismic energy distribution and the vp/vs ratios from a local earthquake tomograhpy study revealed some ideas about the composition and asperity generating processes. The investigation of 295 aftershock focal mechanism solutions supported the resulting fault plane structure and proposed a 3D similar stress state in the area of the Antofagasta fault plane.
Field observations, digital elevation model (DEM) data, and longitudinal profile analysis reveal a perched low- relief upland landscape in the Red River region, Yunnan Province, China, which correlates to an uplifted, regional low- relief landscape preserved over the eastern margin of the Tibetan Plateau. As with other major rivers of the plateau margin, the Red River has deeply incised the low-relief upland landscape, which we interpret to be the remnants of a pre- uplift or relict landscape. We examine longitudinal river profiles for 97 tributaries of the Red River. Most profiles consist of three segments separated by sharp knickpoints: an upper, low-gradient channel segment, a steeper middle channel segment, and a very steep lower channel segment. Upper channel segments correspond to the relict landscape and have not yet experienced river incision. Steeper middle and lower segments indicate onset of rapid, two-phase river incision, on the basis of which changes in external forcings, such as climate or uplift, can be inferred. In terms of two end-member scenarios, two-phase incision could be the result of pulsed plateau growth, in which relatively slow uplift during the first phase is followed by rapid uplift during the second phase, or it could reflect adjustments of the main channel to changing climate conditions against the backdrop of steady plateau growth. Reconstruction of the paleo-Red River indicates 1400 m river incision, 1400-1500 m surface uplift, and a maximum of 750 m vertical displacement across the northern Red River fault, elevating the northern Ailao Shan range above the surrounding relict landscape. On the basis of stratigraphic constraints, incision along the Red River likely began in Pliocene time
Quantitative Analysen magmatischer Gesteine mittels reflexionsspektroskopischer Infrarot-Messungen
(2004)
One of the major challenges in engineering seismology is the reliable prediction of site-specific ground motion for particular earthquakes, observed at specific distances. For larger events, a special problem arises, at short distances, with the source-to-site distance measure, because distance metrics based on a point-source model are no longer appropriate. As a consequence, different attenuation relations differ in the distance metric that they use. In addition to being a source of confusion, this causes problems to quantitatively compare or combine different ground- motion models; for example, in the context of Probabilistic Seismic Hazard Assessment, in cases where ground-motion models with different distance metrics occupy neighboring branches of a logic tree. In such a situation, very crude assumptions about source sizes and orientations often have to be used to be able to derive an estimate of the particular metric required. Even if this solves the problem of providing a number to put into the attenuation relation, a serious problem remains. When converting distance measures, the corresponding uncertainties map onto the estimated ground motions according to the laws of error propagation. To make matters worse, conversion of distance metrics can cause the uncertainties of the adapted ground-motion model to become magnitude and distance dependent, even if they are not in the original relation. To be able to treat this problem quantitatively, the variability increase caused by the distance metric conversion has to be quantified. For this purpose, we have used well established scaling laws to determine explicit distance conversion relations using regression analysis on simulated data. We demonstrate that, for all practical purposes, most popular distance metrics can be related to the Joyner-Boore distance using models based on gamma distributions to express the shape of some "residual function." The functional forms are magnitude and distance dependent and are expressed as polynomials. We compare the performance of these relations with manually derived individual distance estimates for the Landers, the Imperial Valley, and the Chi-Chi earthquakes
The use of ground-motion-prediction equations to estimate ground shaking has become a very popular approach for seismic-hazard assessment, especially in the framework of a logic-tree approach. Owing to the large number of existing published ground-motion models, however, the selection and ranking of appropriate models for a particular target area often pose serious practical problems. Here we show how observed around-motion records can help to guide this process in a systematic and comprehensible way. A key element in this context is a new, likelihood based, goodness-of-fit measure that has the property not only to quantify the model fit but also to measure in some degree how well the underlying statistical model assumptions are met. By design, this measure naturally scales between 0 and 1, with a value of 0.5 for a situation in which the model perfectly matches the sample distribution both in terms of mean and standard deviation. We have used it in combination with other goodness-of-fit measures to derive a simple classification scheme to quantify how well a candidate ground-rnotion-prediction equation models a particular set of observed-response spectra. This scheme is demonstrated to perform well in recognizing a number of popular ground-motion models from their rock-site- recording, subsets. This indicates its potential for aiding the assignment of logic-tree weights in a consistent and reproducible way. We have applied our scheme to the border region of France, Germany, and Switzerland where the M-w 4.8 St. Die earthquake of 22 February 2003 in eastern France recently provided a small set of observed-response spectra. These records are best modeled by the ground-motion-prediction equation of Berge-Thierry et al. (2003), which is based on the analysis of predominantly European data. The fact that the Swiss model of Bay et al. (2003) is not able to model the observed records in an acceptable way may indicate general problems arising from the use of weak-motion data for strong-motion prediction
