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The scientific drilling campaign PALEOVAN was conducted in the summer of 2010 and was part of the international continental drilling programme (ICDP). The main goal of the campaign was the recovery of a sensitive climate archive in the East of Anatolia. Lacustrine deposits underneath the lake floor of ‘Lake Van’ constitute this archive. The drilled core material was recovered from two locations: the Ahlat Ridge and the Northern Basin. A composite core was constructed from cored material of seven parallel boreholes at the Ahlat Ridge and covers an almost complete lacustrine history of Lake Van. The composite record offered sensitive climate proxies such as variations of total organic carbon, K/Ca ratios, or a relative abundance of arboreal pollen. These proxies revealed patterns that are similar to climate proxy variations from Greenland ice cores. Climate variations in Greenland ice cores have been dated by modelling the timing of orbital forces to affect the climate. Volatiles from melted ice aliquots are often taken as high-resolution proxies and provide a base for fitting the according temporal models.
The ICDP PALEOVAN scientific team fitted proxy data from the lacustrine drilling record to ice core data and constructed an age model. Embedded volcaniclastic layers had to be dated radiometrically in order to provide independent age constraints to the climate-stratigraphic age model. Solving this task by an application of the 40Ar/39Ar method was the main objective of this thesis. Earlier efforts to apply the 40Ar/39Ar dating resulted in inaccuracies that could not be explained satisfactorily.
The absence of K-rich feldspars in suitable tephra layers implied that feldspar crystals needed to be 500 μm in size minimum, in order to apply single-crystal 40Ar/39Ar dating. Some of the samples did not contain any of these grain sizes or only very few crystals of that size. In order to overcome this problem this study applied a combined single-crystal and multi-crystal approach with different crystal fractions from the same sample. The preferred method of a stepwise heating analysis of an aliquot of feldspar crystals has been applied to three samples. The Na-rich crystals and their young geological age required 20 mg of inclusion-free, non-corroded feldspars. Small sample volumes (usually 25 % aliquots of 5 cm3 of sample material – a spoon full of tephra) and the widespread presence of melt-inclusion led to the application of combined single- and multigrain total fusion analyses. 40Ar/39Ar analyses on single crystals have the advantage of being able to monitor the presence of excess 40Ar and detrital or xenocrystic contamination in the samples. Multigrain analyses may hide the effects from these obstacles. The results from the multigrain analyses are therefore discussed with respect to the findings from the respective cogenetic single crystal ages. Some of the samples in this study were dated by 40Ar/39Ar on feldspars on multigrain separates and (if available) in combination with only a few single crystals. 40Ar/39Ar ages from two of the samples deviated statistically from the age model. All other samples resulted in identical ages. The deviations displayed older ages than those obtained from the age model. t-Tests compared radiometric ages with available age control points from various proxies and from the relative paleointensity of the earth magnetic field within a stratigraphic range of ± 10 m. Concordant age control points from different relative chronometers indicated that deviations are a result of erroneous 40Ar/39Ar ages. The thesis argues two potential reasons for these ages: (1) the irregular appearance of 40Ar from rare melt- and fluid- inclusions and (2) the contamination of the samples with older crystals due to a rapid combination of assimilation and ejection.
Another aliquot of feldspar crystals that underwent separation for the application of 40Ar/39Ar dating was investigated for geochemical inhomogeneities. Magmatic zoning is ubiquitous in the volcaniclastic feldspar crystals. Four different types of magmatic zoning were detected. The zoning types are compositional zoning (C-type zoning), pseudo-oscillatory zoning of trace ele- ment concentrations (PO-type zoning), chaotic and patchy zoning of major and trace element concentrations (R-type zoning) and concentric zoning of trace elements (CC-type zoning). Sam- ples that deviated in 40Ar/39Ar ages showed C-type zoning, R-type zoning or a mix of different types of zoning (C-type and PO-type). Feldspars showing PO-type zoning typically represent the smallest grain size fractions in the samples. The constant major element compositions of these crystals are interpreted to represent the latest stages in the compositional evolution of feldspars in a peralkaline melt. PO-type crystals contain less melt- inclusions than other zoning types and are rarely corroded. This thesis concludes that feldspars that show PO-type zoning are most promising chronometers for the 40Ar/39Ar method, if samples provide mixed zoning types of Quaternary anorthoclase feldspars.
Five samples were dated by applying the 40Ar/39Ar method to volcanic glass. High fractions of atmospheric Ar (typically > 98%) significantly hampered the precision of the 40Ar/39Ar ages and resulted in rough age estimates that widely overlap the age model. Ar isotopes indicated that the glasses bore a chorine-rich Ar-end member. The chlorine-derived 38Ar indicated chlorine-rich fluid-inclusions or the hydration of the volcanic glass shards. This indication strengthened the evidence that irregularly distributed melt-inclusions and thus irregular distributed excess 40Ar influenced the problematic feldspar 40Ar/39Ar ages. Whether a connection between a corrected initial 40Ar/36Ar ratio from glasses to the 40Ar/36Ar ratios from pore waters exists remains unclear.
This thesis offers another age model, which is similarly based on the interpolation of the temporal tie points from geophysical and climate-stratigraphic data. The model used a PCHIP- interpolation (piecewise cubic hermite interpolating polynomial) whereas the older age model used a spline-interpolation. Samples that match in ages from 40Ar/39Ar dating of feldspars with the earlier published age model were additionally assigned with an age from the PCHIP- interpolation. These modelled ages allowed a recalculation of the Alder Creek sanidine mineral standard. The climate-stratigraphic calibration of an 40Ar/39Ar mineral standard proved that the age versus depth interpolations from PAELOVAN drilling cores were accurate, and that the applied chronometers recorded the temporal evolution of Lake Van synchronously.
Petrochemical discrimination of the sampled volcaniclastic material is also given in this thesis. 41 from 57 sampled volcaniclastic layers indicate Nemrut as their provenance. Criteria that served for the provenance assignment are provided and reviewed critically. Detailed correlations of selected PALEOVAN volcaniclastics to onshore samples that were described in detail by earlier studies are also discussed. The sampled volcaniclastics dominantly have a thickness of < 40 cm and have been ejected by small to medium sized eruptions. Onshore deposits from these types of eruptions are potentially eroded due to predominant strong winds on Nemrut and Süphan slopes. An exact correlation with the data presented here is therefore equivocal or not possible at all.
Deviating feldspar 40Ar/39Ar ages can possibly be explained by inherited 40Ar from feldspar xenocrysts contaminating the samples. In order to test this hypothesis diffusion couples of Ba were investigated in compositionally zoned feldspar crystals. The diffusive behaviour of Ba in feldspar is known, and gradients in the changing concentrations allowed for the calculation of the duration of the crystal’s magmatic development since the formation of the zoning interface. Durations were compared with degassing scenarios that model the Ar-loss during assimilation and subsequent ejection of the xenocrystals. Diffusive equilibration of the contrasting Ba concentrations is assumed to generate maximum durations as the gradient could have been developed in several growth and heating stages. The modelling does not show any indication of an involvement of inherited 40Ar in any of the deviating samples. However, the analytical set-up represents the lower limit of the required spatial resolution. Therefore, it cannot be excluded that the degassing modelling relies on a significant overestimation of the maximum duration of the magmatic history. Nevertheless, the modelling of xenocrystal degassing evidences that the irregular incorporation of excess 40Ar by melt- and fluid inclusions represents the most critical problem that needs to be overcome in dating volcaniclastic feldspars from the PALEOVAN drill cores. This thesis provides the complete background in generating and presenting 40Ar/39Ar ages that are compared to age data from a climate-stratigraphic model. Deviations are identified statistically and then discussed in order to find explanations from the age model and/or from 40Ar/39Ar geochronology. Most of the PALEOVAN stratigraphy provides several chronometers that have been proven for their synchronicity. Lacustrine deposits from Lake Van represent a key archive for reconstructing climate evolution in the eastern Mediterranean and in the Near East. The PALEOVAN record offers a climate-stratigraphic age model with a remarkable accuracy and resolution.
