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- Kar, P. (34)
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La Wehrmacht tenía muy claro a qué escala podía esperar capturar a las tropas soviéticas, pero aun así descuidó los preparativos necesarios para alimentar y alojar a unos hombres que los planificadores económicos y los jefes militares consideraron que serían competidores directos de las fuerzas armadas en lo que a víveres se refiere. Las obvias limitaciones a su libertad de movimiento y la relativa facilidad con la que grandes cantidades de ellos pudieron ser segregados y sus raciones controladas fueron factores cruciales a la hora de explicar la muerte de más de tres millones de prisioneros de guerra soviéticos, la inmensa mayoría de ellos como consecuencia directa o indirecta del hambre y la desnutrición. El proceso se inició con un claro desinterés por encargarse debidamente de aquella gente, pero con la llegada del otoño derivó en la decisión clara y meditada de matar de hambre a todos los que no pudieran aportar su trabajo a la economía de guerra o a los ejércitos alemanes.
Nwosu, Ebuka Canisius ; Roeser, Patricia Angelika ; Yang, Sizhong ; Ganzert, Lars ; Dellwig, Olaf ; Pinkerneil, Sylvia ; Brauer, Achim ; Dittmann, Elke ; Wagner, Dirk ; Liebner, Susanne
Sedimentary ancient DNA-based studies have been used to probe centuries of climate and environmental changes and how they affected cyanobacterial assemblages in temperate lakes. Due to cyanobacteria containing potential bloom-forming and toxin-producing taxa, their approximate reconstruction from sediments is crucial, especially in lakes lacking long-term monitoring data. To extend the resolution of sediment record interpretation, we used high-throughput sequencing, amplicon sequence variant (ASV) analysis, and quantitative PCR to compare pelagic cyanobacterial composition to that in sediment traps (collected monthly) and surface sediments in Lake Tiefer See. Cyanobacterial composition, species richness, and evenness was not significantly different among the pelagic depths, sediment traps and surface sediments (p > 0.05), indicating that the cyanobacteria in the sediments reflected the cyanobacterial assemblage in the water column. However, total cyanobacterial abundances (qPCR) decreased from the metalimnion down the water column. The aggregate-forming (Aphanizomenon) and colony-forming taxa (Snowella) showed pronounced sedimentation. In contrast, Planktothrix was only very poorly represented in sediment traps (meta- and hypolimnion) and surface sediments, despite its highest relative abundance at the thermocline (10 m water depth) during periods of lake stratification (May-October). We conclude that this skewed representation in taxonomic abundances reflects taphonomic processes, which should be considered in future DNA-based paleolimnological investigations.
Sulfated biomolecules are known to influence numerous biological processes in all living organisms. Particularly, they contribute to prevent and inhibit the hypercoagulation condition. The failure of polymeric implants and blood contacting devices is often related to hypercoagulation and microbial contamination. Here, bioactive sulfated biomacromolecules are mimicked by sulfation of poly(glycerol glycidyl ether) (polyGGE) films. Autoclaving, gamma-ray irradiation and ethylene oxide (EtO) gas sterilization techniques were applied to functionalized materials. The sulfate group density and hydrophilicity of sulfated polymers were decreased while chain mobility and thermal degradation were enhanced post autoclaving when compared to those after EtO sterilization. These results suggest that a quality control after sterilization is mandatory to ensure the amount and functionality of functionalized groups are retained.
Peña, Carlos ; Metzger, Sabrina ; Heidbach, Oliver ; Bedford, Jonathan ; Bookhagen, Bodo ; Moreno, Marcos ; Oncken, Onno ; Cotton, Fabrice
Megathrust earthquakes impose changes of differential stress and pore pressure in the lithosphere-asthenosphere system that are transiently relaxed during the postseismic period primarily due to afterslip, viscoelastic and poroelastic processes.
Especially during the early postseismic phase, however, the relative contribution of these processes to the observed surface deformation is unclear.
To investigate this, we use geodetic data collected in the first 48 days following the 2010 Maule earthquake and a poro-viscoelastic forward model combined with an afterslip inversion.
This model approach fits the geodetic data 14% better than a pure elastic model. Particularly near the region of maximum coseismic slip, the predicted surface poroelastic uplift pattern explains well the observations.
If poroelasticity is neglected, the spatial afterslip distribution is locally altered by up to +/- 40%.
Moreover, we find that shallow crustal aftershocks mostly occur in regions of increased postseismic pore-pressure changes, indicating that both processes might be mechanically coupled.
Garbusow, Maria ; Ebrahimi, Claudia ; Riemerschmid, Carlotta ; Daldrup, Luisa ; Rothkirch, Marcus ; Chen, Ke ; Chen, Hao ; Belanger, Matthew J. ; Hentschel, Angela ; Smolka, Michael ; Heinz, Andreas ; Pilhatsch, Maximilan ; Rapp, Michael A.
A mechanism known as Pavlovian-to-instrumental transfer (PIT) describes a phenomenon by which the values of environmental cues acquired through Pavlovian conditioning can motivate instrumental behavior. PIT may be one basic mechanism of action control that can characterize mental disorders on a dimensional level beyond current classification systems. Therefore, we review human PIT studies investigating subclinical and clinical mental syndromes. The literature prevails an inhomogeneous picture concerning PIT. While enhanced PIT effects seem to be present in non-substance-related disorders, overweight people, and most studies with AUD patients, no altered PIT effects were reported in tobacco use disorder and obesity. Regarding AUD and relapsing alcohol-dependent patients, there is mixed evidence of enhanced or no PIT effects.
Additionally, there is evidence for aberrant corticostriatal activation and genetic risk, e.g., in association with high-risk alcohol consumption and relapse after alcohol detoxification. In patients with anorexia nervosa, stronger PIT effects elicited by low caloric stimuli were associated with increased disease severity.
In patients with depression, enhanced aversive PIT effects and a loss of action-specificity associated with poorer treatment outcomes were reported. Schizophrenic patients showed disrupted specific but intact general PIT effects. Patients with chronic back pain showed reduced PIT effects.
We provide possible reasons to understand heterogeneity in PIT effects within and across mental disorders. Further, we strengthen the importance of reliable experimental tasks and provide test-retest data of a PIT task showing moderate to good reliability.
Finally, we point toward stress as a possible underlying factor that may explain stronger PIT effects in mental disorders, as there is some evidence that stress per se interacts with the impact of environmental cues on behavior by selectively increasing cue-triggered wanting.
To conclude, we discuss the results of the literature review in the light of Research Domain Criteria, suggesting future studies that comprehensively assess PIT across psychopathological dimensions.
Kamjunke, Norbert ; Beckers, Liza-Marie ; Herzsprung, Peter ; von Tümpling, Wolf ; Lechtenfeld, Oliver ; Tittel, Jörg ; Risse-Buhl, Ute ; Rode, Michael ; Wachholz, Alexander ; Kallies, Rene ; Schulze, Tobias ; Krauss, Martin ; Brack, Werner ; Comero, Sara ; Gawlik, Bernd Manfred ; Skejo, Hello ; Tavazzi, Simona ; Mariani, Giulio ; Borchardt, Dietrich ; Weitere, Markus
On their way from inland to the ocean, flowing water bodies, their constituents and their biotic communities are ex-posed to complex transport and transformation processes. However, detailed process knowledge as revealed by La-grangian measurements adjusted to travel time is rare in large rivers, in particular at hydrological extremes. To fill this gap, we investigated autotrophic processes, heterotrophic carbon utilization, and micropollutant concentrations applying a Lagrangian sampling design in a 600 km section of the River Elbe (Germany) at historically low discharge. Under base flow conditions, we expect the maximum intensity of instream processes and of point source impacts. Phy-toplankton biomass and photosynthesis increased from upstream to downstream sites but maximum chlorophyll con-centration was lower than at mean discharge. Concentrations of dissolved macronutrients decreased to almost complete phosphate depletion and low nitrate values. The longitudinal increase of bacterial abundance and production was less pronounced than in wetter years and bacterial community composition changed downstream. Molecular analyses revealed a longitudinal increase of many DOM components due to microbial production, whereas saturated lipid-like DOM, unsaturated aromatics and polyphenols, and some CHOS surfactants declined. In decomposition exper-iments, DOM components with high O/C ratios and high masses decreased whereas those with low O/C ratios, low masses, and high nitrogen content increased at all sites. Radiocarbon age analyses showed that DOC was relatively old (890-1870 years B.P.), whereas the mineralized fraction was much younger suggesting predominant oxidation of algal lysis products and exudates particularly at downstream sites. Micropollutants determining toxicity for algae (terbuthylazine, terbutryn, isoproturon and lenacil), hexachlorocyclohexanes and DDTs showed higher concentrations from the middle towards the downstream part but calculated toxicity was not negatively correlated to phytoplankton. Overall, autotrophic and heterotrophic process rates and micropollutant concentrations increased from up-to down-stream reaches, but their magnitudes were not distinctly different to conditions at medium discharges.
Stoof-Leichsenring, Kathleen R. ; Huang, Sichao ; Liu, Sisi ; Jia, Weihan ; Li, Kai ; Liu, Xingqi ; Pestryakova, Luidmila A. ; Herzschuh, Ulrike
Arctic and alpine aquatic ecosystems are changing rapidly under recent global warming, threatening water resources by diminishing trophic status and changing biotic composition. Macrophytes play a key role in the ecology of freshwaters and we need to improve our understanding of long-term macrophytes diversity and environmental change so far limited by the sporadic presence of macrofossils in sediments.
In our study, we applied metabarcoding using the trnL P6 loop marker to retrieve macrophyte richness and composition from 179 surface-sediment samples from arctic Siberian and alpine Chinese lakes and three representative lake cores.
The surface-sediment dataset suggests that macrophyte richness and composition are mostly affected by temperature and conductivity, with highest richness when mean July temperatures are higher than 12 degrees C and conductivity ranges between 40 and 400 mu S cm(-1). Compositional turnover during the Late Pleistocene/Holocene is minor in Siberian cores and characterized by a less rich, but stable emergent macrophyte community. Richness decreases during the Last Glacial Maximum and rises during wetter and warmer climate in the Late-glacial and Mid-Holocene.
In contrast, we detect a pronounced change from emergent to submerged taxa at 14 ka in the Tibetan alpine core, which can be explained by increasing temperature and conductivity due to glacial runoff and evaporation.
Our study provides evidence for the suitability of the trnL marker to recover modern and past macrophyte diversity and its applicability for the response of macrophyte diversity to lake-hydrochemical and climate variability predicting contrasting macrophyte changes in arctic and alpine lakes under intensified warming and human impact.
Land-use type temporarily affects active pond community structure but not gene expression patterns
(2022)
Bizic, Mina ; Ionescu, Danny ; Karnatak, Rajat ; Musseau, Camille L. ; Onandia, Gabriela ; Berger, Stella A. ; Nejstgaard, Jens C. ; Lischeid, Gunnar ; Gessner, Mark O. ; Wollrab, Sabine ; Grossart, Hans-Peter
Changes in land use and agricultural intensification threaten biodiversity and ecosystem functioning of small water bodies. We studied 67 kettle holes (KH) in an agricultural landscape in northeastern Germany using landscape-scale metatranscriptomics to understand the responses of active bacterial, archaeal and eukaryotic communities to land-use type. These KH are proxies of the millions of small standing water bodies of glacial origin spread across the northern hemisphere. Like other landscapes in Europe, the study area has been used for intensive agriculture since the 1950s. In contrast to a parallel environmental DNA study that suggests the homogenization of biodiversity across KH, conceivably resulting from long-lasting intensive agriculture, land-use type affected the structure of the active KH communities during spring crop fertilization, but not a month later. This effect was more pronounced for eukaryotes than for bacteria. In contrast, gene expression patterns did not differ between months or across land-use types, suggesting a high degree of functional redundancy across the KH communities. Variability in gene expression was best explained by active bacterial and eukaryotic community structures, suggesting that these changes in functioning are primarily driven by interactions between organisms. Our results indicate that influences of the surrounding landscape result in temporary changes in the activity of different community members. Thus, even in KH where biodiversity has been homogenized, communities continue to respond to land management. This potential needs to be considered when developing sustainable management options for restoration purposes and for successful mitigation of further biodiversity loss in agricultural landscapes.
A room full of ‘views’
(2023)
Quantitative research into the effectiveness of the UN human rights treaty bodies (UNTBs) in eliciting remedial responses from states is impeded by a lack of usable data on how states respond to their decisions. The new Treaty Body Views Dataset (TBVD) aims to fill this gap. It comprises details on all published decisions in individual complaints cases issued by the UNTBs between 1979 and 2019 and matches these with information on their state of compliance. The TBVD can be used for research on the activities of the treaty bodies, the nature of the decisions themselves, or state behavior following a decision. An empirical application illustrates how the TBVD can advance knowledge about the factors that correlate with compliance with adverse UNTB decisions. Results show that the likelihood of implementation hinges critically on decision-level characteristics, and reveal differences and similarities between compliance with UNTB decisions and regional human rights court judgments.