Anisotropic material properties are usually neglected during inversions for source parameters of earthquakes. In general anisotropic media, however, moment tensors for pure-shear sources can exhibit significant non-double-couple components. Such effects may be erroneously interpreted as an indication for volumetric changes at the source. Here we investigate effects of anisotropy on seismic moment tensors and radiation patterns for pure-shear and tensile-type sources. Anisotropy can significantly influence the interpretation of the source mechanisms. For example, the orientation of the slip within the fault plane may affect the total seismic moment. Also, moment tensors due to pure- shear and tensile faulting can have similar characteristics depending on the orientation of the elastic tensor. Furthermore, the tensile nature of an earthquake can be obscured by near-source anisotropic properties. As an application, we consider effects of inhomogeneous anisotropic properties on the seismic moment tensor and the radiation patterns of a selected type of micro-earthquakes observed in W-Bohemia. The combined effects of near-source and along- path anisotropy cause characteristic amplitude distortions of the P, S1 and S2 waves. However, the modeling suggests that neither homogeneous nor inhomogeneous anisotropic properties alone can explain the observed large non-double-couple components. The results also indicate that a correct analysis of the source mechanism, in principle, is achievable by application of anisotropic moment tensor inversion
In this paper we present densely sampled fumarole temperature data, recorded continuously at a high-temperature fumarole of Mt. Merapi volcano (Indonesia). These temperature time series are correlated with continuous records of rainfall and seismic waveform data collected at the Indonesian - German multi-parameter monitoring network. The correlation analysis of fumarole temperature and precipitation data shows a clear influence of tropical rain events on fumarole temperature. In addition, there is some evidence that rainfall may influence seismicity rates, indicating interaction of meteoric water with the volcanic system. Knowledge about such interactions is important, as lava dome instabilities caused by heavy-precipitation events may result in pyroclastic flows. Apart from the strong external influences on fumarole temperature and seismicity rate, which may conceal smaller signals caused by volcanic degassing processes, the analysis of fumarole temperature and seismic data indicates a statistically significant correlation between a certain type of seismic activity and an increase in fumarole temperature. This certain type of seismic activity consists of a seismic cluster of several high-frequency transients and an ultra-long-period signal (< 0.002 Hz), which are best observed using a broadband seismometer deployed at a distance of 600 m from the active lava dome. The corresponding change in fumarole temperature starts a few minutes after the ultra-long-period signal and simultaneously with the high-frequency seismic cluster. The change in fumarole temperature, an increase of 5 degreesC on average, resembles a smoothed step. Fifty-four occurrences of simultaneous high-frequency seismic cluster, ultra-long period signal and increase of fumarole temperature have been identified in the data set from August 2000 to January 2001. The observed signals appear to correspond to degassing processes in the summit region of Mt. Merapi. (C) 2004 Elsevier B.V. All rights reserved
K-Ar ages of 37 samples collected from the Bicol peninsula, the Luzon island, Philippines, were determined by the unspiked sensitivity method in order to constrain the timing of initiation of subduction along the Philippine Trench. The measured K-Ar ages range from 0 to 7 Ma with two old outliers of 27 and 43 Ma. Together with K-Ar ages previously reported on volcanics in Leyte and eastern Mindanao, subduction volcanism has likely propagated from north to south: similar to 6.6 Ma in Bicol and similar to 3.5 Ma in Leyte and its vicinity. The temporal and spatial distribution suggests that the subduction volcanism started earlier in the north than in the south. This is consistent with the southern propagation of subduction along the Philippine Trench from similar to 8 Ma. (C) 2003 Elsevier Ltd. All rights reserved
A recent K-Ar study elucidated that eruptive style in the eastern Izu peninsula changed from polygenetic to monogenetic volcano at 0.3-0.2 Ma. To narrow down the time of change, we determined 10 K-Ar ages on Togasayama Andesite of Amagi volcano, the youngest polygenetic volcano in the area, and Togasayama Monogenetic Volcano, one of the oldest monogenetic volcanoes in the area, which overlies a part of the Togasayama Andesite. Dating results showed that the Togasayama Andesite effused at least from 0.34 to 0.20 Ma, whereas the Togasayama Monogenetic Volcano erupted at 0.26- 0.29 Ma, suggesting that the northern part of the Togasayama Andesite effused after the eruption of the Togasayama Monogenetic Volcano. Considering previous data, it is therefore inferred that change of eruptive style in the eastern Izu area occurred during the period 0.29-0.20 Ma, with considerable overlap of both polygenetic and monogenetic volcanism
The ellipticity of Rayleigh surface waves, which is an important parameter characterizing the propagation medium, is studied for several models with increasing complexity. While the main focus lies on theory, practical implications of the use of the horizontal to vertical component ratio (H/V-ratio) to Study the subsurface structure are considered as well. Love's approximation of the ellipticity for an incompressible layer over an incompressible half-space is critically discussed especially concerning its applicability for different impedance contrasts. The main result is an analytically exact formula of H/V for a 2-layer model of compressible media, which is a generalization of Love's formula. It turns out that for a limited range of models Love's approximation can be used also in the general case. (C) 2003 Elsevier B.V. All rights reserved