The aim of this doctoral thesis was to establish a technique for the analysis of biomolecules with infrared matrix-assisted laser dispersion (IR-MALDI) ion mobility (IM) spectrometry. The main components of the work were the characterization of the IR-MALDI process, the development and characterization of different ion mobility spectrometers, the use of IR-MALDI-IM spectrometry as a robust, standalone spectrometer and the development of a collision cross-section estimation approach for peptides based on molecular dynamics and thermodynamic reweighting.
First, the IR-MALDI source was studied with atmospheric pressure ion mobility spectrometry and shadowgraphy. It consisted of a metal capillary, at the tip of which a self-renewing droplet of analyte solution was met by an IR laser beam. A relationship between peak shape, ion desolvation, diffusion and extraction pulse delay time (pulse delay) was established. First order desolvation kinetics were observed and related to peak broadening by diffusion, both influenced by the pulse delay. The transport mechanisms in IR-MALDI were then studied by relating different laser impact positions on the droplet surface to the corresponding ion mobility spectra. Two different transport mechanisms were determined: phase explosion due to the laser pulse and electrical transport due to delayed ion extraction. The velocity of the ions stemming from the phase explosion was then measured by ion mobility and shadowgraphy at different time scales and distances from the source capillary, showing an initially very high but rapidly decaying velocity. Finally, the anatomy of the dispersion plume was observed in detail with shadowgraphy and general conclusions over the process were drawn.
Understanding the IR-MALDI process enabled the optimization of the different IM spectrometers at atmospheric and reduced pressure (AP and RP, respectively). At reduced pressure, both an AP and an RP IR-MALDI source were used. The influence of the pulsed ion extraction parameters (pulse delay, width and amplitude) on peak shape, resolution and area was systematically studied in both AP and RP IM spectrometers and discussed in the context of the IR-MALDI process. Under RP conditions, the influence of the closing field and of the pressure was also examined for both AP and RP sources. For the AP ionization RP IM spectrometer, the influence of the inlet field (IF) in the source region was also examined. All of these studies led to the determination of the optimal analytical parameters as well as to a better understanding of the initial ion cloud anatomy.
The analytical performance of the spectrometer was then studied. Limits of detection (LOD) and linear ranges were determined under static and pulsed ion injection conditions and interpreted in the context of the IR-MALDI mechanism. Applications in the separation of simple mixtures were also illustrated, demonstrating good isomer separation capabilities and the advantages of singly charged peaks. The possibility to couple high performance liquid chromatography (HPLC) to IR-MALDI-IM spectrometry was also demonstrated. Finally, the reduced pressure spectrometer was used to study the effect of high reduced field strength on the mobility of polyatomic ions in polyatomic gases.
The last focus point was on the study of peptide ions. A dataset obtained with electrospray IM spectrometry was characterized and used for the calibration of a collision cross-section (CCS) determination method based on molecular dynamics (MD) simulations at high temperature. Instead of producing candidate structures which are evaluated one by one, this semi-automated method uses the simulation as a whole to determine a single average collision cross-section value by reweighting the CCS of a few representative structures. The method was compared to the intrinsic size parameter (ISP) method and to experimental results. Additional MD data obtained from the simulations was also used to further analyze the peptides and understand the experimental results, an advantage with regard to the ISP method. Finally, the CCS of peptide ions analyzed by IR-MALDI were also evaluated with both ISP and MD methods and the results compared to experiment, resulting in a first validation of the MD method. Thus, this thesis brings together the soft ionization technique that is IR-MALDI, which produces mostly singly charged peaks, with ion mobility spectrometry, which can distinguish between isomers, and a collision cross-section determination method which also provides structural information on the analyte at hand.
Spatio-temporal data denotes a category of data that contains spatial as well as temporal components. For example, time-series of geo-data, thematic maps that change over time, or tracking data of moving entities can be interpreted as spatio-temporal data.
In today's automated world, an increasing number of data sources exist, which constantly generate spatio-temporal data. This includes for example traffic surveillance systems, which gather movement data about human or vehicle movements, remote-sensing systems, which frequently scan our surroundings and produce digital representations of cities and landscapes, as well as sensor networks in different domains, such as logistics, animal behavior study, or climate research.
For the analysis of spatio-temporal data, in addition to automatic statistical and data mining methods, exploratory analysis methods are employed, which are based on interactive visualization. These analysis methods let users explore a data set by interactively manipulating a visualization, thereby employing the human cognitive system and knowledge of the users to find patterns and gain insight into the data.
This thesis describes a software framework for the visualization of spatio-temporal data, which consists of GPU-based techniques to enable the interactive visualization and exploration of large spatio-temporal data sets. The developed techniques include data management, processing, and rendering, facilitating real-time processing and visualization of large geo-temporal data sets. It includes three main contributions:
- Concept and Implementation of a GPU-Based Visualization Pipeline.
The developed visualization methods are based on the concept of a GPU-based visualization pipeline, in which all steps -- processing, mapping, and rendering -- are implemented on the GPU. With this concept, spatio-temporal data is represented directly in GPU memory, using shader programs to process and filter the data, apply mappings to visual properties, and finally generate the geometric representations for a visualization during the rendering process. Data processing, filtering, and mapping are thereby executed in real-time, enabling dynamic control over the mapping and a visualization process which can be controlled interactively by a user.
- Attributed 3D Trajectory Visualization.
A visualization method has been developed for the interactive exploration of large numbers of 3D movement trajectories. The trajectories are visualized in a virtual geographic environment, supporting basic geometries such as lines, ribbons, spheres, or tubes. Interactive mapping can be applied to visualize the values of per-node or per-trajectory attributes, supporting shape, height, size, color, texturing, and animation as visual properties. Using the dynamic mapping system, several kind of visualization methods have been implemented, such as focus+context visualization of trajectories using interactive density maps, and space-time cube visualization to focus on the temporal aspects of individual movements.
- Geographic Network Visualization.
A method for the interactive exploration of geo-referenced networks has been developed, which enables the visualization of large numbers of nodes and edges in a geographic context. Several geographic environments are supported, such as a 3D globe, as well as 2D maps using different map projections, to enable the analysis of networks in different contexts and scales. Interactive filtering, mapping, and selection can be applied to analyze these geographic networks, and visualization methods for specific types of networks, such as coupled 3D networks or temporal networks have been implemented.