LegacyPollen 1.0
(2022)
Herzschuh, Ulrike ; Li, Chenzhi ; Boehmer, Thomas ; Postl, Alexander K. ; Heim, Birgit ; Andreev, Andrei A. ; Cao, Xianyong ; Wieczorek, Mareike ; Ni, Jian
Here we describe the LegacyPollen 1.0, a dataset of 2831 fossil pollen records with metadata, a harmonized taxonomy, and standardized chronologies.
A total of 1032 records originate from North America, 1075 from Europe, 488 from Asia, 150 from Latin America, 54 from Africa, and 32 from the Indo-Pacific.
The pollen data cover the late Quaternary (mostly the Holocene). The original 10 110 pollen taxa names (including variations in the notations) were harmonized to 1002 terrestrial taxa (including Cyperaceae), with woody taxa and major herbaceous taxa harmonized to genus level and other herbaceous taxa to family level.
The dataset is valuable for synthesis studies of, for example, taxa areal changes, vegetation dynamics, human impacts (e.g., deforestation), and climate change at global or continental scales.
The harmonized pollen and metadata as well as the harmonization table are available from PANGAEA (https://doi.org/10.1594/PANGAEA.929773; Herzschuh et al., 2021). R code for the harmonization is provided at Zenodo (https://doi.org/10.5281/zenodo.5910972; Herzschuh et al., 2022) so that datasets at a customized harmonization level can be easily established.
Michaelis, Vivien ; Aengenheister, Leonie ; Tuchtenhagen, Max ; Rinklebe, Jörg ; Ebert, Franziska ; Schwerdtle, Tanja ; Buerki-Thurnherr, Tina ; Bornhorst, Julia
Manganese (Mn) as well as iron (Fe) are essential trace elements (TE) important for the maintenance of physiological functions including fetal development. However, in the case of Mn, evidence suggests that excess levels of intrauterine Mn are associated with adverse pregnancy outcomes. Although Mn is known to cross the placenta, the fundamentals of Mn transfer kinetics and mechanisms are largely unknown. Moreover, exposure to combinations of TEs should be considered in mechanistic transfer studies, in particular for TEs expected to share similar transfer pathways. Here, we performed a mechanistic in vitro study on the placental transfer of Mn across a BeWo b30 trophoblast layer. Our data revealed distinct differences in the placental transfer of Mn and Fe. While placental permeability to Fe showed a clear inverse dose-dependency, Mn transfer was largely independent of the applied doses. Concurrent exposure of Mn and Fe revealed transfer interactions of Fe and Mn, indicating that they share common transfer mechanisms. In general, mRNA and protein expression of discussed transporters like DMT1, TfR, or FPN were only marginally altered in BeWo cells despite the different exposure scenarios highlighting that Mn transfer across the trophoblast layer likely involves a combination of active and passive transport processes.
Klaus, Benita ; Müller, Patrick ; van Wickeren, Nora ; Dordevic, Milos ; Schmicker, Marlen ; Zdunczyk, Yael ; Brigadski, Tanja ; Lessmann, Volkmar ; Vielhaber, Stefan ; Schreiber, Stefanie ; Müller, Notger G.
Myasthenia gravis is an autoimmune disease affecting neuromuscular transmission and causing skeletal muscle weakness. Additionally, systemic inflammation, cognitive deficits and autonomic dysfunction have been described.
However, little is known about myasthenia gravis-related reorganization of the brain. In this study, we thus investigated the structural and functional brain changes in myasthenia gravis patients.
Eleven myasthenia gravis patients (age: 70.64 +/- 9.27; 11 males) were compared to age-, sex- and education-matched healthy controls (age: 70.18 +/- 8.98; 11 males). Most of the patients (n = 10, 0.91%) received cholinesterase inhibitors.
Structural brain changes were determined by applying voxel-based morphometry using high-resolution T-1-weighted sequences. Functional brain changes were assessed with a neuropsychological test battery (including attention, memory and executive functions), a spatial orientation task and brain-derived neurotrophic factor blood levels.
Myasthenia gravis patients showed significant grey matter volume reductions in the cingulate gyrus, in the inferior parietal lobe and in the fusiform gyrus. Furthermore, myasthenia gravis patients showed significantly lower performance in executive functions, working memory (Spatial Span, P = 0.034, d = 1.466), verbal episodic memory (P = 0.003, d = 1.468) and somatosensory-related spatial orientation (Triangle Completion Test, P = 0.003, d = 1.200).
Additionally, serum brain-derived neurotrophic factor levels were significantly higher in myasthenia gravis patients (P = 0.001, d = 2.040). Our results indicate that myasthenia gravis is associated with structural and functional brain alterations. Especially the grey matter volume changes in the cingulate gyrus and the inferior parietal lobe could be associated with cognitive deficits in memory and executive functions.
Furthermore, deficits in somatosensory-related spatial orientation could be associated with the lower volumes in the inferior parietal lobe. Future research is needed to replicate these findings independently in a larger sample and to investigate the underlying mechanisms in more detail.
Klaus et al. compared myasthenia gravis patients to matched healthy control subjects and identified functional alterations in memory functions as well as structural alterations in the cingulate gyrus, in the inferior parietal lobe and in the fusiform gyrus.
Large-scale groundwater models are required to estimate groundwater availability and to inform water management strategies on the national scale.
However, parameterization of large-scale groundwater models covering areas of major river basins and more is challenging due to the lack of observational data and the mismatch between the scales of modeling and measurements.
In this work, we propose to bridge the scale gap and derive regional hydraulic parameters by spectral analysis of groundwater level fluctuations.
We hypothesize that specific locations in aquifers can reveal regional parameters of the hydraulic system.
We first generate ensembles of synthetic but realistic aquifers which systematically differ in complexity. Applying Liang and Zhang's (2013), , semi-analytical solution for the spectrum of hydraulic head time series, we identify for each ensemble member and at different locations representative aquifer parameters.
Next, we extend our study to investigate the use of spectral analysis in more complex numerical models and in real settings.
Our analyses indicate that the variance of inferred effective transmissivity and storativity values for stochastic aquifer ensembles is small for observation points which are far away from the Dirichlet boundary.
Moreover, the head time series has to cover a period which is roughly 10 times as long as the characteristic time of the aquifer. In deterministic aquifer models we infer equivalent, regionally valid parameters. A sensitivity analysis further reveals that as long as the aquifer length and the position of the groundwater measurement location is roughly known, the parameters can be robustly estimated.
Worldwide, companies are increasingly making claims about their current climate efforts and their future mitigation commitments. These claims tend to be underpinned by carbon credits issued in voluntary carbon markets to offset emissions. Corporate climate claims are largely unregulated which means that they are often (perceived to be) misleading and deceptive. As such, corporate climate claims risk undermining, rather than contributing to, global climate mitigation. This paper takes as its point of departure the proposition that a better understanding of corporate climate claims is needed to govern such claims in a manner that adequately addresses potential greenwashing risks. To that end, the paper reviews the nascent literature on corporate climate claims relying on the use of voluntary carbon credits. Drawing on the reviewed literature, three key dimensions of corporate climate claims as related to carbon credits are discussed: 1) the intended use of carbon credits: offsetting versus non-offsetting claims; 2) the framing and meaning of headline terms: net-zero versus carbon neutral claims; and 3) the status of the claim: future aspirational commitments versus stated achievements. The paper thereby offers a preliminary categorization of corporate climate claims and discusses risks associated with and governance implications for each of these categories.
The 2022 Kunming-Montreal Global Biodiversity Framework (GBF) and Paris Agreement (PA) are highly complementary agreements where each depends on the other’s success to be effective. The GBF offers a very specific framework of interim goals and targets that break down the objective of the Convention on Biodiversity (CBD) into a decade-spanning work plan. Comprised of 10 sections – including a 2050 vision and a 2030 mission, four overarching goals and 23 specific targets – the GBF is expected to guide biodiversity policy around the world in the coming years to decades. A similar set of global interim climate policy targets could translate the global temperature goal into concrete policy milestones that would provide policy makers and civil society with reference points for policy making and efforts to hold governments accountable. Beyond inspiring climate policy experts to convert temperature goals into policy milestones, GBF has the potential to strengthen the implementation of the PA at the nexus of biodiversity and climate (adaptation and mitigation) action. For example, the GBF can help to ensure that nature-based climate solutions are implemented with full consideration of biodiversity concerns, of the rights and interests of Indigenous Peoples and local communities, and with fair and transparent benefit sharing arrangements. In sum, the GBF should be mandatory reading for all climate policy makers.
From laggards to leaders
(2021)
The 2015 Paris Agreement on climate change embraces the participation of non-state actors in a separate governance track – the ‘Non-state actor zone for global action’ (nazca) – that runs alongside the formal track of unfccc negotiations and the implementation of the Paris Agreement by State Parties through ‘nationally determined contributions’. unfccc Secretariat is entrusted with orchestrating non-state global and transnational initiatives, partnerships and networks. The involvement of non-state actors in the implementation of the Paris Agreement helps to address an action gap by countries that are unable or unwilling to implement ambitious ndcs.
However, the increased prominence of initiatives driven by non-state actors also increases their direct and indirect influence on processes and rules which raises a number of questions with regards to the legitimacy of action and the democratic deficit of the global climate regime. Balancing legitimacy with effectiveness requires non-state initiatives to ensure transparent and inclusive governance, and accountability towards progress against their goals and pledges.
Despite its encouragement towards private initiatives, the Paris Agreement creates surprisingly little regulatory space for non-state actors to gain hold. Neither are there measures that would link ndcs to nazca initiatives, nor are functional requirements such as transparency or reporting extended to non-state initiatives. While the Paris Agreement marks an important step towards harnessing private sector ability and ambition for climate action, more remains to be done to create a truly enabling framework for private action to strive and complement public efforts to address climate change.
Wiese, Heike ; Alexiadou, Artemis ; Allen, Shanley ; Bunk, Oliver ; Gagarina, Natalia ; Iefremenko, Kateryna ; Martynova, Maria ; Pashkova, Tatiana ; Rizou, Vicky ; Schroeder, Christoph ; Shadrova, Anna ; Szucsich, Luka ; Tracy, Rosemarie ; Tsehaye, Wintai ; Zerbian, Sabine ; Zuban, Yulia
We argue for a perspective on bilingual heritage speakers as native speakers of both their languages and present results from a large-scale, cross-linguistic study that took such a perspective and approached bilinguals and monolinguals on equal grounds.
We targeted comparable language use in bilingual and monolingual speakers, crucially covering broader repertoires than just formal language. A main database was the open-access RUEG corpus, which covers comparable informal vs. formal and spoken vs. written productions by adolescent and adult bilinguals with heritage-Greek, -Russian, and -Turkish in Germany and the United States and with heritage-German in the United States, and matching data from monolinguals in Germany, the United States, Greece, Russia, and Turkey. Our main results lie in three areas.
(1) We found non-canonical patterns not only in bilingual, but also in monolingual speakers, including patterns that have so far been considered absent from native grammars, in domains of morphology, syntax, intonation, and pragmatics.
(2) We found a degree of lexical and morphosyntactic inter-speaker variability in monolinguals that was sometimes higher than that of bilinguals, further challenging the model of the streamlined native speaker.
(3) In majority language use, non-canonical patterns were dominant in spoken and/or informal registers, and this was true for monolinguals and bilinguals. In some cases, bilingual speakers were leading quantitatively. In heritage settings where the language was not part of formal schooling, we found tendencies of register leveling, presumably due to the fact that speakers had limited access to formal registers of the heritage language.
Our findings thus indicate possible quantitative differences and different register distributions rather than distinct grammatical patterns in bilingual and monolingual speakers. This supports the integration of heritage speakers into the native-speaker continuum. Approaching heritage speakers from this perspective helps us to better understand the empirical data and can shed light on language variation and change in native grammars.
Furthermore, our findings for monolinguals lead us to reconsider the state-of-the art on majority languages, given recurring evidence for non-canonical patterns that deviate from what has been assumed in the literature so far, and might have been attributed to bilingualism had we not included informal and spoken registers in monolinguals and bilinguals alike.