As part of the international refraction measurements in Central Europe in the year 2000, three profiles traversed the region of earthquake swarms in West-Bohemia/Vogtland. The shots were also recorded at the permanent stations of the local seismic networks. The travel times of P-waves, observed in the West-Bohemian region, are discussed and interpreted in the present paper. In general, significantly lower P-wave velocities were found in the Saxothuringian (northern) part of the studied area than in the adjacent southern parts. The observed travel times are interpreted separately for the individual geological units, in particular for the plutons, crystallinicum, and the Marianske Lazne(Marienbad) Complex. After smoothing the selected data using rational approximations, the Wiechert-Herglotz method was used to compute vertically inhomogeneous velocity models. The characteristic features of the derived models are relatively low P-wave velocities at the surface and prominent velocity increases within the uppermost crust down to a depth of about one kilometer
With controlled seismic sources and specifically designed receiver arrays, we image a subvertical boundary between two lithological blocks at the Arava Fault (AF) in the Middle East. The AF is the main strike-slip fault of the Dead Sea Transform (DST) in the segment between the Dead Sea and the Red Sea. Our imaging (migration) method is based on array beamforming and coherence analysis of P to P scattered seismic phases. We use a 1-D background velocity model and the direct P arrival as a reference phase. Careful resolution testing is necessary, because the target volume is irregularly sampled by rays. A spread function describing energy dispersion at localized point scatterers and synthetic calculations for large planar structures provides estimates of the resolution of the images. We resolve a 7 km long steeply dipping reflector offset roughly 1 km from the surface trace of the AF. The reflector can be imaged from about 1 km down to 4 km depth. Previous and ongoing studies in this region have shown a strong contrast across the fault: low seismic velocities and electrical resistivities to the west and high velocities and resistivities to the east of it. We therefore suggest that the imaged reflector marks the contrast between young sedimentary fill in the west and Precambrian rocks in the east. If correct, the boundary between the two blocks is offset about 1 km east of the current surface trace of the AF
The Dead Sea Transform (DST) is a prominent shear zone in the Middle East. It separates the Arabian plate from the Sinai microplate and stretches from the Red Sea rift in the south via the Dead Sea to the Taurus-Zagros collision zone in the north. Formed in the Miocene about 17 Ma ago and related to the breakup of the Afro-Arabian continent, the DST accommodates the left-lateral movement between the two plates. The study area is located in the Arava Valley between the Dead Sea and the Red Sea, centered across the Arava Fault (AF), which constitutes the major branch of the transform in this region. A set of seismic experiments comprising controlled sources, linear profiles across the fault, and specifically designed receiver arrays reveals the subsurface structure in the vicinity of the AF and of the fault zone itself down to about 3-4 km depth. A tomographically determined seismic P velocity model shows a pronounced velocity contrast near the fault with lower velocities on the western side than east of it. Additionally, S waves from local earthquakes provide an average P-to-S velocity ratio in the study area, and there are indications for a variations across the fault. High-resolution tomographic velocity sections and seismic reflection profiles confirm the surface trace of the AF, and observed features correlate well with fault-related geological observations. Coincident electrical resistivity sections from magnetotelluric measurements across the AF show a conductive layer west of the fault, resistive regions east of it, and a marked contrast near the trace of the AF, which seems to act as an impermeable barrier for fluid flow. The correlation of seismic velocities and electrical resistivities lead to a characterisation of subsurface lithologies from their physical properties. Whereas the western side of the fault is characterised by a layered structure, the eastern side is rather uniform. The vertical boundary between the western and the eastern units seems to be offset to the east of the AF surface trace. A modelling of fault-zone reflected waves indicates that the boundary between low and high velocities is possibly rather sharp but exhibits a rough surface on the length scale a few hundreds of metres. This gives rise to scattering of seismic waves at this boundary. The imaging (migration) method used is based on array beamforming and coherency analysis of P-to-P scattered seismic phases. Careful assessment of the resolution ensures reliable imaging results. The western low velocities correspond to the young sedimentary fill in the Arava Valley, and the high velocities in the east reflect mainly Precambrian igneous rocks. A 7 km long subvertical scattering zone reflector is offset about 1 km east of the AF surface trace and can be imaged from 1 km to about 4 km depth. The reflector marks the boundary between two lithological blocks juxtaposed most probably by displacement along the DST. This interpretation as a lithological boundary is supported by the combined seismic and magnetotelluric analysis. The boundary may be a strand of the AF, which is offset from the current, recently active surface trace. The total slip of the DST may be distributed spatially and in time over these two strands and possibly other faults in the area.