As a demonstration of the developed visualization concepts, interactive visualization tools for two distinct use cases have been developed. The first contains the visualization of attributed 3D movement trajectories of airplanes around an airport. It allows users to explore and analyze the trajectories of approaching and departing aircrafts, which have been recorded over the period of a month. By applying the interactive visualization methods for trajectory visualization and interactive density maps, analysts can derive insight from the data, such as common flight paths, regular and irregular patterns, or uncommon incidents such as missed approaches on the airport.
The second use case involves the visualization of climate networks, which are geographic networks in the climate research domain. They represent the dynamics of the climate system using a network structure that expresses statistical interrelationships between different regions. The interactive tool allows climate analysts to explore these large networks, analyzing the network's structure and relating it to the geographic background. Interactive filtering and selection enables them to find patterns in the climate data and identify e.g. clusters in the networks or flow patterns.
Die Klangeigenschaften von Musikinstrumenten werden durch das Zusammenwirken der auf ihnen anregbaren akustischen Schwingungsmoden bestimmt, welche sich wiederum aus der geometrischen Struktur des Resonators in Kombination mit den verwendeten Materialien ergeben. In dieser Arbeit wurde das Schwingungsverhalten von Streichinstrumenten durch den Einsatz minimal-invasiver piezoelektrischer Polymerfilmsensoren untersucht. Die studierten Kopplungsphänomene umfassen den sogenannten Wolfton und Schwingungstilger, die zu dessen Abschwächung verwendet werden, sowie die gegenseitige Beeinflussung von Bogen und Instrument beim Spielvorgang. An Dielektrischen Elastomeraktormembranen wurde dagegen der Einfluss der elastischen Eigenschaften des Membranmaterials auf das akustische und elektromechanische Schwingungsverhalten gezeigt. Die Dissertation gliedert sich in drei Teile, deren wesentliche Ergebnisse im Folgenden zusammengefasst werden.
In Teil I wurde die Funktionsweise eines abstimmbaren Schwingungstilgers zur Dämpfung von Wolftönen auf Streichinstrumenten untersucht. Durch Abstimmung der Resonanzfrequenz des Schwingungstilgers auf die Wolftonfrequenz kann ein Teil der Saitenschwingungen absorbiert werden, so dass die zu starke Anregung der Korpusresonanz vermieden wird, die den Wolfton verursacht. Der Schwingungstilger besteht aus einem „Wolftöter“, einem Massestück, welches auf der Nachlänge der betroffenen Saite (zwischen Steg und Saitenhalter) installiert wird. Hier wurde gezeigt, wie die Resonanzen dieses Schwingungstilgers von der Masse des Wolftöters und von dessen Position auf der Nachlänge abhängen. Aber auch die Geometrie des Wolftöters stellte sich als ausschlaggebend heraus, insbesondere bei einem nicht-rotationssymmetrischen Wolftöter: In diesem Fall entsteht – basierend auf den zu erwartenden nicht-harmonischen Moden einer massebelasteten Saite – eine zusätzliche Mode, die von der Polarisationsrichtung der Saitenschwingung abhängt.
Teil II der Dissertation befasst sich mit Elastomermembranen, die als Basis von Dielektrischen Elastomeraktoren dienen, und die wegen der Membranspannung auch akustische Resonanzen aufweisen. Die Ansprache von Elastomeraktoren hängt unter anderem von der Geschwindigkeit der elektrischen Anregung ab. Die damit zusammenhängenden viskoelastischen Eigenschaften der hier verwendeten Elastomere, Silikon und Acrylat, wurden einerseits in einer frequenzabhängigen dynamisch-mechanischen Analyse des Elastomers erfasst, andererseits auch optisch an vollständigen Aktoren selbst gemessen. Die höhere Viskosität des Acrylats, das bei tieferen Frequenzen höhere Aktuationsdehnungen als das Silikon zeigt, führt zu einer Verminderung der Dehnungen bei höheren Frequenzen, so dass über etwa 40 Hertz mit Silikon größere Aktuationsdehnungen erreicht werden. Mit den untersuchten Aktoren konnte die Gitterkonstante weicher optischer Beugungsgitter kontrolliert werden, die als zusätzlicher Film auf der Membran installiert wurden. Über eine Messung der akustischen Resonanzfrequenz von Elastomermebranen aus Acrylat in 1Abhängigkeit von ihrer Vorstreckung konnte in Verbindung mit einer Modellierung des hyperelastischen Verhaltens des Elastomers (Ogden-Modell) der Schermodul bestimmt werden.
Schließlich wird in Teil III die Untersuchung von Geigen und ihrer Streichanregung mit Hilfe minimal-invasiver piezoelektrischer Polymerfilme geschildert. Es konnten am Bogen und am Steg von Geigen – unter den beiden Füßen des Stegs – jeweils zwei Filmsensoren installiert werden. Mit den beiden Sensoren am Steg wurden Frequenzgänge von Geigen gemessen, welche eine Bestimmung der frequenzabhängigen Stegbewegung erlaubten. Diese Methode ermöglicht damit auch eine umfassende Charakterisierung der Signaturmoden in Bezug auf die Stegdynamik. Die Ergebnisse der komplementären Methoden von Impulsanregung und natürlichem Spielen der Geigen konnten dank der Sensoren verglichen werden. Für die Nutzung der Sensoren am Bogen – insbesondere für eine Messung des Bogendrucks – wurde eine Kalibrierung des Bogen-Sensor-Systems mit Hilfe einer Materialprüfmaschine durchgeführt. Bei einer Messung während des natürlichen Spielens wurde mit den Sensoren am Bogen einerseits die Übertragung der Saitenschwingung auf den Bogen festgestellt. Dabei konnten außerdem longitudinale Bogenhaarresonanzen identifiziert werden, die von der Position der Saite auf dem Bogen abhängen. Aus der Analyse dieses Phänomens konnte die longitudinale Wellengeschwindigkeit der Bogenhaare bestimmt werden, die eine wichtige Größe für die Kopplung zwischen Saite und Bogen ist. Mit Hilfe des Systems aus Sensoren an Bogen und Steg werden auf Grundlage der vorliegenden Arbeit Studien an Streichinstrumenten vorgeschlagen, in denen die Bespielbarkeit der Instrumente zu den jeweils angeregten Steg- und Bogenschwingungen in Beziehung gesetzt werden kann. Damit könnte nicht zuletzt auch die bisher nicht vollständig geklärte Rolle des Bogens für Klang und Bespielbarkeit besser beurteilt werden
In this thesis we provide a construction of the operator framework starting from the functional formulation of group field theory (GFT). We define operator algebras on Hilbert spaces whose expectation values in specific states provide correlation functions of the functional formulation. Our construction allows us to give a direct relation between the ingredients of the functional GFT and its operator formulation in a perturbative regime. Using this construction we provide an example of GFT states that can not be formulated as states in a Fock space and lead to math- ematically inequivalent representations of the operator algebra. We show that such inequivalent representations can be grouped together by their symmetry properties and sometimes break the left translation symmetry of the GFT action. We interpret these groups of inequivalent representations as phases of GFT, similar to the classification of phases that we use in QFT’s on space-time.