L’impero della distruzione
(2022)
La prima storia complessiva degli efferati crimini nazisti, che dimostra come diffuse e generalizzate politiche di sterminio fossero cruciali per la strategia del regime al fine di vincere la guerra e impossessarsi del mondo. La Germania nazista uccise circa tredici milioni di civili e altri non combattenti con deliberate politiche di omicidi di massa, soprattutto durante gli anni della guerra. Quasi la metà delle vittime furono ebree, sistematicamente annientate dall'Olocausto, fulcro del programma paneuropeo di purificazione razziale messo in atto dai nazisti. Alex Kay sostiene che è anche possibile esaminare il genocidio degli ebrei europei inserendolo nel contesto piú ampio delle uccisioni di massa naziste. Per la prima volta, L'impero della distruzione considera gli ebrei europei insieme a tutti gli altri principali gruppi di vittime: prigionieri dell'Armata Rossa, popolazione urbana sovietica, civili inermi vittime di terrore preventivo e rappresaglie, disabili psichici e fisici, rom europei e intellighenzia polacca. Ciascuno di questi gruppi era considerato dal regime nazista come una potenziale minaccia alla capacità della Germania di condurre con successo una guerra per l'egemonia in Europa. Un'opera fondamentale e innovativa che associa i numeri complessivi dello sterminio con la ricostruzione di singoli casi di orrore quotidiano.
The present study proposes and tests pathways by which racial discrimination might be positively related to bullying victimization among Black and White adolescents. Data were derived from the 2016 National Survey of Children's Health, a national survey that provides data on children's physical and mental health and their families. Data were collected from households with one or more children between June 2016 to February 2017.
A letter was sent to randomly selected households, who were invited to participate in the survey. The caregivers consisted of 66.9% females and 33.1% males for the White sample, whose mean age was 47.51 (SD = 7.26), and 76.8% females and 23.2% males for the Black sample, whose mean age was 47.61 (SD = 9.71).
In terms of the adolescents, 49.0% were females among the White sample, whose mean age was 14.73 (SD = 1.69). For Black adolescents, 47.9% were females and the mean age was 14.67(SD = 1.66).
Measures for the study included bullying perpetration, racial discrimination, academic disengagement, and socio-demographic variables of the parent and child.
Analyses included descriptive statistics, bivariate correlations, and structural path analyses.
For adolescents in both racial groups, racial discrimination appears to be positively associated with depression, which was positively associated with bullying perpetration. For White adolescents, racial discrimination was positively associated with academic disengagement, which was also positively associated with bullying perpetration. For Black adolescents, although racial discrimination was not significantly associated with academic disengagement, academic disengagement was positively associated with bullying perpetration.
The holocaust in the USSR
(2021)
This paper sketches the current status of international scholarship on the subject of the Holocaust in the USSR and its place in the wider military conflict of the Second World War. Research on this topic over the last 20 to 30 years has been truly international and the findings of this research cannot be sketched here without pointing to the contributions made by German, American, Russian, Israeli, British and Australian historians. Historians from these countries have made important contributions to our understanding of key questions relating to this subject. These questions address, among other things, pre-invasion orders issued to German units; the radicalisation of German policy, culminating in the root-and-branch extermination of Soviet Jewry; the network of ghettos set up on Soviet territory; the nature of the killing and the methods used to murder these victims; the total death toll of the Holocaust in the USSR; and the relationship between war and extermination, in which genocide can be regarded as an actual strategy of warfare pursued by the German Reich.
forum:logopädie 36.2022, 4
(2022)
Taleb, Aiham ; Rohrer, Csaba ; Bergner, Benjamin ; De Leon, Guilherme ; Rodrigues, Jonas Almeida ; Schwendicke, Falk ; Lippert, Christoph ; Krois, Joachim
High annotation costs are a substantial bottleneck in applying deep learning architectures to clinically relevant use cases, substantiating the need for algorithms to learn from unlabeled data.
In this work, we propose employing self-supervised methods. To that end, we trained with three self-supervised algorithms on a large corpus of unlabeled dental images, which contained 38K bitewing radiographs (BWRs). We then applied the learned neural network representations on tooth-level dental caries classification, for which we utilized labels extracted from electronic health records (EHRs). Finally, a holdout test-set was established, which consisted of 343 BWRs and was annotated by three dental professionals and approved by a senior dentist.
This test-set was used to evaluate the fine-tuned caries classification models. Our experimental results demonstrate the obtained gains by pretraining models using self-supervised algorithms. These include improved caries classification performance (6 p.p. increase in sensitivity) and, most importantly, improved label-efficiency.
In other words, the resulting models can be fine-tuned using few labels (annotations).
Our results show that using as few as 18 annotations can produce >= 45% sensitivity, which is comparable to human-level diagnostic performance.
This study shows that self-supervision can provide gains in medical image analysis, particularly when obtaining labels is costly and expensive.
Stuenzi, Simone Maria ; Kruse, Stefan ; Boike, Julia ; Herzschuh, Ulrike ; Oehme, Alexander ; Pestryakova, Luidmila A. ; Westermann, Sebastian ; Langer, Moritz
Boreal forests cover over half of the global permafrost area and protect underlying permafrost. Boreal forest development, therefore, has an impact on permafrost evolution, especially under a warming climate.
Forest disturbances and changing climate conditions cause vegetation shifts and potentially destabilize the carbon stored within the vegetation and permafrost. Disturbed permafrost-forest ecosystems can develop into a dry or swampy bush- or grasslands, shift toward broadleaf- or evergreen needleleaf-dominated forests, or recover to the pre-disturbance state.
An increase in the number and intensity of fires, as well as intensified logging activities, could lead to a partial or complete ecosystem and permafrost degradation. We study the impact of forest disturbances (logging, surface, and canopy fires) on the thermal and hydrological permafrost conditions and ecosystem resilience.
We use a dynamic multilayer canopy-permafrost model to simulate different scenarios at a study site in eastern Siberia. We implement expected mortality, defoliation, and ground surface changes and analyze the interplay between forest recovery and permafrost. We find that forest loss induces soil drying of up to 44%, leading to lower active layer thicknesses and abrupt or steady decline of a larch forest, depending on disturbance intensity.
Only after surface fires, the most common disturbances, inducing low mortality rates, forests can recover and overpass pre-disturbance leaf area index values. We find that the trajectory of larch forests after surface fires is dependent on the precipitation conditions in the years after the disturbance. Dryer years can drastically change the direction of the larch forest development within the studied period.
Filbert, Alfred
(2022)
Bibliographie-Eintrag: Der Jurist Alfred Filbert gehörte von 1935 bis 1945 zu den Funktionseliten im Hauptamt des Sicherheitsdienstes des Reichsführers-SS und im Reichssicherheitshauptamt. 1941 verantwortete er als Leiter des SS-Einsatzkommandos 9 die Ermordung von rund 18 000 Juden. 1945 untergetaucht, wurde er 1959 verhaftet, 1962 zu lebenslanger Haft verurteilt und 1975 vorzeitig entlassen.
Das Reich der Vernichtung
(2022)
Der organisierte Massenmord an ethnischen und sozialen Bevölkerungsgruppen als Kriegsstrategie. Von 1939 bis 1945 ermordete das nationalsozialistische Regime rund 13 Millionen Zivilisten und andere Nichtkombattanten in Vernichtungslagern und außerhalb davon. Fast die Hälfte der Opfer des Nationalsozialismus waren Juden. Die Judenverfolgung und die Shoah sind in der Geschichte ohne Beispiel, aber als Teil eines systematischen Massenmordprogramms zu betrachten. Zu den Opfern der NS-Verbrechen gehörten auch Behinderte, Roma, polnische Eliten, gefangene Rotarmisten und unbewaffnete Zivilisten. Der Massenmord als Kriegsstrategie: die erste integrative, umfassende Analyse. Vom britischen Historiker Alex J. Kay, der bereits fünf bedeutende Bücher über die Zeit des Nationalsozialismus veröffentlicht hat. Die Geschichte des Holocausts und die Ermordung ethnischer und sozialer Bevölkerungsgruppen. Fundamentaler Beitrag zur Aufarbeitung der nationalsozialistischen Verbrechen im 2. Weltkrieg. Die erste integrative Gesamtdarstellung der Völkermord-Politik des NS-Regimes. Erstmals führt Alex J. Kay die systematischen Mordprogramme und ihre Opfer in einer differenzierten Darstellung der deutschen Kriegsverbrechen zusammen. Es wird deutlich, dass Genozid und Vergeltungsmaßnahmen integrativer Bestandteil der Kriegsstrategie zur Durchsetzung der nationalsozialistischen Ideologie waren. In seiner bahnbrechenden Analyse zeigt er, wie eine strategisch geplante, staatliche Politik des Massenmords Millionen von Menschen das Leben kostete.
Reeve, Holly A. ; Nicholson, Jake ; Altaf, Farieha ; Lonsdale, Thomas H. ; Preissler, Janina ; Lauterbach, Lars ; Lenz, Oliver ; Leimkühler, Silke ; Hollmann, Frank ; Paul, Caroline E. ; Vincent, Kylie A.
We demonstrate a recycling system for synthetic nicotinamide cofactor analogues using a soluble hydrogenase with turnover number of >1000 for reduction of the cofactor analogues by H-2.
Coupling this system to an ene reductase, we show quantitative conversion of N-ethylmaleimide to N-ethylsuccinimide.
The biocatalyst system retained >50% activity after 7 h.
Roe, Stephanie ; Streck, Charlotte ; Beach, Robert ; Busch, Jonah ; Chapman, Melissa ; Daioglou, Vassilis ; Deppermann, Andre ; Doelman, Jonathan ; Emmet-Booth, Jeremy ; Engelmann, Jens ; Fricko, Oliver ; Frischmann, Chad ; Funk, Jason ; Grassi, Giacomo ; Griscom, Bronson ; Havlik, Petr ; Hanssen, Steef ; Humpenöder, Florian ; Landholm, David ; Lomax, Guy ; Lehmann, Johannes ; Mesnildrey, Leah ; Nabuurs, Gert-Jan ; Popp, Alexander ; Rivard, Charlotte ; Sanderman, Jonathan ; Sohngen, Brent ; Smith, Pete ; Stehfest, Elke ; Woolf, Dominic ; Lawrence, Deborah
Land-based climate mitigation measures have gained significant attention and importance in public and private sector climate policies. Building on previous studies, we refine and update the mitigation potentials for 20 land-based measures in >200 countries and five regions, comparing “bottom-up” sectoral estimates with integrated assessment models (IAMs). We also assess implementation feasibility at the country level. Cost-effective (available up to $100/tCO2eq) land-based mitigation is 8–13.8 GtCO2eq yr−1 between 2020 and 2050, with the bottom end of this range representing the IAM median and the upper end representing the sectoral estimate. The cost-effective sectoral estimate is about 40% of available technical potential and is in line with achieving a 1.5°C pathway in 2050. Compared to technical potentials, cost-effective estimates represent a more realistic and actionable target for policy. The cost-effective potential is approximately 50% from forests and other ecosystems, 35% from agriculture, and 15% from demand-side measures. The potential varies sixfold across the five regions assessed (0.75–4.8 GtCO2eq yr−1) and the top 15 countries account for about 60% of the global potential. Protection of forests and other ecosystems and demand-side measures present particularly high mitigation efficiency, high provision of co-benefits, and relatively lower costs. The feasibility assessment suggests that governance, economic investment, and socio-cultural conditions influence the likelihood that land-based mitigation potentials are realized. A substantial portion of potential (80%) is in developing countries and LDCs, where feasibility barriers are of greatest concern. Assisting countries to overcome barriers may result in significant quantities of near-term, low-cost mitigation while locally achieving important climate adaptation and development benefits. Opportunities among countries vary widely depending on types of land-based measures available, their potential co-benefits and risks, and their feasibility. Enhanced investments and country-specific plans that accommodate this complexity are urgently needed to realize the large global potential from improved land stewardship.
Silva, Bibiana ; Oliveira Costa, Ana Carolina ; Tchewonpi, Sorel Sagu ; Bönick, Josephine ; Huschek, Gerd ; Gonzaga, Luciano Valdemiro ; Fett, Roseane ; Baldermann, Susanne ; Rawel, Harshadrai Manilal
Honey traceability is an important topic, especially for honeydew honeys, due to the increased incidence of adulteration. This study aimed to establish specific markers to quantify proteins in honey. A proteomics strategy to identify marker peptides from bracatinga honeydew honey was therefore developed. The proteomics approach was based on initial untargeted identification of honey proteins and peptides by LC-ESI-Triple-TOF-MS/MS, which identified the major royal jelly proteins (MRJP) presence. Afterwards, the peptides were selected by the in silico digestion. The marker peptides were quantified by the developed targeted LC-QqQ-MS/MS method, which provided good linearity and specificity, besides recoveries between 92 and 100% to quantify peptides from bracatinga honeydew honey. The uniqueness and high response in mass spectrometry were backed by further complementary protein analysis (SDS-PAGE). The selected marker peptides EALPHVPIFDR (MRJP 1), ILGANVK (MRJP 2), TFVTIER (MRJP 3), QNIDVVAR (MRJP 4), FINNDYNFNEVNFR (MRJP 5) and LLQPYPDWSWTK (MRJP 7), quantified by LC-QqQ-MS/MS, highlighted that the content of QNIDVVAR from MRJP 4 could be used to differentiate bracatinga honeydew honey from floral honeys (p < 0.05) as a potential marker for its authentication. Finally, principal components analysis highlighted the QNIDVVAR content as a good descriptor of the analyzed bracatinga honeydew honey samples.