VLT on-axis optical spectroscopy of the z = 0.144 radio-loud quasar HE 1434-1600 is presented. The spatially resolved spectra of the host galaxy are deconvolved and separated from those of the central quasar in order to study the dynamics of the stars and gas as well as the physical conditions of the ISM. We find that the host of HE 1434-1600 is an elliptical galaxy that resides in a group of at least 5 member galaxies, and that most likely experienced a recent collision with its nearest companion. Compared with other quasar host galaxies, HE 1434-1600 has a highly ionized ISM. The ionization state corresponds to that of typical Seyferts, but the ionized regions are not distributed in a homogeneous way around the QSO, and are located preferentially several kiloparsecs away from it. While the stellar absorption lines do not show any significant velocity field, the gas emission lines do. The observed gas velocity field is hard to reconcile with dynamical models involving rotating disk. modified Hubble laws or power laws, that all require extreme central masses (M > 10(9) M-circle dot) to provide only poor fit to the data. Power law models, which best fit the data, provide a total mass of M(<10 kpc) = 9.2 x 10(10) M-&ODOT;. We conclude that the recent interaction between HE 1434-1600 and its closest companion has strongly affected the gas velocity and ionization state, from the center of the galaxy to its most external parts
The combined passive and active seismic TRANSALP experiment produced an unprecedented high-resolution crustal image of the Eastern Alps between Munich and Venice. The European and Adriatic Mohos (EM and AM, respectively) are clearly imaged with different seismic techniques: near-vertical incidence reflections and receiver functions (RFs). The European Moho dips gently southward from 35 km beneath the northern foreland to a maximum depth of 55 km beneath the central part of the Eastern Alps, whereas the Adriatic Moho is imaged primarily by receiver functions at a relatively constant depth of about 40 km. In both data sets, we have also detected first-order Alpine shear zones, such as the Helvetic detachment, Inntal fault and SubTauern ramp in the north. Apart from the Valsugana thrust, receiver functions in the southern part of the Eastern Alps have also observed a north dipping interface, which may penetrate the entire Adriatic crust [Adriatic Crust Interface (ACI)]. Deep crustal seismicity may be related to the ACI. We interpret the ACI as the currently active retroshear zone in the doubly vergent Alpine collisional belt. (C) 2004 Elsevier B.V. All rights reserved
This study presents results of ambient noise measurements from temporary single station and small-scale array deployments in the northeast of Basle. H/V spectral ratios were determined along various profiles crossing the eastern masterfault of the Rhine Rift Valley and the adjacent sedimentary rift fills. The fundamental H/V peak frequencies are decreasing along the profile towards the eastern direction being consistent with the dip of the tertiary sediments within the rift. Using existing empirical relationships between H/V frequency peaks and the depth of the dominant seismic contrast, derived on basis of the lambda/4-resonance hypothesis and a power law depth dependence of the S-wave velocity, we obtain thicknesses of the rift fill from about 155 m in the west to 280 in in the east. This is in agreement with previous studies. The array analysis of the ambient noise wavefield yielded a stable dispersion relation consistent with Rayleigh wave propagation velocities. We conclude that a significant amount of surface waves is contained in the observed wavefield. The computed ellipticity for fundamental mode Rayleigh waves for the velocity depth models used for the estimation of the sediment thicknesses is in agreement with the observed H/V spectra over a large frequency band
The P and S wave velocity structure of the D" layer beneath the southwestern Pacific was investigated by using short-period data from 12 deep events in the Tonga-Fiji region recorded by the J-Array and the Hi-net (two large- aperture seismic arrays) in Japan. Reflected wave beam forming (RWB) and a migration method were used to extract weak signals originating from heterogeneities in the lowermost mantle. In order to acquire high resolution a double-array method was applied to the data. The results of the RWB method indicate that seismic energy is reflected at discontinuities near the depths of 2520 and 2650 km, which have a negative P wave velocity contrast of 1% at the most. In addition, there is a positive seismic discontinuity at a depth of 2800 km. In the case of the S wave, reflected energy is produced almost at the same depth (2550 km depth). An apparent depth shift (50 km) of the discontinuity at the depth of 2850 km may indicate that the S wave velocity reduction in the lowermost mantle is similar to2-3 times stronger than that of P. A two-dimensional cross section, constructed with the RWB method, suggests that the observed discontinuities can be characterized as intermittent lateral heterogeneities whose lateral extent is a few hundred kilometers. The migration shows weak evidence of scattering objects which belong to the seismic discontinuities detected by the RWB method. These anomalous structures may represent a part of hot plume generated beneath the southwestern Pacific in the lowermost mantle
Following work is embedded in the multidisciplinary study DESERT (DEad SEa Rift Transect) that has been carried out in the Middle East since the beginning of the year 2000. It focuses on the structure of the southern Dead Sea Transform (DST), the transform plate boundary between Africa (Sinai) and the Arabian microplate. The left-lateral displacement along this major active strike-slip fault amounts to more than 100 km since Miocene times. The DESERT near-vertical seismic reflection (NVR) experiment crossed the DST in the Arava Valley between Red Sea and Dead Sea, where its main fault is called Arava Fault. The 100 km long profile extends in a NW—SE direction from Sede Boqer/Israel to Ma'an/Jordan and coincides with the central part of a wide-angle seismic refraction/reflection line. Near-vertical seismic reflection studies are powerful tools to study the crustal architecture down to the crust/mantle boundary. Although they cannot directly image steeply dipping fault zones, they can give indirect evidence for transform motion by offset reflectors or an abrupt change in reflectivity pattern. Since no seismic reflection profile had crossed the DST before DESERT, important aspects of this transform plate boundary and related crustal structures were not known. Thus this study aimed to resolve the DST's manifestation in both the upper and the lower crust. It was to show, whether the DST penetrates into the mantle and whether it is associated with an offset of the crust/mantle boundary, which is observed at other large strike-slip zones. In this work a short description of the seismic reflection method and the various processing steps is followed by a geological interpretation of the seismic data, taking into account relevant information from other studies. Geological investigations in the area of the NVR profile showed, that the Arava Fault can partly be recognized in the field by small scarps in the Neogene sediments, small pressure ridges or rhomb-shaped grabens. A typical fault zone architecture with a fault gauge, fault-related damage zone, and undeformed host rock, that has been reported from other large fault zones, could not be found. Therefore, as a complementary part to the NVR experiment, which was designed to resolve deeper crustal structures, ASTER (Advanced Spacebourne Thermal Emission and Reflection Radiometer) satellite images were used to analyze surface deformation and determine neotectonic activity.