In this thesis, we treat the extreme Newman-Penrose components of both the Maxwell field (s=±1) and the linearized gravitational perturbations (or "linearized gravity" for short) (s=±2) in the exterior of a slowly rotating Kerr black hole. Upon different rescalings, we can obtain spin s components which satisfy the separable Teukolsky master equation (TME). For each of these spin s components defined in Kinnersley tetrad, the resulting equations by performing some first-order differential operator on it once and twice (twice only for s=±2), together with the TME, are in the form of an "inhomogeneous spin-weighted wave equation" (ISWWE) with different potentials and constitute a linear spin-weighted wave system. We then prove energy and integrated local energy decay (Morawetz) estimates for this type of ISWWE, and utilize them to achieve both a uniform bound of a positive definite energy and a Morawetz estimate for the regular extreme Newman-Penrose components defined in the regular Hawking-Hartle tetrad.
We also present some brief discussions on mode stability for TME for the case of real frequencies. This says that in a fixed subextremal Kerr spacetime, there is no nontrivial separated mode solutions to TME which are purely ingoing at horizon and purely outgoing at infinity. This yields a representation formula for solutions to inhomogeneous Teukolsky equations, and will play a crucial role in generalizing the above energy and Morawetz estimates results to the full subextremal Kerr case.
Diese Arbeit besteht aus drei Aufsätzen. Der erste Aufsatz („Die Arbeitsmarktpolitik in Südosteuropa: Von der Transformation bis zur EU-Integration“) erörtert die wirtschaftlichen und politischen Rahmenbedingungen in Südosteuropa und die damit einhergehenden Entwicklungen auf den jeweiligen Arbeitsmärkten seit 1991. Im Fokus steht dabei der Einfluss der Arbeitslosigkeit (als systemunabhängiges Problem) auf den EU-Integrationsprozess in den jugoslawischen Nachfolgestaaten und Albanien.
Welchen Einfluss haben der qualifikatorische und regionale Mismatch auf die Arbeitslosigkeit in Kroatien? Um diese Frage zu beantworten, wird im zweiten Kapitel dieser Arbeit („Arbeitslosigkeit im Transformationsprozess: Qualifikatorischer und regionaler Mismatch in Kroatien“) der Mismatch sowohl statisch mit Mismatch-Indikatoren als auch dynamisch im Rahmen der Matching-Funktion erörtert. Unter Anwendung von Paneldaten für neun Berufsgruppen und 21 Regionen im Zeitraum zwischen Januar 2004 und Juni 2015 wird in diesem Kapitel mithilfe von Fixed-Effects-Modellen dieser Einfluss geschätzt.
Führt die Anpassung der Arbeitslosenversicherungsgesetze an die EU-Standards zu einer Verbesserung der Arbeitsmarktergebnisse in den Staaten Südosteuropas? Mit Hilfe von Paneldaten für den Zeitraum 1996–2014 wird für fünf südosteuropäische Staaten (Albanien, Kroatien, Mazedonien, Montenegro und Serbien) dieser Einfluss im Rahmen eines Differenz-in-Differenzen-Modells im dritten Aufsatz („Unvollständige Integration: Eine Differenz-in-Differenzen-Analyse der südosteuropäischen Arbeitsmärkte“) geschätzt.
Be Creative, Now!
(2018)
Purpose – This thesis set out to explore, describe, and evaluate the reality behind the rhetoric of freedom and control in the context of creativity. The overarching subject is concerned with the relationship between creativity, freedom, and control, considering freedom is also seen as an element of control to manage creativity.
Design/methodology/approach – In-depth qualitative data gathered from at two innovative start-ups. Two ethnographic studies were conducted. The data are based on participatory observations, interviews, and secondary sources, each of which included a three months field study and a total of 41 interviews from both organizations.
Findings – The thesis provides explanations for the practice of freedom and the control of creativity within organizations and expands the existing theory of neo-normative control. The findings indicate that organizations use complex control systems that allow a high degree of freedom that paradoxically leads to more control. Freedom is a cover of control, which in turn leads to creativity. Covert control even results in the responsibility to be creative outside working hours.
Practical implications – Organizations, which rely on creativity might use the results of this thesis. Positive workplace control of creativity provides both freedom and structure for creative work. While freedom leads to organizational members being more motivated and committing themselves more strongly to their and the organization’s goals, and a specific structure also helps to provide the requirements for creativity.
Originality/value – The thesis provides an insight into an approach to workplace control, which has mostly neglected in creativity research and proposes a modified concept of neo-normative control. It serves to provide a further understanding of freedom for creativity and to challenge the liberal claims of new control forms.
Microswimmers, i.e. swimmers of micron size experiencing low Reynolds numbers, have received a great deal of attention in the last years, since many applications are envisioned in medicine and bioremediation. A promising field is the one of magnetic swimmers, since magnetism is biocom-patible and could be used to direct or actuate the swimmers. This thesis studies two examples of magnetic microswimmers from a physics point of view.
The first system to be studied are magnetic cells, which can be magnetic biohybrids (a swimming cell coupled with a magnetic synthetic component) or magnetotactic bacteria (naturally occurring bacteria that produce an intracellular chain of magnetic crystals). A magnetic cell can passively interact with external magnetic fields, which can be used for direction. The aim of the thesis is to understand how magnetic cells couple this magnetic interaction to their swimming strategies, mainly how they combine it with chemotaxis (the ability to sense external gradient of chemical species and to bias their walk on these gradients). In particular, one open question addresses the advantage given by these magnetic interactions for the magnetotactic bacteria in a natural environment, such as porous sediments. In the thesis, a modified Active Brownian Particle model is used to perform simulations and to reproduce experimental data for different systems such as bacteria swimming in the bulk, in a capillary or in confined geometries. I will show that magnetic fields speed up chemotaxis under special conditions, depending on parameters such as their swimming strategy (run-and-tumble or run-and-reverse), aerotactic strategy (axial or polar), and magnetic fields (intensities and orientations), but it can also hinder bacterial chemotaxis depending on the system.
The second example of magnetic microswimmer are rigid magnetic propellers such as helices or random-shaped propellers. These propellers are actuated and directed by an external rotating magnetic field. One open question is how shape and magnetic properties influence the propeller behavior; the goal of this research field is to design the best propeller for a given situation. The aim of the thesis is to propose a simulation method to reproduce the behavior of experimentally-realized propellers and to determine their magnetic properties. The hydrodynamic simulations are based on the use of the mobility matrix. As main result, I propose a method to match the experimental data, while showing that not only shape but also the magnetic properties influence the propellers swimming characteristics.
Die Dissertation untersucht die Sexualmetaphorik im Nürnberger Fastnachtspiel des 15. Jahrhunderts und wählt als Textgrundlage die Ausgabe der Nürnberger Fastnachtspiele von Adelbert von Keller als einzig vollständige Sammlung. Anliegen der Dissertation ist es, die Einzigartigkeit des Wortschatzes des Fastnachtspiels herauszuarbeiten, indem mit Fokus auf die Bildhaftigkeit und die Metaphorik der obszönen Redeweise über deren Aussage- und Wirkkraft im historischen Fastnachtspielkontext reflektiert wird. Wie die Metapher gezielt tabuisierte, intime Inhalte zum Zwecke der Komik legitimiert, wird erst theoretisch ergründet und dann in einer Interpretation der sprachlichen Gestaltung von Sexualität und Obszönität mit Blick auf den soziokulturellen Hintergrund des Nürnberger Fastnachtspiels kritisch reflektiert.