Stevanato, Luca ; Baroni, Gabriele ; Oswald, Sascha ; Lunardon, Marcello ; Mareš, Vratislav ; Marinello, Francesco ; Moretto, Sandra ; Polo, Matteo ; Sartori, Paolo ; Schattan, Paul ; Rühm, Werner
Measuring the variability of incoming neutrons locally would be usefull for the cosmic-ray neutron sensing (CRNS) method. As the measurement of high energy neutrons is not so easy, alternative particles can be considered for such purpose. Among them, muons are particles created from the same cascade of primary cosmic-ray fluxes that generate neutrons at the ground. In addition, they can be easily detected by small and relatively inexpensive detectors. For these reasons they could provide a suitable local alternative to incoming corrections based on remote neutron monitor data. The reported measurements demonstrated that muon detection system can detect incoming cosmic-ray variations locally. Furthermore the precision of this measurement technique is considered adequate for many CRNS applications.
Svennevig, Kristian ; Hermanns, Reginald L. ; Keiding, Marie ; Binder, Daniel ; Citterio, Michele ; Dahl-Jensen, Trine ; Mertl, Stefan ; Sørensen, Erik Vest ; Voss, Peter Henrik
A large landslide (frozen debris avalanche) occurred at Assapaat on the south coast of the Nuussuaq Peninsula in Central West Greenland on June 13, 2021, at 04:04 local time. We present a compilation of available data from field observations, photos, remote sensing, and seismic monitoring to describe the event. Analysis of these data in combination with an analysis of pre- and post-failure digital elevation models results in the first description of this type of landslide. The frozen debris avalanche initiated as a 6.9 * 10(6) m(3) failure of permafrozen talus slope and underlying colluvium and till at 600-880 m elevation. It entrained a large volume of permafrozen colluvium along its 2.4 km path in two subsequent entrainment phases accumulating a total volume between 18.3 * 10(6) and 25.9 * 10(6) m(3). About 3.9 * 10(6) m(3) is estimated to have entered the Vaigat strait; however, no tsunami was reported, or is evident in the field. This is probably because the second stage of entrainment along with a flattening of slope angle reduced the mobility of the frozen debris avalanche. We hypothesise that the initial talus slope failure is dynamically conditioned by warming of the ice matrix that binds the permafrozen talus slope. When the slope ice temperature rises to a critical level, its shear resistance is reduced, resulting in an unstable talus slope prone to failure. Likewise, we attribute the large-scale entrainment to increasing slope temperature and take the frozen debris avalanche as a strong sign that the permafrost in this region is increasingly at a critical state. Global warming is enhanced in the Arctic and frequent landslide events in the past decade in Western Greenland let us hypothesise that continued warming will lead to an increase in the frequency and magnitude of these types of landslides. Essential data for critical arctic slopes such as precipitation, snowmelt, and ground and surface temperature are still missing to further test this hypothesis. It is thus strongly required that research funds are made available to better predict the change of landslide threat in the Arctic.
A novel idea for an optimal time delay state space reconstruction from uni- and multivariate time series is presented. The entire embedding process is considered as a game, in which each move corresponds to an embedding cycle and is subject to an evaluation through an objective function. This way the embedding procedure can be modeled as a tree, in which each leaf holds a specific value of the objective function. By using a Monte Carlo ansatz, the proposed algorithm populates the tree with many leafs by computing different possible embedding paths and the final embedding is chosen as that particular path, which ends at the leaf with the lowest achieved value of the objective function. The method aims to prevent getting stuck in a local minimum of the objective function and can be used in a modular way, enabling practitioners to choose a statistic for possible delays in each embedding cycle as well as a suitable objective function themselves. The proposed method guarantees the optimization of the chosen objective function over the parameter space of the delay embedding as long as the tree is sampled sufficiently. As a proof of concept, we demonstrate the superiority of the proposed method over the classical time delay embedding methods using a variety of application examples. We compare recurrence plot-based statistics inferred from reconstructions of a Lorenz-96 system and highlight an improved forecast accuracy for map-like model data as well as for palaeoclimate isotope time series. Finally, we utilize state space reconstruction for the detection of causality and its strength between observables of a gas turbine type thermoacoustic combustor.
Kong, Xiangzhen ; Ghaffar, Salman ; Determann, Maria ; Friese, Kurt ; Jomaa, Seifeddine ; Mi, Chenxi ; Shatwell, Tom ; Rinke, Karsten ; Rode, Michael
Deforestation is currently a widespread phenomenon and a growing environmental concern in the era of rapid climate change.
In temperate regions, it is challenging to quantify the impacts of deforestation on the catchment dynamics and downstream aquatic ecosystems such as reservoirs and disentangle these from direct climate change impacts, let alone project future changes to inform management.
Here, we tackled this issue by investigating a unique catchment-reservoir system with two reservoirs in distinct trophic states (meso- and eutrophic), both of which drain into the largest drinking water reservoir in Germany.
Due to the prolonged droughts in 2015-2018, the catchment of the mesotrophic reservoir lost an unprecedented area of forest (exponential increase since 2015 and ca. 17.1% loss in 2020 alone).
We coupled catchment nutrient exports (HYPE) and reservoir ecosystem dynamics (GOTM-WET) models using a process-based modeling approach. The coupled model was validated with datasets spanning periods of rapid deforestation, which makes our future projections highly robust.
Results show that in a short-term time scale (by 2035), increasing nutrient flux from the catchment due to vast deforestation (80% loss) can turn the mesotrophic reservoir into a eutrophic state as its counterpart.
Our results emphasize the more prominent impacts of deforestation than the direct impact of climate warming in impairment of water quality and ecological services to downstream aquatic ecosystems. Therefore, we propose to evaluate the impact of climate change on temperate reservoirs by incorporating a time scale-dependent context, highlighting the indirect impact of deforestation in the short-term scale. In the long-term scale (e.g. to 2100), a guiding hypothesis for future research may be that indirect effects (e.g., as mediated by catchment dynamics) are as important as the direct effects of climate warming on aquatic ecosystems.
Yuan, Jun ; Zhang, Chujun ; Qiu, Beibei ; Liu, Wei ; So, Shu Kong ; Mainville, Mathieu ; Leclerc, Mario ; Shoaee, Safa ; Neher, Dieter ; Zou, Yingping
Organic solar cells (OSCs) have progressed rapidly in recent years through the development of novel organic photoactive materials, especially non-fullerene acceptors (NFAs). Consequently, OSCs based on state-of-the-art NFAs have reached significant milestones, such as similar to 19% power conversion efficiencies (PCEs) and small energy losses (less than 0.5 eV). Despite these significant advances, understanding of the interplay between molecular structure and optoelectronic properties lags significantly behind. For example, despite the theoretical framework for describing the energetic disorder being well developed for the case of inorganic semiconductors, the question of the applicability of classical semiconductor theories in analyzing organic semiconductors is still under debate. A general observation in the inorganic field is that inorganic photovoltaic materials possessing a polycrystalline microstructure exhibit suppressed disorder properties and better charge carrier transport compared to their amorphous analogs. Accordingly, this principle extends to the organic semiconductor field as many organic photovoltaic materials are synthesized to pursue polycrystalline-like features. Yet, there appears to be sporadic examples that exhibit an opposite trend. However, full studies decoupling energetic disorder from aggregation effects have largely been left out. Hence, the potential role of the energetic disorder in OSCs has received little attention. Interestingly, recently reported state-of-the-art NFA-based devices could achieve a small energetic disorder and high PCE at the same time; and interest in this investigation related to the disorder properties in OSCs was revived. In this contribution, progress in terms of the correlation between molecular design and energetic disorder is reviewed together with their effects on the optoelectronic mechanism and photovoltaic performance. Finally, the specific challenges and possible solutions in reducing the energetic disorder of OSCs from the viewpoint of materials and devices are proposed.
Kroh, Daniel ; Eller, Fabian ; Schötz, Konstantin ; Wedler, Stefan ; Perdigón-Toro, Lorena ; Freychet, Guillaume ; Wei, Qingya ; Dörr, Maximilian ; Jones, David ; Zou, Yingping ; Herzig, Eva M. ; Neher, Dieter ; Köhler, Anna
In organic solar cells, the resulting device efficiency depends strongly on the local morphology and intermolecular interactions of the blend film. Optical spectroscopy was used to identify the spectral signatures of interacting chromophores in blend films of the donor polymer PM6 with two state-of-the-art nonfullerene acceptors, Y6 and N4, which differ merely in the branching point of the side chain. From temperature-dependent absorption and luminescence spectroscopy in solution, it is inferred that both acceptor materials form two types of aggregates that differ in their interaction energy. Y6 forms an aggregate with a predominant J-type character in solution, while for N4 molecules the interaction is predominantly in a H-like manner in solution and freshly spin-cast film, yet the molecules reorient with respect to each other with time or thermal annealing to adopt a more J-type interaction. The different aggregation behavior of the acceptor materials is also reflected in the blend films and accounts for the different solar cell efficiencies reported with the two blends.
From victims to activists
(2022)
The question if a given partial solution to a problem can be extended reasonably occurs in many algorithmic approaches for optimization problems.
For instance, when enumerating minimal vertex covers of a graph G = (V, E), one usually arrives at the problem to decide for a vertex set U subset of V (pre-solution), if there exists a minimal vertex cover S (i.e., a vertex cover S subset of V such that no proper subset of S is a vertex cover) with U subset of S (minimal extension of U).
We propose a general, partial-order based formulation of such extension problems which allows to model parameterization and approximation aspects of extension, and also highlights relationships between extension tasks for different specific problems.
As examples, we study a number of specific problems which can be expressed and related in this framework. In particular, we discuss extension variants of the problems dominating set and feedback vertex/edge set.
All these problems are shown to be NP-complete even when restricted to bipartite graphs of bounded degree, with the exception of our extension version of feedback edge set on undirected graphs which is shown to be solvable in polynomial time.
For the extension variants of dominating and feedback vertex set, we also show NP-completeness for the restriction to planar graphs of bounded degree.
As non-graph problem, we also study an extension version of the bin packing problem. We further consider the parameterized complexity of all these extension variants, where the parameter is a measure of the pre-solution as defined by our framework.
Classical linguistic theory assumes that formal aspects, like sound, are not internally related to the meaning of words. However, recent research suggests language might code affective meaning such as threat and alert sublexically. Positing affective phonological iconicity as a systematic organization principle of the German lexicon, we calculated sublexical affective values for sub-syllabic phonological word segments from a large-scale affective lexical German database by averaging valence and arousal ratings of all words any phonological segment appears in. We tested word stimuli with either consistent or inconsistent mappings between lexical affective meaning and sublexical affective values (negative-valence/high-arousal vs. neutral-valence/lowarousal) in an EEG visual-lexical-decision task. A mismatch between sublexical and lexical affective values elicited an increased N400 response. These results reveal that systematic affective phonological iconicity - extracted from the lexicon - impacts the extraction of lexical word meaning during reading.
Frauenfeind, aber kein Incel
(2020)
Der Attentater von Hanau war, das verrät sein Manifest, ein Frauenfeind – aber kein Incel. Warum die Einschätzung als Incel bequem und gefährlich ist, erläutert dieser Gastbeitrag der Wissenschaftlerinnen Megan Kelly, Ann-Kathrin Rothermel und Greta Jasser, Fellows am Institute for Research on Male Supremacism (IRMS).
Stimulus data and experimental design for a self-paced reading study on emoji-word substitutions
(2022)
This data paper presents the experimental design and stimuli from an online self-paced reading study on the processing of emojis substituting lexically ambiguous nouns. We recorded reading times for the target ambiguous nouns and for emojis depicting either the intended target referent or a contextually inappropriate homophonous noun. Furthermore, we recorded comprehension accuracy, demographics and a self-assessment of the participants' emoji usage frequency. The data includes all stimuli used, the raw data, the full JavaScript code for the online experiment, as well as Python and R code for the data analysis. We believe that our dataset may give important insights related to the comprehension mechanisms involved in the cognitive processing of emojis. For interpretation and discussion of the experiment, please see the original article entitled "The processing of emoji-word substitutions: A self-paced-reading study".