We studied the oxidation and migration processes of inorganic compounds in iron gall inks with a combination of micro X-ray fluorescence analysis (micro-XRF) and micro X-ray absorption near edge structure spectroscopy (micro-XANES). With elemental mapping by micro-XRF, the correlation of the minor elements in the ink to the major element Fe was investigated. Along concentration profiles of Fe, micro-XANES measurements were carried out in order to determine the oxidation state and the local environment. With the help of model inks, we could show that Cu is a further important element in the paper degradation process due to iron gall ink corrosion. (C) 2004 Elsevier B.V. All rights reserved
The recent discovery of HP-LT parageneses in the basal unit of the Lycian nappes and in the Mesozoic cover of the Menderes massif leads us to reconsider and discuss the correlation of this region with the nearby collapsed Hellenides in the Aegean domain. Although similarities have long been pointed Out by various authors, a clear correlation has not yet been proposed and most authors insist more on differences than similarities. The Menderes massif is the eastern extension of the Aegean region but it has been less severely affected by the Aegean extension during the Oligo-Miocene. It would thus be useful to use the structure of the Menderes massif as an image of the Aegean region before a significant extension has considerably reduced its crustal thickness. But the lack of correlation between the two regions has so far hampered Such comparisons. We describe the main tectonic units and metamorphic events in the two regions and propose a correlation. We then show possible sections of the two regions before the Aegean extension and discuss the involvement of continental basement in the Hellenic accretionary complex. In our interpretation the Hellenic- Tauric accretionary complex was composed of stacked basement and cover units which underwent variable P-T histories. Those which were not exhumed early enough later followed a high-T evolution which led to partial melting in the Cyclades during post-orogenic extension. Although the Menderes massif contains a larger volume of basement units it does not show significant evidence for the Oligo-Miocene migmatites observed in the center of the Cyclades suggesting that crustal partial melting is strictly related to post-orogenic extension in this case
delta(18)O(benthic), values from Leg 194 Ocean Drilling Program Sites 1192 and 1195, (drilled on the Marion Plateau) were combined with deep-sea values to reconstruct the magnitude range of the late middle Miocene sea-level fall (13.6-11.4 Ma). In parallel, an estimate for the late middle Miocene sea-level fall was calculated from the stratigraphic relationship identified during Leg 194 and the structural relief of carbonate platforms that form the Marion Plateau. Corrections for thermal subsidence induced by Late Cretaceous rifting, flexural sediment loading, and sediment compaction were taken into account. The response of the lithosphere to sediment loading was considered for a range of effective elastic thicknesses (10 < T-e < 40 km). By overlapping the sea-level range of both the deep-sea isotopes and the results from the backstripping analysis, we demonstrate that the amplitude of the late middle Miocene sea-level fall was 45-68 m (56.5 +/- 11.5 m). Including an estimate for sea-level variation using the delta(18)O(benthic) results from the subtropical Marion Plateau, the range of sea-level fall is tightly constrained between 45 and 55 in (50.0 +/- 5.0 m). This result is the first precise quantitative estimate for the amplitude of the late middle Miocene eustatic fall that sidesteps the errors inherent in using benthic foraminifera assemblages to predict paleo-water depth. The estimate also includes an error analysis for the flexural response of the lithosphere to both water and sediment loads. Our result implies that the extent of ice buildup in the Miocene was larger than previously estimated, and conversely that the amount of cooling associated with this event was less important
Seismic hazard evaluation is proposed by a methodological approach that allows the study of the influence of different modelling assumptions relative to the spatial and temporal distribution of earthquakes on the maximum values of expected intensities. In particular, we show that the estimated hazard at a fixed point is very sensitive to the assumed spatial distribution of epicentres and their estimators. As we will see, the usual approach, based on uniformly distributing the epicentres inside each seismogenic zone is likely to be biased towards lower expected intensity values. This will be made more precise later. Recall that the term "bias" means, that the expectation of the estimated quantity ( taken as a random variable on the space of statistics) is different from the expectation of the quantity itself. Instead, our approach, based on an estimator that takes into account the observed clustering of events is essentially unbiased, as shown by a Monte-Carlo simulation, and is configured on a 11011-isotropic macroseismic attenuation model which is independently estimated for each zone