In einer interdisziplinären Annäherung werden zunächst sowohl Erkenntnisse und Theorien aus der Fastnachtspiel- und Mittelalterforschung als auch theoretische Ansätze aus der Metaphorologie und der Komikforschung zusammengetragen und diskutiert. Im Rahmen des breitgefächerten, wissenschaftlichen Diskurses zu den Fastnachtspielen wird das Nürnberger Fastnachtspiel aus inhaltlicher, funktionaler, genderbezogener, kulturgeschichtlicher und sprachlicher Perspektive beleuchtet, um ein besseres Verständnis der Sprache des Fastnachtspiels zu erlangen. Im nächsten Schritt werden das mittelalterliche Ehe- und Familienleben und die soziale und rechtliche Stellung von Mann und Frau analysiert, indem theologisch-normativer und literarischer Ehediskurs einander gegenübergestellt und gattungsspezifisch untersucht werden. So können Logiken und Verfahrensweisen in der mittelalterlichen Alltags-, Glaubens- und Rechtspraxis aufgedeckt werden. Dadurch ist es möglich, die Inszenierungen des Körpers im Fastnachtspiel einzuschätzen, die die mittelalterliche Sexualmoral verhandeln und so mannigfaltige Bilder und Vorstellungen von Mann und Frau entwerfen. Anschließend wird in der Diskussion relevanter Metapherntheorien ergründet, wie die metaphorische Sprache dabei den obszönen Inhalten gleichzeitig die Tür öffnet und sie auf Distanz hält. Bei der Betrachtung poststrukturalistischer, erkenntnistheoretischer, kognitiver, semantischer und philosophischer Theorien zur Beschreibung der Arbeits- und Wirkweise der Metapher erweisen sich insbesondere analogieorientierte und funktionale Ansätze als gewinnbringend, weil sie die Kontextualisierung der Metapher als bindend voraussetzen und sie als komplexes, metakognitives Phänomen diskutieren, das auf Interaktions- und Übertragungsprozessen beruht. Sodann werden die vielfältigen Anlässe, sozialen Formen und Funktionen des Lachens in der mittelalterlichen Gesellschaft näher in den Blick genommen, um den komisch-derbsinnlichen Duktus der Fastnachtspiele nachvollziehen zu können. Mit der Bewusstmachung wiederkehrender Elemente und Muster des Komischen kann der Unterhaltungswert der Fastnachtspielsprache exemplarisch verdeutlicht werden.
Die sich anschließende umfassende Interpretation der Fastnachtspiele wird methodisch angeleitet durch die Theorie der bildlichen Rede von Hans Georg Coenen. Er bleibt mit seinen Analogiedefinitionen der klassischen Rhetorik verpflichtet und unterscheidet unter anderem „kreative“, „konventionalisierte“ und „lexikalisierte“ Metaphern. Bei der außerordentlichen Vielfalt sexualmetaphorischer Ausdrucksweisen liegt der Fokus auf den Darstellungen der Geschlechtsorgane von Mann und Frau und dem Koitus.
Die Verfasserin gelangt zu folgenden Ergebnissen: Die Metapher sorgt durch ihre bildgestaltende Vermittlung jeweils dafür, dass der sexuelle Inhalt darstellbar wird, ohne jedoch in unmissverständlicher Direktheit auf den Betrachter zu treffen. Ob sie mit ihren alltäglichen, meist bäuerlichen Bildmotiven für die Schamsphäre über- oder untertreibt, abwertet oder aufwertet, verhüllt oder entlarvt - in jedweder Form und Gestalt kann die Metapher den sexuellen Inhalt ästhetisieren. Weil sie ihn unter neuer oder anderer Perspektive betrachtet, entrückt sie ihn formal. Damit erscheint das Sprechen über Sexualität in der metaphorischen Rede wie auf Abstand gerechtfertigt und das Ausmaß bzw. Übermaß der Inszenierung von Sexualität im Fastnachtspiel überhaupt erst möglich. Häufig werden Bilder vom Penis als Esel, von der Vagina als Wiese und vom Koitus als Speerkampf entworfen. Die Metapher stellt damit gewohnte Vorstellungen von Mann und Frau mitsamt den normativ gesetzten Erwartungen und Strukturen im Eheleben auf den Kopf. Das kann als obszön und unanständig, aber auch als amüsant empfunden worden sein und heute noch empfunden werden. Immer bleibt die Metapher dabei ambigue. In ihrer mehrkanaligen Wirkweise, ihrer innovativen Kraft und auch in ihrer Widersprüchlichkeit liegen ihre dichterische Begabung und ihre Qualität zur Komisierung. Damit stellt sich die kunstfertige Sprache des Fastnachtspiels der Körperlichkeit der Spielinhalte entgegen.
Die Dissertation demonstriert das innovative, normkritische Potenzial der Fastnachtspielsprache, die sie als eine Poetik der Ambiguität lesbar und als einen Schatz an vielfältigen und differenzierten Ausdrucksweisen für die Schamsphäre wertschätzbar macht. Damit leistet die Arbeit einen wichtigen Beitrag zur sprach- und literaturwissenschaftlichen Analyse des Nürnberger Fastnachtsspiels und zu einem differenzierteren Verständnis von dessen kulturgeschichtlicher Bedeutung.
Global climate change is one of the greatest challenges of the 21st century, with influence on the environment, societies, politics and economies. The (semi-)arid areas of Southern Africa already suffer from water scarcity. There is a great variety of ongoing research related to global climate history but important questions on regional differences still exist.
In southern African regions terrestrial climate archives are rare, which makes paleoclimate studies challenging. Based on the assumption that continental pans (sabkhas) represent a suitable geo-archive for the climate history, two different pans were studied in the southern and western Kalahari Desert. A combined approach of molecular biological and biogeochemical analyses is utilized to investigate the diversity and abundance of microorganisms and to trace temporal and spatial changes in paleoprecipitation in arid environments. The present PhD thesis demonstrates the applicability of pan sediments as a late Quaternary geo-archive based on microbial signature lipid biomarkers, such as archaeol, branched and isoprenoid glycerol dialkyl glycerol tetraethers (GDGTs) as well as phospholipid fatty acids (PLFA). The microbial signatures contained in the sediment provide information on the current or past microbial community from the Last Glacial Maximum to the recent epoch, the Holocene. The results are discussed in the context of regional climate evolution in southwestern Africa. The seasonal shift of the Innertropical Convergence Zone (ITCZ) along the equator influences the distribution of precipitation- and climate zones. The different expansion of the winter- and summer rainfall zones in southern Africa was confirmed by the frequency of certain microbial biomarkers. A period of increased precipitation in the south-western Kalahari could be described as a result of the extension of the winter rainfall zone during the last glacial maximum (21 ± 2 ka). Instead a period of increased paleoprecipitation in the western Kalahari was indicated during the Late Glacial to Holocene transition. This was possibly caused by a southwestern shift in the position of the summer rainfall zone associated to the southward movement of the ITCZ.