Large-Scale interseismic strain mapping of the NE Tibetan Plateau from Sentinel-1 Interferometry
(2022)
Ou, Qi ; Daout, Simon ; Weiss, Jonathan R. ; Shen, Lin ; Lazecky, Milan ; Wright, Tim J. ; Parsons, Barry E.
The launches of the Sentinel-1 synthetic aperture radar satellites in 2014 and 2016 started a new era of high-resolution velocity and strain rate mapping for the continents. However, multiple challenges exist in tying independently processed velocity data sets to a common reference frame and producing high-resolution strain rate fields. We analyze Sentinel-1 data acquired between 2014 and 2019 over the northeast Tibetan Plateau, and develop new methods to derive east and vertical velocities with similar to 100 m resolution and similar to 1 mm/yr accuracy across an area of 440,000 km(2). By implementing a new method of combining horizontal gradients of filtered east and interpolated north velocities, we derive the first similar to 1 km resolution strain rate field for this tectonically active region. The strain rate fields show concentrated shear strain along the Haiyuan and East Kunlun Faults, and local contractional strain on fault junctions, within the Qilianshan thrusts, and around the Longyangxia Reservoir. The Laohushan-Jingtai creeping section of the Haiyuan Fault is highlighted in our data set by extremely rapid strain rates. Strain across unknown portions of the Haiyuan Fault system, including shear on the eastern extension of the Dabanshan Fault and contraction at the western flank of the Quwushan, highlight unmapped tectonic structures. In addition to the uplift across most of the lowlands, the vertical velocities also contain climatic, hydrological or anthropogenic-related deformation signals. We demonstrate the enhanced view of large-scale active tectonic processes provided by high-resolution velocities and strain rates derived from Sentinel-1 data and highlight associated wide-ranging research applications.
The EU and its member countries have been laggards in using forest carbon to reduce EU emissions. The European Green Deal aims to change this. As part of its long-term emissions reductions, the EU aims to offset this by creating land-based carbon sinks, especially forest carbon sinks as well as carbon capture and storage. This chapter focuses on the role of forest carbon as part of the EU's climate policies towards achieving net-zero greenhouse gas emissions by 2050. It furthermore examines the European Commission's proposed forest strategy and its proposal for a revised LULUCF Regulation. The chapter shows that the logic of appropriateness dominates the European Commission's forest policies. Finally, the chapter makes policy recommendations on how the EU could credibly use long-term carbon sinks to achieve climate neutrality.
Long-term environmental policy remains a vexing puzzle of environmental policy. Following its definition, the author reviews the methods suitable for the study of long-term environmental policy and develops a typology of policy instruments to cope with these challenges. The concluding section offers five central research challenges to advance the study of long-term environmental policy.
Ijomone, Omamuyovwi M. ; Iroegbu, Joy D. ; Morcillo, Patricia ; Ayodele, Akinyemi J. ; Ijomone, Olayemi K. ; Bornhorst, Julia ; Schwerdtle, Tanja ; Aschner, Michael
Manganese (Mn), although important for multiple cellular processes, has posed environmental health concerns due to its neurotoxic effects. In recent years, there have been extensive studies on the mechanism of Mn-induced neuropathology, as well as the sex-dependent vulnerability to its neurotoxic effects. Nonetheless, cellular mechanisms influenced by sex differences in susceptibility to Mn have yet to be adequately characterized. Since oxidative stress is a key mechanism of Mn neurotoxicity, here, we have probed Hsp70 and Nrf2 proteins to investigate the sex-dependent changes following exposure to Mn. Male and female rats were administered intraperitoneal injections of MnCl2 (10 mg/kg and 25 mg/kg) 48 hourly for a total of eight injections (15 days). We evaluated changes in body weight, as well as Mn accumulation, Nrf2 and Hsp70 expression across four brain regions; striatum, cortex, hippocampus and cerebellum in both sexes. Our results showed sex-specific changes in body-weight, specifically in males but not in females. Additionally, we noted sex-dependent accumulation of Mn in the brain, as well as in expression levels of Nrf2 and Hsp70 proteins. These findings revealed sex-dependent susceptibility to Mn-induced neurotoxicity corresponding to differential Mn accumulation, and expression of Hsp70 and Nrf2 across several brain regions.
Crovetto, Andrea ; Kojda, Danny ; Yi, Feng ; Heinselman, Karen N. ; LaVan, David A. ; Habicht, Klaus ; Unold, Thomas ; Zakutayev, Andriy
Numerous phosphorus-rich metal phosphides containing both P-P bonds and metal-P bonds are known from the solid-state chemistry literature. A method to grow these materials in thin-film form would be desirable, as thin films are required in many applications and they are an ideal platform for high-throughput studies. In addition, the high density and smooth surfaces achievable in thin films are a significant advantage for characterization of transport and optical properties. Despite these benefits, there is hardly any published work on even the simplest binary phosphorus-rich phosphide films. Here, we demonstrate growth of single-phase CuP2 films by a two-step process involving reactive sputtering of amorphous CuP2+x and rapid annealing in an inert atmosphere. At the crystallization temperature, CuP2 is thermodynamically unstable with respect to Cu3P and P-4. However, CuP2 can be stabilized if the amorphous precursors are mixed on the atomic scale and are sufficiently close to the desired composition (neither too P poor nor too P rich). Fast formation of polycrystalline CuP2, combined with a short annealing time, makes it possible to bypass the diffusion processes responsible for decomposition. We find that thin-film CuP2 is a 1.5 eV band gap semiconductor with interesting properties, such as a high optical absorption coefficient (above 10(5) cm(-1)), low thermal conductivity (1.1 W/(K m)), and composition-insensitive electrical conductivity (around 1 S/cm). We anticipate that our processing route can be extended to other phosphorus-rich phosphides that are still awaiting thin-film synthesis and will lead to a more complete understanding of these materials and of their potential applications.
We investigate a class of diffusion-controlled reactions that are initiated at the time instance when a prescribed number K among N particles independently diffusing in a solvent are simultaneously bound to a target region.
In the irreversible target-binding setting, the particles that bind to the target stay there forever, and the reaction time is the Kth fastest first-passage time to the target, whose distribution is well-known. In turn, reversible binding, which is common for most applications, renders theoretical analysis much more challenging and drastically changes the distribution of reaction times.
We develop a renewal-based approach to derive an approximate solution for the probability density of the reaction time.
This approximation turns out to be remarkably accurate for a broad range of parameters.
We also analyze the dependence of the mean reaction time or, equivalently, the inverse reaction rate, on the main parameters such as K, N, and binding/unbinding constants. Some biophysical applications and further perspectives are briefly discussed.
Cesar Fernández, Guillermo ; Lecomte, Karina ; Vignoni, Paula ; Soto-Rueda, Eliana Marcela ; Coria, Silvia H. ; Lirio, Juan Manuel ; Mlewski, Estela Cecilia
The James Ross archipelago houses numerous lakes and ponds. In this region, a vast diatom and cyanobacterial variety has been reported; however, the prokaryotic diversity in microbial mats from these lakes remains poorly explored.
Here, a high-throughput sequencing of 16S rRNA gene in microbial mats from Lake Bart-Roja in James Ross Island and lakes Pan Negro and North Pan Negro located in Vega Island was performed. Combined with mineralogical and environmental characteristics, we analyzed the diversity and structure of the microbial communities. Sequences assigned to Archaea were extremely low, while Bacteria domain prevailed with the abundance of Proteobacteria (mostly Betaproteobacteriales) followed by Bacteroidetes, Verrucomicrobia, Firmicutes, and Cyanobacteria.
Local environmental conditions, such as conductivity and Eh, provided differential microbial assemblages that might have implications in the oligotrophic status of the lakes. Consequently, a clear segregation at the family level was observed.
In this sense, the assigned diversity was related to taxa recognized as denitrifiers and sulfur oxidizers. Particularly, in Lake Pan Negro sulfur-reducing and methanogenic representatives were also found and positively correlate with alkalinity and water depth.
Moreover, Deinococcus-Thermus was observed in Lake Bart-Roja, while Melainabacteria (Cyanobacteria)-poorly reported in Antarctic mats-was detected in Lake Pan Negro. Epsilonbacteraeota was exclusively found in this lake, suggesting new potential phylotypes. This study contributes to the understanding of the diversity, composition, and structure of Antarctic benthic microbial ecosystems and provides highly valuable information, which can be used as a proxy to evaluate environmental changes affecting Antarctic microbiota.
Landslides in deglaciated and deglaciating mountains represent a major hazard, but their distribution at the spatial scale of entire mountain belts has rarely been studied. Traditional models of landslide distribution assume that landslides are concentrated in the steepest, wettest, and most tectonically active parts of the orogens, where glaciers reached their greatest thickness.
However, based on mapping large landslides (>0.9 km(2)) over an unprecedentedly large area of Southern Patagonia (similar to 305,000 km(2)), we show that the distribution of landslides can have the opposite trend.
We show that the largest landslides within the limits of the former Patagonian Ice Sheet (PIS) cluster along its eastern margins occupying lower, tectonically less active, and arid part of the Patagonian Andes. In contrast to the heavily glaciated, highest elevations of the mountain range, the peripheral regions have been glaciated only episodically, leaving a larger volume of unstable sedimentary and volcanic rocks that are subject to ongoing slope instability.
Incorporation of noncanonical amino acids (ncAAs) with bioorthogonal reactive groups by amber suppression allows the generation of synthetic proteins with desired novel properties. Such modified molecules are in high demand for basic research and therapeutic applications such as cancer treatment and in vivo imaging. The positioning of the ncAA-responsive codon within the protein's coding sequence is critical in order to maintain protein function, achieve high yields of ncAA-containing protein, and allow effective conjugation. Cell-free ncAA incorporation is of particular interest due to the open nature of cell-free systems and their concurrent ease of manipulation. In this study, we report a straightforward workflow to inquire ncAA positions in regard to incorporation efficiency and protein functionality in a Chinese hamster ovary (CHO) cell-free system. As a model, the well-established orthogonal translation components Escherichia coli tyrosyl-tRNA synthetase (TyrRS) and tRNATyr(CUA) were used to site-specifically incorporate the ncAA p-azido-l-phenylalanine (AzF) in response to UAG codons. A total of seven ncAA sites within an anti-epidermal growth factor receptor (EGFR) single-chain variable fragment (scFv) N-terminally fused to the red fluorescent protein mRFP1 and C-terminally fused to the green fluorescent protein sfGFP were investigated for ncAA incorporation efficiency and impact on antigen binding. The characterized cell-free dual fluorescence reporter system allows screening for ncAA incorporation sites with high incorporation efficiency that maintain protein activity. It is parallelizable, scalable, and easy to operate. We propose that the established CHO-based cell-free dual fluorescence reporter system can be of particular interest for the development of antibody-drug conjugates (ADCs).
Law smells
(2022)
Building on the computer science concept of code smells, we initiate the study of law smells, i.e., patterns in legal texts that pose threats to the comprehensibility and maintainability of the law. With five intuitive law smells as running examples-namely, duplicated phrase, long element, large reference tree, ambiguous syntax, and natural language obsession-, we develop a comprehensive law smell taxonomy. This taxonomy classifies law smells by when they can be detected, which aspects of law they relate to, and how they can be discovered. We introduce text-based and graph-based methods to identify instances of law smells, confirming their utility in practice using the United States Code as a test case. Our work demonstrates how ideas from software engineering can be leveraged to assess and improve the quality of legal code, thus drawing attention to an understudied area in the intersection of law and computer science and highlighting the potential of computational legal drafting.