In recent years, H/V measurements have been increasingly used to map the thickness of sediment fill in sedimentary basins in the context of seismic hazard assessment. This parameter is believed to be an important proxy for the site effects in sedimentary basins (e.g. in the Los Angeles basin). Here we present the results of a test using this approach across an active normal fault in a structurally well known situation. Measurements on a 50 km long profile with 1 km station spacing clearly show a change in the frequency of the fundamental peak of H/V ratios with increasing thickness of the sediment layer in the eastern part of the Lower Rhine Embayment. Subsequently, a section of 10 km length across the Erft-Sprung system, a normal fault with ca. 750 m vertical offset, was measured with a station distance of 100 m. Frequencies of the first and second peaks and the first trough in the H/V spectra are used in a simple resonance model to estimate depths of the bedrock. While the frequency of the first peak shows a large scatter for sediment depths larger than ca. 500 m, the frequency of the first trough follows the changing thickness of the sediments across the fault. The lateral resolution is in the range of the station distance of 100 m. A power law for the depth dependence of the S-wave velocity derived from down hole measurements in an earlier study [Budny, 1984] and power laws inverted from dispersion analysis of micro array measurements [Scherbaum et al., 2002] agree with the results from the H/V ratios of this study
[1] The development of topography within and erosional removal of material from an orogen exerts a primary control on its structure. We develop a model that describes the temporal development of a frontally accreting, critically growing Coulomb wedge whose topography is largely limited by bedrock fluvial incision. We present general results for arbitrary initial critical wedge geometries and investigate the temporal development of a critical wedge with no initial topography. Increasing rock erodibility and/or precipitation, decreasing mass flux accreting to the wedge front, increasing wedge sole-out depth, decreasing wedge and basal decollement overpressure, and increasing basal decollement friction lead to narrow wedges. Large power law exponent values cause the wedge geometry to quickly reach a condition in which all material accreted to the front of the wedge is removed by erosion. We apply our model to the Aconcagua fold-and-thrust belt in the central Andes of Argentina where wedge development over time is well constrained. We solve for the erosional coefficient K that is required to recreate the field-constrained wedge growth history, and these values are within the range of independently determined values in analogous rock types. Using qualitative observations of rock erodibilities within the wedge, we speculate that power law exponents of 1/3 less than or equal to m less than or equal to 0.4 and 2/3 less than or equal to n less than or equal to 1 characterize the erosional growth of the Aconcagua fold-and-thrust belt. This general model may be used to understand the development of mountain belts where orogenic wedges grow as they deform at their Coulomb failure limit
[1] Orogenic structure appears to be partially controlled by the addition to and removal of material from the mountain belt by tectonic accretion and geomorphic erosion, respectively. We developed a coupled erosion-deformation model for orogenic wedges that are in erosional steady state and deform at their Coulomb failure limit. Erosional steady state is reached when all material introduced into the wedge is removed by erosion that is limited by the rate at which rivers erode through bedrock. We found that the ultimate form of a wedge is controlled by the wedge mechanical properties, sole-out depth of the basal decollement, erosional exponents, basin geometry, and the ratio of the added material flux to the erosional constant. As this latter ratio is increased, wedge width and surface slopes increase. We applied these models to the Taiwan and Himalayan orogenic wedges and found that despite a higher flux of material entering the former, the inferred ratio was larger for the latter. Calculated values for the erodibility of each wedge showed at least an order of magnitude lower value for the Himalaya relative to Taiwan. These values are consistent with the lower precipitation regime in the Himalaya relative to Taiwan and the exposure of crystalline rocks within the Himalayan orogenic wedge. Independently determined rock erodibility estimates are consistent with the accretionary wedge sediments and metasediments and the crystalline and high-grade metamorphic rocks exposed within Taiwan and the Himalaya, respectively. Therefore differences in rock type and climate apparently lead to key differences in the erosion and hence orogenic structure of these two mountain belts