Furthermore, for the first time this study characterizes the bacterial and archaeal life based on 16S rRNA gene high-throughput sequencing in continental pan sediments and provides an insight into the recent microbial community structure. Near-surface processes play an important role for the modern microbial ecosystem in the pans. Water availability as well as salinity might determine the abundance and composition of the microbial communities. The microbial community of pan sediments is dominated by halophilic and dry-adapted archaea and bacteria. Frequently occurring microorganisms such as, Halobacteriaceae, Bacillus and Gemmatimonadetes are described in more detail in this study.
Mit der New Economic Geography (NEG) kann die Verteilung von Unternehmen und Arbeitskräften auf Regionen modellhaft diskutiert werden. In diesem Beitrag wird untersucht, welche räumlichen Verteilungen der mobilen Arbeitskräfte und Unternehmen in einem NEG-Modellansatz resultieren, wenn die Größe einer Region und damit der ihr zur Verfügung stehende Boden, die zu überwindende Distanz für den Gütertransport innerhalb der Regionen, sowie Bodennutzungskonkurrenzen zwischen Wohnen, Industrie und Landwirtschaft berücksichtigt werden. Auch wird der Frage nachgegangen, welche Wohlfahrtswirkungen hierbei resultieren.
In the thesis there are constructed new quantizations for pseudo-differential boundary value problems (BVPs) on manifolds with edge. The shape of operators comes from Boutet de Monvel’s calculus which exists on smooth manifolds with boundary. The singular case, here with edge and boundary, is much more complicated. The present approach simplifies the operator-valued symbolic structures by using suitable Mellin quantizations on infinite stretched model cones of wedges with boundary. The Mellin symbols themselves are, modulo smoothing ones, with asymptotics, holomorphic in the complex Mellin covariable. One of the main results is the construction of parametrices of elliptic elements in the corresponding operator algebra, including elliptic edge conditions.
Basaltic fissure eruptions, such as on Hawai'i or on Iceland, are thought to be driven by the lateral propagation of feeder dikes and graben subsidence. Associated solid earth processes, such as deformation and structural development, are well studied by means of geophysical and geodetic technologies. The eruptions themselves, lava fountaining and venting dynamics, in turn, have been much less investigated due to hazardous access, local dimension, fast processes, and resulting poor data availability.
This thesis provides a detailed quantitative understanding of the shape and dynamics of lava fountains and the morphological changes at their respective eruption sites. For this purpose, I apply image processing techniques, including drones and fixed installed cameras, to the sequence of frames of video records from two well-known fissure eruptions in Hawai'i and Iceland. This way I extract the dimensions of multiple lava fountains, visible in all frames. By putting these results together and considering the acquisition times of the frames I quantify the variations in height, width and eruption velocity of the lava fountains. Then I analyse these time-series in both time and frequency domains and investigate the similarities and correlations between adjacent lava fountains. Following this procedure, I am able to link the dynamics of the individual lava fountains to physical parameters of the magma transport in the feeder dyke of the fountains.
The first case study in this thesis focuses on the March 2011 Pu'u'O'o eruption, Hawai'i, where a continuous pulsating behaviour at all eight lava fountains has been observed. The lava fountains, even those from different parts of the fissure that are closely connected, show a similar frequency content and eruption behaviour. The regular pattern in the heights of lava fountain suggests a controlling process within the magma feeder system like a hydraulic connection in the underlying dyke, affecting or even controlling the pulsating behaviour.
The second case study addresses the 2014-2015 Holuhraun fissure eruption, Iceland. In this case, the feeder dyke is highlighted by the surface expressions of graben-like structures and fault systems. At the eruption site, the activity decreases from a continuous line of fire of ~60 vents to a limited number of lava fountains. This can be explained by preferred upwards magma movements through vertical structures of the pre-eruptive morphology. Seismic tremors during the eruption reveal vent opening at the surface and/or pressure changes in the feeder dyke. The evolving topography of the cinder cones during the eruption interacts with the lava fountain behaviour. Local variations in the lava fountain height and width are controlled by the conduit diameter, the depth of the lava pond and the shape of the crater. Modelling of the fountain heights shows that long-term eruption behaviour is controlled mainly by pressure changes in the feeder dyke.
This research consists of six chapters with four papers, including two first author and two co-author papers. It establishes a new method to analyse lava fountain dynamics by video monitoring. The comparison with the seismicity, geomorphologic and structural expressions of fissure eruptions shows a complex relationship between focussed flow through dykes, the morphology of the cinder cones, and the lava fountain dynamics at the vents of a fissure eruption.
Fluvial terraces, floodplains, and alluvial fans are the main landforms to store sediments and to decouple hillslopes from eroding mountain rivers. Such low-relief landforms are also preferred locations for humans to settle in otherwise steep and poorly accessible terrain. Abundant water and sediment as essential sources for buildings and infrastructure make these areas amenable places to live at. Yet valley floors are also prone to rare and catastrophic sedimentation that can overload river systems by abruptly increasing the volume of sediment supply, thus causing massive floodplain aggradation, lateral channel instability, and increased flooding. Some valley-fill sediments should thus record these catastrophic sediment pulses, allowing insights into their timing, magnitude, and consequences.
This thesis pursues this theme and focuses on a prominent ~150 km2 valley fill in the Pokhara Valley just south of the Annapurna Massif in central Nepal. The Pokhara Valley is conspicuously broad and gentle compared to the surrounding dissected mountain terrain,
and is filled with locally more than 70 m of clastic debris. The area’s main river, Seti Khola, descends from the Annapurna Sabche Cirque at 3500-4500 m asl down to 900 m asl where it incises into this valley fill. Humans began to settle on this extensive
fan surface in the 1750’s when the Trans-Himalayan trade route connected the Higher Himalayas, passing Pokhara city, with the subtropical lowlands of the Terai. High and unstable river terraces and steep gorges undermined by fast flowing rivers with highly seasonal (monsoon-driven) discharge, a high earthquake risk, and a growing population make the Pokhara Valley an ideal place to study the recent geological and geomorphic history of its sediments and the implication for natural hazard appraisals.
The objective of this thesis is to quantify the timing, the sedimentologic and geomorphic processes as well as the fluvial response to a series of strong sediment pulses. I report
diagnostic sedimentary archives, lithofacies of the fan terraces, their geochemical provenance, radiocarbon-age dating and the stratigraphic relationship between them. All these various and independent lines of evidence show consistently that multiple sediment pulses filled the Pokhara Valley in medieval times, most likely in connection with, if not triggered by, strong seismic ground shaking. The geomorphic and sedimentary evidence is
consistent with catastrophic fluvial aggradation tied to the timing of three medieval Himalayan earthquakes in ~1100, 1255, and 1344 AD. Sediment provenance and calibrated radiocarbon-age data are the key to distinguish three individual sediment pulses, as these are not evident from their sedimentology alone. I explore various measures of adjustment and fluvial response of the river system following these massive aggradation pulses. By using proxies such as net volumetric erosion, incision and erosion rates, clast provenance on active river banks, geomorphic markers such as re-exhumed tree trunks in growth position, and knickpoint locations in tributary valleys, I estimate the response of the river network in the Pokhara Valley to earthquake disturbance over several centuries. Estimates of the removed volumes since catastrophic valley filling began, require average net sediment
yields of up to 4200 t km−2 yr−1 since, rates that are consistent with those reported for Himalayan rivers. The lithological composition of active channel-bed load differs from that of local bedrock material, confirming that rivers have adjusted 30-50% depending on data of different tributary catchments, locally incising with rates of 160-220 mm yr−1. In many tributaries to the Seti Khola, most of the contemporary river loads come from a Higher Himalayan source, thus excluding local hillslopes as sources. This imbalance in sediment provenance emphasizes how the medieval sediment pulses must have rapidly traversed up to 70 km downstream to invade the downstream reaches of the tributaries
up to 8 km upstream, thereby blocking the local drainage and thus reinforcing, or locally creating new, floodplain lakes still visible in the landscape today.