Deep lipidomics in human plasma: cardiometabolic disease risk and effect of dietary fat modulation
(2022)
Eichelmann, Fabian ; Sellem, Laury ; Wittenbecher, Clemens ; Jäger, Susanne ; Kuxhaus, Olga ; Prada, Marcela ; Cuadrat, Rafael ; Jackson, Kim G. ; Lovegrove, Julie A. ; Schulze, Matthias Bernd
Background: In blood and tissues, dietary and endogenously generated fatty acids (FAs) occur in free form or as part of complex lipid molecules that collectively represent the lipidome of the respective tissue. We assessed associations of plasma lipids derived from high-resolution lipidomics with incident cardiometabolic diseases and subsequently tested if the identified risk-associated lipids were sensitive to dietary fat modification. Methods: The EPIC Potsdam cohort study (European Prospective Investigation into Cancer and Nutrition) comprises 27 548 participants recruited within an age range of 35 to 65 years from the general population around Potsdam, Germany. We generated 2 disease-specific case cohorts on the basis of a fixed random subsample (n=1262) and all respective cohort-wide identified incident primary cardiovascular disease (composite of fatal and nonfatal myocardial infarction and stroke; n=551) and type 2 diabetes (n=775) cases. We estimated the associations of baseline plasma concentrations of 282 class-specific FA abundances (calculated from 940 distinct molecular species across 15 lipid classes) with the outcomes in multivariable-adjusted Cox models. We tested the effect of an isoenergetic dietary fat modification on risk-associated lipids in the DIVAS randomized controlled trial (Dietary Intervention and Vascular Function; n=113). Participants consumed either a diet rich in saturated FAs (control), monounsaturated FAs, or a mixture of monounsaturated and n-6 polyunsaturated FAs for 16 weeks. Results: Sixty-nine lipids associated (false discovery rate<0.05) with at least 1 outcome (both, 8; only cardiovascular disease, 49; only type 2 diabetes, 12). In brief, several monoacylglycerols and FA16:0 and FA18:0 in diacylglycerols were associated with both outcomes; cholesteryl esters, free fatty acids, and sphingolipids were largely cardiovascular disease specific; and several (glycero)phospholipids were type 2 diabetes specific. In addition, 19 risk-associated lipids were affected (false discovery rate<0.05) by the diets rich in unsaturated dietary FAs compared with the saturated fat diet (17 in a direction consistent with a potential beneficial effect on long-term cardiometabolic risk). For example, the monounsaturated FA-rich diet decreased diacylglycerol(FA16:0) by 0.4 (95% CI, 0.5-0.3) SD units and increased triacylglycerol(FA22:1) by 0.5 (95% CI, 0.4-0.7) SD units. Conclusions: We identified several lipids associated with cardiometabolic disease risk. A subset was beneficially altered by a dietary fat intervention that supports the substitution of dietary saturated FAs with unsaturated FAs as a potential tool for primary disease prevention.
Gomez-Zapata, Juan Camilo ; Pittore, Massimiliano ; Cotton, Fabrice ; Lilienkamp, Henning ; Shinde, Simantini ; Aguirre, Paula ; Santa Maria, Hernan
In seismic risk assessment, the sources of uncertainty associated with building exposure modelling have not received as much attention as other components related to hazard and vulnerability. Conventional practices such as assuming absolute portfolio compositions (i.e., proportions per building class) from expert-based assumptions over aggregated data crudely disregard the contribution of uncertainty of the exposure upon earthquake loss models. In this work, we introduce the concept that the degree of knowledge of a building stock can be described within a Bayesian probabilistic approach that integrates both expert-based prior distributions and data collection on individual buildings. We investigate the impact of the epistemic uncertainty in the portfolio composition on scenario-based earthquake loss models through an exposure-oriented logic tree arrangement based on synthetic building portfolios. For illustrative purposes, we consider the residential building stock of Valparaiso (Chile) subjected to seismic ground-shaking from one subduction earthquake. We have found that building class reconnaissance, either from prior assumptions by desktop studies with aggregated data (top-down approach), or from building-by-building data collection (bottom-up approach), plays a fundamental role in the statistical modelling of exposure. To model the vulnerability of such a heterogeneous building stock, we require that their associated set of structural fragility functions handle multiple spectral periods. Thereby, we also discuss the relevance and specific uncertainty upon generating either uncorrelated or spatially cross-correlated ground motion fields within this framework. We successively show how various epistemic uncertainties embedded within these probabilistic exposure models are differently propagated throughout the computed direct financial losses. This work calls for further efforts to redesign desktop exposure studies, while also highlighting the importance of exposure data collection with standardized and iterative approaches.
Gut zwei Jahrzehnte nach dem Millenniumsgipfel der Vereinten Nationen bleiben berechtigte Zweifel an der Wirksamkeit von Entwicklungszusammenarbeit (EZ). Ist das Politikfeld von den Realitäten überholt worden? Welchen Beitrag haben Entwicklungstheorien für die Weiterentwicklung von Entwicklungspolitik leisten können? Der Beitrag zieht eine Bilanz, die von der ersten Entwicklungsdekade in den 1960er-Jahren bis zu den Folgen der Covid-19-Pandemie reicht. Er plädiert für eine herrschaftskritische Weiterentwicklung des Entwicklungsbegriffs und für eine Stärkung globaler Kooperation.
Hot, compact, hydrogen-deficient pre-white dwarfs (pre-WDs) with effective temperatures of Teff > 70 000 K and a surface gravity of 5.0 < logg < 7.0 are rather rare objects despite recent and ongoing surveys. It is believed that they are the outcome of either single star evolution (late helium-shell flash or late helium-core flash) or binary star evolution (double WD merger). Their study is interesting because the surface elemental abundances reflect the physics of thermonuclear flashes and merger events. Spectroscopically they are divided in three different classes, namely PG1159, O(He), or He-sdO. We present a spectroscopic analysis of five such stars that turned out to have atmospheric parameters in the range Teff = 70 000-80 000 K and logg = 5.2-6.3. The three investigated He-sdOs have a relatively high hydrogen mass fraction (10%) that is unexplained by both single (He core flash) and binary evolution (He-WD merger) scenarios. The O(He) star JL 9 is probably a binary helium-WD merger, but its hydrogen content (6%) is also at odds with merger models. We found that RL 104 is the 'coolest' (Teff = 80 000 K) member of the PG1159 class in a pre-WD stage. Its optical spectrum is remarkable because it exhibits C※ IV lines involving Rydberg states with principal quantum numbers up to n = 22. Its rather low mass (0.48-0.02+0.03 M·) is difficult to reconcile with the common evolutionary scenario for PG1159 stars due to it being the outcome of a (very) late He-shell flash. The same mass-problem faces a merger model of a close He-sdO plus CO WD binary that predicts PG1159-like abundances. Perhaps RL 104 originates from a very late He-shell flash in a CO/He WD formed by a merger of two low-mass He-WDs.
The benefits of counting butterflies: recommendations for a successful citizen science project
(2022)
Kühn, Elisabeth ; Becker, Marc ; Harpke, Alexander ; Kühn, Ingolf ; Kuhlicke, Christian ; Schmitt, Thomas ; Settele, Josef ; Musche, Martin
Citizen science (CS) projects, being popular across many fields of science, have recently also become a popular tool to collect biodiversity data. Although the benefits of such projects for science and policy making are well understood, relatively little is known about the benefits participants get from these projects as well as their personal backgrounds and motivations. Furthermore, very little is known about their expectations. We here examine these aspects, with the citizen science project "German Butterfly Monitoring" as an example. A questionnaire was sent to all participants of the project and the responses to the questionnaire indicated the following: center dot Most transect walkers do not have a professional background in this field, though they do have a high educational level, and are close to retirement, with a high number of females; center dot An important motivation to join the project is to preserve the natural environment and to contribute to scientific knowledge; center dot Participants benefit by enhancing their knowledge about butterflies and especially their ability to identify different species (taxonomic knowledge); center dot Participants do not have specific expectations regarding the project beyond proper management and coordination, but have an intrinsic sense of working for a greater good. The willingness to join a project is higher if the project contributes to the solution of a problem discussed in the media (here, insect decline). Based on our findings from the analysis of the questionnaire we can derive a set of recommendations for establishing a successful CS project. These include the importance of good communication, e.g., by explaining what the (scientific) purpose of the project is and what problems are to be solved with the help of the data collected in the project. The motivation to join a CS project is mostly intrinsic and CS is a good tool to engage people during difficult times such as the COVID-19 pandemic, giving participants the feeling of doing something useful.
In this paper, we employ an experimental paradigm using insights from the psychology of reasoning to investigate the question whether certain modals generate and draw attention to alternatives. The article extends and builds on the methodology and findings of Mascarenhas & Picat (2019). Based on experimental results, they argue that the English epistemic modal might raises alternatives. We apply the same methodology to the English modal allowed to to test different hypotheses regarding the involvement of alternatives in deontic modality. We find commonalities and differences between the two modals we tested. We discuss theoretical consequences for existing semantic analyses of these modals, and argue that reasoning tasks can serve as a diagnostic tool to discover which natural language expressions involve alternatives.
So far, various studies have aimed at decomposing the integrated terrestrial water storage variations observed by satellite gravimetry (GRACE, GRACE-FO) with the help of large-scale hydrological models. While the results of the storage decomposition depend on model structure, little attention has been given to the impact of the way that vegetation is represented in these models. Although vegetation structure and activity represent the crucial link between water, carbon, and energy cycles, their representation in large-scale hydrological models remains a major source of uncertainty. At the same time, the increasing availability and quality of Earth-observation-based vegetation data provide valuable information with good prospects for improving model simulations and gaining better insights into the role of vegetation within the global water cycle. In this study, we use observation-based vegetation information such as vegetation indices and rooting depths for spatializing the parameters of a simple global hydrological model to define infiltration, root water uptake, and transpiration processes. The parameters are further constrained by considering observations of terrestrial water storage anomalies (TWS), soil moisture, evapotranspiration (ET) and gridded runoff ( Q) estimates in a multi-criteria calibration approach. We assess the implications of including varying vegetation characteristics on the simulation results, with a particular focus on the partitioning between water storage components. To isolate the effect of vegetation, we compare a model experiment in which vegetation parameters vary in space and time to a baseline experiment in which all parameters are calibrated as static, globally uniform values. Both experiments show good overall performance, but explicitly including varying vegetation data leads to even better performance and more physically plausible parameter values. The largest improvements regarding TWS and ET are seen in supply-limited (semi-arid) regions and in the tropics, whereas Q simulations improve mainly in northern latitudes. While the total fluxes and storages are similar, accounting for vegetation substantially changes the contributions of different soil water storage components to the TWS variations. This suggests an important role of the representation of vegetation in hydrological models for interpreting TWS variations. Our simulations further indicate a major effect of deeper moisture storages and groundwater-soil moisture-vegetation interactions as a key to understanding TWS variations. We highlight the need for further observations to identify the adequate model structure rather than only model parameters for a reasonable representation and interpretation of vegetation-water interactions.
Tung, Wing Tai ; Maring, Janita A. ; Xu, Xun ; Liu, Yue ; Becker, Matthias ; Somesh, Dipthi Bachamanda ; Klose, Kristin ; Wang, Weiwei ; Sun, Xianlei ; Ullah, Imran ; Kratz, Karl ; Neffe, Axel T. ; Stamm, Christof ; Ma, Nan ; Lendlein, Andreas
Guidance of postinfarct myocardial remodeling processes by an epicardial patch system may alleviate the consequences of ischemic heart disease. As macrophages are highly relevant in balancing immune response and regenerative processes their suitable instruction would ensure therapeutic success. A polymeric mesh capable of attracting and instructing monocytes by purely physical cues and accelerating implant degradation at the cell/implant interface is designed. In a murine model for myocardial infarction the meshes are compared to those either coated with extracellular matrix or loaded with induced cardiomyocyte progenitor cells. All implants promote macrophage infiltration and polarization in the epicardium, which is verified by in vitro experiments. 6 weeks post-MI, especially the implantation of the mesh attenuates left ventricular adverse remodeling processes as shown by reduced infarct size (14.7% vs 28-32%) and increased wall thickness (854 mu m vs 400-600 mu m), enhanced angiogenesis/arteriogenesis (more than 50% increase compared to controls and other groups), and improved heart function (ejection fraction = 36.8% compared to 12.7-31.3%). Upscaling as well as process controls is comprehensively considered in the presented mesh fabrication scheme to warrant further progression from bench to bedside.
In the picture-word interference paradigm, participants name pictures while ignoring a written or spoken distractor word. Naming times to the pictures are slowed down by the presence of the distractor word. The present study investigates in detail the impact of distractor and target word properties on picture naming times, building on the seminal study by Miozzo and Caramazza. We report the results of several Bayesian meta-analyses based on 26 datasets. These analyses provide estimates of effect sizes and their precision for several variables and their interactions. They show the reliability of the distractor frequency effect on picture naming latencies (latencies decrease as the frequency of the distractor increases) and demonstrate for the first time the impact of distractor length, with longer naming latencies for trials with longer distractors. Moreover, distractor frequency interacts with target word frequency to predict picture naming latencies. The methodological and theoretical implications of these findings are discussed.