A fault scaling law suggests that, over eight orders of magnitude, fault length L is linearly related to maximum displacement D. Individual faults may therefore retain a constant ratio of D/L as they grow. If erosion is minor compared with tectonic uplift, the length and along-strike relief of young mountain ranges should thus reflect fault growth. Topographic profiles along the crests of mountain ranges in the actively deforming foreland of north-east Tibet exhibit a characteristic shape with maximum height near their centre and decreasing elevation toward the tips. We interpret the along-strike relief of these ranges to reflect the slip distribution on high-angle reverse faults. A geometric model illustrates that the lateral propagation rate of such mountain ranges may be deciphered if their length- to-height ratio has remained constant. As an application of the model, we reconstruct the growth of the Heli Shan using a long-term uplift rate of similar to1.3 mm yr(-1) derived from Ne-21 and Be-10 exposure dating
We derive a slip rate for a thrust at the central Qilian Shan mountain front by combining structural investigations, satellite imagery, topographic profiling, luminescence dating, and Be-10 exposure dating. The seismically active Zhangye thrust transects late Pleistocene alluvial fan deposits and forms a prominent north facing scarp. The fault consists of two segments that differ in orientation, scarp height, and age. A series of loess-covered terraces records the uplift history of the western thrust segment. Loess accumulation on all terraces started at 8.5 +/- 1.5 kyr and postdates terrace formation. Gravels from the highest terrace yielded a Be-10 exposure age of 90 +/- 11 kyr, which dates the onset of faulting. With a displacement of 55-60 m derived from fault scarp profiles, this yields a vertical slip rate of 0.64 +/- 0.08 mm yr(-1). Along the eastern thrust segment, three Be-10 ages from the uplifted alluvial fan constrain that faulting started at similar to31 +/- 5 kyr. Together with a displacement of 25-30 m this leads to a vertical faulting rate of 0.88 +/- 0.16 mm yr(-1). A dip estimate of 40degrees to 60degrees for the fault plane combined with lower and upper limits of similar to0.6 and similar to0.9 mm yr(-1) for the vertical slip rate gives minimum and maximum horizontal shortening rates of 0.4 and 1.1 mm yr(-1) across the Zhangye thrust. Our results are consistent with geologic and GPS constraints, which suggest that NNE directed shortening across the northeastern Tibetan Plateau is distributed on several active faults with a total shortening rate of 4 to 10 mm yr(-1)
In addition to salinity and temperature, nutrient concentrations in surface waters are known to have a significant impact on distribution of carbonate-producing biota, but have never been quantitatively evaluated against different temperatures along a latitudinal transect. The western coast of the Gulf of California, Mexico, presents a natural laboratory for investigating the influence of oceanographic parameters such as salinity, temperature, and chlorophyll a, a proxy for nutrients, on the composition of a range of modern heterozoan and photozoan carbonate environments along a north-south latitudinal gradient spanning the entire warm-temperate realm (29degreesN-23degreesN). Chlorophyll a, measured in situ at half-hour resolution, is highly variable throughout the year due to short-term upwelling, and increases significantly from the southern to northern Gulf of California. Salinity, in contrast, fluctuates little and remains at an average of 35%. From south to north, carbonate production ranges from oligotrophic- mesotrophic, coral reefdominated shallow-water areas (minimum temperature 18.6 degreesC) through mesotrophic-eutrophic, red algal-dominated, inner-shelf carbonate production in the central gulf (minimum temperature 16 degreesC), and to molluscan-bryozoan, eutrophic inner- to outer-shelf environments (minimum temperature 13.7 degreesC). The Gulf of California data, supplemented with oceanographic and compositional information from a database compiled from a spectrum of modern carbonate systems worldwide, demonstrates the significance of nutrient control in the formation of heterozoan, photozoan, and transitional heterozoan-photozoan carbonate systems and serves as a basis for more accurately interpreting fossil carbonates
Earthquake swarms are often assumed to result from an intrusion of fluids into the seismogenic zone, causing seismicity patterns which significantly differ from aftershock sequences. But neither the temporal evolution nor the energy release of earthquake swarms is generally well understood. Because of the lack of descriptive empirical laws, the comparison with model simulations is typically restricted to aspects of the overall behaviour such as the frequency- magnitude distribution. However, previous investigations into a large earthquake swarm which occurred in the year 2000 in Vogtland/northwest Bohemia, Central Europe, revealed some well-defined characteristics which allow a rigorous test of model assumptions. In this study, simulations are performed of a discretized fault plane embedded in a 3-D elastic half- space. Earthquakes are triggered by fluid intrusion as well as by co-seismic and post-seismic stress changes. The model is able to reproduce the main observations, such as the fractal temporal occurrence of earthquakes, embedded aftershock sequences, and a power-law increase of the average seismic moment release. All these characteristics are found to result from stress triggering, whereas fluid diffusion is manifested in the spatiotemporal spreading of the hypocentres