Understanding the formation, origin, mechanism and geomorphic processes of this valley fill is crucial to understand the landscape evolution and response to catastrophic sediment pulses. Several earthquake-triggered long-runout rock-ice avalanches or catastrophic dam burst in the Higher Himalayas are the only plausible mechanisms to explain both the geomorphic and sedimentary legacy that I document here. In any case, the Pokhara Valley was most likely hit by a cascade of extremely rare processes over some two centuries starting in the early 11th century. Nowhere in the Himalayas do we find valley fills of
comparable size and equally well documented depositional history, making the Pokhara Valley one of the most extensively dated valley fill in the Himalayas to date. Judging from the growing record of historic Himalayan earthquakes in Nepal that were traced and
dated in fault trenches, this thesis shows that sedimentary archives can be used to directly aid reconstructions and predictions of both earthquake triggers and impacts from a sedimentary-response perspective. The knowledge about the timing, evolution, and response of the Pokhara Valley and its river system to earthquake triggered sediment pulses is important to address the seismic and geomorphic risk for the city of Pokhara. This
thesis demonstrates how geomorphic evidence on catastrophic valley infill can help to independently verify paleoseismological fault-trench records and may initiate re-thinking on post-seismic hazard assessments in active mountain regions.
Characterization of altered inflorescence architecture in Arabidopsis thaliana BG-5 x Kro-0 hybrid
(2018)
A reciprocal cross between two A. thaliana accessions, Kro-0 (Krotzenburg, Germany) and BG-5 (Seattle, USA), displays purple rosette leaves and dwarf bushy phenotype in F1 hybrids when grown at 17 °C and a parental-like phenotype when grown at 21 °C. This F1 temperature-dependent-dwarf-bushy phenotype is characterized by reduced growth of the primary stem together with an increased number of branches. The reduced stem growth was the strongest at the first internode. In addition, we found that a temperature switch from 21 °C to 17 °C induced the phenotype only before the formation of the first internode of the stem. Similarly, the F1 dwarf-bushy phenotype could not be reversed when plants were shifted from 17 °C to 21 °C after the first internode was formed. Metabolic analysis showed that the F1 phenotype was associated with a significant upregulation of anthocyanin(s), kaempferol(s), salicylic acid, jasmonic acid and abscisic acid. As it has been previously shown that the dwarf-bushy phenotype is linked to two loci, one on chromosome 2 from Kro-0 and one on chromosome 3 from BG-5, an artificial micro-RNA approach was used to investigate the necessary genes on these intervals. From the results obtained, it was found that two genes, AT2G14120 that encodes for a DYNAMIN RELATED PROTEIN3B and AT2G14100 that encodes a member of the Cytochrome P450 family protein CYP705A13, were necessary for the appearance of the F1 phenotype on chromosome 2. It was also discovered that AT3G61035 that encodes for another cytochrome P450 family protein CYP705A13 and AT3G60840 that encodes for a MICROTUBULE-ASSOCIATED PROTEIN65-4 on chromosome 3 were both necessary for the induction of the F1 phenotype. To prove the causality of these genes, genomic constructs of the Kro-0 candidate genes on chromosome 2 were transferred to BG-5 and genomic constructs of the chromosome 3 candidate genes from BG-5 were transferred to Kro-0. The T1 lines showed that these genes are not sufficient alone to induce the phenotype. In addition to the F1 phenotype, more severe phenotypes were observed in the F2 generations that were grouped into five different phenotypic classes. Whilst seed yield was comparable between F1 hybrids and parental lines, three phenotypic classes in the F2 generation exhibited hybrid breakdown in the form of reproductive failure. This F2 hybrid breakdown was less sensitive to temperature and showed a dose-dependent effect of the loci involved in F1 phenotype. The severest class of hybrid breakdown phenotypes was observed only in the population of backcross with the parent Kro-0, which indicates a stronger contribution of the BG-5 allele when compared to the Kro-0 allele on the hybrid breakdown phenotypes. Overall, the findings of my thesis provide a further understanding of the genetic and metabolic factors underlying altered shoot architecture in hybrid dysfunction.
Remote sensing technology, such as airborne, mobile, or terrestrial laser scanning, and photogrammetric techniques, are fundamental approaches for efficient, automatic creation of digital representations of spatial environments. For example, they allow us to generate 3D point clouds of landscapes, cities, infrastructure networks, and sites. As essential and universal category of geodata, 3D point clouds are used and processed by a growing number of applications, services, and systems such as in the domains of urban planning, landscape architecture, environmental monitoring, disaster management, virtual geographic environments as well as for spatial analysis and simulation.
While the acquisition processes for 3D point clouds become more and more reliable and widely-used, applications and systems are faced with more and more 3D point cloud data. In addition, 3D point clouds, by their very nature, are raw data, i.e., they do not contain any structural or semantics information. Many processing strategies common to GIS such as deriving polygon-based 3D models generally do not scale for billions of points. GIS typically reduce data density and precision of 3D point clouds to cope with the sheer amount of data, but that results in a significant loss of valuable information at the same time.
This thesis proposes concepts and techniques designed to efficiently store and process massive 3D point clouds. To this end, object-class segmentation approaches are presented to attribute semantics to 3D point clouds, used, for example, to identify building, vegetation, and ground structures and, thus, to enable processing, analyzing, and visualizing 3D point clouds in a more effective and efficient way. Similarly, change detection and updating strategies for 3D point clouds are introduced that allow for reducing storage requirements and incrementally updating 3D point cloud databases. In addition, this thesis presents out-of-core, real-time rendering techniques used to interactively explore 3D point clouds and related analysis results. All techniques have been implemented based on specialized spatial data structures, out-of-core algorithms, and GPU-based processing schemas to cope with massive 3D point clouds having billions of points.
All proposed techniques have been evaluated and demonstrated their applicability to the field of geospatial applications and systems, in particular for tasks such as classification, processing, and visualization. Case studies for 3D point clouds of entire cities with up to 80 billion points show that the presented approaches open up new ways to manage and apply large-scale, dense, and time-variant 3D point clouds as required by a rapidly growing number of applications and systems.
This project was focused on exploring the phase behavior of poly(styrene)187000-block-poly(2-vinylpyridine)203000 (SV390) with high molecular weight (390 kg/mol) in thin films, in which the self-assembly of block copolymers (BCPs) was realized via thermo-solvent annealing. The advanced processing technique of solvent vapor treatment provides controlled and stable conditions.