The purpose of the present study was to investigate the moderating effect of technology use for friendship maintenance in the associations between self-isolation during the COVID-19 pandemic and friendship quality, measured 6 months later (Time 2). Participants were 1,567 seventh and eighth graders (51% female; 51% white; M-age = 13.47) from the United States. They completed questionnaires on friendship quality at Time 1, and self-isolation during COVID-19 and technology use for friendship maintenance and friendship quality at Time 2. The findings revealed that self-isolation during COVID-19 was related positively to technology use for friendship maintenance and negatively to Time 2 friendship quality. Higher technology use for friendship maintenance buffered against the negative impacts on friendship quality associated with self-isolation during COVID-19, while lower technology use had the opposite effects on Time 2 friendship quality.
DDR im Plural
(2023)
Es gab nicht nur eine DDR. Ob Unrechtsstaat, Fürsorgediktatur oder „Nischengesellschaft“: Der ehemalige ostdeutsche Teilstaat hat in Geschichtswissenschaft und öffentlichen Debatten diverse Deutungen erfahren. Ebenso plural sind die Erfahrungen und Erinnerungen der Menschen, die in der DDR lebten. In „Die DDR im Plural“ zeigen 25 junge Wissenschaftlerinnen und Wissenschaftler in anschaulichen Beiträgen, wie sie sich mit neuen Forschungsansätzen dem vielschichtigen Wesen der DDR und seinen Nachwirkungen bis in die gesamtdeutsche Gegenwart annähern. In prägnanten, kurzen Texten widmen sie sich unter anderem dem alltäglichen Leben, kulturellen Räumen, aber auch dem Politik- und Sicherheitsapparat. Die gewählten Perspektiven reichen von der Aufbauzeit bis zu den Jahren nach der „Wende“. Der Band spiegelt die Methodenvielfalt aktueller Forschungen und lädt zum weiteren Nachdenken über die DDR und Ostdeutschland ein.
Kants Recht der Freiheit
(2024)
Das vorliegende Buch berücksichtigt neben den drei Kritiken und der späten Rechtslehre Kants Grundlegung zur Metaphysik der Sitten, seine Anthropologie in pragmatischer Hinsicht, den Weltbürgeressay, den Streit der Fakultäten, die Friedensschrift und die Abhandlung über den Gemeinspruch, aus der die Formulierung ‚Recht der Freiheit‘ stammt.
Erstes Kant-Buch zu seiner eigenen Wortschöpfung "Recht der Freiheit".
Erörtert Kants "Rechtslehre und Gerichtsbarkeit" in der Kritik der reinen Vernunft
In this article we prove upper bounds for the Laplace eigenvalues lambda(k) below the essential spectrum for strictly negatively curved Cartan-Hadamard manifolds. Our bound is given in terms of k(2) and specific geometric data of the manifold. This applies also to the particular case of non-compact manifolds whose sectional curvature tends to -infinity, where no essential spectrum is present due to a theorem of Donnelly/Li. The result stands in clear contrast to Laplacians on graphs where such a bound fails to be true in general.
Bundesrechnungshof
(2021)
Der Bundesrechnungshof schaut mittlerweile auf eine über 300 jährige Geschichte der Finanzkontrolle zurück (vgl. Engels 2014). Auch wenn Aufgaben und Organisation damaliger Rechenkammern bestenfalls rudimentär mit den Einrichtungen moderner Finanzkontrolle vergleichbar sind, so legten sie doch einst deren Grundstein. Heute ist der Bundesrechnungshof eine oberste Bundesbehörde und prüft laut Artikel 114 Abs. 2 GG die „Rechnung sowie die Wirtschaftlichkeit und Ordnungsmäßigkeit der Haushalts- und Wirtschaftsführung des Bundes.“ Weitere Regelungen für den Bundesrechnungshof finden sich in der Bundeshaushaltsordnung (BHO, hier Teil V Rechnungsprüfung bis Teil VIII Entlastung, §§ 88 bis 114) und im Bundesrechnungshofgesetz (BRHG vom 11.07.1985, mit letzter Änderung vom 05.02.2009).
Human induced pluripotent stem cells (hiPSCs) are highly sensitive to extrinsic physical and biochemical signals from their extracellular microenvironments. In this study, we analyzed the effect of cyclic temperature changes on hiPSCs behaviors, especially by means of scanning force microscopy (BIO-AFM). The alternation in cellular mechanics, as well as the secretion and pattern of deposition of extracellular matrix (ECM) protein in hiPSCs were evaluated. The arrangement of the actin cytoskeleton changed with the variation of the temperature. The rearranged cytoskeleton architecture led to the subsequent changes in cell mechanics (Young's modulus of hiPSCs). With the exposure to the cyclic cold stimuli, an increase in the average surface roughness (Ra) and roughness mean square (RMS) was detected. This observation might be at least in part due to the upregulated secretion of Laminin alpha 5 during repeated temporary cooling. The expression of pluripotent markers, NANOG and SOX2, was not impaired in hiPSCs, when exposed to the cyclic cold stimuli for 24 h. Our findings provide an insight into the effect of temperature on the hiPSC behaviors, which may contribute to a better understanding of the application of locally controlled therapeutic hypothermia.
We consider an array of nonlocally coupled oscillators on a ring, which for equally spaced units possesses a Kuramoto-Battogtokh chimera regime and a synchronous state. We demonstrate that disorder in oscillators positions leads to a transition from the synchronous to the chimera state. For a static (quenched) disorder we find that the probability of synchrony survival depends on the number of particles, from nearly zero at small populations to one in the thermodynamic limit. Furthermore, we demonstrate how the synchrony gets destroyed for randomly (ballistically or diffusively) moving oscillators. We show that, depending on the number of oscillators, there are different scalings of the transition time with this number and the velocity of the units.
The following article deals with the new-institutionalist concept of buffering. The concept describes in short, how organizations cope with external and internal demands in order to gain or maintain legitimacy. The article applies this approach to quality management in higher education. We argue, that the introduction of quality management is a reaction to external demands to achieve more quality in teaching and learning. Simultaneously, it functions as a buffer for other organizational subunits within the higher education institution and tries to prevent them from becoming overloaded with external demands. Based on interviews from a research project, the article shows, that both quality managers and higher education managers partly perceive quality management as service unit, which prevents the departments from exaggerating external demands.
Binary III-V nitrides such as AlN, GaN and InN in the wurtzite-type structure have long been considered as potent semiconducting materials because of their optoelectronic properties, amongst others. With rising concerns over the utilization of scarce elements, a replacement of the trivalent cations by others in ternary and multinary nitrides has led to the development of different variants of nitrides and oxide nitrides crystallizing in lower-symmetry variants of wurtzite. This work presents the symmetry relationships between these structural types specific to nitrides and oxide nitrides and updates some prior work on this matter. The non-existence of compounds crystallizing in Pmc2(1), formally the highest subgroup of the wurtzite type fulfilling Pauling's rules for 1:1:2 stoichiometries, has been puzzling scientists for a while; a rationalization is given, from a crystallographic basis, of why this space group is unlikely to be adopted.
Lozano, Yudi M. ; Aguilar-Trigueros, Carlos A. ; Onandia, Gabriela ; Maaß, Stefanie ; Zhao, Tingting ; Rillig, Matthias C.
1. Microplastics in soils have become an important threat for terrestrial systems as they may potentially alter the geochemical/biophysical soil environment and can interact with drought. As microplastics may affect soil water content, this could exacerbate the well-known negative effects of drought on ecosystem functionality. Thus, functions including litter decomposition, soil aggregation or those related with nutrient cycling can be altered. Despite this potential interaction, we know relatively little about how microplastics, under different soil water conditions, affect ecosystem functions and multifunctionality.
2. To address this gap, we performed an experiment using grassland plant communities growing in microcosms. Microplastic fibres (absent, present) and soil water conditions (well-watered, drought) were applied in a fully factorial design. At harvest, we measured soil ecosystem functions related to nutrient cycling (beta-glucosaminidase, beta-D-cellobiosidase, phosphatase, beta-glucosidase enzymes), respiration, nutrient retention, pH, litter decomposition and soil aggregation (water stable aggregates). As terrestrial systems provide these functions simultaneously, we also assessed ecosystem multifunctionality, an index that encompasses the array of ecosystem functions measured here.
3. We found that the interaction between microplastic fibres and drought affected ecosystem functions and multifunctionality. Drought had negatively affected nutrient cycling by decreasing enzymatic activities by up to similar to 39%, while microplastics increased soil aggregation by similar to 18%, soil pH by similar to 4% and nutrient retention by up to similar to 70% by diminishing nutrient leaching. Microplastic fibres also impacted soil enzymes, respiration and ecosystem multifunctionality, but importantly, the direction of these effects depended on soil water status. That is, under well-watered conditions, these functions decreased with microplastic fibres by up to similar to 34% while under drought they had similar values irrespective of the microplastic presence, or tended to increase with microplastics. Litter decomposition had a contrary pattern increasing with microplastics by similar to 6% under well-watered conditions while decreasing to a similar percentage under drought.
4. Synthesis and applications. Single ecosystem functions can be positively or negatively affected by microplastics fibres depending on soil water status. However, our results suggest that microplastic fibres may cause negative effects on ecosystem soil multifunctionality of a similar magnitude as drought. Thus, strategies to counteract this new global change factor are necessary.
Challenges, triggers and initiators of climate policies and implications for policy formulation
(2020)
Eine evidenzbasierte Gestaltung von Studium und Lehre, wie sie heute normativ eingefordert wird, bedarf des integrierten Zusammenwirkens von Qualitätsmanagement und Hochschuldidaktik – aber gibt es dieses in der Praxis? Mit Blick auf die allgemeine Befundlage, aber auch anhand einer eigenen empirischen Untersuchung zeigt der Beitrag diesbezüglich auf, dass Qualitätsmanagement und Hochschuldidaktik als weitgehend desintegrierte Funktionsbereiche wahrgenommen werden und Evidenzbasierung in der Praxis folglich keinen sehr hohen Stellenwert genießt. Ausgehend von einer Ursachenanalyse wird auf die dysfunktionalen, aber auch auf die funktionalen Auswirkungen dieser Separierung aufmerksam gemacht.
Räuberischer Menschenraub
(2022)
Einen Straftatbestand mit dem Namen „Räuberischer Menschenraub“ gibt es im deutschen Strafrecht nicht. Was es aber gibt, sind wirkliche Straftaten, die wegen ihrer tatsächlichen Bestandteile und deren strafrechtlicher Bedeutung mit „Räuberischer Menschenraub“ zutreffend bezeichnet sind. Die Frage ist daher, welchem Straftatbestand des geltenden Strafrechts eine solche Tat zugeordnet werden kann. Eine neue Entscheidung des BGH gibt Antwort auf die Frage. Der zugrunde liegende Sachverhalt enthält so viele weitere interessante strafrechtliche Elemente, dass er fast unverändert als Strafrechtsaufgabe im Examen Verwendung finden könnte. Die Beschäftigung mit dem Fall ist daher zu empfehlen. Hier soll das Hauptaugenmerk auf die mit dem „Räuberischen Menschenraub“ zusammenhängenden Probleme gerichtet werden.
Vielleicht stellen sich auch andere Benutzer der Berliner S-Bahn hin und wieder die Frage, wer von den Mitfahrenden wohl ein gültiges Ticket dabei hat. Selbstverständlich soll hier niemand diskriminiert werden; aber bei manchem Mitreisenden, der um eine kleine Spende bittet, eine Obdachlosenzeitung offeriert oder musikalische Darbietungen gibt, habe ich manchmal Zweifel. Nicht ganz fernliegend ist dann wohl die Erwägung, dass es sich jedenfalls zum Teil um Mitbürger handelt, deren Einkommens- und Vermögenssituation schlecht ist. Das gibt Anlass zu der Frage, ob unter dieser Voraussetzung die strafrechtliche Beurteilung der – das sei hier des Themas wegen unterstellt – unbefugt erlangten unentgeltlichen Personenbeförderung zu einem anderen Ergebnis führt als bei einem „Schwarzfahrer“, der über genügend Finanzmittel verfügt, um die Fahrt zu bezahlen. Einige Gerichtsentscheidungen zu Fällen, in denen es zwischen einem Taxichauffeur und dem von ihm beförderten Fahrgast zu gewalttätigen Auseinandersetzungen über die – vom Fahrgast verweigerte − Fahrpreisentrichtung gekommen war, suggerieren eine Straflosigkeit des Täters, der keinerlei pfändbares Vermögen hat. Die Entscheidungen betrafen den Erpressungstatbestand (§§ 253, 255 StGB), sind aber vielleicht auch präjudiziell für § 263 StGB und für § 265 a StGB. Dem soll hier nachgegangen werden.