Gangschwärme nehmen eine bedeutende Stellung im Verständnis zur kontinentalen Fragmentierung ein. Einerseits markieren sie das Paläo-Spannungsfeld und helfen bei der Rekonstruktion der strukturellen Entwicklung der gedehnten Lithosphäre, andererseits gibt ihre petrologische Beschaffenheit Aufschluß über die Entstehung des Magmas, Aufstieg und Platznahme und schließlich erlaubt ihre Altersbestimmung die Rekonstruktion einer chronologischen Reihenfolge magmatischer und struktureller Ereignisse. Das Arbeitsgebiet im namibianischen Henties Bay-Outjo Dike swarm (HOD) war zur Zeit der Unterkreide einem Rifting mit intensiver Platznahme von überwiegend mafischen Gängen unterworfen. Geochemische Signaturen weisen die Gänge als erodierte Förderkanäle der Etendeka Plateaubasalte aus. Durch den Einsatz von hochauflösenden Aeromagnetik- und Satellitendaten war es möglich, die Geometrie des Gangschwarmes erstmals detailliert synoptisch zu erfassen. Viele zu den Schichten des Grundgebirges foliationsparallel verlaufende magnetische Anomalien können unaufgeschlossenen kretazischen Intrusionen zugeordnet werden. Bei der nach Norden propagierenden Südatlantiköffnung spielte die unterschiedliche strukturelle Vorzeichnung durch die neoproterozoischen Faltengürtel sowie Lithologie und Spannungsfeld des Angola Kratons eine bedeutende Rolle. Im küstennahen zentralen Bereich war dank der Vorzeichnung des Nordost streichenden Damara-Faltengürtels ein Rifting in Nordwest-Südost-Richtung dominierend, bis das Angola Kraton ein weiteres Fortscheiten nach Nordosten hemmte und die Vorzeichnung des Nordwest streichenden Kaoko-Faltengürtels an der Westgrenze den weiteren Riftverlauf und die letztendlich erfolgreiche Öffnung des Südatlantiks bestimmte. Aus diesem Grund kann das Gebiet des HOD als ein failed rift betrachtet werden. Die Entwicklung des Spannungsfeldes im HOD kann folgendermaßen skizziert werden: 1. Platznahme von Gängen bei gleichzeitig hoher Dehnungsrate und hohem Magmenfluß. 2. Platznahme von Zentralvulkanen entlang reaktivierter paläozoischer Lineamente bei Abnahme der Dehnungsrate und fortbestehendem hohen Magmenfluß. 3. Abnahme/Versiegen des Magmenflusses und neotektonische Bewegungen führen zur Bildung von Halbgräben.
In the earliest emplaced granite subintrusion of the multiphase peraluminous Satzung pluton, Erzgebirge, Germany, a mineral aggregate was observed consisting of sekaninaite (X-Fe = 0.74-0.94), Zn-rich hercynite (X-Zn = 0.03- 0.11), tri- and dioctahedral layer silicates of different composition and color, and minor quartz. Geological, textural, and compositional criteria argue that the sekaninaite, hercynite, quartz, and the brown biotite are not primary or secondary granite minerals, but are of metamorphic origin representing a xenolith uptaken from the granite melt near its level of emplacement. The metamorphic origin is supported by the occurrence of this mineral assemblage in metamorphic rocks exposed locally in the Erzgebirge basement. Reaction of the polymineralic metamorphic aggregate with the surrounding melt and subsequent interaction with alkali-, F- and LILE-rich residual fluids account for the widespread decomposition of the sekaninaite and formation of several layer silicates including green biotite, muscovite, berthierine/Fe chlorite, and sericite. The observed enrichment of the relic sekaninaite and its replacement products in elements such as Na, Li, Be, Rb, Cs, and F is result of interaction of the metamorphic fragment with the surrounding melt/fluid, in accordance with the evolved nature of the Satzung magmatic-hydrothermal system
The Niederschlema-Alberoda uranium deposit, in the Erzgebirge region of Germany, contains an uncommon assemblage of metallic minerals, in particular selenides, sulfides, arsenides, tellurides, and native elements, in addition to uraninite and coffinite. The complex mineralogy resulted from the superposition of several mineralizing events over the time interval from the Permian to the Cretaceous; these events introduced and redeposited a great variety of metallic elements within the hydrothermal uranium deposit (Pb, Ag, Cu, Hg, Tl, Bi, Co, Ni, As, Sb, Se, S, Te). One of the exotic minerals is jolliffeite, an arsenoselenide with end-member composition NiAsSe, so far only known from Lake Athabasca, Saskatchewan, Canada. A single, small, anhedral grain of jolliffeite from Niederschlema-Alberoda is included and partly replaced by sulfurian eskebornite. Associated minerals comprise hematite, Ni-Co-Se-bearing lollingite, clausthalite, tiemannite, mercurian hakite-giraudite solid solutions, sulfurian berzelianite, sulfurian umangite, hessite, Ni-Co-As-bearing pyrite, and Se-rich chalcopyrite. The sulfurian jolliffeite has the empirical formula (Ni0.85Cu0.09Co0.05Fe0.02Ag0.01)Sigma(1.02)As(0.98)(Se0.77S0.23)(Sigma1. 00) and differs from type jolliffeite mainly by substantial substitution of Cu (2.6-3.3 wt.%) for Ni and S (3.2-4.1 wt.%) for Se. Substantial S-for-Se substitution in jolliffeite implies extensive and probably complete miscibility between NiAsSe and its S-dominant analogue, gersdorffite-Pa3 (NiAsS). We suggest that a localized accumulation of Ni and As in the Se-(S)-bearing hydrothermal fluid gave rise to the crystallization of jolliffeite at some rare locations at a late stage of formation of the Jurassic selenide assemblage