In Chapter 3, the factors to influence the annealing process and the swelling behavior of homopolymers are presented and discussed. The swelling behavior of BCP in films is controlled by the temperature of the vapor and of the substrate, on one hand, and variation of the saturation of the solvent vapor atmosphere (different solvents), on the other hand. Additional factors like the geometry and material of the chamber, the type of flow inside the chamber etc. also influence the reproducibility and stability of the processing. The slightly selective solvent vapor of chloroform gives 10% more swelling of P2VP than PS in films with thickness of ~40 nm.
The tunable morphology in ultrathin films of high molecular weight BCP (SV390) was investigated in Chapter 4. First, the swelling behavior can be precisely tuned by temperature and/or vapor flow separately, which provided information for exploring the multiple-parameter-influenced segmental chain mobility of polymer films. The equilibrium state of SV390 in thin films influenced by temperature was realized at various temperatures with the same degree of swelling. Various methods including characterization with SFM, metallization and RIE were used to identify the morphology of films as porous half-layer with PS dots and P2VP matrix. The kinetic investigations demonstrate that on substrates with either weak or strong interaction the original morphology of the BCP with high molecular weight is changed very fast within 5 min, and the further annealing serves for annihilation of defects.
The morphological development of symmetric BCP in films with thickness increasing from half-layer to one-layer influenced by confinement factors of gradient film thicknesses and various surface properties of substrates was studied in Chapter 5. SV390 and SV99 films show bulk lamella-forming morphology after slightly selective solvent vapor (chloroform) treatment. SV99 films show cylinder-forming morphology under strongly selective solvent vapor (toluene) treatment since the asymmetric structure (caused by toluene uptake in PS blocks only) of SV99 block copolymer during annealing. Both kinds of morphology (lamella and cylinder) are influenced by the film thickness. The annealed morphology of SV390 and SV99 influenced by the combination of confined film and substrate property is similar to the morphology on flat silicon wafers. In this chapter the gradients in the film thickness and surface properties of the substrates with regard to their influence on the morphological development in thin BCP films are presented. Directed self-assembly (graphoepitaxy) of this SV390 was also investigated to compare with systematically reported SV99.
In Chapter 6 an approach to induced oriented microphase separation in thick block copolymer films via treatment with the oriented vapor flow using mini-extruder is envisaged to be an alternative to existing methodologies, e.g. via non-solvent-induced phase separation. The preliminary tests performed in this study confirm potential perspective of this method, which alters the structure through the bulk of the film (as revealed by SAXS measurements), but more detailed studies have to be conducted in order to optimize the preparation.
To reach its climate targets, the European Union has to implement a major sustainability transition in the coming decades. While the socio-technical change required for this transition is well discussed in the academic literature, the economics that go along with it are often reduced to a cost-benefit perspective of climate policy measures. By investigating climate change mitigation as a coordination problem, this thesis offers a novel perspective: It integrates the economic and the socio-technical dimension and thus allows to better understand the opportunities of a sustainability transition in Europe.
First, a game theoretic framework is developed to illustrate coordination on green or brown investment from an agent perspective. A model based on the coordination game "stag hunt" is used to discuss the influence of narratives and signals for green investment as a means to coordinate expectations towards green growth. Public and private green investment impulses – triggered by credible climate policy measures and targets – serve as an example for a green growth perspective for Europe in line with a sustainability transition. This perspective also embodies a critical view on classical analyses of climate policy measures.
Secondly, this analysis is enriched with empirical results derived from stakeholder involvement. In interviews and with a survey among European insurance companies, coordination mechanisms such as market and policy signals are identified and evaluated by their impact on investment strategies for green infrastructure. The latter, here defined as renewable energy, electricity distribution and transmission as well as energy efficiency improvements, is considered a central element of the transition to a low-carbon society.
Thirdly, this thesis identifies and analyzes major criticisms raised towards stakeholder involvement in sustainability science. On a conceptual level, different ways of conducting such qualitative research are classified. This conceptualization is then evaluated by scientists, thereby generating empirical evidence on ideals and practices of stakeholder involvement in sustainability science.
Through the combination of theoretical and empirical research on coordination problems, this thesis offers several contributions: On the one hand, it outlines an approach that allows to assess the economic opportunities of sustainability transitions. This is helpful for policy makers in Europe that are striving to implement climate policy measures addressing the targets of the Paris Agreement as well as to encourage a shift of investments towards green infrastructure. On the other hand, this thesis enhances the stabilization of the theoretical foundations in sustainability science. Therefore, it can aid researchers who involve stakeholders when studying sustainability transitions.
Die Arbeit beschäftigt sich mit den aktuellen Regelungen des deutschen Aufenthaltsrechts in Bezug auf die Möglichkeiten des Familiennachzuges. Es werden Schwachstellen der aktuellen Regelungen aufgezeigt, Ursachen, Rechtfertigungsgründe und mögliche Lösungsansätze betrachtet.
Schwerpunkt der Betrachtung sind die Konflikte, welche sich unter dem Begriff der Inländerdiskriminierung zusammenfassen lassen. Hierzu wird das Phänomen der Inländerdiskriminierung untersucht und die im Kontext des Familiennachzuges hierzu ergangene Rechtsprechung des EuGH betrachtet. Dabei gilt das Hauptaugenmerk der Figur des grenzüberschreitenden Bezuges, welche der EuGH im Ergebnis mittlerweile aufgelöst hat. Als Ergebnis dieses Abschnittes der Arbeit wird festgestellt, dass eine Unterscheidung von Nachzug zu Deutschen oder zu Unionsbürgern gegen Gleichheitssätze verstößt und aufzuheben ist.
Weiterhin betrachtet die Arbeit verschiedene alternative Lebensmodelle neben der klassischen verschiedengeschlechtlichen Ehe. In Bezug auf gleichgeschlechtliche Lebensgemeinschaften werden auch nach Einführung der „Ehe für alle“ weitere Schwachstellen verortet, die vor allem darauf fußen, dass Nachzugsrechte vom Bestehen eines Instituts abhängen, welches in großen Teilen der Welt nicht gibt. In Hinblick auf nichtehelichen Lebensgemeinschaften wird hingegen die geltende Rechtslage als ausreichend betrachtet. Zuletzt betrachtet die Arbeit Ehemodelle, welche im deutschen Recht nicht vorgesehen und anerkannt sind. Dies sind die Zwangs-, Kinder- und Mehrehe. Es wird beleuchtet, wie das deutsche Recht und insbesondere das Aufenthaltsrecht mit diesen Ehen umgeht und welcher Zweck mit den bestehenden Regelungen verfolgt wird. Während der Gesetzgeber den Schutz der Opfer solcher Eheschließungen vor Augen hatte, kommt die Untersuchung zu dem Ergebnis, dass vielmehr eine weitere Gefährdung eintritt, welche nur zu vermeiden wäre, wenn auch diese Ehemodelle zunächst anerkannt würden und den Opfern im Inland sodann Hilfe angeboten würde.
Insgesamt stellt die Arbeit gravierende Mängel in menschenrechtlicher Hinsicht im bestehenden Recht des Familiennachzugs fest und schlägt eine generelle Neuordnung vor.
Die betrachteten Regelungen entsprechen dem Regelungsstand im Juli 2018.