Die Macht der Sonntagsfrage
(2023)
Für das Jahr 2024 sind entscheidende Wahlen geplant – unter ihnen die
US-Präsidentschaftswahl und die Wahlen zum Europäischen Parlament. In
Deutschland werden in Brandenburg, Sachsen und Thüringen die Landtage
gewählt. Wahlumfragen, insbesondere die Sonntagsfrage, sind zu einem
integralen Bestandteil von Wahlkämpfen geworden; gleichzeitig steht auch
deren Zuverlässigkeit im Zentrum medialer Aufmerksamkeit. Eine Debatte über
die Kommunikation und Darstellung von Meinungsumfragen ist in Deutschland
dringend notwendig. Eine bindende Selbstverpflichtung der Umfrageinstitute und
Medienhäuser wäre eine vielversprechende Lösung.
Satellite-measured tidal magnetic signals are of growing importance. These fields are mainly used to infer Earth's mantle conductivity, but also to derive changes in the oceanic heat content. We present a new Kalman filter-based method to derive tidal magnetic fields from satellite magnetometers: KALMAG. The method's advantage is that it allows to study a precisely estimated posterior error covariance matrix. We present the results of a simultaneous estimation of the magnetic signals of 8 major tides from 17 years of Swarm and CHAMP data. For the first time, robustly derived posterior error distributions are reported along with the reported tidal magnetic fields. The results are compared to other estimates that are either based on numerical forward models or on satellite inversions of the same data. For all comparisons, maximal differences and the corresponding globally averaged RMSE are reported. We found that the inter-product differences are comparable with the KALMAG-based errors only in a global mean sense. Here, all approaches give values of the same order, e.g., 0.09 nT-0.14 nT for M2. Locally, the KALMAG posterior errors are up to one order smaller than the inter-product differences, e.g., 0.12 nT vs. 0.96 nT for M2.
Krassakis, Pavlos ; Karavias, Andreas ; Zygouri, Evangelia ; Roumpos, Christos ; Louloudis, Georgios ; Pyrgaki, Konstantina ; Koukouzas, Nikolaos ; Kempka, Thomas ; Karapanos, Dimitris
Planned decommissioning of coal-fired plants in Europe requires innovative technical and economic strategies to support coal regions on their path towards a climate-resilient future. The repurposing of open pit mines into hybrid pumped hydro power storage (HPHS) of excess energy from the electric grid, and renewable sources will contribute to the EU Green Deal, increase the economic value, stabilize the regional job market and contribute to the EU energy supply security. This study aims to present a preliminary phase of a geospatial workflow used to evaluate land suitability by implementing a multi-criteria decision making (MCDM) technique with an advanced geographic information system (GIS) in the context of an interdisciplinary feasibility study on HPHS in the Kardia lignite open pit mine (Western Macedonia, Greece). The introduced geospatial analysis is based on the utilization of the constraints and ranking criteria within the boundaries of the abandoned mine regarding specific topographic and proximity criteria. The applied criteria were selected from the literature, while for their weights, the experts' judgement was introduced by implementing the analytic hierarchy process (AHP), in the framework of the ATLANTIS research program. According to the results, seven regions were recognized as suitable, with a potential energy storage capacity from 1.09 to 5.16 GWh. Particularly, the present study's results reveal that 9.27% (212,884 m(2)) of the area had a very low suitability, 15.83% (363,599 m(2)) had a low suitability, 23.99% (550,998 m(2)) had a moderate suitability, 24.99% (573,813 m(2)) had a high suitability, and 25.92% (595,125 m(2)) had a very high suitability for the construction of the upper reservoir. The proposed semi-automatic geospatial workflow introduces an innovative tool that can be applied to open pit mines globally to identify the optimum design for an HPHS system depending on the existing lower reservoir.
Beckmann, Nadine ; Schumacher, Fabian ; Kleuser, Burkhard ; Gulbins, Erich ; Nomellini, Vanessa ; Caldwell, Charles C.
Infection is a common and often deadly complication after burn injury. A major underlying factor is burn-induced immune dysfunction, particularly with respect to neutrophils as the primary responders to infection. Temporally after murine scald injury, we demonstrate impaired bone marrow neutrophil chemotaxis toward CXCL1 ex vivo. Additionally, we observed a reduced recruitment of neutrophils to the peritoneal after elicitation 7 days after injury. We demonstrate that neutrophil ceramide levels increase after burn injury, and this is associated with decreased expression of CXCR2 and blunted chemotaxis. A major signaling event upon CXCR2 activation is Akt phosphorylation and this was reduced when ceramide was elevated. In contrast, PTEN levels were elevated and PTEN-inhibition elevated phospho-Akt levels and mitigated the burn-induced neutrophil chemotaxis defect. Altogether, this study identifies a newly described pathway of ceramide-mediated suppression of neutrophil chemotaxis after burn injury and introduces potential targets to mitigate this defect and reduce infection-related morbidity and mortality after burn.
Full-length transcriptome
(2021)
Huang, Lixing ; Qiao, Ying ; Xu, Wei ; Gong, Linfeng ; He, Rongchao ; Qi, Weilu ; Gao, Qiancheng ; Cai, Hongyan ; Grossart, Hans-Peter ; Yan, Qingpi
Fish is considered as a supreme model for clarifying the evolution and regulatory mechanism of vertebrate immunity. However, the knowledge of distinct immune cell populations in fish is still limited, and further development of techniques advancing the identification of fish immune cell populations and their functions are required. Single cell RNA-seq (scRNA-seq) has provided a new approach for effective in-depth identification and characterization of cell subpopulations. Current approaches for scRNA-seq data analysis usually rely on comparison with a reference genome and hence are not suited for samples without any reference genome, which is currently very common in fish research. Here, we present an alternative, i.e. scRNA-seq data analysis with a full-length transcriptome as a reference, and evaluate this approach on samples from Epinephelus coioides-a teleost without any published genome. We show that it reconstructs well most of the present transcripts in the scRNA-seq data achieving a sensitivity equivalent to approaches relying on genome alignments of related species. Based on cell heterogeneity and known markers, we characterized four cell types: T cells, B cells, monocytes/macrophages (Mo/M phi) and NCC (non-specific cytotoxic cells). Further analysis indicated the presence of two subsets of Mo/M phi including M1 and M2 type, as well as four subsets in B cells, i.e. mature B cells, immature B cells, pre B cells and early-pre B cells. Our research will provide new clues for understanding biological characteristics, development and function of immune cell populations of teleost. Furthermore, our approach provides a reliable alternative for scRNA-seq data analysis in teleost for which no reference genome is currently available.
Neutrons on rails
(2021)
Schrön, Martin ; Oswald, Sascha ; Zacharias, Steffen ; Kasner, Mandy ; Dietrich, Peter ; Attinger, Sabine
Large-scale measurements of the spatial distribution of water content in soils and snow are challenging for state-of-the-art hydrogeophysical methods. Cosmic-ray neutron sensing (CRNS) is a noninvasive technology that has the potential to bridge the scale gap between conventional in situ sensors and remote sensing products in both, horizontal and vertical domains. In this study, we explore the feasibility and potential of estimating water content in soils and snow with neutron detectors in moving trains. Theoretical considerations quantify the stochastic measurement uncertainty as a function of water content, altitude, resolution, and detector efficiency. Numerical experiments demonstrate that the sensitivity of measured water content is almost unperturbed by train materials. Finally, three distinct real-world experiments provide a proof of concept on short and long-range tracks. With our results a transregional observational soil moisture product becomes a realistic vision within the next years.
Teaching quality is a key factor in student academic success, but few studies have investigated how teaching quality changes at the beginning of secondary education and how such changes are predicted by dimensions of teacher motivation. This study investigated the changes in class-level student perceptions of teaching quality over one school year at the beginning of secondary school and examined how teachers? self-efficacy and enthusiasm predicted such changes. Data from 1996 students (53.8% male; mean age: 11.09 years, SD = 0.55) and their homeroom teachers (N = 105), who were surveyed at the beginning of Grades 5 and 6, were analyzed. Results showed a significant decline in class-level student-perceived emotional support, classroom management, and instructional clarity. Teacher-reported self-efficacy was not significantly related to changes in teaching quality. Teacher-reported enthusiasm buffered the decline in students? class-level classroom management.
Klein, Andreas ; Roediger, Lukas ; Bendau, Antonia ; Viohl, Leonard ; Ernst, Felicitas ; Helbig, Jonas ; Kühne, Franziska ; Petzold, Moritz Bruno ; Betzler, Felix
Objective
Problem-drinking among university students is common and poses serious health-related risks. Therefore, identifying and addressing associated factors is important.
Participants and methods
A large cross-sectional online-survey with 12,914 university students from Berlin was conducted from November 2016 to August 2017. Relative-risk- and correlation-analysis was used to identify factors associated with problem-drinking and regular heavy-drinking. Independent t-tests compared impulsivity and personality traits, chi-square-tests compared drinking motives between risk- and non-risk-drinkers.
Results
Male gender, tobacco-smoking, illegal substance use, impulsivity and various sociodemographic and psychosocial variables were significantly related to problem/heavy-drinking. Extraversion was a risk, conscientiousness and agreeableness were protective factors. Drinking-motives did not differ significantly between risk- and non-risk-drinkers. Generally, the main drinking-motives were to feel elated, relax and social purposes.
Conclusion
The identified markers and related problem behaviors may serve as a tool to enhance the identification of student subgroups at risk for problem/heavy-drinking, and hence improve targeted health-intervention-programs.
Objectives To compare image quality of deep learning reconstruction (AiCE) for radiomics feature extraction with filtered back projection (FBP), hybrid iterative reconstruction (AIDR 3D), and model-based iterative reconstruction (FIRST). Methods Effects of image reconstruction on radiomics features were investigated using a phantom that realistically mimicked a 65-year-old patient's abdomen with hepatic metastases. The phantom was scanned at 18 doses from 0.2 to 4 mGy, with 20 repeated scans per dose. Images were reconstructed with FBP, AIDR 3D, FIRST, and AiCE. Ninety-three radiomics features were extracted from 24 regions of interest, which were evenly distributed across three tissue classes: normal liver, metastatic core, and metastatic rim. Features were analyzed in terms of their consistent characterization of tissues within the same image (intraclass correlation coefficient >= 0.75), discriminative power (Kruskal-Wallis test p value < 0.05), and repeatability (overall concordance correlation coefficient >= 0.75). Results The median fraction of consistent features across all doses was 6%, 8%, 6%, and 22% with FBP, AIDR 3D, FIRST, and AiCE, respectively. Adequate discriminative power was achieved by 48%, 82%, 84%, and 92% of features, and 52%, 20%, 17%, and 39% of features were repeatable, respectively. Only 5% of features combined consistency, discriminative power, and repeatability with FBP, AIDR 3D, and FIRST versus 13% with AiCE at doses above 1 mGy and 17% at doses >= 3 mGy. AiCE was the only reconstruction technique that enabled extraction of higher-order features. Conclusions AiCE more than doubled the yield of radiomics features at doses typically used clinically. Inconsistent tissue characterization within CT images contributes significantly to the poor stability of radiomics features.
Mei, Shilin ; Siebert, Andreas ; Xu, Yaolin ; Quan, Ting ; Garcia-Diez, Raul ; Bär, Marcus ; Härtel, Paul ; Abendroth, Thomas ; Dörfler, Susanne ; Kaskel, Stefan ; Lu, Yan
Applications of advanced cathode materials with well-designed chemical components and/or optimized nanostructures promoting the sulfur redox kinetics and suppressing the shuttle effect of polysulfides are highly valued. However, in the case of actual lithium-sulfur (Li-S) batteries under practical working conditions, one long-term obstacle still exists, which is mainly due to the difficulties in massive synthesis of such nanomaterials with low cost and ease of control on the nanostructure. Herein, we develop a facile synthesis of carbon coated Ti4O7 hollow nanoparticles (Ti4O7) using spherical polymer electrolyte brush as soft template, which is scalable via utilizing a minipilot reactor. The C Ti4O7 hollow nanoparticles provide strong chemical adsorption to polysulfides through the large polar surface and additional physical confinement by rich micro- & mesopores and have successfully been employed as an efficient sulfur host for multilayer pouch cells. Besides, the sluggish kinetics of the sulfur and lithium sulfide redox mechanism can be improved by the highly conductive Ti4O7 via catalyzation of the conversion of polysulfides. Consequently, the C-Ti4O7 based pouch cell endows a high discharge capacity of 1003 mAhg(-1) at 0.05 C, a high-capacity retention of 83.7% after 100 cycles at 0.1 C, and a high Coulombic efficiency of 97.5% at the 100th cycle. This work proposes an effective approach to transfer the synthesis of hollow Ti4O7 nanoparticles from lab- to large-scale production, paving the way to explore a wide range of advanced nanomaterials for multilayer Li-S pouch cells.